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1.
天然褐铁矿处理含Hg(Ⅱ)废水的实验研究   总被引:4,自引:0,他引:4       下载免费PDF全文
利用水合金属氧化物和氢氧化物矿物表面重金属离子发生吸附作用的原理,进行了天然褐铁矿处理含Hg(Ⅱ)废水的实验。结果表明:试样用量、粒径、废水浓度、pH值、离子强度、反应时间、振荡器转速等因素对Hg(Ⅱ)的吸附率有一定的影响,其中pH值的影响最大;Hg(Ⅱ)在天然褐铁矿上的吸附等温曲线不同于Langmuir和Fre-undlich等温线,而为台阶型,符合分级离子/配位子交换等温曲线。  相似文献   

2.
高岭土吸附剂去除含锰废水中锰离子的实验研究   总被引:13,自引:2,他引:11  
高岭土吸附剂处理含锰废水中锰离子的实验表明:高岭土的最佳粒度为0.177 mm,pH值控制在7.5~ 8.5间,常温搅拌30 min,吸附剂与水量比为12 g∶1 L,对锰离子质量浓度为100 mg/L的废水的处理效果最好,使锰离子质量浓度由100 mg/L降至0.1 mg/L,锰离子的去除率超过90%,达到GB8978-1996工业废水排放的一级标准.高岭土对锰离子吸附的等温吸附曲线符合Freundlich模型,其吸附机理主要是吸附作用和沉淀作用.  相似文献   

3.
天然铁的硫化物处理含Hg(Ⅱ)废水的实验研究   总被引:13,自引:1,他引:12  
本文利用沉淀转化的原理研究了天然铁的硫化物在处理含汞废水中的应用。重点探讨了介质pH值,试样用量、试样粒径对Hg(Ⅱ)去除效果的影响,以及试样用量与废水浓度和废水体积的。还研究了试样的重复使用性能,提出了通过调节处理过程中的PH值来提高反应速度的新方法。  相似文献   

4.
利用出芽短梗霉进行吸附水体中Cr(Ⅵ)、Cd(Ⅱ)共存离子实验, Cr(Ⅵ)、Cd(Ⅱ)毒性浓度均为300 mg/L时,菌种生长良好。吸附性能实验结果表明:出芽短梗霉吸附水中Cr(Ⅵ)的最佳条件是pH值为3.0、时间为2 h、温度为30℃,吸附量为8.575 mg/g;吸附Cd(Ⅱ)的最佳条件是pH为5.0、时间为30 min、温度为30℃,吸附量为15.49 mg/g。  相似文献   

5.
利用出芽短梗霉进行吸附水体中Cr(Ⅵ)、Cd(Ⅱ)共存离子实验, Cr(Ⅵ)、Cd(Ⅱ)毒性浓度均为300 mg/L时,菌种生长良好.吸附性能实验结果表明:出芽短梗霉吸附水中Cr(Ⅵ)的最佳条件是pH值为3.0、时间为2 h、温度为30℃,吸附量为8.575 mg/g;吸附Cd(Ⅱ)的最佳条件是pH为5.0、时间为30 min、温度为30℃,吸附量为15.49 mg/g.  相似文献   

6.
天然锰钾矿去除水体中苯胺的影响因素及其机制的研究表明,酸度是影响苯胺降解反应的主要因素,温度、振荡速度、矿物用量、矿物粒径及电介质浓度都不同程度地影响苯胺的降解;当介质pH值为3.0时,160~200目锰钾矿用量为10g/L、反应温度为25℃、振荡速度为200r/min、反应4h可以使50mL浓度为20mg/L的苯胺去除95%,达到工业废水一级排放标准;天然锰钾矿在酸性条件下具有强氧化性。可以使苯胺逐步降解为无机物质。以上结果都说明天然锰钾矿降解苯胺废水是一种经济有效的方法。  相似文献   

7.
13X沸石对Ni2+吸附性能的实验研究   总被引:8,自引:0,他引:8  
在静态条件下,实验研究了13X沸石的用量、温度、时间、溶液pH值、初始Ni^2 质量浓度对Ni^2 吸附性能的。结果表明:在室温下,13X沸石对Ni^2 的吸附平衡时间为15min,对Ni^2 的最大吸附量为49.7mg/g沸石;静态等温吸附过程符合Langmiur吸附等温方程式;13X沸石对Ni^2 的吸附机理为离子交换吸附和表面络合吸附。  相似文献   

8.
含氟废水的粉煤灰处理实验研究   总被引:5,自引:0,他引:5  
进行了影响粉煤灰处理含氟废水的各种条件实验,(pH、水灰比、氟浓度、振荡平衡时间),结果表明最佳处理条件是pH值为2.5、水灰比为小于20、氟浓度小于500mg/l、振荡平衡时间大于2.5h,并研究了粉煤灰处理含氟废水的机理,给出了其吸附等温式。  相似文献   

9.
天然铁的硫化物处理含Pb(Ⅱ)废水的实验研究   总被引:15,自引:1,他引:14  
本文利用天然铁的硫化物处理含Pb(Ⅱ)废水,实验结果表明:增另投样量、减小试样粒径、升高初始PH值、降低含Pb(Ⅱ)废水体积,均有利于降低溶液中溶解Pb(Ⅱ)的浓度。此外要拉一文对一些实验机理也作了初步讨论。  相似文献   

10.
坡缕石对Zn^2+的吸附性能及吸附工艺条件优化研究   总被引:1,自引:2,他引:1  
从坡缕石粘土提纯人手,进行了坡缕石吸附Zn^2 的实验研究,结果表明坡缕石对水中Zn^2 的吸附性能主要受振荡速度、吸附时间、溶液pH值、吸附剂用量等因素影响,30℃时坡缕石对Zn^2 的等温吸附曲线同时符合Langmuir方程和BET方程。在本实验条件下,坡缕石对水中的Zn^2 (20mL,Zn^2 浓度均为50mg/L)的最佳吸附工艺条件为:振荡速度150r/min,吸附时间120min,吸附剂用量0.120g,溶液pH为6.2,此条件下去除率达到T95.5%。  相似文献   

11.
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.  相似文献   

12.
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.  相似文献   

13.
Robert L. Linnen   《Lithos》2005,80(1-4):267-280
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.  相似文献   

14.
Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ1 roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003).  相似文献   

15.
HYDROGEOLOGY     
正20141756 Chen Ruige(Mathematical College,China University of Geosciences,Beijing100083,China);Zhou Xun Numerical Simulation of Groundwater Level Fluctuation in a Coastal Confined Aquifer with Sloping Initial Groundwater Level Induced by the Tide(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(7),2013,p.1099-1104,6 illus.,16 refs.) Key words:confined water,groundwater level  相似文献   

16.
正20141408 Cai Jia(Institute of Geology,Chinese Academy of Geological Sciences,Beijing100037,China);Liu Fulai Petrogenesis and Metamorphic P-T Conditions of Garnet-Spinel-Biotitebearing Paragneiss in Danangou Area,Daqingshan-Wulashan Metamorphic Complex Belt(Acta Petrologica Sinica,ISSN1000-0569,CN11-1922/P,29(7),  相似文献   

17.
18.
正20142386An Guoying(China Aero Geophysical Survey and Remote Sensing Center for Land and Resources,Beijing 100083,China)Application of Satellite Remote Sensing in Regional Hydrogeological Investigation:Taking Cenozoic Strata in Wenquan Sheet(1∶250 000)of Karakoram Range as an Example(Geosci-  相似文献   

19.
正20141016An Chengbang(Key Laboratory of Western China’s Environmental Systems,Ministry of Education,Lanzhou University,Lanzhou 730000,China);Zhao Yongtao Lake Records during the Last Glacial Maximum from Xinjiang,NW China and Their Climatic Impli-  相似文献   

20.
正20141538 Cao Qing(School of Earth Sciences and Engineering,Xi’an Petroleum University,Xi’an 710065,China);Zhao Jingzhou Characteristics and Significance of Fluid Inclusions from Majiagou Formation,Yichuan Huangling Area,Ordos Basin(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,28(7),2013,p.819-828,7 illus.,3 tables,43 refs.)  相似文献   

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