Petromagnetic and paleomagnetic characterization deposits at Mesozoic/Cenozoic boundary: The Tetritskaro section (Georgia)

Petromagnetic and magnetostratigraphic characteristics are obtained for the Tetritskaro section. The boundary layer at the Mesozoic/Cenozoic (K/T) boundary is fixed primarily by an abrupt rise in the paramagnetic magnetization (total Fe concentration) and, to a lesser degree, by an increase in the concentration of such magnetic minerals as goethite, hemoilmenite, and magnetite. The along-section distribution of titanomagnetite of volcanic origin and metallic iron of cosmic origin does not correlate with the K/T boundary and lithologic properties of the sediments.The boundary of the Mesozoic and Cenozoic geological eras lies within the reversed polarity chron C29r and is marked by an abrupt rise in the geomagnetic field paleointensity and an instability of paleomagnetic directions, rather than by a polarity change. The accumulation time of the boundary clay layer is about 1.5–2 kyr, while abrupt changes in the paleointensity and direction of the geomagnetic field encompass 30–40 kyr. Such long occurrence intervals of the events in question cannot be related to a short-term impact phenomenon.     

Rock magnetic properties of Nihewan sediments at Xujiayao

Rock magnetic measurements of Nihewan sediments from Xujiayao section demonstrate that magnetite, hematite and maghemite are dominant remanent magnetization carriers. Monitoring the variations of magnetic susceptibility (MS) and saturating isothermal remanent magnetization (SIRM) at low temperature are the attractive ways of detecting the presence of magnetite, maghemitization and superparamagnetic grain sizes. Low-temperature MS investigations suggest that susceptibility enhancement for Xujiayao samples is mainly due to the remarkable presence of SD/MD magnetite to some degree though some magnetite grains have been partially oxidized at some depths. It is tentatively concluded that both SD/MD magnetite and hematite are of detrital origin and carry a characteristic remanent magnetization (ChRM), whereas maghemite can be attributed to be chemical origin, overprinting a reversed polarity component of Matuyama age.     

High-frequency polarity swings during the Gauss-Matuyama reversal from Baoji loess sediment

Paleomagnetic records of the Gauss-Matuyama reversal were obtained from two loess sections at Baoji on the Chinese Loess Plateau. Stepwise thermal demagnetization shows two obvious magnetization components. A low-temperature component isolated between 100 and 200–250°C is close to the present geomagnetic field direction, and a high-temperature component isolated above 200–250°C reveals clearly normal, reversed, and transitional polarities. Magnetostratigraphic results of both sections indicated that the Gauss-Matuyama reversal consists of a high-frequency polarity fluctuation zone, but the characteristic remanent magnetization directions during the reversal are clearly inconsistent. Rock magnetic experiments demonstrated that for all the specimens with normal, reversed, and transitional polarities magnetite and hematite are the main magnetic carriers. Anisotropy of magnetic susceptibility indicates that the studied loess sediments have a primary sedimentary fabric. Based on virtual geomagnetic pole latitudes, the Gauss-Matuyama reversal records in the two sections are accompanied by 14 short-lived geomagnetic episodes (15 rapid polarity swings) and 12 short-lived geomagnetic episodes (13 rapid polarity swings), respectively. Our new records, together with previous ones from lacustrine, marine, and aeolian deposits, suggest that high-frequency polarity swings coexist with the Gauss-Matuyama reversal, and that the Gauss-Matuyama reversal may have taken more than 11 kyr to complete. However, we need more detailed analyses of sections across polarity swings during reversals as well as more high-resolution reversal records to understand geomagnetic behavior and inconsistent characteristic remanent magnetization directions during polarity reversals.     

Stable Eocene Magnetization Carried by Magnetite and Iron Sulphides in Marine Marls (Pamplona-Arguis Formation,Southern Pyrenees,Northern Spain)

In order to establish the magnetic carriers and assess the reliability of previous paleomagnetic results obtained for Eocene marine marls from the south Pyrenean basin, we carried out a combined paleo- and rock-magnetic study of the Pamplona-Arguis Formation, which crops out in the western sector of the southern Pyrenees (N Spain). The unblocking temperatures suggest that the characteristic remanent magnetization (ChRM) is carried by magnetite and iron sulphides. The ChRM has both normal and reversed polarities regardless of whether it resides in magnetite or iron sulphides, and represents a primary Eocene magnetization acquired before folding. Rock magnetic results confirm the presence of magnetite and smaller amounts of magnetic iron sulphides, most likely pyrrhotite, in all the studied samples. Framboidal pyrite is ubiquitous in the marls and suggests that iron sulphides formed during early diagenesis under sulphate-reducing conditions. ChRM directions carried by magnetic iron sulphides are consistent with those recorded by magnetite. These observations suggest that magnetic iron sulphides carry a chemical remanent magnetization that coexists with a remanence residing in detrital magnetite. We suggest that the south Pyrenean Eocene marls are suitable for magnetostratigraphic and tectonic purposes but not for studies of polarity transitions, secular variations and geomagnetic excursions, because it is difficult to test for short time differences in remanence lock-in time for the two minerals. The presence of iron sulphide minerals contributing to the primary magnetization in Eocene marine marls reinforces the idea that these minerals can persist over long periods of time in the geological record.     

Gauss-Matuyama极性转换期间地球磁场方向和强度变化特征

粒度分析和风化强度研究表明 ,黄土高原渭南阳郭剖面黄土层L33沉积期间成壤化作用相对较弱 .在此基础上 ,为研究极性转换期间地球磁场变化特征 ,本文对黄土层L33进行了详细的岩石磁学和古地磁学研究 ,其结果表明黄土层L33的主要载磁矿物为磁铁矿和磁赤铁矿 ,并以沉积剩磁为主 ;由逐步热退磁确定的特征剩磁 （ChRM ）揭示了G M（Gauss Matuyama）极性转换过程的持续时间为 9 43± 0 64ka;在G M极性转换之前 ,地球磁场曾发生过持续时间为 2 2± 0 1 3ka的短极性漂移事件 ;相对强度研究表明 ,G M极性转换期间地球磁场强度减弱 .     

Timing of diagenetic haematite growth in red pelagic limestones from Gubbio (Italy)

Magnetite, haematite, and to a minor extent maghaemite are recognised in the Cretaceous and Paleocene red pelagic limestones at Gubbio. The magnetite is detrital (or biological), whereas the haematite grew during diagenesis from a goethitic precursor. Thermal and AF demagnetization of samples collected from close to reversal boundaries indicate that the various magnetization components do not record the polarity reversal at exactly the same stratigraphic level. In the few tens of centimetersbelow a recorded geomagnetic reversal, defined by the magnetite magnetization, some of the haematite grains are magnetized in the post-reversal field. The blocking temperature spectra of this haematite fraction (with post-reversal magnetization) are found to shift toward higher temperatures as the reversal boundary is approached. The blocking temperature spectra reflect the grain size spectra of the haematite, which we interpret as arising by the continual nucleation of grains down to a certain burial depth where the conditions are no longer conducive to further haematite growth. The depth below reversal boundaries to which haematite with post-reversal magnetization can occur, is estimated to be about 60 cm (after compaction), and is equivalent to a time of about 10⁵ years for these particular sediments. A detailed study of the magnetization components at reversal boundaries indicates that the first diagenetic growth of haematite through the single-domain critical volume occurs prior to the mechanical fixation of the detrital (or biological) magnetite. Subsequently the diagenetic haematite grains do not rotate in response to the ambient geomagnetic field polarity as easily as the magnetite, because of their occurrence as pigmentary coatings on larger non-magnetic grains.     

Remagnetization history of Middle Triassic Leikoupo Formation on Wangcang section in Sichuan Province,China

An intensive paleomagnetic investigation has been conducted on the Middle Triassic Leikoupo Formation on the Wangcang section (32.14°N, 103. 17°E). The results indicate the magnetic minerals are dominant by multidomain magnetite or maghemite, and the characteristic remnant magnetization revealed by stepwise thermal/alternating field demagnetization is close to the present-day geomagnetic direction of the sampling site. This suggests that dolomitization/thermal viscous magnetization is responsible for the remagnetization of this kind of rocks.     

The late Pleistocene geomagnetic field as recorded by sediments from Fargher Lake,Washington, U.S.A.

Measurement of the remanent magnetization of a 6.88-m oriented core of soft sediments and tephras from Fargher Lake near Mount St. Helens in southwestern Washington State shows that no significant geomagnetic reversals were recorded in the sediments of the lake. Radiocarbon and palynological dating of the tephra layers from the lake bed indicates deposition during the interval 17, 000–34, 000 years B.P. although geochemical correlation of a prominent tephra layer in the core with tephra set C of Mount St. Helens could mean that the maximum age of the sediments may be at least 36, 000 years B.P. The core was divided into specimens 0.02 m long, each representing approximately 55 years of deposition assuming a constant rate of sedimentation. Pilot alternating field demagnetization studies of every tenth specimen indicated a strong, stable remanence with median destructive field of 15 mT, and the remaining specimens were subsequently demagnetized in fields of this strength. The mean inclination for all specimens exclusive of the unstably magnetized muck and peat from near the surface is 56.1° which is 8° shallower than the present axial dipole field at this site, perhaps because of inclination error in the detrital remanent magnetization of the sediments, although because of the variability in the data, this departure from the axial dipole field may not be significant. The ranges of inclination and declination are comparable to those of normal secular variation at northern latitudes. Although three isolated specimens have remanence with negative inclination, these anomalous directions are due to sampling and depositional effects. Measurement of a second core of 6.86 m length also revealed only normal magnetic polarity, but this result is of little stratigraphic value as this core failed to penetrate the distinctive tephra found near the base of the former core.Studies of a concentrate of the magnetic minerals in the sediments by optical microscopy and X-ray diffraction indicate that the primary magnetic constituent is an essentially pure magnetite of detrital origin. The magnetite occurs in a wide range of grain sizes with much of it of sub-multidomain size (< 15 μm).As a whole, this study provides substantial evidence against the existence of large-scale worldwide geomagnetic reversals during the time interval of Fargher Lake sedimentation, a segment of geological time for which many excursions and reversals have been reported elsewhere.     

Remagnetization history of Middle Triassic Leikoupo Formation on Wangcang section in Sichuan Province,China

An intensive paleomagnetic investigation has been conducted on the Middle Triassic Leikoupo Formation on the Wangcang section (32.14°N, 103. 17°E). The results indicate the magnetic minerals are dominant by multidomain magnetite or maghemite, and the characteristic remnant magnetization revealed by stepwise thermal/alternating field demagnetization is close to the present-day geomagnetic direction of the sampling site. This suggests that dolomitization/thermal viscous magnetization is responsible for the remagnetization of this kind of rocks.

     

A paleomagnetic reinvestigation of the Upper Devonian Perry Formation: evidence for Late Paleozoic remagnetization

In view of the recent recognition of widespread Late Paleozoic remagnetization of Devonian formations across North America, we undertook a reinvestigation of the Upper Devonian Perry Formation of coastal Maine and adjacent New Brunswick. Thermal demagnetization of samples from the redbeds yielded a characteristic direction (D = 166°, I = 4°) that fails a fold test. Comparison of the corresponding paleopole (312°E, 41°S) with previously published Paleozoic poles for North America suggests that the sediments were remagnetized in the Late Carboniferous. After the removal of a steep, northerly component, the volcanics also reveal a shallow and southerly direction ( D = 171°, I = 25° without tilt correction). No stability test is available to date the magnetization of the volcanics; however, similarity of several of the directions to those seen in the sediments raises the suspicion that the volcanics are also remagnetized. Although the paleopole without tilt correction (303°E, 32°S) could be taken to indicate an early Carboniferous age for the remagnetization, scatter in the data suggests that the directions are contaminated by the incomplete removal of a steeper component due to present-day field. Thus, it is more likely that the volcanics were remagnetized at the same time as the sediments. Isothermal remanent magnetization (IRM) acquisition curves, blocking temperatures, coercivities and reflected light microscopy indicate that the magnetization is carried by hematite in the sediments and by both magnetite and hematite in the volcanics. It is therefore likely that the remagnetization of the Perry Formation involved both thermal and chemical processes related to the Variscan/Alleghenian orogeny. Our results indicate that previously published directions for the Perry Formation were based on the incomplete resolution of two magnetic components. These earlier results can no longer be considered as representative of the Devonian geomagnetic field.     

南海南部约80ka以来的古地磁记录

晚更新世以来以一系列地磁漂移事件是区域地层对比和确定沉积物年代框架的重要工具.但是在海相沉积物中,识别这些地磁漂移事件多依赖相对磁场强度(RPI)的变化,在地磁方向异常方面鲜有报到,从而影响对这些事件可靠性的讨论.本文选择南海南部巽他陆架附近重力活塞钻孔BKAS2PC的沉积物,进行系统的岩石磁学和古地磁研究,获得该钻孔沉积记录的RPI和磁倾角变化信息.岩石磁学及扫描电镜结果表明沉积物的原生主要载磁矿物为单畴(SD)和假单畴(PSD)钛磁铁矿.在一些层位,沉积后发生的还原作用形成胶黄铁矿等铁硫化物.磁性矿物的浓度和粒度等参数呈现显著的两阶段变化特征,上部(约220 cm以上)含量低而粒度细,下部含量高但粒度相对较粗,整体上均在一个数量级范围内波动.样品的交变退磁特征显示当交变场超过60 mT时,受胶黄铁矿影响产生旋转磁化,剩磁强度反而上升.因此,在20～60 mT之间确定原生特征剩磁,并把RPI定义为NRM_((20-40)mT)/ARM_((20-40)mT).通过~(14)C限定,并与其他有良好年代控制的相对磁场强度曲线进行对比,建立了钻孔的年代框架.结果显示,钻孔沉积物记录了几次显著的地磁漂移事件,这为联合应用RPI与磁场方向异常构建海相沉积物年代学框架提供了新的依据.     

Origin of the magnetization of Permo-Carboniferous sediments of Spitsbergen, Svalbard Archipelago

Rock magnetic investigations of Permo-Carboniferous carbonate sediments from two areas on Spitsbergen are described, conducted to identify the carriers of the NRM in these rocks. Since microscopic and magnetic separation techniques could not profitably be applied, the nature of magnetic minerals was investigated by thermal demagnetization of the NRM and decay of saturation isothermal remanence (I_rs) during heating to 600°C, as well as by the distribution of the median destructive fields of the NRM and observation of magnetic susceptibility after subsequent heatings. The results show that the NRM of these limestones resides mainly in magnetite, but creation of magnetic pyrrhotite and of fresh magnetite is observed during heating to 600°C. Presence of sulphides indicates that magnetite is an oxidation product of pyrite or of non-magnetic pyrrhotite. Examination of rock magnetic properties of limestones leads to the conclusion that most of the magnetite in the rocks of the Bellsund area is of detrital origin, whereas the rocks at Festningen contain magnetite derived from pyrite probably during an early stage of the diagenetic process.     

鲁科一井上白垩统沉积岩岩石磁学和天然剩磁分析:兼论利用剩磁方向恢复钻孔岩芯原始方位的可行性

本文对"鲁科一井"(CCSD-LK-Ⅰ)768.9~1112.3m之间的上白垩统沉积岩样品进行了岩石磁学、磁化率各向异性(AMS)以及天然剩磁组分的研究.在此基础上,分析了利用特征剩磁(ChRM)和黏滞剩磁(VRM)方向恢复岩芯原始方位的可行性.三轴等温剩磁热退磁曲线、磁滞回线、反向场退磁曲线、一阶反转曲线等岩石磁学测量结果表明,沉积岩的主要载磁矿物为磁铁矿和赤铁矿.335块样品的AMS测量结果表明磁化率椭球主轴的最大轴K1和中间轴K2与水平面夹角较小,最小轴K3接近垂直于水平面分布,说明沉积岩保留了原始沉积磁组构特征.系统热退磁实验表明,多数样品在25~350℃和500~690℃温度段分别获得VRM和ChRM分量.利用ChRM偏角方向,并考虑构造旋转量校正,对VRM偏角方向进行恢复,Fisher统计得到DVRM=-1.3°,IVRM=59.6°,与当地现代地磁场方向(D=-6.7°,I=53.9°)基本一致.用ChRM偏角方向对磁化率主轴K1偏角方向进行校正,校正的结果为:D_(ch_K1)=349.2°,I_(ch_K1)=-0.7°.本文研究结果对于地质勘探中利用古地磁学方法恢复钻孔岩芯原始方位具有一定参考意义.     

河西走廊早新生代红层次生剩磁及其对原生剩磁影响评价

系统研究了河西走廊火烧沟组陆相红层200个采点岩石的热退磁行为和17个代表性样品的岩石磁学特征,结果表明有102个采点可以分离出A、B、C三个剩磁分量,有82个采点只有一个分量(C分量),16个采点只能分离出A、B分量.A、B分量分别由针铁矿和磁赤铁矿携带,C分量在砂岩中由磁铁矿携带,在泥质砂岩和泥岩中由磁铁矿和赤铁矿共同携带.A、B分量剩磁方向随机分布,不能获得置信水平的古地磁平均方向,为次生剩磁.它们的存在并不影响岩石原生剩磁的分离,也不影响原生剩磁信号的稳定性和获得的古地磁数据的可靠性.16个砂岩采点中不能分离出C分量,是由于后生的赤铁矿彻底改变了由磁铁矿携带的原生剩磁组分,在高密度采样的情况下剔除这些采点并不影响古地磁极性柱的构建和解释.     

Magnetite dissolution,diachronous greigite formation,and secondary magnetizations from pyrite oxidation: Unravelling complex magnetizations in Neogene marine sediments from New Zealand

Detailed rock magnetic and electron microscope analyses indicate that the magnetic signature of Neogene marine sediments from the east coast of New Zealand is dominated by the authigenic iron sulphide greigite. The greigite is present as a mixed population of stable single domain and superparamagnetic grains, which is consistent with authigenic growth from solution. This growth can result from pyritization reactions soon after deposition, which also leads to dissolution of most detrital magnetite; however, where constrained by field tests, our data suggest that remanence acquisition can occur > 1 Myr after deposition, and can vary in timing at the outcrop scale. Strong viscous overprints result from oxidation of the iron sulphides, probably during percolation of oxic ground water. This process can sometimes destroy any ancient remanent magnetization. This complex magnetic behaviour, particularly the presence of late-forming magnetizations carried by greigite, means that the remanence in New Zealand Cenozoic sediments, and in similar sediments elsewhere, cannot be assumed to be primary without confirmation by field tests. The reversals test should be employed with caution in such sediments, as patchy remagnetizations can lead to false polarity stratigraphies.     

Magnetic mineral diagenesis in anoxic laminated sediments from the Southern Gulf of California

Diagenetic effects on the magnetic mineralogy in marine sediments have long been investigated, including oxidation/reduction reactions, magnetic dilution, formation of iron sulfides and oxides, magnetization acquisition mechanisms and reliability of the paleomagnetic record. This study investigates diagenetic effects in low-oxygen depositional environments characterized by recent and past magnetic mineral dissolution zones. We analyze a marine sequence from the Alfonso Basin in the southern Gulf of California in which the topmost sediments show diagenetic effects marked by high magnetic enhancement factors. The susceptibility logs show high values at the top sediments with well-defined small amplitude low frequency fluctuations down core. Magnetic hysteresis loops indicate low coercivity saturation, characteristic of magnetites and low-tititanomagnetites with varying paramagnetic contributions. Intensity of natural remanent, isothermal and anhysteretic magnetizations and coercivity parameters show similar variation patterns with depth. The anhysteretic remanence intensity-susceptibility ratio shows an inverse correlation to magnetic susceptibility, indicating varying concentration of fine grained single domain and superparamagnetic particles. The magnetic logs record diagenetic changes and magnetite authigenesis, with preserved recent and old dissolution zones marked by enriched single-domain/pseudo-singledomain/multi-domain magnetite in between the dissolution fronts. The oxidation/reduction processes relate to climatic and water/sediment interface factors controlling the dissolution processes, which occur in the Alfonso Basin anoxic conditions.     

Absolute geomagnetic paleointensity as recorded by ∼1.09 Ga Lake Shore Traps (Keweenaw Peninsula, Michigan)

Absolute geomagnetic paleointensity measurements were made on 255 samples from 38 lava flows of the ～1.09 Ga Lake Shore Traps exposed on the Keweenaw Peninsula (Michigan, USA). Samples from the lava flows yield a well-defined characteristic remanent magnetization (ChRM) component within a ～375°C–590°C unblocking temperature range. Detailed rock magnetic analyses indicate that the ChRM is carried by nearly stoichiometric pseudo-single-domain magnetite and/or low-Ti titanomagnetite. Scanning electron microscopy reveals that the (titano)magnetite is present in the form of fine intergrowths with ilmenite, formed by oxyexsolution during initial cooling. Paleointensity values were determined using the Thellier double-heating method supplemented by low-temperature demagnetization in order to reduce the effect of magnetic remanence carried by large pseudosingle-domain and multidomain grains. One hundred and two samples from twenty independent cooling units meet our paleointensity reliability criteria and yield consistent paleofield values with a mean value of 26.3 ± 4.7μT, which corresponds to a virtual dipole moment of 5.9 ± 1.1×10²² Am². The mean and range of paleofield values are similar to those of the recent Earth’s magnetic field and incompatible with a “Proterozoic dipole low”. These results are consistent with a stable compositionally-driven geodynamo operating by the end of Mesoproterozoic.     

TRM in low magnetic fields: a minimum field that can be recorded by large multidomain grains

Thermally acquired remanent magnetization is important for the estimation of the past magnetic field present at the time of cooling. Rocks that cool slowly commonly contain magnetic grains of millimeter scale. This study investigated 1-mm-sized magnetic minerals of iron, iron–nickel, magnetite, and hematite and concluded that the thermoremanent magnetization (TRM) acquired by these grains did not accurately record the ambient magnetic fields less than 1 μT. Instead, the TRM of these grains fluctuated around a constant value. Consequently, the magnetic grain ability to record the ambient field accurately is reduced. Above the critical field, TRM acquisition is governed by an empirical law and is proportional to saturation magnetization (M_s). The efficiency of TRM is inversely proportional to the mineral's saturation magnetization M_s and is related to the number of domains in the magnetic grains. The absolute field for which we have an onset of TRM sensitivity is inversely proportional to the size of the magnetic grain. These results have implications for previous reports of random directions in meteorites during alternating field demagnetization, or thermal demagnetization of TRM. Extraterrestrial magnetic fields in our solar system are weaker than the geomagnetic field by several orders of magnitude. Extraterrestrial rocks commonly contain large iron-based magnetic minerals as a common part of their composition, and therefore ignoring this behavior of multidomain grains can result in erroneous paleofield estimates.     

羌北地块早-中志留世古地磁学初步研究结果及其构造意义

本文报道羌北地块早-中志留世龙木措组灰岩古地磁研究初步结果,据此探讨羌北地块早-中志留世的古位置及其起源问题.在日土县龙木措北岸(34.4°N,80.3°E)龙木措组中采集了10个采点,共125块古地磁独立定向样品.岩相学与岩石磁学结果表明样品中主要载磁矿物为磁铁矿.系统热退磁与交变退磁显示,退磁曲线具有双分量或单分量...     

Authigenic or detrital origin of pyrrhotite in sediments?: Resolving a paleomagnetic conundrum

Monoclinic pyrrhotite (Fe₇S₈) is widely claimed to carry magnetizations acquired during early diagenesis in anoxic sedimentary environments. In contrast, geochemical literature indicates that pyrrhotite formation is extremely slow below 180 °C, which makes it a highly unlikely carrier of early diagenetic remanences in sediments. This view is confirmed by the occurrence of late diagenetic Fe₇S₈ in ancient sediments and the general lack of Fe₇S₈ in modern sediments. Horng et al. [C.S. Horng, M. Torii, K.S. Shea, S.J. Kao, Inconsistent magnetic polarities between greigite- and pyrrhotite/magnetite-bearing marine sediments from the Tsailiao-chi section, southwestern Taiwan, Earth Planet. Sci. Lett. 164 (1998) 467–481.] documented the presence of Fe₇S₈ that carries a magnetic signal indistinguishable from that of detrital magnetite in Pleistocene marine sediments from Taiwan. We tested the possibility that the Fe₇S₈ could have a detrital origin by conducting a source-to-sink study and found Fe₇S₈ in metamorphic rocks of the Taiwan Central Range and in material eroded from these rocks in the transportation pathway and in the depositional sink. This confirms that the Fe₇S₈ has a detrital origin. Rapid transportation from source to sink (e.g., by typhoon-associated flood events) probably assists preservation of the Fe₇S₈, which might otherwise oxidize during transportation. The widespread occurrence of exhumed metamorphic rocks in orogenic belts around the world makes them a likely source of Fe₇S₈ in marginal sedimentary basins. Detrital Fe₇S₈ should therefore be more routinely considered to be responsible for paleomagnetic records when it is present in sediments with partial metamorphic provenance.