Source contributions to Devonian granite magmatism near the Laurentian border, New Hampshire and Western Maine, USA

Radiogenic isotope data (initial Nd, Pb) and elemental concentrations for the Mooselookmeguntic igneous complex, a suite of mainly granitic intrusions in New Hampshire and western Maine, are used to evaluate petrogenesis and crustal variations across a mid-Paleozoic suture zone. The complex comprises an areally subordinate monzodiorite suite [377±2 Ma; ε_Nd (at 370 Ma)=−2.7 to −0.7; initial ²⁰⁷Pb/²⁰⁴Pb=15.56–15.58] and an areally dominant granite [370±2 Ma; ε_Nd (at 370 Ma)=−7.0 to −0.6; initial ²⁰⁷Pb/²⁰⁴Pb=15.55–15.63]. The granite contains meter-scale enclaves of monzodiorite, petrographically similar to but older than that of the rest of the complex [389±2 Ma; ε_Nd (at 370 Ma)=−2.6 to +0.3; initial ²⁰⁷Pb/²⁰⁴Pb 15.58, with one exception]. Other granite complexes in western Maine and New Hampshire are 30 Ma older than the Mooselookmeguntic igneous complex granite, but possess similar isotopic signatures.

Derivation of the monzodioritic rocks of the Mooselookmeguntic igneous complex most likely occurred by melting of Bronson Hill belt crust of mafic to intermediate composition. The Mooselookmeguntic igneous complex granites show limited correlation of isotopic variations with elemental concentrations, precluding any significant presence of mafic source components. Given overlap of initial Nd and Pb isotopic compositions with data for Central Maine belt metasedimentary rocks, the isotopic heterogeneity of the granites may have been produced by melting of rocks in this crustal package or through a mixture of metasedimentary rocks with magmas derived from Bronson Hill belt crust.

New data from other granites in western Maine include Pb isotope data for the Phillips pluton, which permit a previous interpretation that leucogranites were derived from melting heterogeneous metasedimentary rocks of the Central Maine belt, but suggest that granodiorites were extracted from sources more similar to Bronson Hill belt crust. Data for the Redington pluton are best satisfied by generation from sources in either the Bronson Hill belt or Laurentian basement. Based on these data, we infer that Bronson Hill belt crust was more extensive beneath the Central Maine belt than previously recognized and that mafic melts from the mantle were not important to genesis of Devonian granite magma.     

Unstable flow,magma mixing and magma-rock deformation in a deep-seated conduit: the Gil-Márquez Complex,south-west Spain

The Gil-Marquez Complex is an exceptional outcrop of plutonic rocks ranging in composition from diorites to granites emplaced into Devonian terrigenous metasediments of the southernmost part of the Hercynian basement of Iberia. A combined study of this complex, including field geology, petrology, structural geology and geochemistry, reveals that it represents an ancient conduit of magma transport through the continental crust. This conduit allowed the intrusion of magmas of contrasted compositions. Two end-members and several hybrids are identified. The first end-member is a biotite granite and the second is a basaltic magma generated by partial melting of a depletedmantle source. Both magmas rose through a common channel in which favorable conditions for unstable flow and magma mixing occurred. The observed relations in the Gil-Márquez Complex show that mixing in conduits may be an important mechanism for producing homogeneous hybrid magmas.     

花岗岩与大陆构造、岩浆热场与成矿

文中指出,花岗岩研究存在两个误区:(1)花岗岩没有自己独立的理论,花岗岩主要是效仿玄武岩的理论;(2)花岗岩的理论主要是应用板块构造的理论,而板块构造的理论并不适合大陆花岗岩。板块构造理论只能解决海洋里及海洋边缘的问题(如安第斯),不能解决大陆本身的问题。花岗岩在海洋里很少,绝大部分在大陆。花岗岩能否分离结晶是学术界争论的重大问题,本文从野外和镜下关系上、从理论上、方法学上和三段论法的逻辑学上进行了分析,指出花岗岩分离结晶作用是不可能的。混合作用是又一个争论的焦点,花岗岩是能够发生混合作用的,关键是笔者认为,花岗岩的混合作用主要发生在下地壳底部,而不是在花岗岩侵位和上升的过程中。目前,花岗岩研究领域里地球化学最受重视,花岗岩地球化学研究应当着力解决两个问题:(1)解决生产中提出的问题;(2)解决地球化学学科自身发展提出的问题。离开这两条,花岗岩地球化学研究即迷失了方向。笔者认为,花岗岩区分为大洋系列和大陆系列,位于海洋和海洋边缘受俯冲作用影响的为大洋系列;位于大陆内部的属于大陆系列。现存的一些花岗岩构造环境判别图仅适用于大洋系列的花岗岩,而不适用于大陆系列的花岗岩。大陆系列花岗岩的地球动力学意义不是构造环境或碰撞环境,而是地壳底部温度和压力状况。我们提出的花岗岩按照Sr-Yb的分类,适合于解释大陆花岗岩的地球动力学问题。花岗岩与成矿的关系是学术界争论的重大问题,争论的焦点主要集中在两个问题上:(1)岩浆是怎么形成的?岩浆源自哪里?(2)流体是怎么形成的?流体来自哪里,流体如何上升?为了探讨上述问题,文中主要讨论了岩浆热场理论,希望用这个理论去解释与花岗岩有关的各种成矿作用,包括与岩浆有关的各种变质和沉积热液成矿作用以及岩浆热场对煤和油气的影响等。在此基础上,提出了"与花岗岩有关的成矿组合"的概念。岩浆热场最重要的意义可能是解释了大规模岩浆活动为什么与大规模成矿作用有关的问题,指出大规模岩浆活动所造成的是1+12的效果。大数据技术是当今社会的热门话题,大数据的特点主要不在于数据的大,而在于思维的新,用新思维去处理数据才是大数据的特点。不强调"因果关系",重视"关联关系";不关注"为什么",只关心"是什么",是大数据思维的特点。其实这个特点可能恰恰最符合地质找矿的实际。板块构造引发了地球科学的一场变革,但是,它只限于地球科学理论上的变革。而大数据带来的这场变革主要不是体现在地球科学理论方面,而是地球科学研究方法和研究思路方面,它所带来的效益将是前所未有的。     

Late Pleistocene mammoth remains from Coastal Maine, USA

Remains identified as those of a woolly mammoth (Mammuthus primigenius) dated at 12,200 ± 55 ¹⁴C yr B.P. were recovered while excavating in a complex sequence of glaciomarine sediments in Scarborough, Maine, USA. The mammoth was found in the top meter of a fossiliferous unit of mud and sand laminites. These sediments were deposited during a marine regressive phase following the transgression that accompanied northward retreat of the margin of the Laurentide ice sheet. A Portlandia arctica valve from the underlying transgressive unit provides a minimum age of 14,820 ± 105 ¹⁴C yr B.P. for local deglaciation. The mammoth, an adult female, died in midwinter with no evidence of human involvement. Tusk growth rates and oxygen-isotope variation over the last few years of life record low seasonality. The mammoth was transported to the site as a partial carcass by the late-glacial proto-Saco River. It sank in a near-shore setting, was subjected to additional disarticulation and scattering of elements, and was finally buried in sediments reworked by the shallowing sea.     

Isotopic responses to basaltic injections into silicic magma chambers: a whole-rock and microsampling study of macrorhythmic units in the Pleasant Bay layered gabbro-diorite complex, Maine, USA

The Pleasant Bay layered gabbro-diorite complex (420 Ma) formed via repeated injections of mafic magma into a felsic magma chamber. It is dominated by repeating sequences (macrorhythmic units) with chilled gabbroic bases which may grade upward into medium-grained gabbro, diorite and granite. Each unit represents an injection of mafic magma into the chamber followed by differentiation. Increases in Sr_i and decreases in )_Ndi with stratigraphic height indicate open-system isotopic behaviour and exchange between the mafic and felsic magmas. Isotopic variations of whole-rock samples in individual macrorhythmic units do not conform to bulk mixing or AFC models between potential parental magmas. Sr isotopic studies of single feldspar crystals from one macrorhythmic unit indicate that exchange of crystals between the resident felsic magma and mafic influxes was important, that some of the rocks contain feldspar xenocrysts, and that the rocks are isotopically heterogeneous on an intercrystal scale. Xenocryst abundance increases with stratigraphic height, suggesting that crystal exchange occurred in situ. The lack of disequilibrium textures in the xenocrystic feldspar indicates the evolved macrorhythmic magma and resident silicic magma were of a similar composition and likely in thermal equilibrium at the time of crystal transfer. Mafic chilled margins are enriched in alkalis and isotopically evolved compared with mafic dikes (representing the parental melts) and suggest rapid in-situ diffusional exchange following emplacement of individual mafic replenishments.     

Isotopic studies of processes in mafic magma chambers: II. The Skaergaard Intrusion,East Greenland

Isotopic ratios of Nd and Sr have been measured in a suite of samples spanning most of the exposed stratigraphy of the Skaergaard intrusion in order to detect and quantify input (such as assimilated wallrock and fresh magma) into the magma chamber during crystallization. Unlike ¹⁸O and D, Nd and Sr isotope ratios do not appear to have been significantly affected by circulation of meteoric waters in the upper part of the intrusion. Variations in initial ⁸⁷Sr/⁸⁶Sr and _Nd suggest that the Skaergaard magma chamber was affected during its crystallization by a small amount (2%–4%) of assimilation of Precambrian gneiss wallrock (high ⁸⁷Sr/⁸⁶Sr, low _Nd) and possibly recharge of uncontaminated magma. Decreases in _Nd and increases in ⁸⁷Sr/⁸⁶Sr during the early stages (0%–30%) of crystallization give way to approximately unchanging isotopic ratios through crystallization of the latest-deposited cumulates. Modelling of assimilation-fractional crystallization-recharge processes using these data as constraints shows that the assimilation rate must have been decreasing throughout crystallization. In addition, the isotope data allow replenishment by an amount of uncontaminated magma equal to 20%–30% of the total intrusion mass, occurring either continuously or in pulses over the first 75% of crystallization. Comparison of the recharge models with published Mg/(Mg+Fe²⁺) data from Skaergaard cumulates shows that the modelled replenishment rates are not inconsistent with available major element data, although significant recharge during the final 25% of crystallization can be ruled out. The isotope data show that the Skaergaard magma could have incorporated only a small amount of the gneiss that it displaced from the floor of the chamber; assimilation appears to have taken place primarily across a partially molten zone that formed at the roof from the wallrock that was dislodged during emplacement. In the latest stages of crystallization (>75% crystallized), the Skaergaard magma may have become stratified into two separately-convecting layers, effectively insulating Layered Series cumulates from further contamination.     

Magma plumbing beneath Anak Krakatau volcano, Indonesia: evidence for multiple magma storage regions

Understanding magma plumbing is essential for predicting the behaviour of explosive volcanoes. We investigate magma plumbing at the highly active Anak Krakatau volcano (Indonesia), situated on the rim of the 1883 Krakatau caldera by employing a suite of thermobarometric models. These include clinopyroxene-melt thermobarometry, plagioclase-melt thermobarometry, clinopyroxene composition barometry and olivine-melt thermometry. Petrological studies have previously identified shallow magma storage in the region of 2–8 km beneath Krakatau, while existing seismic evidence points towards mid- to deep-crustal storage zone(s), at 9 and 22 km, respectively. Our results show that clinopyroxene in Anak Krakatau lavas crystallized at a depth of 7–12 km, while plagioclase records both shallow crustal (3–7 km) and sub-Moho (23–28 km) levels of crystallization. These magma storage regions coincide with well-constrained major lithological boundaries in the crust, implying that magma ascent and storage at Anak Krakatau is strongly controlled by crustal properties. A tandem seismic tomography survey independently identified a separate upper crustal (<7 km) and a lower to mid-crustal magma storage region (>7 km). Both petrological and seismic methods are sensitive in detecting magma bodies in the crust, but suffer from various limitations. Combined geophysical and petrological surveys, in turn, offer increased potential for a comprehensive characterization of magma plumbing at active volcanic complexes.     

Isotopic characteristics of potassic rocks: evidence for the involvement of subducted sediments in magma genesis

The potassic igneous rock suite (with molar K₂O/Na₂O > 1) can be divided into an “orogenic” subgroup that occur in subduction-related tectonic settings and an “anorogenic” sub-group that are confined to stable continental settings. Representatives of both sub-groups possess trace element and isotopic features consistent with the contamination of their magma sources by incompatible element rich and isotopically evolved “metasomatic” components. It is argued here that these metasomatic components are principally derived from subducted lithosphere, including subducted sediments. Most examples of orogenic potassic magmatism (e.g. Italian potassic rocks, Spanish lamproites, Sunda arc leucitites) have trace-element and Sr, Nd and Pb isotopic characteristics consistent with the contamination of their mantle sources by a component derived from marine sediments. Anorogenic sub-group potassic magmas have generally similar incompatible trace element and Sr and Nd isotopic characteristics to those of orogenic potassic magmas, but many examples have unusual Pb isotopic compositions with unradiogenic ²⁰⁶Pb/²⁰⁴Pb. Modern marine sediments characteristically have low U/Pb ratios and the unradiogenic ²⁰⁶Pb/²⁰⁴Pb of anorogenic potassic magmas may have evolved during long-term storage of subducted sediments (or components derived from them) within the subcontinental lithosphere. These unusual Pb isotopic compositions require substantial time periods (> 1 Ga) to have elapsed between the fractionation events lowering the U/Pb ratio (i.e. erosion and sedimentation at the Earth's surface) and subsequent potassic magmatism and it is therefore not surprising that most examples of anorogenic potassic magmatism are not associated with recent subduction processes. Although the eruption of potassic magmas is commonly related to rifting or hotspot activity, these processes do not necessarily play an important role in the genesis of the unusual sources from which potassic magmas are derived.     

Isotopic evidence on the diagenetic evolution of coastal sabkha reservoirs from the Solimões Basin, northern Brazil

The isotopic composition of diagenetic carbonates, sulfates, illites and associated diagenetic constituents of the Carboniferous Juruá sandstones, Solimões Basin, largest hydrocarbon reservoirs of northern Brazil, was analyzed in conjunction with petrographic characterization and chemical composition. Eolian Juruá sandstones, deposited in a coastal sabkha of a wide cratonic sag, are the best reservoirs, but diagenetic processes introduced strong and complex heterogeneities, which affect hydrocarbon production. Dolomite and anhydrite cementation, together with compaction, exerts the main control on the quality of the reservoirs. Early dolomite cements precipitated under strong evaporation, while late dolomites are related to thermal decarboxylation. Late anhydrite cements are related to the interbedded evaporites and possibly to the oxidation of dissolved sulfide. Authigenic illite K–Ar ages are related to the voluminous Triassic basic magmatism (around 200 Ma), and to the Jurassic–Cretaceous tectonism (around 150 Ma), which may have also affected the late anhydrite and dolomite–ankerite cementation. This isotopic study revealed the major conditions of the diagenetic processes that strongly affected the Juruá reservoirs, which are essential for the development of models that will optimize the production, as well as decrease the risks in the exploration for new Juruá reservoirs.     

An investigation of the relationship between bulk composition, inferred reaction progress and fluid-flow parameters for layered micaceous carbonates from Maine, USA

Reaction progress exhibited by multivariant assemblages in micaceous limestones can provide an excellent record of metamorphic fluid flow. However, it is necessary to understand the sensitivity of these assemblages to bulk‐composition parameters. Here, analysis of bulk composition on different scales and pseudosection construction are used to draw conclusions on relationships between bulk composition, fluid flow and reaction progress. Issues addressed include the effects of bulk composition on the mineralogical evolution of micaceous carbonates, the sensitivity of bulk composition to bulk‐composition sampling methods, the magnitude of cross‐layer fluid‐composition gradients, the potential for metasomatism to drive reaction progress, and the relative timing of reaction in adjacent layers. Pseudosections successfully represent observed mineral assemblages, constrain the position of reactions in T–X(CO₂) space, and allow assessment of the sensitivity of reaction position, inferred reaction progress and calculated fluid fluxes to uncertainties in bulk composition. The scale of bulk‐composition sampling affects bulk compositions, calculated modes, predicted mineral assemblages and calculated fluid compositions. Larger samples record an average of different lithological subdomains, while point‐count‐derived bulk compositions are subject to uncertainties related to the small number of sample points. The optimum bulk composition for pseudosection purposes probably lies between measured bulk compositions. Results suggest that reaction progress in some extensively reacted layers was driven by infiltration of H₂O‐rich fluid which flowed or diffused parallel to layering, perpendicular to layering in response to fluid‐composition gradients, and out of veins. Small variations in fluid composition across layering (ΔX(CO₂) < 0.02) were maintained by internal buffering by the mineral assemblages. Internal buffering must also have driven samples up a sequence of narrow low‐variance fields in T–X(CO₂) space, and so reaction in adjacent layers must have close to simultaneous. Metasomatic effects on reaction progress are likely to have been small, so long as the porosity was low.     

Sand and gravel mining: effects on ground water resources in Hancock county,Maine, USA

Based on this preliminary study, existing sand and gravel mining regulations (in Maine, USA) can be inferred to provide some protection to water resources. Sand and gravel deposits are important natural resources that have dual uses: mining for construction material and pumping for drinking water. How the mining of sand and gravel affects aquifers and change aquifer vulnerability to contamination is not well documented. Mining regulations vary greatly by state and local jurisdiction. This study test metrics to measure the effectiveness of mining regulations. The sand and gravel aquifer system studied is covered with former and active gravel pits to nearly 25% of its areal extent. Data from homeowner interviews and field measurements found scant evidence of changes in water quantity. Water quality analyses collected from springs, streams, ponds and wells indicate that the aquifer was vulnerable to contamination by chloride and nitrate. However, water quality changes can not be related directly to mining activities.     

Microstructural evidence for magma confluence and reusage of magma pathways: implications for magma hybridization,Karakoram Shear Zone in NW India

In the Karakoram Shear Zone, Ladakh, NW India, Miocene leucogranitic dykes form an extensive, varied and complex network, linking an anatectic terrane exposed in the Pangong Range, with leucogranites of the Karakoram Batholith. Mineral paragenesis of the heterogeneous anatectic source rocks suggests melting has resulted from water influx into rocks at upper amphibolite facies conditions, and microstructures suggest anatexis was contemporaneous with shearing. The network is characterized by continuous and interconnected dykes, with only rare cross‐cutting relationships, forming swarms and chaotic injection complexes where magmatic rocks cover up to 50% of the outcrop area. Despite this volume of magma, the system did not lose continuity, suggesting that it did not flow en masse and that the magma network was not all liquid simultaneously. Leucogranites in this network, including leucosomes in migmatites, carry an isotopic signature intermediate between the two main anatectic rocks in the source, suggesting efficient homogenization of the magmatic products. Here, we describe a number of microscopic features of these magmatic rocks which suggests that several pulses of magma used the same pathways giving rise to textural and chemical disequilibrium features. These include: (i) narrow, tortuous corridors of fine‐grained minerals cutting across or lining the boundaries of larger grains, interpreted to be remnants of magma‐filled cracks cutting across a pre‐existing magmatic rock; (ii) corrosion of early formed grains at the contact with fine‐grained material; (iii) compositional zoning of early formed plagioclase and K‐feldspar grains and quartz overgrowths documented by cathodoluminescence imaging; (iv) incipient development of rapakivi and anti‐rapakivi textures, and (iv) different crystallographic preferred orientation of early formed quartz and fine‐grained quartz. Mapping of the fine‐grained corridors interpreted to represent late melt channels reveal an interlinked network broadly following the S‐C fabric defined by pre‐existing magmatic grains. We conclude that early formed dykes provided a pathway exploited intermittently or continuously by new magma batches. New influxes of magma opened narrow channels and migrated through a microscopic network following predominantly grain boundaries along an S‐C fabric related to syn‐magmatic shearing. A mixed isotopic signature resulted not from the mixing of magmas, but from the micro‐scale interaction between new magma batches and previously crystallized magmatic rocks, through local equilibration.     

Field evidence,mineral chemical and geochemical constraints on mafic-felsic magma interactions in a vertically zoned magma chamber from the Chotanagpur Granite Gneiss Complex of Eastern India

The Nimchak granite pluton (NGP) of Chotanagpur Granite Gneiss Complex (CGGC), Eastern India, provides ample evidence of magma interaction in a plutonic regime for the first time in this part of the Indian shield. A number of outcrop level magmatic structures reported from many mafic-felsic mixing and mingling zones worldwide, such as synplutonic dykes, mafic magmatic enclaves and hybrid rocks extensively occur in our study domain. From field observations it appears that the Nimchak pluton was a vertically zoned magma chamber that was intruded by a number of mafic dykes during the whole crystallization history of the magma chamber leading to magma mixing and mingling scenario. The lower part of the pluton is occupied by coarse-grained granodiorite (64.84–66.61?wt.% SiO₂), while the upper part is occupied by fine-grained granite (69.80–70.57?wt.% SiO₂). Field relationships along with textural and geochemical signatures of the pluton suggest that it is a well-exposed felsic magma chamber that was zoned due to fractional crystallization. The intruding mafic magma interacted differently with the upper and lower granitoids. The lower granodiorite is characterized by mafic feeder dykes and larger mafic magmatic enclaves, whereas the enclaves occurring in the upper granite are comparatively smaller and the feeder dykes could not be traced here, except two late-stage mafic dykes. The mafic enclaves occurring in the upper granite show higher degrees of hybridization with respect to those occurring in the lower granite. Furthermore, enclaves are widely distributed in the upper granite, whereas enclaves in the lower granite occur adjacent to the main feeder dykes.Geochemical signatures confirm that the intermediate rocks occurring in the Nimchak pluton are mixing products formed due to the mixing of mafic and felsic magmas. A number of important physical properties of magmas like temperature, viscosity, glass transition temperature and fragility have been used in magma mixing models to evaluate the process of magma mixing. A geodynamic model of pluton construction and evolution is presented that shows episodic replenishments of mafic magma into the crystallizing felsic magma chamber from below. Data are consistent with a model whereby mafic magma ponded at the crust-mantle boundary and melted the overlying crust to form felsic (granitic) magma. The mafic magma episodically rose, injected and interacted with an overlying felsic magma chamber that was undergoing fractional crystallization forming hybrid intermediate rocks. The intrusion of mafic magma continued after complete solidification of the magma chamber as indicated by the presence of two late-stage mafic dykes.     

Evolution of Mayurbhanj Granite Pluton, eastern Singhbhum, India: a case study of petrogenesis of an A-type granite in bimodal association

The A-type Mayurbhanj Granite Pluton (3.09 Ga), occurring along the eastern margin of the Singhbhum-Orissa Craton, eastern India, represents the final phase of acid plutonism in this crustal block of Archean age. The granite shows a bimodal association with a voluminous gabbroid body, exposed mainly along its western margin, and is associated with the Singhbhum Shear zone. The granite pluton is composed mainly of a coarse ferrohastingsite–biotite granite phase, with an early fine-grained granophyric microgranitic phase and a late biotite aplogranitic phase. Petrogenetic models of partial melting, fractional crystallisation and magma mixing have been advocated for the evolution of this pluton. New data, combined with earlier information, suggest that two igneous processes were responsible for the evolution of the Mayurbhanj Granite Pluton: partial melting of the Singhbhum Granite; followed by limited amount of mixing of acid and basic magmas in an anorogenic extensional setting. The necessary heat for partial melting was provided by the voluminous basaltic magma, now represented by the gabbroid body, emplaced at a shallow crustal level and showing a bimodal association with the Mayurbhanj Granite Pluton. The Singhbhum Shear Zone provided a possible channel way for the emplacement of the basic magma during crustal extension. It is concluded that all three phases of the Mayurbhanj Granite Pluton were derived from the same parent magma, generated by batch partial melting of the Singhbhum Granite at relatively high temperatures (980 °C) and low pressures (4 to <2 kbar) under anhydrous conditions. The coarse ferrohastingsite biotite granite phase shows evidence of limited and heterogeneous assimilation of country rock metasediments. However, the early microgranite phase and late aplogranite phase have not assimilated any metasediments. Compositional irregularities observed along the western margin of the Mayurbhanj Granite Pluton in contact with the gabbro body including a continuous fractionating sequence from quartz diorite to alkali-feldspar granite in the Notopahar area. Gradational contacts between the gabbro and the Mayurbhanj Granite Pluton in the Gorumahisani area etc., may be attributed to a limited amount of mixing between the gabbroid magma and the newly generated Mayurbhanj Granite magma. The mixing was mainly of liquid–liquid diffusive type, with a subordinate amount of mixing of solid–liquid type. Although A-type granites are commonly described as having high total REE (e.g. 270–400 ppm), studies on the late aplogranite phase of the Mayurbhanj Granite show that total REE values (100 ppm) are low. This low REE abundance may be attributed to the progressive residual nature of the Singhbhum Granite source during continued partial melting, when the magmas of the microgranite and coarse granite phases had already been removed from the source region.     

Zircon crystal morphology and internal structures as a tool for constraining magma sources: Examples from northern Portugal Variscan biotite-rich granite plutons

In northern Portugal, large volumes of granitoids were emplaced during the last stage (D₃) of the Variscan orogeny and display a wide range of petrological signatures. We studied the morphologies and internal structures of zircons from syn-, late- and post-D₃ granitoids. The sin-D₃ granitoids include the Ucanha–Vilar, Lamego, Felgueiras, Sameiro, and Refoios do Lima plutons, the late- and post-D₃ granitoids are represented by the Vieira do Minho and the Vila Pouca de Aguiar plutons, respectively. Typological investigations after Pupin (1980) along with scanning electron microprobe imaging reveal that the external morphology of zircon changes consistently with a decrease in the crystallization temperature. Zircon populations from the Refoios do Lima and the Vieira do Minho granites show gradual changes in the internal morphologies and their typologic evolution trends are consistent with their mainly crustal origin. The Sameiro, Felgueiras, Lamego and Ucanha-Vilar granites have more complex internal and external morphology and typological evolution trends that cross the domain of the calc-alkaline to the aluminous granites compatible with a mixing process. Finally, the morphological types of the Vila Pouca de Aguiar granites are found both in calc-alkaline and sub-alkaline granites and their typological evolutionary trends follow the calc-alkaline/sub-alkaline trend, suggesting crustal sources with some mantle contribution.     

The role of dextral transpressional faulting in the evolution of an early Carboniferous mafic–felsic plutonic and volcanic complex: Cobequid Highlands, Nova Scotia, Canada

The Wentworth plutonic complex, consisting of gabbro and granite, was emplaced in the earliest Carboniferous in the Cobequid shear zone of the northern Appalachians. The plutonic complex is coeval with a 5-km-thick pile of volcanic rocks. Early alkalic A-type granite correlates with thick felsic pyroclastics and minor basalt, which are overlain by 1.5-km-thick basalts that correlate with a large gabbro pluton that is intruded, in turn, by late granites. The basalt and gabbro are Fe-rich tholeiites. The geochemistry of the late granites suggests that they formed by differentiation of a granodioritic magma resulting from assimilation of early granite by the gabbroic magma. The Wentworth plutonic complex lies on the north side of the dextral Rockland Brook fault, near the western tip of wedge-shaped basement block of the Avalon terrane. Field observations of mesoscopic structures and map contacts show that the plutonic bodies at all structural levels are related to transpressive strike–slip faults. Dykes parallel to the mylonitic foliation in the Rockland Brook fault zone and at the contacts between igneous phases suggest that the plutons developed largely through dyke to pluton construction. The plutonism was initiated by dyking related to major faults under transpression that was partitioned into shear zone-bounded blocks, while the sinking of those blocks finally provided the space for mafic magma emplacement. Dyking was active over at least a 10-Ma time period. The overall location of plutonism in the Cobequid shear zone appears related to its position at the intersection of the shear zone bounding the southwestern margin of the Magdalen basin and the E–W transpressional contact of the Avalon and Meguma terranes. Magmatism enabled thermomechanical softening of the crust and the vertical and lateral extrusion of the wedge-shaped basement blocks, whose movement controlled the localisation of the voluminous magmatic activity.     

河北武安坦岭多斑斜长斑岩的成因:冻结岩浆房活化机制

流变学实验表明,当岩浆中晶体体积分数达到约50vol%时,岩浆体实际上处于冻结状态,不再具有整体迁移的能力。但在自然界中仍存在含大量斑晶的浅成火成岩和火山岩。因此,富晶体岩浆的上升过程和侵位机制是近年来地球科学领域关注的热点之一。目前,冻结岩浆房的活化机制主要有二种:升温活化机制和流体活化机制。河北武安坦岭地区新发现的多斑斜长斑岩为揭示冻结岩浆房的活化提供了契机。野外观察和晶体粒度分布(CSD)分析表明,坦岭斜长斑岩中斜长石斑晶高达70vol%,基质为显微晶质结构。斜长石斑晶粒径分布均一,大小约为3.1×1.7mm;显微镜观察和背散射图像揭示,斜长石斑晶具环带结构,由宽广的斜长石核部+宽度可变的条纹长石边部组成,且无熔蚀现象;电子探针成分剖面分析表明,斑晶核部成分为更长石(An_(27)Ab_(71)Or_2),幔部为更长石(An_(13)Ab_(83)Or_4),边部为条纹长石。边部条纹长石的成分有一定变化,从内侧到外侧,主晶钠长石成分由Ab_(53)Or_(47)变为Ab_(99)Or_1,客晶钾长石成分由Ab_(48)Or_(51)变为Ab3Or97。斑晶斜长石核部存在细长条状或斑点状钾长石,且越靠近中心,钾长石斑点的数量越少。这些特点表明,边部条纹长石为交代成因。稀土和微量元素分析则显示,边部条纹长石具弱正Eu异常,相对富集LREE和K、Rb、Ba、Sr等大离子亲石元素,亏损Th、Zr、Nb的特点。CSD相关图解及以上特征表明,斜长石斑晶形成于稳定,封闭的结晶环境,并受到晚期碱交代作用的改造。基质主要由微粒钙质角闪石,条纹长石,石英,钾长石和钠长石组成,含少量自形-半自形磁铁矿和钛铁矿、磷灰石、榍石、金红石和锆石等11种矿物组成。11种矿物相和结构特征暗示基质形成于极端不稳定的结晶环境,与斜长石斑晶形成条件鲜明对照。根据基质的矿物组成,推测形成基质的岩浆具有富含K、Na、Fe、Si和挥发分的特征。这种特征与上述关于条纹长石环边形成条件的判断一致。据此,本文认为:产生斜长石斑晶的岩浆曾经在地壳深部作过长时间滞留,导致了斜长石的稳定结晶,增加了岩浆的粘度和密度,使岩浆处于冻结状态;富碱高铁熔体-流体流的注入大幅降低了岩浆的总粘度,并提高了岩浆的浮力,从而促使冻结岩浆房迅速活化和上升侵位;同时,富碱高铁熔体-流体流强烈交代了先存的斜长石斑晶,使其边部形成条纹长石;这种熔体-流体流则在快速排气,冷却过程中迅速结晶,形成了具有不平衡矿物组合的显微晶质基质。在岩浆侵入体较深部位,富碱高铁熔体-流体经历了很缓慢的固结过程,而相分离产生的流体有可能萃取携带岩浆中的铁质,形成富Fe流体流,后者可能对区内"铁矿浆"型铁矿的形成具有重要的贡献。     

Titanite: A potential solidus barometer for granitic magma systems

Constraining crystallization pressure and thus intrusion depth of granites in various geodynamic settings remains challenging, yet important to further our understanding of magma system and crustal evolution. We propose that titanite, which is a common accessory in metaluminous and weakly peraluminous granites, can be used as a barometer if it crystallized in magmatic, near-solidus conditions and in equilibrium with amphibole, plagioclase, K-feldspar, quartz, biotite, and magnetite ± ilmenite. Titanite Al₂O₃ increases with pressure (P) according to: P (in MPa) = 101.66 × Al₂O₃ in titanite (in wt%) + 59.013 (R² = 0.83) with estimated uncertainties of ~±60 to ~±100 MPa for crystallization between ~150 and 400 MPa. We highlight that the current calibration dataset is limited, and that systematic experimental studies are needed to rigorously quantify the relation. The most important use of this empirical barometer will be for rocks in which amphibole is present but significantly altered, or in combination with amphibole barometry, as titanite can be easily dated by LA-ICP-MS.     

Isotopic evidence for glacial meltwater recharge to the Cambrian-Ordovician aquifer, north-central United States

The chemistry of water in the Cambrian-Ordovician aquifer in six midwestern states has been studied as part of the Northern Midwest Regional Aquifer-System Analysis of the U.S. Geological Survey. Dissolved-solids concentrations generally increase perpendicular to the direction of regional groundwater flow, from less than 400 mg/liter in southeast Minnesota, southwest Wisconsin, and northeast Iowa to more than 10,000 mg/liter in northwest Missouri. Isotopic ratios of hydrogen and oxygen are significantly depleted from north to south, with an areal distribution approximately parallel to the distribution of dissolved solids. For example, δ¹⁸O in southern Iowa and northern Missouri is about 6 parts per thousand lighter than δ¹⁸O of modern recharge water in Minnesota and Wisconsin. Covariance between δ¹⁸O and δD of the groundwater, similar to that of modern precipitation, suggests that the differences in isotopic ratios between groundwater and modern recharge water reflect meteoric signatures of water during past recharge events rather than geochemical processes such as isotopic exchange with aquifer materials. The pronounced parallelism between the distribution of isotopes and dissolved solids over large areas probably reflects largescale recharge of Pleistocene glacial meltwater into the aquifer system, which probably had a paleoflow system with a gradient from northeast to southwest rather than from northwest to southeast.     

Lake Boga Granite,northwestern Victoria: mineralogy,geochemistry and geochronology

The Devonian Lake Boga Granite in northern Victoria, while almost entirely under thin Murray Basin cover, is one of the largest plutons in the western Lachlan Fold Belt. Its only exposure is a quarry penetrating the Cenozoic sediments. In the quarry, prominent pod pegmatites and miarolitic cavities suggest a high level of emplacement. The granite, a non-magnetic, fractionated S-type, contains a large range of accessory minerals, including primary uranium- and REE-bearing phosphates and oxides, and primary copper sulfides. Monazite-series minerals show an exceptionally wide range of compositions, from normal monazite-(Ce) through cheralite (Ca – Th-rich) to rare huttonitic monazite (Th-rich) and brabantite; U contents in monazite also vary widely (0 – 7.9 wt%). Primary low-Ca uraninites are well preserved and are unusual in having low Th/U and LREE. Late-stage cavity fluorapatite crystals up to several centimetres across show intricate elemental zoning patterns with extreme U gradients (<10 – 6900 ppm) in some crystals. New ⁴⁰Ar – ³⁹Ar ages for magmatic biotite, muscovite and K-rich feldspar average 365 ± 3 Ma, which approximates the emplacement age of the granite. This is supported by a 377 ± 12 Ma U – Th – Pb (CHIME) age for primary uraninite. New whole-rock geochemical data support earlier observations: the granite is strongly fractionated (SiO₂ 70.7 – 76.0 wt%; 4.2 – 0.6 wt% FeO_t) and peraluminous (ASI = 1.23 – 1.45), and has slightly elevated Na₂O and P₂O₅ (0.30 wt%) contents compared with other fractionated S-type granites from the Lachlan Fold Belt. Trace-element abundances are typical of fractionated granites, although U and Cu concentrations vary strongly and reach >60 and ≈1400 ppm, respectively. REE patterns also vary strongly, from LREE-enriched with moderate Eu depletion, to flat with strong Eu depletion. The flattest of the REE patterns, in samples with FeO_total < 1%, are characterised by M-type tetrad effects. These and other samples also show low (subcrustal average) and variable Zr/Hf (35 – 16) and Nb/Ta (8 – 4) ratios; these and other unusual elemental fractionations are related to changes in elemental partitioning during the late magmatic stage, when felsic peraluminous magma and high-temperature magmatic fluid coexisted.