U-Pb (SHRIMP-II) isotope dating of zircons from alkali rocks of Vitim province,West Transbaikalia

A U-Pb (SHRIMP-II) geochronological study of rocks from the Sayzhenski, Snezhny and Nizhne-Burulzayski massifs, incorporated into the Vitim alkali province (Sayzhenski Complex) has been made. The acquired data indicate that the rocks formed in the interval of 520-486 Ma. The proximity of their age to accretionary-collision processes in the Central Asian fold belt, accompanied by intràplate magmatism, has been noted. Two independent stages in the evolution of Vitim Province magmatism are suggested: Early Paleozoic (520-485 Ma) and Late Paleozoic (350-290 Ma).     

Composition,sources, and mechanisms of origin of rare-metal granitoids in the Late Paleozoic Eastern Sayan zone of alkaline magmatism: A case study of the Ulaan Tolgoi massif

The Ulaan Tolgoi massif of rare-metal (Ta, Nb, and Zr) granites was formed at approximately 300Ma in the Eastern Sayan zone of rare-metal alkaline magmatism. The massif consists of alkaline salic rocks of various composition (listed in chronologic order of their emplacement): alkaline syenite → alkaline syenite pegmatite → pantellerite → alkaline granite, including ore-bearing alkaline granite, whose Ta and Nb concentrations reach significant values. The evolution of the massif ended with the emplacement of trachybasaltic andesite. The rocks of the massif show systematic enrichment in incompatible elements in the final differentiation products of the alkaline salic magmas. The differentiation processes during the early evolution of the massif occurred in an open system, with influx of melts that contained various proportions of incompatible elements. The magma system was closed during the origin of the ore-bearing granites. Rare-metal granitoids in the Eastern Sayan zone were produced by magmas formed by interaction between mantle melts (which formed the mafic dikes) with crustal material. The mantle melts likely affected the lower parts of the crust and either induced its melting, with later mixing the anatectic and mantle magmas, or assimilated crustal material and generated melts with crustal–mantle characteristics. The origin of the Eastern Sayan zone of rare-metal alkaline magmatism was related to rifting, which was triggered by interaction between the Tarim and Barguzin mantle plumes. The Eastern Sayan zone was formed in the marginal part of the Barguzin magmatic province, and rare-metal magmas in it were likely generated in relation with the activity of the Barguzin plume.     

The age of unusual xenogenic zircons from Yakutian kimberlites

Several spindle-shaped grains of zircon, which have a small size (<0.25 mm) and a distinct purplish pink coloration were found in the crushed samples of kimberlites from the Aykhal, Komsomolskaya-Magnitnaya, Botuobinskaya (Siberian platform), and Nyurbinskaya (Yakutia) pipes and olivine lamproites of the Khani massif (West Aldan). U-Pb SHRIMP II zircon dating performed at the VSEGEI Center for Isotopic Research yielded the ages of 1870–1890 Ma for the pipes of the Western province (Aykhal and Komsomolskaya) and 2200–2750 Ma for the pipes of the eastern province (Nyurbinskaya and Botuobinskaya), which allowed us to consider these zircons to be xenogenic to kimberlites. Although these zircons resemble in their age and color those from the granulite xenoliths in the Udachnaya pipe [2], no other granulite minerals are found there. Thus, major geological events in the mantle and lower crust, which led to the formation of zircon-bearing rocks, happened at 1800–1900 Ma in the northern part of the kimberlite province, whereas in the Eastern part of the province (Nakyn field) these events were much older (2220–2700 Ma). It is known that the period of 1800–1900 Ma in the Earth’s history was accompanied by intense tectonic movements and widespread alkaline-carbonatite magmatism. This magmatism was related to plume activity responsible for overheating the large portions of the mantle to the temperatures at which some diamonds in mantle rocks would burn (northern part of the kimberlite province). In the Nakyn area, the mantle underwent few or no geological processes at that time, and perhaps for this reason this area hosts more diamondiferous kimberlites. The age of olivine lamproites from the Khani massif is 2672–2732 Ma. Thus, these are some of the world’s oldest known K-alkaline rocks.     

Late Cenozoic Volcanism of the Vitim Depression and Its Correlation with the Vitim Lava Plateau (Western Transbaikalia) according to K–Ar Geochronology

New data on the geology, age, and composition of the Late Cenozoic volcanic rocks of the Vitim Depression, a satellite of the Vitim Lava Plateau (VLP), have been obtained. Two-stage volcanic activity has been revealed. In the Middle Miocene (14–13 Ma), a basalt and trachybasalt (hawaiite) lava covers were formed. In the Pleistocene (1.6–0.7 Ma), basanite erupted from scoria cones. Both stages of volcanism were coeval to similar pulses of volcanism within the VLP. However, unlike the latter, there were no Pliocene and Late Miocene eruptions within the Vitim Depression. Additionally, the Vitim Depression basalts have depleted geochemical characteristics comparative to those of the VLP. These features of the Vitim Depression volcanics imply their autonomous formation, whereas the synchroneity of the initial and final stages of volcanism in the depression and in the VLP reflects the existence of a common regulating mechanism of igneous activity.     

Biostratigraphy and deposition environments of the Middle-Late Miocene volcanosedimentary section in the Dzhilinda basin,Western Transbaikalia

We report results of an integrated study of volcanosedimentary rocks of the Middle-Late Miocene Dzhilinda Formation consisting of the prevolcanic sedimentary Lower Dzhilinda and volcanosedimentary Upper Dzhilinda subformations. The section was studied in three wells drilled near Lake Mukhal (Khoigot paleovalley, Vitim upland). The Dzhilinda sediments contain ubiquitous Alveolophora jouseana (Moiss.) Moiss. typical of Miocene environments. Deposition occurred in two main stages represented by different water (diatoms) and land (spores and pollen) plant communities. The upsection successive changes in diatom species are attendant with changes in pollen and spore assemblages. The K-Ar ages of lavas indicate that the mostly sedimentary lower section of the Dzhilinda Formation deposited between 12 and 14 Ma and the more volcanic upper section, with a lacustrine lens at base, formed at about 10.8–9.5 Ma. The isotope dating of volcanic rocks agrees with the ages inferred from the diatom and spore-pollen analyses. The prevolcanic Lower Dzhilinda subformation deposited during the Middle Miocene climate optimum. The stratigraphy, lithology and facies of sediments suggest that the Dzhilinda deposition was associated with the development of a deep freshwater lake in the conditions of active tectonism and volcanism.     

Sequence of magmatic events in the Late Paleozoic of Transbaikalia,Russia (U-Pb isotope data)

The Late Paleozoic intrusive rocks, mostly granitoids, totally occupy more than 200,000 km² on the territory of Transbaikalia. Isotopic U-Pb zircon dating (about 30 samples from the most typical plutons) shows that the Late Paleozoic magmatic cycle lasted for 55–60 m.y., from ~330 Ma to ~275 Ma. During this time span, five intrusive suites were emplaced throughout the region. The earliest are high-K calc-alkaline granites (330–310 Ma) making up the Angara–Vitim batholith of 150,000 km² in area. At later stages, formation of geochemically distinct intrusive suites occurred with total or partial overlap in time. In the interval of 305–285 Ma two suites were emplaced: calc-alkaline granitoids with decreased SiO₂ content (the Chivyrkui suite of quartz monzonite and granodiorite) and the Zaza suite comprising transitional from calc-alkaline to alkaline granite and quartz syenite. At the next stage, in the interval of 285–278 Ma the shoshonitic Low Selenga suite made up of monzonite, syenite and alkali rich microgabbro was formed; this suite was followed, with significant overlap in time (281–276 Ma), by emplacement of Early Kunalei suite of alkaline (alkali feldspar) and peralkaline syenite and granite. Concurrent emplacement of distinct plutonic suites suggests simultaneous magma generation at different depth and, possibly, from different sources. Despite complex sequence of formation of Late Paleozoic intrusive suites, a general trend from high-K calc-alkaline to alkaline and peralkaline granitoids, is clearly recognized. New data on the isotopic U-Pb zircon age support the Rb-Sr isotope data suggesting that emplacement of large volumes of peralkaline and alkaline (alkali feldspar) syenites and granites occurred in two separate stages: Early Permian (281–278 Ma) and Late Triassic (230–210 Ma). Large volumes and specific compositions of granitoids suggest that the Late Paleozoic magmatism in Transbaikalia occurred successively in the post-collisional (330–310 Ma), transitional (305–285 Ma) and intraplate (285–275 Ma) setting.     

Proterozoic Gremyakha-Vyrmes Polyphase Massif, Kola Peninsula: An example of mixing basic and alkaline mantle melts

The paper presents newly obtained data on the geological structure, age, and composition of the Gremyakha-Vyrmes Massif, which consists of rocks of the ultrabasic, granitoid, and foidolite series. According to the results of the Rb-Sr and Sm-Nd geochronologic research and the U-Pb dating of single zircon grains, the three rock series composing the massif were emplaced within a fairly narrow age interval of 1885 ± 20 Ma, a fact testifying to the spatiotemporal closeness of the normal ultrabasic and alkaline melts. The interaction of these magmas within the crust resulted in the complicated series of derivatives of the Gremyakha-Vyrmes Massif, whose rocks show evidence of the mixing of compositionally diverse mantle melts. Model simulations based on precise geochemical data indicate that the probable parental magmas of the ultrabasic series of this massif were ferropicritic melts, which were formed by endogenic activity in the Pechenga-Varzuga rift zone. According to the simulation data, the granitoids of the massif were produced by the fractional crystallization of melts genetically related to the gabbro-peridotites and by the accompanying assimilation of Archean crustal material with the addition of small portions of alkaline-ultrabasic melts. The isotopic geochemical characteristics of the foidolites notably differ from those of the other rocks of the massif: together with carbonatites, these rocks define a trend implying the predominance of a more depleted mantle source in their genesis. The similarities between the Sm-Nd isotopic characteristics of foidolites from the Gremyakha-Vyrmes Massif and the rocks of the Tiksheozero Massif suggest that the parental alkaline-ultrabasic melts of these rocks were derived from an autonomous mantle source and were only very weakly affected by the crust. The occurrence of ultrabasic foidolites and carbonatites in the Gremyakha-Vyrmes Massif indicates that domains of metasomatized mantle material were produced in the sublithospheric mantle beneath the northeastern part of the Fennoscandian Shield already at 1.88 Ga, and these domains were enriched in incompatible elements and able to produce alkaline and carbonatite melts. The involvement of these domains in plume-lithospheric processes at 0.4–0.36 Ga gave rise to the peralkaline melts that formed the Paleozoic Kola alkaline province.     

Age of carbonatite magmatism in Transbaikalia

The paper reports Ar-Ar, Rb-Sr, and U-Pb (SHRIMP II) geochronologic data on carbonatites in Transbaikalia, related metasomatically altered rocks, and comagmatic silicate alkaline rocks. Metamorphic processes at two carbonatite occurrences were dated at 550–559 Ma (U-Pb and Rb-Sr methods). Geochronologic data make it possible to distinguish two major epochs when carbonatite were formed: Late Mesozoic in southwestern Transbaikalia and Late Riphean-Vendian in northern Transbaikalia. Small carbonatite occurrences are also known in the Vitim and Baikal alkaline provinces, which were formed in the Middle-Late Paleozoic. The Late Mesozoic carbonatite-forming epoch is definitely correlated with the development of the Western Transbaikalia rift structure and the Late Riphean-Vendian epoch, with the breakup of Laurasia in the Late Riphean.     

The Late Paleozoic geodynamics of the West Transbaikalian segment of the Central Asian fold belt

New data testifying to Late Paleozoic tectonometamorphic processes at the West Transbaikalian segment of the Central Asian Fold Belt have been obtained. Zircon dating (SHRIMP-II) of highly metamorphosed rocks showed that the processes took place at 295.3 ± 1.6 Ma. Based on these data, the Late Paleozoic ages of granitoids of the Angara–Vitim areal pluton (340–280 Ma) and some dike complexes in Transbaikalia (300–280 Ma), and the Late Paleozoic age of some carbonate-terrigenous strata dated earlier to the Early Paleozoic, we have substantiated the significant role of Hercynian tectogenesis in the consolidation of the regional continental crust. We have also shown that the Late Paleozoic endogenous events and accompanying sedimentation processes were related to the geodynamic conditions governed by the changing parameters of the subsidence of the Mongol-Okhotsk oceanic subduction slab beneath the Siberian continent. Changes in the slope and rate of the slab subsidence resulted in A-subduction conditions in the distal part of the suprasubduction plate, which led to the formation of accretion-collisional orogen and the Angara–Vitim areal pluton.     

Zirconology of serpentinites from Nyashevo massif (Southern Urals)

Zircons in serpentinites from Nyashevo massif of the Ilmenogorskii complex were dated for the first time by means of the SHRIMP technique. The maximum date of 1892 ± 23 Ma for the zircons accounts for the minimum age of their mantle substrate probably constituting the restite residue. The date is comparable to those for metamorphic rocks of the Selyankino group, as well as of fenite–sand amphibolites of the Ilmenogorskii complex. The Upper Ordovician age limit of 443 ± 12 Ma is adequate for formation of the massif and conforms to the age of the Buldym massif and miaskites. The Early Permian dates of zircons (275.8 ± 2.1 Ma) represent late shear processes in the Ilmenogorskii complex.     

Age and Sources of Dunite from the Konder Massif (Aldan Shield)

The Sm–Nd and Rb–Sr isotope characteristics were studied in clinopyroxenes (Cpx) of ultrabasic rocks (dunite, wehrlite, pyroxenite, and kosvite) from the Konder massif, which is a source of a unique placer platinum deposit. The chemical composition of the clinopyroxenes studied provides evidence for their crystallization from a single melt in the course of magmatic differentiation. The Sm–Nd isotope characteristics of Cpx in dunite from the Konder massif correspond to the regression with an age of 128 ± 40 Ma, which provides evidence for the same age of rocks of the “dunite core,” wehrlite, pyroxenite, kosvite, and alkaline rocks of the subsequent intrusive stage in the Konder massif. Variations in the Sr and Nd isotope characteristics in dunite, wehrlite, pyroxenite, and kosvite result from contamination of the picritic melt with rocks of the continental crust in the course of its cumulative evolution, which allows us to exclude the model of diapiric intrusion of mantle dunite.     

Permo-Triassic stage of alkaline magmatism in the Vitim plateau (western Transbaikalia)

We present results of geochronological (⁴⁰Ar-³⁹Ar, U-Pb SHRIMP-II, and LA-ICP-MS) and geochemical studies of alkaline rocks of the Amalat, Sirikta, Tsipa, Pravyi Uligli, and Verkhnii Uligli massifs in the Vitim plateau (western Transbaikalia). The formation of the alkaline rocks and the accompanying albitization are dated at 261-242 Ma. The isotope inhomogeneity (?_Nd(T) = + 8.4 to -1.7) of the alkaline rocks indicates the heterogeneous composition of the source of their material, having a depleted component, an enriched juvenile metasomatic fluid, and a crustal substrate.     

U-Pb SHRIMP-II ages of titanite and timing constraints on apatite-nepheline mineralization in the Khibiny and Lovozero alkaline massifs (Kola Peninsula)

Results of this study of titanite samples collected from silicate rocks and apatite-nepheline-(sphene) ores from Paleozoic polyphase alkaline nepheline syenite complexes of the Khibiny and Lovozero massifs revealed the possibility of their in-situ U-Pb dating using sensitive high-resolution ion microprobe SHRIMP-II with an accuracy of 1.0-1.5%, which is comparable with that of U-Pb zircon analysis. Employing different approaches to age determination of the formation of the U-Pb system of titanites, the combined isochrons and mixing lines were plotted from the data obtained from the differentiated complex samples (121 analyses of five Khibiny samples and 52 analyses of one Lovozero sample) and apatite-nepheline ores (120 analyses of five Khibiny samples and 88 analyses of three Lovozero samples). They indicate synchronous crystallization of titanite in silicate rocks throughout the complexes: 374.1 ± 3.7 Ma for the Khibiny massif and 380.9 ± 4.5 Ma for the Lovozero massif, and attest to the later formation of phosphate-rare-metal ores: 371.0 ± 4.2 and 361.4 ± 3.2 Ma, respectively. The relatively delayed ore mineralization specific to the Lovozero massif can be accounted for the significantly lower volumes of magmatic melt and ore fluid involved, different thermal conditions, and the pattern of the investigated mineralization. As such, the obtained U-Pb data from titanite make it possible to limit significantly the time interval (most likely, not exceeding 15-20 Ma) comprising the evolution and activity of the ore-magmatic system of major agpaitic complexes, which is probably associated with plume magmatism.     

Geodynamics of Late Paleozoic batholith-forming processes in western Transbaikalia

Isotopic dates newly obtained for the northwestern portion of the Angara–Vitim batholith are consistent with preexisting data on the duration of the Late Paleozoic magmatic cycle: 55–60 Ma (from 325 to 280 Ma). These data also indicate that alkaline mafic magmatism in western Transbaikalia began simultaneously with the transition from crustal granite-forming processes to the derivation of granites of a mixed mantle–crustal nature, with gradual enrichment of the juvenile component in the source of the magmas. Analysis of the currently discussed geodynamic models of Late Paleozoic magmatism shows that a key role in all models of extensive granite-forming processes in the region is assigned to mafic mantle magmas, which can be generated in various geotectonic environments: subduction, delamination, decompression, and a mantle plume. The plume model is most consistent with the intraplate character of the Angara–Vitim batholith. The derivation of the vast volume of granitic material (approximately 1 million km³) should have required a comparable volume of mafic magma that should have been pooled in the middle crust of the Baikal fold area. However, the density structure of the region does not provide evidence of significant volumes of mafic rocks. This suggests that the mechanism of plume–lithospheric interaction that should have induced extensive crustal melting and the origin of vast granite areas was more complicated than simply conductive melting of crustal protoliths in contact with mafic intrusions.     

Phlogopite and phlogopite–amphibole parageneses in the lithospheric mantle of the Birekte terrane (Siberian craton)

Mantle xenoliths containing phlogopite and phlogopite–amphibole mineralization from kimberlites of the Kuoika field have been studied. Such xenoliths were found in two series of rocks: magnesian (Mg) pyroxenite–peridotite and Fe-type phlogopite–ilmenite hyperbasite. The ⁴⁰Ar/³⁹Ar phlogopite age (1600–1800 Ma) and Re–Os and oxygen isotope data in rocks and minerals of the first series of rocks allow us to suggest that Phl–Amph metasomatism of the lithospheric mantle under the Birekte block and its accretion to the Siberian craton occurred in the subduction zone. The second series of rocks is comagmatic to potassium ultramafites and mafites, finding in the Siberian Platform. The phlogopite ages (870–850 Ma) from Phl–Ilm ultramafites corresponds to the beginning of the breakup of the supercontinent Rodinia and is close to ancient age datings of the alkaline ultramafic-carbonatite Tomtor massif. Phlogopite from xenoliths with garnet is much younger in age (500–600 Ma).

     

Chronology of the formation of the gabbro-syenite-granite series of the Oshurkovo pluton, western Transbaikalia

This paper reports the results of Rb-Sr, ⁴⁰Ar-³⁹Ar, and U-Pb geochronological investigations for igneous and metamorphic rocks from the regions of the Oshurkovo basic massif. It was shown that the gabbro-syenite-granite complex that was formed there is similar to the bimodal basalt-rhyolite series of volcanic associations. Three major stages of magmatic activity were recognized: syenite-granite (132–127 Ma), basic (126–117 Ma), and granite (121–112 Ma). The silicic igneous rocks were formed owing to anatexis under the influence of heat released from the parent chamber of alkaline gabbroids.     

Late Paleozoic granitoids in western Transbaikalia: sequence of formation,sources of magmas,and geodynamics

The evolution of Late Paleozoic granitoid magmatism in Transbaikalia shows a general tendency for an increase in the alkalinity of successively forming intrusive complexes: from high-K calc-alkaline granites of the Barguzin complex (Angara–Vitim batholith) at the early stage through transitional from calc-alkaline to alkaline granites and quartz syenites (Zaza complex) at the intermediate stage to peralkaline granitoids (Early Kunalei complex) at the last stage. This evolution trend is complicated by the synchronous development of granitoid complexes with different sets and geochemical compositions of rocks. The compositional changes were accompanied by the decrease in the scales of granitoid magmatism occurrence with time. Crustal metaterrigenous protoliths, possibly of different compositions and ages, were the source of granitoids of the Angara–Vitim batholith. The isotopic composition of all following granitoid complexes points to their mixed mantle–crustal genesis. The mechanisms of granitoid formation are different. Some granitoids formed through the mixing of mantle and crustal magmas; others resulted from the fractional crystallization of hybrid melts; and the rest originated from the fractional crystallization of mantle products or the melting of metabasic sources with the varying but subordinate contribution of crustal protoliths. Synplutonic basic intrusions, combined dikes, and mafic inclusions, specific for the post-Barguzin granitoids, are direct geologic evidence for the synchronous occurrence of crustal and mantle magmatism. The geodynamic setting of the Late Paleozoic magmatism in the Baikal folded area is still debatable. Three possible models are proposed: (1) mantle plume impact, (2) active continental margin, and (3) postcollisional rifting. The latter model agrees with the absence of mafic rocks from the Angara–Vitim batholith structure and with the post-Barguzin age of peralkaline rocks of the Vitim province.     

A Pb isotope investigation of the Lovozero Agpaitic Nepheline Syenite,Kola Peninsula,Russia

For the first time Pb isotope composition was established in Lovozero rocks and raremetal ores, which is important for identifying their sources. The world’s largest layered intrusion of agpaitic nepheline syenite-the Lovozero alkaline massif—is located near the center of the Kola Peninsula in Russia. This superlarge complex plutonic body hosts the economically important loparite and eudiallyte deposits [1]. These deposits contain immense resources of REE, Nb, Ta, Zr, and constitute a world class mineral district. The Lovozero massif belongs to the Kola ultramafic alkaline and carbonatitic province (KACP) of Devonian age. Previous bulk rock studies have shown that the initial Sr and Nd isotope ratios of Lovozero rocks plot in the depleted mantle quadrant of Sr-Nd diagrams [2]. More recently, Hf isotope data obtained by Kogarko et al. (3) confirm that the Lovozero and Khibina massifs with ?_Hf between 6 and 8 are derived predominantly from a depleted mantle source. It was shown that Sr, Nd, and Hf abundances are significantly elevated in the Kola alkaline rocks, and thus their isotopic compositions are relatively insensitive to minor contamination by the overlying crustal rocks. By contrast, Pb in the KACP rocks is a much more sensitive indicator of a crustal component. In this paper we investigate the lead isotopic signature of all resentative types of Lovozero rocks (Table 1) in order to further characterize their mantle sources. The Lovozero massif consists of four intrusive phases. Rocks of phase I (mostly nepheline syenites) comprise about 5% of the total volume, phase II (urtites, foyaite, lujavrites) forms the main portion of the massif comprising 77% in volume, and phase III (eudialyte lujavrites) contributes about 18%. Country rocks are represented by Devonian effusive rocks and Archean gneisses.     

云开地块印支期变质-深熔作用:混合岩、片麻岩锆石U-Pb年代学和Hf同位素证据

云开地块中生代构造演化是华南地区的研究热点之一.通过对云开地块变质基底中的混合岩、片麻岩（5个样品）和花岗岩（1个样品）开展锆石LA-ICP-MS U-Pb定年,获得440.3±3.3 Ma、230.2±2.9 Ma、230.7±1.3 Ma、459.5±2.7 Ma、431.5±4.3 Ma、229.2±5.4 Ma、229.7±2.7 Ma 7组变质（深熔）或岩浆年龄和2组（样品1432-1和ID7-3）碎屑锆石年龄,碎屑锆石年龄范围均为太古代-新元古代,且具有~1.0 Ga年龄主峰,与天堂山岩群和云开群碎屑锆石年龄谱相似.区域资料表明云开地块天堂山岩群和云开群具有相似的物质组成,均形成于早古生代-新元古代,存在变质程度和物质面貌的差异;在加里东期构造-热事件的基础上,广泛叠加了印支期区域变质（深熔）-构造-流体作用影响.4个样品中（1431-1、1432-1、D116-3和ID7-3）锆石原位Lu-Hf同位素组成显示,加里东期变质和深熔锆石Lu/Hf同位素组成基本一致,应继承了原岩的同位素组成特征.印支期变质和深熔锆石Lu/Hf同位素组成不同,可能主要由变质作用和深熔作用的差异所致.以古-中元古代为主的地壳物质参与了加里东期和印支期变质-深熔作用,在加里东期和印支期深熔作用过程中,均有少量幔源物质的加入,印支期幔源物质的贡献相对显著.      

Structure,age, and ore potential of the Burpala rare-metal alkaline massif,northern Baikal region

The Burpala alkaline massif is a unique geological object. More than 50 Zr, Nb, Ti, Th, Be, and REE minerals have been identified in rare-metal syenite of this massif. Their contents often reach tens of percent, and concentrations of rare elements in rocks are as high as 3.6% REE, 4% Zr, 0.5% Y, 0.5% Nb, 0.5% Th, and 0.1% U. Geological and geochemical data show that all rocks in the Burpala massif are derivatives of alkaline magma initially enriched in rare elements. These rocks vary in composition from shonkinite, melanocratic syenite, nepheline and alkali syenites to alaskite and alkali granite. The extreme products of magma fractionation are rare-metal pegmatites, apatite-fluorite rocks, and carbonatites. The primary melts were related to the enriched EM-2 mantle source. The U-Pb zircon ages of pulaskite (main intrusive phase) and rare-metal syenite (vein phase) are estimated at 294 ± 1 and 283 ± 8 Ma, respectively. The massif was formed as a result of impact of the mantle plume on the active continental margin of the Siberian paleocontinent.