Patterns of fluid flow in the contact aureole of the Late Miocene Monte Capanne pluton (Elba Island,Italy): the role of structures and rheology

Fluid–rock interaction was investigated in the inner aureole of the Late Miocene Monte Capanne pluton on Elba Island (Tuscany, central Italy) by integrating structural, petrological, fluid inclusion, and stable isotope analyses. In the north-western sector of the aureole (Procchio–Spartaia area), calc–silicates alternate with nearly pure carbonate layers at the metre scale. Close to the pluton, the prograde metamorphic sequence includes calc–silicates that transition within a few metres to overlying nearly pure calcite marbles. The calc–silicates are extensively metasomatised to form massive wollastonite-grossular-bearing exoskarn. The mineralogical assemblage found in the marbles and the unshifted carbon and oxygen isotopic ratios in calcite attest that the fluid phase was internally buffered. On the other hand, the calc–silicates constituted channels for infiltration of disequilibrium fluids of magmatic origin. Fluid infiltration was enhanced by hydrofracturing and structurally-controlled by existing planar anisotropies in calc–silicates (layering and lithological boundaries). At the metamorphic peak (∼600°C and 1.5–2 kbar), the marble–calc–silicate interface acted as a barrier to fluids exsolved from the crystallising intrusions, separating two different flow patterns in the inner aureole: a high fluid–flux region on its higher grade side (Wol-zone) and a low fluid–flux region on the lower-grade side (Cpx zone). Results of this study: (1) documented that fluid pathways in the aureole rocks at the top of the pluton were largely horizontal, controlled by the lithological layering and the pluton–host rock contact; and (2) elucidated the primary control exerted by the structural and rheological properties of the host rocks on the geometry of fluid flow during pluton emplacement.     

The emplacement of the Late Miocene Monte Capanne intrusion (Elba Island,Central Italy): constraints from magnetic fabric analyses

Anisotropy of magnetic susceptibility (AMS) analysis has been carried out in the thermometamorphic aureole surrounding the Late Miocene Monte Capanne pluton (Elba Island, Central Italy). The identification and separation of the main carriers of the magnetic susceptibility by low-temperature and high-field AMS measurements demonstrate that a correct knowledge of the magnetic fabric is needed in order to use AMS for tectonic interpretations. Magnetic fabric data, combined with structural data from the aureole, and their comparison with data from the pluton itself, were used to constraint the mode of pluton emplacement. Results document an intimate linkage between the magmatic flow pattern and the syn-metamorphic fabrics acquired during pluton emplacement in the host rocks. The magnetic/structural fabric in the aureole rocks is dominated by flattening deformation and no systematic relationship with any regional tectonic feature is observed. These results suggest that local processes induced by magma ascent in the upper crust might have played a primary role in space generation for pluton emplacement in the Tuscan Magmatic Province, suggesting a revaluation of the modes of pluton emplacement during the post-orogenic evolution of the northern Apennine system as a whole.     

New data on the paleogeography of Southern Tuscany (Italy) since Late Miocene time

In order to add new data to the knowledge of the paleogeography of Southern Tuscany and the Tuscan shelf, a multidisciplinary study on the petrology and distribution of magmatic clasts of the widely exposed Messinian, Pliocene, and Quaternary sediments in Southern Tuscany was carried out. The magmatic clasts consist of porphyric aplites and subordinate granite porphyries, which derive from eroded subvolcanic acidic bodies. The porphyric aplite clasts were analyzed in detail to define their textural, petrographic, and chemical (major and trace elements, Sr and Nd isotopic composition) features. The porphyric aplite clasts show strong affinities with the 8.4–7.9 Ma old Capo Bianco aplite, whereas the granite porphyry clasts have affinities with the Portoferraio porphyry (ca. 8 Ma) which intruded the Cretaceous and Paleogene Flysch Units and the Ophiolitic Unit in central-western Elba Island (Northern Tyrrhenian Sea). The present outcrops of the Capo Bianco aplite in central Elba Island cannot be considered as the source rock for the Late Messinian gravels, because at that time such Capo Bianco aplite (located at the lower portion of the laccolitic stack) was there buried at several kilometers depth. However, other Capo Bianco-like aplitic bodies outcropped during the latest Miocene in the host rocks above and also around the 6.8 Ma M. Capanne Pluton in the western Elba areas. The exposure of such bodies was made possible by the activation of the central Elba detachment fault (=CEF), due to the uplift of the M. Capanne pluton. This uplift displaced a significant portion of the cover (including the upper portion of the laccolithic stack) of the granitoid body at about 6, 7 Ma, thus allowing the erosion of the lower part of the laccolith complex made up of the Capo Bianco aplite and of the Portoferraio porphyry and leaving still buried the M. Capanne pluton. The paleogeographic picture of Southern Tuscany arising from the collected evidences is the following: during Late Messinian, the clasts were dispersed by a SSW/NNE-trending complex fluvial system in the Colline Metallifere area. The Early Pliocene extensional tectonics cut off the detrital inputs from the Messinian source areas, because of the onset of the Piombino Channel and of the Campiglia–Gavorrano Ridge. During the Pliocene, the clasts were cannibalized from the previous sedimentary units and reached the easternmost areas due the eastward progressive uplift of the Colline Metallifere, likely connected with the coeval magmatic intrusions. Finally, the Quaternary regional uplift allowed a drainage reversal and a backward displacement of the aplitic clasts toward the Tyrrhenian coast. These data point to a rapidly evolving drainage pattern in Southern Tuscany during the considered time interval, which was mostly driven by the intrusion and uplift of the Messinian to Quaternary plutons. The morpho-tectonic evolution is well framed also within the models since long accepted for the Northern Apennine geodynamics, characterized by an overall eastward shift of the orogenic front.     

Isotopic Heterogeneities in the Granitic Intrusion of Monte Capanne (Elba Island, Italy) and Dating Concepts

The Monte Capanne granodiorite-rhyolite-aplite association exhibitsK-Ar ages which cluster around 7.9 m.y. Rb-Sr mineral ages andU-Pb dating on zircons, however, give 6.2 m.y. which is thepreferred age of emplacement. Evidence of subsequent eventsrelated to either dyke emplacement, or conductive/convectivecooling is provided by ages as young as 5.4 m.y. A significantheterogeneity of the whole-rock ⁸⁷Sr/⁸⁶Sr initial ratios, whichfall in the range 0.711–0.715, is interpreted as beingdue in part to exchanges with the low ⁸⁷Sr⁸⁶Sr country rocksat the deuteric stage via fluid interaction, and in part topossible different magma sources. In the geological future,these heterogeneities should be progressively smeared out bythe radioactive decay of ⁸⁷Rb, but even if the system remainsperfectly closed, a residual bias in excess of 100 m.y. shouldpermanently affect the theoretical isochron ages. It is inferredthat Rb-Sr isochron ages determined on samples of Precambrianage must be regarded with caution: a residual bias may somewhatalter the information obtained even from statistically acceptableisochrons. In this respect, when great accuracy is needed forplutonic emplacement ages (to within few m.y.), U-Pb datingappears to be less sensitive to inherited components and providesmore reliable chronometric information.     

Hercynite as the product of staurolite decomposition in the contact aureole of Vedrette di Ries,eastern Alps,Italy

Metapelitic hornfelses in the contact aureole of the Vedrette di Ries pluton exhibit the terminal decomposition of Zn-poor Fe-staurolite in a muscovite-quartz-free domain. The reaction takes place only within coarsegrained sillimanite that has replaced andalusite porphyroblasts during prograde metamorphism. The product is a gahnite-poor hercynitic spinel, which occurs as very small grains closely associated in space with resorbed staurolite. Microstructural observations indicate that bereynite growth postdates the pseudomorphs of sillimanite after andalusite. The textural evidence for a genetic relationship between hercynite and staurolite is confirmed by the identical Fe/Mg/Zn ratios of the two minerals, which causes the collinearity of hercynite, staurolite and Al₂SiO₅ in FeO–MgO–ZnO–Al₂O₃–SiO₂–H₂O composition space (FMZASH), and indicates hercynite formed by the reaction: Fe-staurolite = 3.85hercynite + 5.1sillimanite + 2.55quartz + 2H₂O Staurolite inclusions within andalusite did not break down to form hercynite, indicating a kinetic control, as well as little overstepping of the equilibrium conditions, of the reaction forming hercynite. Assuming overstepping did not occur, modelling of the reaction with existing thermodynamic data in the simplified FASH system suggests that the terminal breakdown of staurolite to form hercynite occurred at 2.5–3.75kbar and 585–655°C.     

Contact metamorphism and selective metasomatism of the layered Bellerophon Formation in the eastern Monzoni contact aureole, northern Italy

Summary The Monzoni intrusive complex in the central Western Dolomites comprises a series of small monzogabbro, monzodiorite and pyroxenite intrusions, which were emplaced in previously unmetamorphosed Permo-Triassic sediments during the mid-Triassic. Intrusion depth was less than five kilometres, and solidus temperatures were 900–1000 °C. An about one kilometre wide contact aureole developed in the country rocks for which peak metamorphic temperatures of about 800 and 500 °C are derived for the immediate intrusive contact and for a distance of 380 m from the contact, respectively. The Upper Permian Bellerophon Formation is an alternating sequence of dolomite-poor and dolomite-rich limestone layers. These two lithologies behaved differently during contact metamorphism. Whereas the layers derived from dolomite-poor precursors behaved as closed systems, the layers derived from dolomite-rich lithologies were much more susceptible to the infiltration of fluids or melts. The supply of substantial amounts of silica, alumina and ferric iron from the nearby intrusions lead to high temperature metasomatism of these lithologies. Substantial chemical alteration is discernible up to 65 m away from the intrusive contact and produced clinopyroxene rich skarns, which preferentially replaced the layers derived from dolomite-rich protoliths. The presence of clintonite and melilite in the skarn assemblages indicates formation temperatures in excess of 750 °C. In contrast, the high-grade equivalents of the originally dolomite-poor lithologies largely preserved their original chemical and stable isotope compositions and do not show any evidence of pervasive fluid or melt infiltration at high-grade conditions. The syn-metamorphic permeability structure of the Bellerophon Formation appears to have been largely controlled by the lithological layering and was heterogeneous on a decimetre scale. Together with a complex folding of the country rocks this makes large scale syn-metamorphic thermally driven fluid circulation unlikely in the Bellerophon Formation.     

REE-bearing minerals in a Ti-rich vein from the Adamello contact aureole (Italy)

Zirconolite, aeschynite-(Ce), titanite and apatite have been found as minor or accessory minerals in a Ti-rich (TiO₂=2.1–4.5 wt.%) hydrothermal vein occurring in dolomite marbles at the contact with a tonalite intrusion of the Tertiary Adamello batholith (northern Italy). The vein consists of four distinct mineral zones, comprising from margin to center: (1) forsterite+calcite, (2) pargasite+calcite+titanite+sulfides, (3) phlogopite +calcite+titanite+sulfides, and (4) titanian clinohumite +spinel+calcite+sulfides. Zirconolite occurs in two vein zones only: in the phlogopite zone it is invariably anhedral, often corroded, and exhibits complex chemical zonation patterns. In the titanian clinohumite zone zirconolite is idiomorphic and characterized by a pronounced discontinous chemical zoning, but shows no evidence of corrosion. The considerable compositional variation observed for zirconolite (in wt.%: (REE₂O₃)=0.74–16.8, UO₂=0.59–24.0, ThO₂=0.67–17.1) is due to the zoning, and may be attributed to four major substitutions described by the exchange vectors:

Geochemical hazard evaluation of sulphide-rich iron mines: The Rio Marina district (Elba Island,Italy)

Rio Marina mining district (Elba Island) is characterised by hematite + pyrite ore association and was exploited for iron till 1981, leaving waste rock dumps of several millions m³. The effect of open pit mining activity in this site is to produce acid mine drainage (AMD) processes leading to environmental pollution, testified by all the sampled waters (Giove stream, drainage channels, superficial pools and settling basin) which have pH values ranging from 2.08 to 3.35 and heavy metal concentrations that reach 903.16 mg/l for Fe, 45.02 mg/l for Mn, 10.08 mg/l for Zn and 1.75 mg/l for Cu. In the present work a space and time related approach to geochemical hazard evaluation was applied. The geochemical hazard is mainly related to high heavy metal concentration, acid mine drainage processes development and topographic setting. As all these parameters are related in space, hazard evaluation was performed by geostatistical methods. Fifty-four earth material samples (residual soils, waste rocks or debris materials) were collected in a central aligned 100 m mesh square grid. These were analysed for major elements by XRF, for Cu, Pb, Zn by ICP-AES and for AMD potential following the AMIRA procedure. The concentration of heavy metals was compared with Italian law limits. The overlap of Cu, Pb and Zn content maps show that at least one of these heavy metals exceed law limits in all the area. The AMD test results show that more than 50% of samples have a positive NAPP (Net Acid Producing Potential) that could reach 258.9 kg H₂SO₄/t. According to the obtained data, three main geochemical hazard classes were established and their distribution in the mining area was assessed. About 51% of the mining area surface belongs to the major hazard class, where AMD process occurs, about 49% belongs to an intermediate hazard class, where AMD process could occur only if certain conditions are met. Finally, the persistence of the AMD process in the Rio Marina area was evaluated on the basis of yearly rainfall, mining waters pH and NAPP values. A complete leaching of the first 0.25 m of the earth materials can retain the current environmental conditions for several centuries.     

The sagging deep-seated gravitational movements on the eastern side of Mt. Amiata (Tuscany,Italy)

The eastern side of the Mt. Amiata volcano is affected by a series of deep-seated gravitational slope deformations (DsGSDs). The San Piero and the Podere Mezzavia DsGSDs affect the lower part of the slope. The main escarpments are located on the outer edges of the lava flows, but the landslides mostly affect the pre-volcanic Ligurian Terrains. A deeper movement, possibly exceeding 100 m in thickness, is evidenced by a long trench at the base of the main escarpment that indicates a sagging type movement. This deeper movement is responsible for the activation of a series of superficial rock and mud flows that show evidence of ongoing activity. The most likely location of the sliding surface is the tectonized contact between the Santa Fiora and Argille a Palombini Fms within the Ligurian units, although the superficial landslides prevent our determining with certainty if a clear-cut sliding surface already developed connecting the upper and the lower parts of the slope. These DsGSDs were activated along the flanks of a larger movement that affects the lava flow units cropping out in the middle slope of the volcano. A long main escarpment, secondary escarpments, trenches and borehole data suggest that the thickness could locally exceed 200 m and generate another sagging type movement. Up-slope and up-movement-facing counterscarps indicate the existence of a listric elongated spoon-shaped compound embryonic sliding surface. This sagging, which hosts the towns of Abbadia San Salvatore and Piancastagnaio, appears to be in a quiescent stage, according to preliminary monitoring with a global positioning system (GPS) network. The downcutting of the river network along the softer Pliocene terrains of the Radicofani basin is enhanced by the general uplift of the Apennines and seems to be the major factor in the activation of these DsGSDs.     

Fluid‐fluxed melting and melt loss in a syntectonic contact metamorphic aureole from the Variscan eastern Pyrenees

Open‐system behaviour through fluid influx and melt loss can produce a variety of migmatite morphologies and mineral assemblages from the same protolith composition. This is shown by different types of granulite facies migmatite from the contact aureole of the Ceret gabbro–diorite stock in the Roc de Frausa Massif (eastern Pyrenees). Patch, stromatic and schollen migmatites are identified in the inner contact aureole, whereas schollen migmatites and residual melanosomes are found as xenoliths inside the gabbro–diorite. Patch and schollen migmatites record D1 and D2 structures in folded melanosome and mostly preserve the high‐T D2 in granular or weakly foliated leucosome. Stromatic migmatites and residual melanosomes only preserve D2. The assemblage quartz–garnet–biotite–sillimanite–cordierite±K‐feldspar–plagioclase is present in patch and schollen migmatites, whereas stromatic migmatites and residual melanosomes contain a sub‐assemblage with no sillimanite and/or K‐feldspar. A decrease in X _Fe (molar Fe/(Fe + Mg)) in garnet, biotite and cordierite is observed from patch migmatites through schollen and stromatic migmatites to residual melanosomes. Whole‐rock compositions of patch, schollen and stromatic migmatites are similar to those of non‐migmatitic rocks from the surrounding area. These metasedimentary rocks are interpreted as the protoliths of the migmatites. A decrease in the silica content of migmatites from 63 to 40 wt% SiO₂ is accompanied by an increase in Al₂O₃ and MgO+FeO and by a depletion in alkalis. Thermodynamic modelling in the NCKFMASHTO system for the different types of migmatite provides peak metamorphic conditions ~7–8 kbar and 840 °C. A nearly isothermal decompression history down to 5.5 kbar was followed by isobaric cooling from 840 °C through 690 °C to lower temperatures. The preservation of granulite facies assemblages and the variation in mineral assemblages and chemical composition can be modelled by ongoing H₂O‐fluxed melting accompanied by melt loss. The fluids were probably released by the crystallizing gabbro–diorite, infiltrating the metasedimentary rocks and fluxing melting. Release of fluids and melt loss were probably favoured by coeval deformation (D2). The amount of melt remaining in the system varied considerably among the different types of migmatite. The whole‐rock compositions of the samples, the modelled compositions of melts at the solidus at 5.5 kbar and the residues show a good correlation.     

Late Oligocene to early Miocene humidity change recorded in terrestrial sequences in the Ili Basin (south‐eastern Kazakhstan,Central Asia)

Enhanced aridification of Central Asia driven by the combined effects of orogenic surface uplift, Paratethys retreat, changes in atmospheric moisture transport and global cooling is one of the most prominent Cenozoic climate change events of the Northern Hemisphere. Deciphering regional long‐term patterns of Central Asian hydrology is, therefore, a key element in understanding the role of Northern Hemisphere mid‐latitude drying in the global hydrological system. This study characterizes long‐term palaeoenvironmental conditions between the late Oligocene and early Miocene in south‐eastern Kazakhstan based on stable isotopes, elemental geochemistry and laser ablation uranium–lead geochronology from alluvial, fluvial and pedogenic deposits. Sedimentary facies and geochemical weathering indices suggest an increased surface and groundwater discharge fed by orographically enhanced precipitation in the Tien Shan hinterland. In contrast, pedogenic stable isotope data and elevated rates of magnesium fixation in clay minerals mirror enhanced rates of evaporation in the vadose zone due to protracted aridification. This study posits that pronounced surface uplift of the Tien Shan Mountains during the Oligocene–Miocene transition promoted regionally increased orographic precipitation and the development of fluvial discharge systems.     

Migration of geothermal fluids in extensional terrains: the ore deposits of the Boccheggiano-Montieri area (southern Tuscany, Italy)

An integrated study based on fluid inclusion, δ¹⁸O composition and structural analyses was carried out on a Pliocene fossil hydrothermal system, located to the South of the present active Larderello geothermal field, in the Boccheggiano-Montieri area. The study area is typified by mineralized cataclastic levels related to Late Oligocene–Early Miocene thrust surfaces, and to the following two generations of normal faults of Miocene and Pliocene ages, respectively. Within the damage zone of the Pliocene Boccheggiano fault, the mineralization is mainly made up of quartz and pyrite. Quartz + Pb–Zn sulfides, or quartz + Pb–Zn sulfides + fluorite + carbonates assemblages occur instead in the older cataclastic levels. Two generations of liquid-rich fluid inclusions were recognized in quartz and fluorite: the first one, with homogenization temperatures ranging between 172 and 331°C and salinity between 0.0 and 8.8 wt.% NaCl_equiv., records the early stage of hydrothermal activity. The second generation of fluid inclusions documents a later stage, with homogenization temperature from 124 to 288°C and salinity from 0.2 to 1.9 wt.% NaCl_equiv.. Fluid inclusions analyses also indicate that mixing of fluid with distinct salinities and/or temperatures was a widespread process during the early stage, and that fluid temperatures decreased moving from the Boccheggiano fault toward the more distal and older cataclastic levels. The δ¹⁸O values of water in equilibrium with hydrothermal quartz, which range from −5.7 to −0.1‰, are related to the circulation of meteoric water mixed with saline water that leached the evaporite level and enriched in δ¹⁸O through water–rock interaction, and/or with magmatically derived fluids. Results indicate that the damage zone of the Pliocene Boccheggiano fault represented the main channel for the flow of meteoric water, which was heated at depth, then mixed with high salinity fluids, and finally ascend to infiltrate along the older cataclastic levels. Our results, based on fluid inclusions, oxygen isotopic compositions and structural analyses indicate that a single fluid flow path run through the damage zone of the Boccheggiano fault and the older cataclasites, which were thus hydraulically connected.     

Sericitic alteration at the La Crocetta deposit (Elba Island,Italy): interplay between magmatism,tectonics and hydrothermal activity

The La Crocetta mine near Porto Azzurro (Elba Island, Tuscany, Italy) is an important producer of raw material for the ceramic industry. Exploitation focuses on a pervasively sericitized porphyritic aplite of the Tuscan Magmatic Province, locally known as "eurite", which underwent significant potassium enrichment during sericitic alteration. Eurites are located along the hanging wall of the Elba Centrale Fault, a low-angle extensional lineament of regional significance. A later carbonatization stage, apparently associated with high-angle extensional tectonics, locally overprinted the sericitized facies. It is expressed by carbonate ± pyrite ± quartz veins, with adverse effects on ore quality. Sericitization was accompanied by addition of potassium, and loss of Na (± Ca, Fe). Rubidium was not enriched along with potassium during sericitization, contrary to what would be expected for interaction with late-magmatic fluids. New ⁴⁰Ar–³⁹Ar data from eurites provide an isochron age of about 6.7 Ma for the sericitization, whereas the age of the unaltered protolith is ca. 8.8 Ma. Field evidence indicates the Elba Centrale Fault to be the main channel for the hydrothermal fluids. On the other hand, the involvement of heat and/or fluids contributed by the Porto Azzurro pluton, which crops out in the La Crocetta area, is ruled out by field, geochemical and geochronological data (⁴⁰Ar–³⁹Ar age of Porto Azzurro =5.9 Ma, i.e. significantly younger than the sericitization event). Fluid inclusion studies suggest that sericitization was associated with a low-temperature (<250 °C) hydrothermal system. Fluids were locally boiling, of variable salinity (4–17 wt% NaCl equiv.), and contained some CO₂ (XCO₂≤0.027). Their ultimate source is not unequivocally constrained; meteoric and/or magmatic contributions may be possible. Low-salinity (≤2.6 wt% NaCl equiv.), low-temperature (<250 °C) fluids are associated with the late carbonate veining. They are considered to be of dominantly meteoric nature because of their low salinity. In summary, sericitization at La Crocetta is regarded as the product of a detachment fault-related, low temperature hydrothermal system, resulting from the structurally controlled focusing of meteoric and possibly magmatic fluids. Hence, potential targets for exploration for similar resources are represented by aplitic bodies located in the hanging wall of Elba Centrale Fault. Electronic supplementary material to this paper can be obtained by using the Springer LINK server located at http://dx.doi.org/10.1007/s00126-002-0279-2.     

Thermal modelling of the Larderello geothermal field (Tuscany,Italy)

We present a 3-D thermal model of the Larderello geothermal field (Tuscany) to evaluate (1) the extent and contribution of the heat transfer mechanisms (conduction vs. convection) at the intermediate-upper crust levels, (2) the variability of the heat and mass fluxes entering from below and (3) the crucial role of the formation permeability. The model, composed by three main layers, considers the upper 10 km of the crust to better constrain the simulations with experimental data from borehole, fluid inclusion studies and hypocentral distributions. Several sets of simulations were carried out with different bottom boundary temperatures and different formation permeabilities for the two deeper layers. The results indicate that the present temperature (T) and pressure distributions in the Larderello field require deep reservoir rocks with higher permeability than the overlying capping units and underlying intermediate crust. Permeability values of 1 mDarcy for the reservoir rocks are enough to allow fluid convection, if the temperature at 10 km depth is as high as 500 ± 50°C. The presence of localized zones with formation permeability 50–100 times higher than the surrounding rocks strongly favours the migration of over-pressurized fluids, which episodically break through the overburden, feeding the presently exploited geothermal fields.     

Late Miocene fish otoliths from the Colombacci Formation (Northern Apennines,Italy): implications for the Messinian ‘Lago‐mare’ event

A fish otolith assemblage from the Messinian ‘Lago‐mare’ deposits of the Colombacci Formation cropping out in the Montecalvo in Foglia Syncline, Marche, central Italy, is described. The assemblage displays a low diversity and consists of seven taxa belonging to three families: the Gobiidae, Myctophidae and Sciaenidae. Sciaenid otoliths are the most abundant elements representing 88% of the entire assemblage. The palaeoecological analysis reveals a coastal shallow marine environment strongly influenced by continental outflow. The low diversity and high abundance of the euryecious sciaenids are indicative of a very simplified food web, which probably represented an ecological response to the fluctuating environmental parameters and available food resources. The fish remains documented here provide an unambiguous evidence that normal marine conditions were present in the Mediterranean, at least in the upper part of the ‘Lago‐mare’ event, and unquestionably demonstrate that the marine refilling preceded the Mio‐Pliocene boundary. These findings clearly demonstrate that fishes, because of their mobility and migratory behaviour, represent a useful tool for the large‐scale interpretation of the environmental conditions of the Messinian Mediterranean water body. The necessity of a new scenario of palaeoenvironmental evolution for the post‐evaporitic Messinian of the Mediterranean is also discussed. Copyright © 2006 John Wiley & Sons, Ltd.     

Late Holocene vertical deformation along the coast of Pantelleria Island (Sicily Channel, Italy)

According to historical reports, the north-eastern coastal sector of the volcanic Pantelleria Island (Sicily Channel, Italy) was uplifted up to 1.0 m a.s.l. in the year preceding the October 1891 offshore eruptive event. To better understand the nature and timing of coastal uplift, a detailed survey of morphological and biological indicators of raised palaeo-shorelines has been carried out along the island coastline. This survey identified raised palaeo-shoreline levels at three elevation ranges: 2.5–4.2 m a.s.l. (highest), 1.5–2.7 m a.s.l. (intermediate) and 0.4–1.0 m a.s.l. (lowest). Radiocarbon dating on samples of corals and vermetids placed tight temporal constraints on the uplifting of the raised shorelines. In general, they indicate that the north-eastern sector of the island, centred on the area of Cala del Gadir, has undergone major uplifting, tilting the island towards the southwest from 900 years ago. Applying accurate corrections for sea-level variations, the total amount of volcano-tectonic uplift can be estimated. Uplift rates up to 5 mm/a suggest that the vertical deformation was caused by inflation processes related to magmatic intrusion along feeding fissures.     

Late Quaternary multiple incised valley systems: An unusually well‐preserved stratigraphic record of two interglacial valley‐fill successions from the Arno Plain (northern Tuscany,Italy)

Un‐fragmented stratigraphic records of late Quaternary multiple incised valley systems are rarely preserved in the subsurface of alluvial‐delta plains due to older valley reoccupation. The identification of a well‐preserved incised valley fill succession beneath the southern interfluve of the Last Glacial Maximum Arno palaeovalley (northern Italy) represents an exceptional opportunity to examine in detail evolutionary trends of a Mediterranean system over multiple glacial–interglacial cycles. Through sedimentological and quantitative meiofauna (benthic foraminifera and ostracods) analyses of two reference cores (80 m and 100 m long) and stratigraphic correlations, a mid‐Pleistocene palaeovalley, 5 km wide and 50 m deep, was reconstructed. Whereas valley filling is chronologically constrained to the penultimate interglacial (Marine Isotope Stage 7) by four electron spin resonance ages on bivalve shells (Cerastoderma glaucum), its incision is tentatively correlated with the Marine Isotope Stage 8 sea‐level fall. Above basal fluvial‐channel gravels, the incised valley fill is formed by a mud‐prone succession, up to 44 m thick, formed by a lower floodplain unit and an upper unit with brackish meiofauna that reflects the development of a wave‐dominated estuary. Subtle meiofauna changes towards less confined conditions record two marine flooding episodes, chronologically linked to the internal Marine Isotope Stage 7 climate‐eustatic variability. After the maximum transgressive phase, recorded by coastal sands, the interfluves were flooded around 200 ka (latest Marine Isotope Stage 7). The subsequent shift in river incision patterns, possibly driven by neotectonic activity, prevented valley reoccupation guiding the northward formation of the Last Glacial Maximum palaeovalley. The applied multivariate approach allowed the sedimentological characterization of the Marine Isotope Stage 7 and Marine Isotope Stage 1 palaeovalley fills, including shape, size and facies architecture, which revealed a consistent river‐coastal system response over two non‐consecutive glacial–interglacial cycles (Marine Isotope Stages 8 to 7 and Marine Isotope Stages 2 to 1). The recurring stacking pattern of facies documents a predominant control exerted on stratigraphy by Milankovitch and sub‐Milankovitch glacio‐eustatic oscillations across the late Quaternary period.     

Gypsum–anhydrite transformations in Messinian evaporites of central Tuscany (Italy)

The Messinian succession of Tuscany (central Italy) contains three evaporitic units. Among the several exposed evaporitic lithofacies, only selenitic gypsum precipitated directly from evaporating brines. All the other facies, nodular microcrystalline gypsum, gypsarenites and gypsum laminites, despite their macroscopic differences, display the same petrographic textures, indicating that they are the product of dehydration of gypsum to give anhydrite which has been successively rehydrated to secondary gypsum. These secondary facies show an entire array of textures ranging from cloudy ameboid (xenotopic) with anhydrite relics, to idiotopic without anhydrite relics, that are here interpreted as a sequence of progressive stages of rehydration. The presence of completely hydrated petrofacies at the core of nodules which display a less hydrated rim suggests that these rocks have undergone at least two cycles of a dehydration–rehydration process. This interpretation is supported by the presence of satin spar veins that are replaced by microcrystalline gypsum. Satin spar itself is considered to be a by-product of anhydrite hydration. The first dehydration–rehydration event affected the entire gypsum deposit, producing a completely hydrated (idiotopic) facies together with satin spar veins; the second affected only veins, fractures and the rims of nodules, turning the first generation of satin spar and idiotopic gypsum into cloudy ameboid gypsum. Sedimentary structures typical of sabkha environments indicate for the youngest formation that the first dehydration and rehydration process occurred syndepositionally. The preservation of primary gypsum facies only at sites with condensed sections, indicate for the oldest two formations that the first dehydration event occurred upon burial. This event has been estimated to have occurred in the earliest Pliocene. After the Early Pliocene, dehydration was favored even at shallow depths, due to an increased heat flow related with the emplacement of local crustal magmatic bodies. Rehydration possibly occurred when these formations were uplifted and exposed to ground and/or meteoric water. The Volterra Basin has undergone alternating subsidence and uplift events, that can account for two dehydration–rehydration processes at least, also driven by alternating circulation, in the tectonic fractures, of fresh and salty water, the latter derived from dissolution of Messinian halite.