Phytoplankton production characteristics in the upper and lower pools of Volga reservoir HPPs

Data of field observations of 1989–1991 were used to analyze the habitat conditions and the structural–functional characteristics of phytoplankton in near-dam reaches of Volga reservoirs. Averaged data show negative trends, manifesting themselves in a decline in the characteristics of phytoplankton development and production–destruction processes in the lower pools of HPPs against the background of a decrease in water temperature, water transparency, and dissolved oxygen content. Saprobity indices show water quality in near-dam reaches to correspond to β-mesosaprobic zone and not to deteriorate in the lower pools, despite the decline in organic matter destruction. By the combination of abiotic characteristics and phytoplankton production indices, the upper and lower pools of Volga HPP reservoirs occupy close positions in the shortest network and fall in the clusters formed by stations in appropriate reservoirs.     

Phytoplankton dynamics in the central Great Barrier Reef—II. Primary production

Water column primary production was measured 43 times over a 3-year period (1983–1985) on the outer shelf of the central Great Barrier Reef province and in the adjacent East Australian Current. No seasonal production cycle could be established. Estimated daily production rates in shelf and offshore waters ranged between 0.1 and 1.5 g C m⁻², with most between 0.2 and 0.7 g C m⁻². Annual primary production during 1983 in mid-shelf, shelf break and offshore zones was estimated to be 183, 167 and 211 g C m⁻², respectively. Annual production by the<10μm size fraction at the same sites was 114, 94 and 127 g C m⁻², 62, 56 and 60% of total production, respectively. Corresponding proportions of chlorophyll standing crop in the<10μm fraction were 65, 85 and 79%. In a subset of the above experiments, picoplankton (<2μm size fraction) accounted for 37–99% of total water column production and 32–85% of the chlorophyll standing crop. At first order, annual phytoplankton plus coral reef primary production on the outer shelf in the central GBR is estimated to be 404 g C m⁻², with phytoplankton contributing 37%.     

Sedimentation und Phosphorhaushalt im Vierwaldstättersee (Horwer Bucht) und im Rotsee

In 1969/70, chemical and physical parameters, phytoplankton and recent sedimentation at different levels were investigated in the mesotrophic Lake of Lucerne (Horw Bay) and in the highly eutrophic Rotsee. The rates of sedimentation came to 1277.4 g dry matter/m²·year in Horw Bay and to 879.3 g dry matter/m²·year in the Rotsee. The chemical analysis of sediments included the following components: total organic substance (loss on ignition), organic C, clay minerals (HCl-insoluble fraction), Ca, Mg, P, N, Fe and Mn. The Rotsee is distinguished by higher nutrient concentrations, higher rates of sedimentation (exceptions: clay minerals, Fe, to a certain extent N and Mn) and by a greater biomass of phytoplankton. The distribution and succession of selected species and groups of phytoplankton are discussed, the velocity of sinking, the degradation, the growth dynamics and the measure of trophic state are calculated. For both lakes, a phosphorus and a nitrogen balance have been drawn up. The N:P ratio continually decreases running through the nutrient cycle from the input to the storing into the bottom sediments. The intrabiocoenotic phosphorus cycle in the epilimnion is very intensive and supplies approximately two thirds of the nutrient requirements for primary production in both the Horw Bay and the Rotsee.     

Environmental effect of produced water from North Sea oil operations

Produced water from North Sea oil reservoirs contains substantial amounts (about 1g I⁻¹) of non-hydrocarbon organic matter, largely as salts of acetic, propionic and butyric acids, as well as some 20–40 mg I⁻¹ of dissolved hydrocarbons such as benzene, toluene and xylene. The non-hydrocarbon components originate in water in the oil-bearing formation. All of the organic matter can be accounted for, within analytical accuracy. The water also contains some 20–30 mg I⁻¹ of ammoniacal nitrogen and a number of inorganic components.At peak water production from production installations in the North Sea some 1−2 × 10⁵ tonnes yr⁻¹ of organic acids will be discharged in the U.K. sector of the North Sea.The ready biodegradability of the organic constituents and the low toxicity of produced water have been confirmed by direct measurement; acute toxicity is unlikely at dilutions of greater than 100 fold.Dispersion has been modelled and tested in the laboratory indicating some 1000 fold dilution within less than 50 m of the discharge.The laboratory studies are supported by field observations. Any direct deleterious effects are limited to the immediate vicinity of the discharge (within a few tens of metres).     

Organic and inorganic matter in Louisiana coastal waters: Vermilion, Atchafalaya, Terrebonne, Barataria, and Mississippi regions

Chromophoric dissolved organic matter (CDOM) spectral absorption, dissolved organic carbon (DOC) concentration, and the particulate fraction of inorganic (PIM) and organic matter (POM) were measured in Louisiana coastal waters at Vermilion, Atchafalaya, Terrebonne, Barataria, and Mississippi River locations, in 2007-2008. The range of CDOM was 0.092 m⁻¹ at Barataria in June 2008 to 11.225 m⁻¹ at Mississippi in February 2008. An indicator of organic matter quality was predicted by the spectral slope of absorption coefficients from 350 to 412 nm which was between 0.0087 m⁻¹ at Mississippi in May 2008 and 0.0261 m⁻¹ at Barataria in June 2008. CDOM was the dominant component of light attenuation at Terrebonne and Barataria. Detritus and CDOM were the primary components of light attenuation at Vermilion, Atchafalaya, and Mississippi. DOC ranged between 65 and 1235 μM. PIM ranged between 1.1 and 426.3 mg L⁻¹ and POM was between 0.3 and 49.6 mg L⁻¹.     

Storage,properties and seasonal variations in fine‐grained bed sediment within the main channel and headwaters of the River Sanginjoki,Finland

Lowland catchments in Finland are intensively managed, promoting erosion and sedimentation that negatively affects aquatic environments. This study quantified fine‐grained bed sediment in the main channel and upstream headwaters of the River Sanginjoki (399.93 km²) catchment, Northern Finland, using remobilization sediment sampling during the ice‐free period (May 2010–December 2011). Average bed sediment storage in river was 1332 g m^?2. Storage and seasonal variations were greater in small headwater areas (total bed sediment storage mean 1527 g m^?2, range 122–6700 g m^?2 at individual sites; storage of organic sediment: mean 414 g m^?2, range 27–3159 g m^?2) than in the main channel (total bed sediment storage: mean 1137 g m^?2, range 61–4945 g m^?2); storage of organic sediment: mean 329 g m^?2, range 13–1938 g m^?2). Average reach‐specific bed sediment storage increased from downstream to upstream tributaries. In main channel reaches, mean specific storage was 8.73 t km^?1, and mean specific storage of organic sediment 2.45 t km^?1, whereas in tributaries, it was 126.94 and 34.05 t km^?1, respectively. Total fine‐grained bed sediment storage averaged 563 t in the main channel and 6831 t in the catchment. The proportion of mean organic matter at individual sites was 15–47% and organic carbon 4–455 g C m^?2, with both being highest in small headwater tributaries. Main channel bed sediment storage comprised 52% of mean annual suspended sediment flux and stored organic carbon comprised 7% of mean annual total organic carbon load. This indicates the importance of small headwater brooks for temporary within‐catchment storage of bed sediment and organic carbon and the significance of fine‐grained sediment stored in channels for the suspended sediment budget of boreal lowland rivers. Copyright © 2013 John Wiley & Sons, Ltd.     

The effect of tributaries on the environmental conditions in the Enisei River

Multidisciplinary studies carried out in 2007–2008 revealed the features of concentration dynamics of biogenic and organic substances, bacterio- and phytoplankton, and chlorophyll in different reaches of the Enisei River. By the development state of bacterio- and phytoplankton, saprobity index, total primary production g O₂/(m² day), and self-purification index, the water refers to the third quality class (satisfactorily clean), β-mesosaprobic. The Enisei refers to the oligotrophic type upstream of the Angara mouth and to the mesotrophic type downstream of it.     

Heavy Metals in Bottom Sediment in the Upper and Lower Volga

Heavy metal concentrations in bottom sediment in some reaches of the Upper (the Ivankovo Reservoir) and Lower Volga (from Volgograd to the mouth offshore area). The bottom sediment in the Ivankovo Reservoir are shown to be heavily polluted by Cu and Zn and to a lesser extent, by Co and Ni; heavy pollution with Ni and Cr and moderate pollution with Zn and Mn were recorded in the Lower Volga. Principal component procedure was used to assess bottom sediment pollution. The role of organic matter in the formation of the Ivankovo Reservoir bottom sediment pollution with heavy metals is shown to be moderate because of the weak correlation between heavy metal concentration and organic matter content of bottom sediment. The same is true for the Lower Volga because of low organic matter content of bottom sediment. The major role in the redox cycle of elements is shown to belong to Fe in the Ivankovo Reservoir and Mn in the Lower Volga.     

Relative quantification of wind erosion in argan woodlands in the Souss Basin,Morocco

The endemic argan woodlands cover large parts of South Morocco and create a characteristic landscape with areas of sparsely vegetated and bare soil surfaces between single trees. This unique ecosystem has been under extensive agrosilvopastoral management for centuries and is now at risk of degradation caused by overgrazing and increasing scarcity and variability of rainfall. To investigate susceptibility to wind erosion, we conducted an experimental–empirical study including wind tunnel tests and a drone-generated digital elevation model and quantified wind-erodible material on five different associated surface types by means of sediment catchers. The highest emission flux was measured on freshly ploughed surfaces (1875 g m^–2 h^–1), while older ploughed areas with a re-established crust produced a much lower emission flux (795 g m^–2 h^–1). Extensive tillage may have been a sustainable practice for generations, but increasing drought and uncertainty of rainfall now lead to an acute risk of severe soil erosion and dust production. The typical crusted surfaces characterized by residual rock fragment accumulation and wash processes produced the second highest emission flux (1,354 g m^–2 h^–1). Material collected from tree-shaded areas (933 g m^–2 h^–1) was revealed to be a considerable source of organic material, possibly affecting substrate conditions positively on a larger regional scale. The lowest flux was measured on rock fragment-covered surfaces (301 g m^–2 h^–1). The data show that open argan woodland may be a considerable source for wind erosion and dust production, depending on surface characteristics strongly related to management. An adapted management must include the conservation of argan trees to offer a promising approach to prevent severe wind erosion and dust production and mitigate possible impacts of land-use change and climate change related shifts in wind and rainfall patterns. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd     

Seasonal variability of primary production in a fjord ecosystem of the Chilean Patagonia: Implications for the transfer of carbon within pelagic food webs

We characterized the seasonal cycle of productivity in Reloncaví Fjord (41°30′S), Chilean Patagonia. Seasonal surveys that included measurements of gross primary production, community respiration, bacterioplankton secondary production, and sedimentation rates along the fjord were combined with continuous records of water-column temperature variability and wind forcing, as well as satellite-derived data on regional patterns of wind stress, sea surface temperatures, and surface chlorophyll concentrations. The hydrography and perhaps fjord productivity respond to the timing and intensity of wind forcing over a larger region. Seasonal changes in the direction and intensity of winds, along with a late-winter improvement in light conditions, may determine the timing of phytoplankton blooms and potentially modulate productivity cycles in the region.Depth-integrated gross primary production estimates were higher (0.4–3.8 g C m^?2 d^?1) in the productive season (October, February, and May), and lower (0.1–0.2 g C m^?2 d^?1) in the non-productive season (August). These seasonal changes were also reflected in community respiration and bacterioplankton production rates, which ranged, respectively, from 0.3 to 4.8 g C m^?2 d^?1 and 0.05 to 0.4 g C m^?2 d^?1 during the productive and non-productive seasons and from 0.05 to 0.6 g C m^?2 d^?1 and 0.05 to 0.2 g C m^?2 d^?1 during the same two periods. We found a strong, significant correlation between gross primary production and community respiration (Spearman, r=0.95; p<0.001; n=12), which suggests a high degree of coupling between the synthesis of organic matter and its usage by the planktonic community. Similarly, strong correlations were found between bacterioplankton secondary production and both gross primary production (Spearman, r=0.7, p<0.05, n=9) and community respiration (Spearman, r=0.8, p<0.05, n=9), indicating that bacterioplankton may be processing an important fraction (8–59%) of the organic matter produced by phytoplankton in Reloncaví Fjord. In winter, bacterial carbon utilization as a percentage of gross primary production was >100%, suggesting the use of allochthonous carbon sources by bacterioplankton when the levels of gross primary production are low. Low primary production rates were associated with a greater contribution of small cells to autotrophic biomass, highlighting the importance of small-sized plankton and bacteria for carbon cycling and fluxes during the less productive winter months. Fecal pellet sedimentation was minimal during this period, also suggesting that most of the locally produced organic carbon is recycled within the microbial loop. During the productive season, on the other hand, the area exhibited a great potential to export organic matter, be it to higher trophic levels or vertically towards the bottom.     

An isotopic model for the origin of autochthonous organic matter contained in the bottom sediments of a reservoir

Geochemical analysis of surface sediment samples collected in 2005 and 2006 was used to evaluate the potential sources of the organic matter present in sediments of southeast Poland's Solina Reservoir.Statistical analysis of sediment variables(carbon to nitrogen ratio, and the carbon 13 and nitrogen 15 isotope ratios) determined for the organic fraction indicated significant spatial variability with respect to sources of organic matter. A binary mixing model was developed from literature sources to predict the relative contributions of allochthonous and autochthonous production to sediment organic matter.Autochthonous production was shown to account for 60-75% of bulk sedimentation in the lacustrine parts of the reservoir, near the dam. In contrast, autochthonous production accounted for only 25% of sedimentation in the riverine zone receiving stream inputs. Statistical analysis identified the δ~(15)N of organic matter as the best predictor of the source of organic matter. Multiple regression analysis indicated that two water-quality variables(nitrate and dissolved silica) were significantly related to the δ~(15)N signature of organic matter. This led to a conclusion that limnetic nitrate and dissolved silica concentrations were regulating organic matter production in the Solina Reservoir.     

Relationships between the Concentrations of Phyto-Pigments,Nitrogen, and Phosphorus in Bottom Deposits of Water Reservoirs

Samples characterizing the horizontal distribution of bottom deposits of different types in the Upper Volga reservoirs were used to study the statistical relationship between the indicators of the potential and actual trophy of water bodies. These indicators are the amount of biogenic elements (the total nitrogen and phosphorus) and phyto-pigments (in the dry and wet masses of soil and in its organic fraction). The relationship between the above indicators for the channel deposits from the Upper Volga reservoirs and for the deposits in the lake hollows is found to he linear.     

Balance evaluation of the role of lateral inflow in water quality formation in the reservoirs of the water divide reach of the Moscow Canal

Estimates of the chemical load of reservoirs in the water divide reach of the Moscow Canal in terms of phosphates, ammonium ion, nitrates, chlorides, organic matter (by permanganate oxidability), and BOD are given. Matter fluxes for lateral tributaries are compared with the fluxes along the canal, and the obtained relationships are used to evaluate seasonal variations in the role of lateral inflow in water quality formation in the reservoirs. The role of tributaries is shown to increase with decreasing volumes of Volga water transfer.     

Atmospheric Particulate Concentration Measured in an Urban Area Bandung

— Atmospheric particulate concentration for total suspended particles (TSP) and for PM₁₀ (particulate matter under 10 micron) was measured in Jalan Braga and ITB campus, Bandung. Six samples were collected over one- or two-day time periods using High Volume Sampler (HVS) for TSP and Low Volume Sampler (LVS) or Anderson Cascade Impactor for PM₁₀. Samples were further analyzed to determine concentrations of metals, sulfate and nitrate. Concentration of NO_x (NO and NO₂) was also measured hourly and simultaneously during the sampling period. The results from this study show that the atmospheric particulate concentration in Jalan Braga for TSP ranged from 304.04 to 363.17, and for PM₁₀ concentration ranged from 277.02 to 336.44 μg/m³. The lead concentrations were 1.42–2.37 μg/m³ in the TSP and 0.81–1.57 μg/m³ in the PM₁₀. The nitrate concentrations were 5.89–6.51 μg/m³ and 2.27–3.45 μg/m³ for the TSP and PM₁₀, respectively. The hourly NO_x concentration varied between 0.14–0.35 ppm. The total elements (metals, sulfate and nitrate) found in the samples contribute from 20 to 25% of the total particulate concentration.     

The effect of Hurricane Lili on the distribution of organic matter along the inner Louisiana shelf (Gulf of Mexico,USA)

On October 3, 2002 Hurricane Lili made landfall on a previously studied region of the inner Louisiana shelf as a Category 2 storm with winds over 160 km/h. A week after the hurricane, major impacts of the storm were not evident in the water column except for the lower than expected inshore salinities (∼12 psu) for this time of year, which was characterized by low river discharge. Turbidity profiles were typical of those measured during previous investigations with suspended sediment concentrations >75 mg/L at inshore stations and <50 mg/L in surface waters and offshore. The implication is that the sediments resuspended during the hurricane settled soon after the storm passage. Water column particulate organic carbon (POC) concentrations ranged from 0.1 to over 2.0 mg/L, with the highest concentrations measured near the seabed and in the inshore portions of the study area. Suspended particles were characterized by low organic matter content (%POC of 0.5–2 wt%), low chlorophyll:POC ratios (Chl:POC<4 mg/g) and moderately elevated POC:particulate nitrogen ratios (POC:PN of 10–14 mol/mol), all suggesting their source was locally resuspended seabed sediment rather than from algal biomass or land-derived vascular plant detritus.Post hurricane sediment deposition throughout the study area resulted in a storm layer that ranged from <0.5 to 20 cm in thickness. In most locations sediment accumulation ranged from 3 to 10 cm. The storm deposits were generally composed of silty clays with a coarser, somewhat sandy 1–2 cm basal layer. Surface sediments from the storm layer were characterized by relatively high mineral surface areas (SA of 30–50 m²/g) and elevated OC contents (%OC of 1.0–2.0%). The dispersal of fine sediments following the hurricane resulted in marked changes in the SA and %OC values of surface sediments from offshore locations, which prior to the storm contained coarser, organic-poor particles (SA of 5–15 m²/g and %OC of 0.2–0.6%). The OC:SA and OC:N ratios of storm layer sediments ranged from 0.4 to 0.6 mg OC/m² and from 10 to 12 mol/mol, respectively, and were comparable to those measured in surface sediments prior to the hurricane. Such similarities in the composition of the organic matter reinforce the idea that the source of the storm deposits was the finer fraction of resuspended seabed sediments, with little evidence for inputs from local land-derived sources or autochthonous algal production. Overall, the magnitude of sediment and organic matter deposition on the seabed after the storm greatly exceeded the annual inputs from the Atchafalaya River and coastal primary production. The combined effects of hurricane-driven erosion and post-storm deposition represent a major perturbation to the benthic community of the region, which is already subject to these types of disturbances due to the combined effects of peaks in river discharge and the passage of storm fronts.     

Chemical speciation of polycyclic aromatic hydrocarbons in sediments: Partitioning and extraction of humic substances

The primary objective of this study was to examine the chemical speciation of polycyclic aromatic hydrocarbons (PAHs) found in sediments endowed with different characteristics. To achieve this purpose and because the nature of the sediments influences the distribution of PAHs, we have analyzed four different types of sediments. To study the role of organic matter in the sequestration of PAHs, we fractionated humic substances into humic acids and humin-mineral fractions. After their separation and purification, the humic components were examined for their sorptive reactivity by extracting them with organic solvents; these extracts were subsequently subjected to GC/MS analysis. Our results show that PAHs are distributed between labile and sequestered fractions in sediments. A slower uptake of PAHs occurs when the sequestered fraction is formed, and this process can be prolonged and may be influenced by the characteristics if the sediment. Our study suggests that organic contaminants are available in muddy sediments for a longer period of time than in sandy sediments.     

南方水库季节性热分层消亡对沉积物铁和磷迁移的影响——以南宁市天雹水库为例

为了探究我国南方地区水库季节性热分层消亡前后沉积物铁和磷的迁移规律,于2019年11月-2020年1月对天雹水库多点位(浅水区和深水区)水体理化指标进行原位监测,并利用薄膜扩散梯度技术(DGT)高分辨率获取沉积物有效态铁和磷的浓度分布.结果 表明:(1)天雹水库沉积物有效态Fe和P浓度分别为4.67～18.72和0.0...     

Heavy metals mobility in harbour contaminated sediments: the case of Port-en-Bessin

Metallic contaminants associated with sediments showed various behaviours depending on physicochemical conditions. A contaminated sediment core from a harbour in the Bay of Seine was sampled to derive information about metal solubilization from anoxic sediment. In these anaerobic surroundings, physicochemical processes depended on the organic matter cycle, on vertical variation of redox conditions and on precipitation conditions of iron and manganese. In the studied core, anoxic conditions were developed at -15 cm depth. A three-step sequential extraction procedure, modified from the BCR method (now the SM&T), was applied to the anoxic sediment in order to evaluate the potential mobility of fixed metals. Zinc was the most labile metal, recovered in the first extraction stages, and was associated with the non-residual fraction of sediment. Lead was the least labile metal, with up to 70% associated with the residual fraction of the sediment. Copper was associated with organic matter, and its mobility was controlled by the concentration and degradation of the organic fraction. Discharge of organic-rich dredged sediments at sea results in degradation of contained organic matter and may affect the environmental impact of these metals significantly. These results therefore help to improve the waste management of such contaminated sediments.     

Seasonal plankton variability in Chilean Patagonia fjords: Carbon flow through the pelagic food web of Aysen Fjord and plankton dynamics in the Moraleda Channel basin

Two research cruises (CIMAR 13 Fiordos) were conducted in the N–S oriented macrobasin of the Moraleda Channel (42–47°S), which includes the E–W oriented Puyuhuapi Channel and Aysen Fjord, during two contrasting productive seasons: austral winter (27 July–7 August 2007) and spring (2–12 November 2007). These campaigns set out to assess the spatio-temporal variability, defined by the local topography along Moraleda Channel, in the biological, physical, and chemical oceanographic characteristics of different microbasins and to quantify the carbon budget of the pelagic trophic webs of Aysen Fjord.Seasonal carbon fluxes and fjord-system functioning vary widely in our study area. In terms of spatial topography, two constriction sills (Meninea and Elefantes) define three microbasins along Moraleda Channel, herein the (1) north (Guafo-Meninea), (2) central (Meninea-Elefantes), and (3) south (Elefantes-San Rafael Lagoon) microbasins. In winter, nutrient concentrations were high (i.e. nitrate range: 21–14 μM) and primary production was low (153–310 mgC m^?2 d^?1), suggesting that reduced light radiation depressed the plankton dynamics throughout Moraleda Channel. In spring, primary production followed a conspicuous N–S gradient, which was the highest (5167 mgC m^?2 d^?1) in the north microbasin and the lowest (742 mgC m^?2 d^?1) in the south microbasin. The seasonal pattern of the semi-enclosed Puyuhuapi Channel and Aysen Fjord, however, revealed no significant differences in primary production (～800 mgC m^?2 d^?1), and vertical fluxes of particulate organic carbon were nearly twice as high in spring as in winter (266 vs. 168 mgC m^?2 d^?1).At the time-series station (St. 79), the lithogenic fraction dominated the total sedimented matter (seston). The role of euphausiids in the biological carbon pump of the Patagonian fjords was evident, given the predominance of zooplankton fecal material, mostly euphausiid fecal strings (46% of all fecal material), among the recognizable particles contributing to the particulate organic carbon flux.The topographic constriction sills partially modulated the exchange of oceanic waters (Subantarctic Surface Water) with freshwater river discharges along the Moraleda Channel. This exchange affects salinity and nutrient availability and, thus, the plankton structure. The north microbasin was dominated by a seasonal alternation of the classical (spring) and microbial (winter) food webs. However, in the south microbasin, productivity was low and the system was dominated year-round by large inputs of glacier-derived, silt-rich freshwater carrying predominantly small-sized diatoms (Skeletonema spp) and bacteria. When superimposed upon this scenario, highly variable (seasonal) solar radiation and photoperiods could exacerbate north–south differences along Moraleda Channel.