六元体系Li–Na–K–Mg–Cl–SO4–H2O多温相平衡预测

采用基于扩展UNIQUAC模型的AQSOL027软件针对水盐体系Li–Na–K–Mg–Cl–SO₄–H₂O的六个五元子体系进行相平衡理论计算,首次报道了多个五元子体系在多个温度条件下的相图,将计算相图与已有实验相图以及基于其它热力学模型的计算相图进行了比较。结果表明：AQSOL027在相图计算中具有较好的准确性和可靠性。AQSOL027是一款基于Excel、用于计算复杂多温水-盐体系Li–Na–K–Mg–Ca–H–Cl–(HSO₄/SO₄)–(CO₂/HCO₃/CO₃)–(H₃BO₃/B₄O₇/BO₂)–OH–H₂O的计算机软件,集成了扩展UNIQUAC模型和相平衡算法,该软件可结合SysCAD和Aspen过程模拟器,实现盐田工艺过程的计算机辅助设计。     

Rb–Sr,Sm–Nd,and Ar–Ar isotopic systematics of lherzolitic shergottite Yamato 000097

Isotopic analysis of the Martian lherzolitic shergottite Yamato 000097 yields a Rb–Sr age of 147 ± 28 Ma with an initial ⁸⁷Sr/⁸⁶Sr ratio of 0.710490 ± 0.000072, a Sm–Nd age of 152 ± 13 Ma with an initial ɛ¹⁴³Nd-value of +11.7 ± 0.2, and a ³⁹Ar–⁴⁰Ar age of ∼260 Ma. The near concordance of these ages, in combination with the Rb–Sr and Sm–Nd initial isotopic signatures, suggests that Yamato 000097 crystallized from low Rb/Sr, light rare earth element depleted source materials ∼150 Ma ago. Although the obtained ³⁹Ar–⁴⁰Ar age is significantly higher than the Rb–Sr and Sm–Nd ages, Yamato 000097 shows little or no evidence of trapped Martian atmospheric ⁴⁰Ar. The trapped ⁴⁰Ar concentration of Yamato 000097 is similar to that of Zagami, suggesting that both basaltic and lherzolitic shergottites may have similarly inherited excess ⁴⁰Ar from their magmas.The Rb–Sr and Sm–Nd ages, and initial ⁸⁷Sr/⁸⁶Sr and ɛ¹⁴³Nd-values of Yamato 000097 and Yamato 793605 lie on the same isotopic ingrowth curves, suggesting that they came from very similar mantle sources. Allan Hills 77005 was also probably derived from the same source, but Lewis Cliff 88516 appears to be from a distinct but similar source. Yamato 000097 represents the most recent known magmatism from its source, and is the youngest Martian meteorite for which concordant Rb–Sr and Sm–Nd ages have been determined.     

Sm–Nd and Rb–Sr studies of lherzolitic shergottite Yamato 984028

The distribution pattern of the trace elements Rb, Sr, Nd and Sm for Yamato 984028 (Y984028) is consistent with its classification as a lherzolitic shergottite. The Sm–Nd mineral isochron of this lherzolitic shergottite defines its age to be 170 ± 10 Ma for an initial ?_Nd = +11.6 ± 0.2. The corresponding Rb–Sr mineral isochron yields an identical age of 170 ± 9 Ma and an initial ⁸⁷Sr/⁸⁶Sr = 0.710389 ± 0.000029. The concordant Sm–Nd and Rb–Sr isochron ages suggest that Y984028 crystallized 170 ± 7 Ma ago contemporaneously with five other lherzolitic shergottites and ten enriched basaltic and olivine-phyric shergottites. The age, Sr- and Nd- isotopic signatures further suggest that Y984028 and Y-793605, and also probably Y000097 could come from a single magmatic body. Using a two-stage evolution model, the time-averaged ⁸⁷Rb/⁸⁶Sr-ratio for the mantle source of the parent magma of Y984028 is ～0.182, within the range of 0.178–0.182 that has been reported for other lherzolitic shergottites. The corresponding time-averaged ¹⁴⁷Sm/¹⁴⁴Nd-ratio for the source mantle of its parent magma is super-chondritic at ～0.217, implying its source was a depleted mafic part of the Martian mantle similar to that of diabasic shergottite Northwest Africa (NWA) 1460. Rb, Sr, Sm and Nd distributions in Y984028 are likely produced by pyroxene and olivine accumulation, probably from a NWA 1460-like parental melt, in an intrusive magma body.     

TEMPORAL CHARACTERISTICS OF PENNSYLVANIA SNOWFALL, 1950–1951 THROUGH 1989–1990

While speculation exists on global and regional climate change for temperature and precipitation, relatively little research is available on snowfall and its changes. Twenty-six sites were selected to describe and analyze various characteristics of snowfall in Pennsylvania from 1950–1951 through 1989–1990. Overall, the state experienced a significant stepwise change in seasonal snowfall total during this period. Abnormally high seasonal totals prevailed from 1957–1958 through 1971–1972. This rise in snowfall was accompanied by colder-than-normal temperatures and a dramatic increase in large daily snow events. Principal components analysis (PCA) revealed that the seasonal temporal patterns were not uniform across the state. The PCA revealed four distinct seasonal regions. These regions exhibited everything from nearly linear increases and decreases over time to cyclical formations. PCA performed on the months of November through April each unveiled between three and five separate temporal regions. PCA analyses generally identified an eastern region, a north-central region, and a western region across Pennsylvania. [Key words: regionalization, principal components, variability, snowfall, climate change, Pennsylvania.]     

Beyond the Edge and in Between: (Re)conceptualizing the Rural–Urban Interface as Meaning–Model–Metaphor

As examinations of the rural–urban interface move beyond a focus on the rural or urban fringe as a location and move toward examining the patterns and processes that both divide and link rural and urban places, a broader (re)conceptualization of the rural–urban interface becomes increasingly important. Thus far the question of boundaries and interfaces between so-called urban and rural locales has mostly revolved around where and when such boundaries occur (including significant coverage of the differences and conflicts between urban vs. rural people), rather than asking what physical or social functions are being served by the rural–urban interface itself. In response, I (re)frame the rural–urban interface not only as a boundary between two distinct spaces but also as a conduit, a place of exchange, and a flux point between them. Using a particular case of contested ecologies in the exurban Sierra Nevada foothills of California, I (re)conceptualize the rural–urban interface as meaning, model, and metaphor (MMM), situating contrasting people and places in an ongoing negotiation of place and environmental meaning along the (ex)urbanizing edge. Although the differences between rural and urban are increasingly unclear, the division continues to be compelling from environmental and sociopolitical standpoints. I argue that (perceived) boundaries are instrumental in understanding physical–material change and for mitigating social conflicts occurring across them. As such, attention to the patterns, processes, and flows that connect or separate rural and urban areas is critical to forging effective and long-lasting solutions to contemporary social, economic, and environmental problems.     

Black–White and Hispanic–White Segregation in U.S. Counties

Residential segregation in metropolitan areas has been the subject of much research, but this article analyzes patterns of white–black and white–Hispanic segregation in counties across the United States. Our purpose was to understand county variations in this one dimension of inequality. Conceiving of segregation as relative inequality of access to neighborhood resources, we measured segregation in 2000 by the index of dissimilarity (D) calculated by blocks, mapped the index values, and correlated them with census variables. Three filters enabled us to eliminate counties with characteristics that could have corrupted the analyses, leaving us with more than 1,000 counties in each analysis. Both minority groups were less segregated from whites in the West and South and in metropolitan counties. Lower segregation was strongly associated with higher minority socioeconomic status and higher percentages of minorities living in housing built in the 1990s, and Hispanic–white segregation was lower where more Hispanics were U.S.-born or English proficient. The racial threat hypothesis was supported only weakly and inconsistently. Mapping made it possible to identify regional and local patterns of high and low segregation as well as the lower segregation of suburban counties in some large metropolitan areas.     

Byerhvervene. Lokaliseringstendenser 1970–83

Matthiessen. Christian Wichmann: Byerhvervene. Lokaliseringstendenser 1970–83. Geografisk Tidsskrift 87:22–26. København, juni 1987.

The Danish pattern of urban employment changed little 1970–83 although dynamic structural changes occurred, and although the total increased 23% to 2,353,366 urban jobs. The manufacturing deconcentration was more than counteracted by growth in no. of tertiary jobs in the large urban places.