Biochemical and histological responses in mussel (Mytilus edulis) exposed to North Sea oil and to a mixture of North Sea oil and alkylphenols

Several environmental chemicals are suspected to be responsible for adverse health effects on the reproductive system in various organisms. During this work, environmentally relevant concentrations of North Sea oil were used alone or in combination with alkylphenols and additional PAH to study the effect on vitellogenin-like protein expression and gonadal development in mussels. North Sea oil (0.5 ppm) induced the expression of phospho-proteins in both sexes indicating that some compounds are oestrogen-mimics. This induction was not seen in samples dosed with the mixture but signs of toxic effects were observed in the gonads. Indeed, numerous degenerating ovarian follicles in females and foci, similar to vertebrate melanomacrophage centres, were observed in testes.     

Candidate biomarker discovery in plasma of juvenile cod (Gadus morhua) exposed to crude North Sea oil, alkyl phenols and polycyclic aromatic hydrocarbons (PAHs)

In this study we have investigated protein changes in plasma of juvenile Atlantic cod (Gadus morhua) induced by crude North Sea oil and North Sea oil spiked with alkyl phenols and polycyclic aromatic hydrocarbons, a surrogate produced water composition. Using a proteomic approach, we identified 137 differentially expressed proteins at different levels of crude oil exposure. Many of the induced protein changes occurred at low levels of exposure. The results obtained with protein expression profiles after exposure to oil and surrogate produced water indicate effects on fibrinolysis and the complement cascade, the immune system, fertility-linked proteins, bone resorption, fatty acid metabolism as well as increased oxidative stress, impaired cell mobility and increased levels of proteins associated with apoptosis. Although the number of individuals and samples in this study is limited within each treatment group, the protein changes observed in this study represent a first screening for potential biomarker candidates in cod plasma reflecting potential effects of crude oil and produced water exposure on fish.     

Seismic response to collapse structures in the Southern North Sea

The presence of probable salt dissolution-associated collapse structures in the North Sea based on the evidence of contemporary seismic data was discussed by Lohmann (1972). Since then, little attention has been paid to them in North Sea literature, although many oil companies will have studies on file. This Paper describes and illustrates a selection of such features in the area from recent seismic data, and suggest a broad classification for them as they are seen on the seismic section, based on mode of origin. Reference will also be made to certain types of carbonate dissolution and collapse effects.     

Late Devonian rifting in the central North Sea: Evidence from altered felsic volcanic rocks in the Embla oil field

In the Embla oil field on the northern flank of the Mid North Sea High, the central North Sea, multiple quartz porphyric volcanic beds at ca. 4600 m depth form part of a volcano-sedimentary interval above the Caledonian basement as interpreted from seismic data. Zircon U–Pb laser ablation ICPMS date one bed to 374 ± 3 Ma, indicating that the volcanic rocks and interbedded sediments are early Famennian and correlate to the Buchan Formation. The volcanic rocks have been extensively clay and carbonate altered in a near-surface environment, but high field strength element data show that the protoliths were alkali rhyolites, yielding intra-plate signatures in tectonic discrimination diagrams. Famennian quartz porphyric volcanic rocks have also been reported from well A17-1 on the southern flank of the Mid North Sea High. The Famennian volcanism on the northern and southern flanks testify to an active magmatic environment in the central North Sea in the early Famennian, supporting the existence of a late Devonian proto-Central Graben rift extending northwards into the central North Sea. The rift is likely an early example of strain localisation to a zone of reduced crustal strength along the Caledonian suture between Avalonia and Baltica.     

北黄海盆地中生代地层的地质特征和油气潜力(英文)

位于山东半岛东北部的北黄海盆地沿东北方向可以延伸到朝鲜的西朝鲜湾盆地和安州盆地 ,而沿西南方向可以延伸到中国的胶莱盆地。长期以来该盆地的找油重点为第三系 ,结果收效甚微。2 0世纪 80年代末朝鲜在西朝鲜湾靠北黄海盆地一侧钻井数口且在中生代地层中发现了商业性油气流 ,自此中生代地层替代新生代第三纪地层成为人们关注的焦点 ,人们希望在北黄海盆地的中生代地层中也能找出商业性油气流。本文以李四光 ( 1 979)划分的新华夏系第二隆起带理论为指导 ,将胶莱盆地、北黄海盆地、西朝鲜湾盆地和安州盆地作为一个整体进行考虑 ,在详细分析了安州盆地、西朝鲜湾盆地和胶莱盆地的中生代地层分布、油气潜力及其类比关系后认为 ,北黄海盆地在基底结构及其上覆盖层的沉积特征上应具有与安州盆地、西朝鲜湾盆地和胶莱盆地相似的特征。目前 ,西朝鲜湾盆地和胶莱盆地在中生代地层中已取得重要的油气发现和油气显示 ,而它们主要是由下白垩统和上侏罗统组成。因此 ,我们有理由相信 ,北黄海盆地的中生代地层很可能成为有远景的勘探靶区。     

Pile foundations for large North Sea structures

The oil fields in the northern part of the North Sea, with their great water depth and adverse sea conditions, have led to new concepts in the design of pile foundations for production platforms. This paper reviews the current state of the art for North Sea pile design, as determined by the soil conditions on the one hand and the available installation techniques on the other hand. It contains comments on the safety factors used in the design and finally describes the observations to be made during pile installation to check the reliability of the theoretical pile capacities.     

Ecological performance indicators in the North Sea: development and application

Different signals of distress from the North Sea ecosystems started a discussion on the protection of the ecosystem at the third North Sea Ministers Conference in 1990. This was followed by a number of workshops on ecological indicators under the auspices of the North Sea Task Force and the Oslo and Paris Commissions (OSPAR). In 1997 the member countries around the North Sea agreed to develop and apply an ecosystem's approach in the management programs for both the North Sea fisheries and the marine environment. Following this agreement the identification of the ecological qualities objectives for the North Sea ecosystem started. Further work in this direction has lead to the setting up of various national projects geared towards creating a better understanding of the North Sea ecosystem.In the Netherlands, two departments (Water management and Nature and fisheries management) from the Ministry of Transport, Public works and Water Management (V&W) and the Ministry of Agriculture, Nature and Fisheries Management (LNV) agreed to integrate their policies for the management of the Netherlands section of the North Sea. The results from these projects (started in 1996) should enable the policy makers and managers to formulate policies that could lead to the creation of a balance between the effects of human activities and the preservation of the natural qualities of the North Sea ecosystem.One of the projects is strictly designed to develop ecological indicators for the Dutch part of the North Sea. These indicators are based on various monitoring data and related in one way or another with human activities. In this way it is possible to evaluate the effects of human impacts on the ecosystem. Long-term changes in the ecological performance of the ecosystem can be elucidated by the use of the ecological indicators. Thereby making it possible for the policy makers and the managers of the NCP to evaluate the effects of their policies and management recommendations on the quality of the ecosystem.This paper describes the process and the steps taken by the authorities in the countries around the North Sea to develop a set of ecological indicators for the management of the North Sea ecosystem. Focus will be made on the efforts made in the Netherlands to develop indicators that did provide the basis for the development of Water and Nature conservation policies and new management strategies for maintaining the sustainable use of the Dutch section of the North Sea.     

Expression of heat shock protein 70 in a permanent cell line (EPC) exposed to sediment extracts from the North Sea and the Baltic Sea

Heat shock proteins 70 (hsp70) are known to be induced by a great variety of chemical stressors. The effects of different environmental contaminants, which were identified in sediments of the North Sea and the Baltic Sea as main contaminants or as contaminants of special toxicological interest, on the extent of expression of hsp70 in a permanent cell line Epithelioma papulosum cyprini (EPC) were investigated. Concentrations of the single contaminants leading to elevated hsp70 levels were compared to the respective concentrations of these contaminants encountered in the sediment extracts thus allowing an assessment of their contribution to the toxicity of these sediments. Analysis of hsp70 was performed using western blotting techniques with subsequent comparative quantification by densitometry. Eleven of thirteen contaminants have shown a dose-dependent increase in hsp70 levels. An expression of hsp70 was observed in most cases between 0.1 and 10 microg/mL test solution. Some of the investigated stressors led to extremely high hsp70 contents even at low concentrations. However, in most cases contaminant concentrations in sediments were too low to cause an effect. For this reason, effects of the tested sediments are attributed to other contaminants or rather to mixtures of stressors.     

Geological structure and petroleum resource potential of the North Sea basin

The North Sea basin occupies a spacious depression almost isometric in shape. In the west and northwest, the basin is bordered by the continental crust consolidated during the Precambrian, Caledonian, and Hercynian orogenic epochs, which now forms epiplatformal orogenic structures. They are represented by the London-Brabant uplift and the Arden massif in the southwest and south and the Baltic Shield in the east and northeast. The North Sea basin may be considered as an ancient aulacogen that was transformed in the Early Mesozoic into a complex system of continental rifts and grabens. The sedimentary cover of the basin is represented by a thick (8.5?C12.5 km) Ordovician-Quaternary sequence. Oil and gas generation in the sedimentary cover of the basin is likely connected with four main productive sequences: the coaliferous Upper Carboniferous (Westphalian), the subsalt Zechstein, the Jurassic-Lower Cretaceous (Lotharingian, Toarcian, Kimmeridgian, and Weldian bituminose shales), and the shaly Cenozoic. The large oil and gas reserves in the North Sea??s sedimentary cover (over 280 fields) implies that the above-mentioned sequences have realized their oil-generating potential. The present-day position of the main oil and gas generation zones in the sedimentary section of the North Sea explains the distribution of the oil and gas fields through the basin from the genetic standpoint. The petroleum resource potential of the basin is still significant. In this regard, most promising are the spacious shelf areas, turbidite sediments, deep Paleozoic sequences, and continental slopes in the northern part of the basin, which remains insufficiently investigated.     

Lead in the North Sea and the north east Atlantic Ocean

Lead has been determined in 105 water samples from the north east Atlantic and from the North Sea. Rigorous precautions were applied to avoid contamination during sampling and analysis.Two different analytical methods were used: ASV and AAS. Determinations with ASV were carried out on board, directly after sampling. After two months storage, acidified samples were analysed by AAS after freon dithiocarbamate extraction and nitric acid back extraction. Particulate lead was determined by AAS after an acid digestion.The profiles of lead concentration versus depth show around 160 pM at the surface and around 20 pM at the bottom, both in the Atlantic and in the Norwegian Sea. The shapes of the profiles are different, however, depending on the hydrography of the area sampled. The profiles from the north east Atlantic coincide with a recently published profile from the north west Atlantic. Moreover, these profiles have lead concentrations about a factor of three higher than those in the Pacific.Considering the high lead input to the North Sea, the lead concentrations found there are remarkably low, probably because of scavenging effects in estuaries leading to a short residence time in the water column. The dominant lead input in offshore regions is from the atmosphere. The highest lead levels are found in the northern North Sea, around 300 pM in surface water.In the Atlantic, particulate lead is a minor part of the total lead whereas in the North Sea the particulate fraction is larger, up to 40%.     

Hydrocarbon Potential of Pre-cenozoic Strata in the North Yellow Sea Basin

The North Yellow Sea Basin ( NYSB ), which was developed on the basement of North China (Huabei) continental block, is a typical continental Mesozoic Cenozoic sedimentary basin in the sea area. Its Mesozoic basin is a residual basin, below which there is probably a larger Paleozoic sedimentary basin. The North Yellow Sea Basin comprises four sags and three uplifts. Of them, the eastern sag is a Mesozoic Cenozoic sedimentary sag in NYSB and has the biggest sediment thickness; the current Korean drilling wells are concentrated in the eastern sag. This sag is comparatively rich in oil and gas resources and thus has a relatively good petroleum prospect in the sea. The central sag has also accommodated thick Mesozoic-Cenozoic sediments. The latest research results show that there are three series of hydrocarbon source rocks in the North Yellow Sea Basin, namely, black shales of the Paleogene, Jurassic and Cretaceous. The principal hydrocarbon source rocks in NYSB are the Mesozoic black shale. According to the drilling data of Korea, the black shales of the Paleogene, Jurassic and Cretaceous have all come up to the standards of good and mature source rocks. The NYSB owns an intact system of oil generation, reservoir and capping rocks that can help hydrocarbon to form in the basin and thus it has the great potential of oil and gas. The vertical distribution of the hydrocarbon resources is mainly considered to be in the Cretaceous and then in the Jurassic.     

Oil and fishing — conflict in the North Sea

A programme of research is underway at Aberdeen University on the conflicts arising in the North Sea between the fishing and offshore oil and gas industries. This research note summarizes the work that has been undertaken to date and the main aspects on which future work will concentrate.     

Climatological annual cycles of nutrients and chlorophyll in the North Sea

A large amount of nutrient and chlorophyll data from the North Sea were compiled and organised in a research data base to produce annual cycles on a relatively fine spatial resolution of 1° in each horizontal direction. The data originate from many different sources and were partly provided by the ECOMOD data base of the Institut fur Meereskunde in Hamburg and partly by ICES in Copenhagen to cover the time range from 1950 to 1994. While the annual cycles of nutrients and chlorophyll derived for the continental coastal zone are representative for the decade 1984–1993 only, those for the remaining parts of the North Sea may be considered climatological annual cycles based on data from more than four decades. The composite data set of climatological annual cycles of medians and their climatological ranges is well suited to serve for validational and forcing purposes for ecosystem models of the North Sea, which have a resolution larger than or equal to 1° in both longitude and latitude. The annual cycles of the macronutrients and chlorophyll presented here for 1° × 1° squares in the North Sea show especially that sufficient observational data exist to provide initial, forcing and validational data for the simulations with the 130-box setup (ND130) of the ecosystem model ERSEM. The annual cycles presented give a clear picture for the whole of the North Sea. The highest concentrations occur at the continental coasts as a result of continued river input, which is added to the ongoing atmospheric input over the North Sea. Also, from the Atlantic Ocean water with relatively high nutrient concentrations enters the North Sea via the northern boundary. In the productive areas on and around the Dogger Bank nutrient concentrations are lower than in the other parts of the North Sea, even in winter. The areas with seasonal stratification have very different annual cycles in the upper (0–30 m) and lower layers (30 m-bottom). The shallow boxes are fully mixed and exhibit a relatively fast increase of nutrient concentrations caused by summer regeneration of nutrients.     

The North Sea: problems of de-commissioning

The development of oil and gas in the North Sea has given rise to the problem not immediate but for the near future — of what steps to take to de-commission the present massive installations when the reserves are depleted. In the process, to what extent can the interests of those concerned be reconciled navigation (surface and submarine), fishing, the environment, the oil industry, governments? Should removal be total or partial? what measures, national and international should apply? This report takes a general view of matters as they stand at the present.     

Labrador Sea convection and subpolar North Atlantic Deep Water export in the SODA assimilation model

Labrador Sea convection was most intense and reached the greatest depths in the early 1990s, followed by weaker, shallower, and more variable convection after 1995. The Simple Ocean Data Assimilation (SODA) version 2.0.2/2.0.4 assimilation model is used to explore convective activity in the North Atlantic Ocean for the period from 1992 to 2007. Hydrographic conditions, which are relatively well observed during this period, are used to compare modeled and observed winter mixed-layer depths and water mass anomalies in relation to Deep Western Boundary Current transports and meridional overturning circulation (MOC) changes at the exit of the subpolar basin. The assimilation differs markedly from local observations in the March mixed-layer depth, which represents deep convection and water mass transformation. However, mean MOC rates at the exit of the subpolar gyre, forced by stratification in the mid-latitudes, are similar to estimates based on observations and show no significant decrease during the 1992–2007 period. SODA reproduces the deep Labrador Sea Water formation in the western North Atlantic without any clear indication of significant formation in the Irminger Sea while the lighter upper Labrador Sea Water density range is reached in the Irminger Sea in the 1990s, in agreement with existing assumptions of deep convection in the Irminger Sea and also supported by computed lag correlations with the Labrador Sea. Deep Water transformation mainly takes place in the eastern North Atlantic. The introduction of CFC-11 into the SODA model as a tracer reproduces the mean and multiyear variations of observed distributions.     

North sea offshore structures

Existing and planned North Sea offshore structures for exploration (drillings) and structures for exploitation (production platforms) are mentioned. Introductorily the mereorological conditions, wave climate and bottom composition in the North Sea are reviewed briefly. They are determining factors for design as well as for operation. Furthermore a brief account on present and planned activities on exploration for and exploitation of oil and gas in the North Sea is given.     

Long-term simulation of the eutrophication of the North Sea: temporal development of nutrients, chlorophyll and primary production in comparison to observations

The ecosystem model ERSEM II has been used to hindcast the development of the ecosystem of the North Sea during the years 1955 to 1993. The simulation was driven by the box-aggregated output from a general circulation model of the North Sea of corresponding duration; radiation, river inputs, atmospheric input and boundary conditions at the borders to the Atlantic Ocean and to the Baltic Sea were applied as realistically as possible. The general features of the eutrophication process are reproduced in the hindcast: the coastal areas show strong changes in nutrient concentrations in the hindcast as well as in the observations. Eutrophication not only shows up in the nutrient concentrations, but also in primary production. The simulated spatial distributions of phosphate, nitrate and primary production compare well with the observed ones. In addition, the hindcast simulates considerable trend-like changes of the nutrients in the southern part of the North Sea, where the nutrients are transported from the continental coastal strip to the southern central North Sea. The line from the river Humber to southern Norway separates the region of noticeable anthropogenic influence of riverine and atmospheric input from the northern area, which is mainly influenced by the Atlantic nutrient inflow. The observed annual cycles in the central and northern North Sea are quite well reproduced by the hindcast. The comparison of the hindcast with the long-term observations at two sites in the continental coastal zone of the North Sea shows that the long-term behaviour of phosphate, nitrate and silicate is simulated well. Primary production is increased in summers during the main period of eutrophication, 1975 to 1989, in the hindcast and in the observations. The flagellates at Helgoland, however, experience much more pronounced annual cycles with much less interannual variability in the hindcast than in the observations.     

Regional sedimentology and petroleum geology of marine,late Bathonian-Valanginian sandstone in the North Sea

A large number of marine, late Bathonian-Valanginian sandstone units have been identified in the North Sea, north of the Mid North Sea High. This paper discusses their complex areal distribution and outlines sedimentological models. The sandstone formations are interpreted as shallow marine, transgressive and regressive units interbedded with beach, lagoonal and coastal plain deposits. Coarse grained scarp fed fans occur along fault-controlled rift margins.The total proven recoverable reserves in these sandstone reservoirs are 2.3 x 10⁹ ton oil equivalent, of which approximately one third is oil. The play types are intimately linked with the Mesozoic rift system of the Viking, Witch Ground and Central Grabens. Along this rift system the sand units provide good trapping potential and they are generally interbedded with or lie immediately below the Kimmeridgian-Ryazanian source rocks, so that migration paths are relatively simple and migration efficiency is high.     

2010 年夏季大连溢油事件期间北黄海漂流浮标移动轨迹的数值模拟

采用双层单向嵌套的普林斯顿大学海洋模式(POM)对2010年夏季大连溢油事件期间北黄海释放的表层漂流浮标的移动轨迹进行了数值模拟,模拟结果与实测轨迹基本吻合,模拟的表层流速纬向和经向分量与观测数据的相关系数在两观测点分别达到了0.6548,0.3659和0.4836,0.3961,均明显大于95%置信区间下的显著性临界值0.1946,但是模拟的浮标移动速度明显慢于观测。模拟出的速度时间序列在变化趋势上与实测吻合良好,但是流速数值相对于观测整体上偏小。该数值模拟系统能够较准确地模拟出2010年大连溢油事件期间北黄海的流场及漂流浮标的运动趋势,为北黄海的环境预警、灾害评估等相关研究提供有益的参考。