N2 emission in the twilight

About a year's observations of the N₂⁺ band (3914 Å) at Kitt Peak (latitude 32°) are reported. Morning intensities are the same throughout the year, but there is a strong winter maximum in the evening. It is suggested that the additional ionization is produced by photoelectrons from the magnetic conjugate point. Heights are estimated by the zenith-horizon method, which gives 235 km for the constant component and 350 km during the evening enhancement. The intensity variation through twilight is therefore entirely due to changes of the N₂⁺ concentration; each ion scatters light at a constant rate. The rotational distribution resembles that for a temperature of 1600°K, much higher than the temperature of the atmosphere. It is suggested that part of the ions may be produced by charge transfer from metastable O⁺(²D). N₂⁺ concentrations resulting from photoionization are calculated; they give a fair account of the observed horizon intensities, but not the zenith. Non-local electrons from higher in the atmosphere are suggested as a possible extra source; alternatively, the zenith measurements may be perturbed by scattered horizon light. The band intensity in the nightglow cannot be measured; the upper limit is 1 R.     

Resonance scattering by N2

A study is made of the intensity distribution among the bands of the Meinel and first negative system of N₂⁺ due to resonance scattering of sunlight. Absolute transition probabilities are used to calculate the relative populations among the ion states under resonance scattering conditions; the mean lifetime for deactivation is the parameter which determines the amount of resonance scattering. Photon scattering rates are calculated for most of the ion bands and it is suggested that an appropriate value for the 3914 Å band would be 0·050 photons/ sec per ion. Observations of the Δυ = −1 sequence of the first negative system in the twilight spectrum are reported. Extended vibrational development is detected which indicates that only about 80 per cent of the emission is resonance scattered. Sunlit auroral spectra of N₂⁺, however, which have been generally considered to be due predominantly to resonance scattering, indicates only about 40 per cent of the emission is due to resonance scattering. Measurable effects resulting from a charge-transfer ion source (O⁺(²D)) are predicted.     

Rocket measurements of the 6300 Å and 3914 Å dayglow features

Rocket results are presented on the OI 6300 Å line and on the N₂⁺ 3914 Å band in the dayglow. An altitude range of 78–335 km is covered. Theoretical interpretations are given, using results of simultaneous measurements of electron density and electron temperature. The apparent brightness of the 6300 Å line at the base of the emitting region is found to be 13 kR, of which 5.5 kR are ascribed to excitation through the Schumann-Runge dissociation of O₂ by the solar UV radiations, 0.55 kR to the dissociative recombination of O₂⁺ and NO⁺ ions, and 0.03 kR to the excitation of O by thermal electrons. An additional source of excitation above 280 km is suggested. The deactivation of O(¹D) by O₂(X³Σ_g⁻) is found to be appreciable below 200 km, and its rate coefficient is estimated to be 2 × 10⁻¹⁰ cm³/sec. The apparent brightness of the 3914 Å band at the base of the emitting region is found to be 6.5 kR, decreasing to 3.2 kR at 330 km. Assuming that fluorescent scattering of solar radiation is the mechanism involved the distribution of N₂⁺ ions is calculated. The rate coefficients for the loss of these ions are hence calculated.     

Chemistry of the nightside ionosphere of Venus

We have constructed a one-dimensional model of the nightside ionosphere of Venus in which it is assumed that the ionization is maintained by day-to-night transport of atomic ions. Downward fluxes of O⁺, C⁺ and N⁺ in the ratios measured on the dayside at high altitudes are imposed at the upper boundary of the model (about 235 km). We discuss the resulting sources and sinks of the molecular ions NO⁺,CO⁺,N₂⁺,CO₂⁺ and O₂⁺. As the O⁺ flux is increased, the peak density of O⁺ increases proportionally and the altitude of the peak decreases. The O₂⁺ peak density is approximately proportional to the square root of the O⁺ flux and the peak rises as the O⁺ flux increases. NO⁺ densities near the peak are relatively unaffected by changes in the O⁺ flux. If the ionosphere is maintained mostly by transport, the ratio of the peak densities of O⁺ and O₂⁺ indicates the downward flux ofO⁺, independent of the absolute magnitudes of the densities. The densities of mass-28 ions are, however, still considered to be the most sensitive indicator of the importance of electron precipitation. We examine here the inbound and outbound portions of six early nightside orbits with low periapsis and use data from the Pioneer Venus orbiter ion mass spectrometer, the retarding potential analyzer and the electron temperature probe to determine the relative importance of ion transport and electron precipitation. For most of the orbits, precipitation is inferred to be of low to moderate importance. Only for orbit 65, which was the first nightside orbit published by Taylor et al. [J. geophys. Res. 85, 7765 (1980)] and for the inbound portion of orbit 73 does the ionization structure appear to be greatly affected by electron precipitation.     

An auroral F-region study using in situ measurements by the Atmosphere Explorer-C satellite

On 14 July 1974 the Atmosphere Explorer-C satellite flew through an aurora at F-region altitudes just after local midnight. The effects of the particle influx are clearly evident in the ion densities, the 6300 Å airglow, and the electron and ion temperatures. This event provided an opportunity to study the agreement between the observed ion densities and those calculated from photochemical theory using in situ measurements of such atmospheric parameters as the neutral densities and the differential electron energy spectra obtained along the satellite track. Good agreement is obtained for the ions O₂⁺, NO⁺ and N₂⁺ using photochemical theory and measured rate constants and electron impact cross sections. Atomic nitrogen densities are calculated from the observed [NO⁺]/[O₂⁺] ratio. In the region of most intense electron fluxes (20 erg cm⁻² sec⁻¹) at 280 km, the N density is found to be between 2 and 7 × 10⁷ cm⁻³. The resulting N densities are found to account for approx. 60% of the production of N⁺ through electron impact on N and the resonant charge exchange of O⁺(²P) with N(⁴S). This reaction also provides a significant source of O(¹S) in the aurora at F-region altitudes. In the region of intense fast electron influx, the reaction with atomic nitrogen is found to be the main loss of O⁺(²P).     

A theoretical study of the time-dependent behaviour of O in the mid-latitude plasmasphere

The behaviour of O²⁺ at L = 3 in the plasmasphere is studied. Starting with a low O²⁺ flux-tube content to characterize post-magnetic-storm conditions the time-dependent equations of continuity and momentum for O²⁺ are solved to give densities and fluxes for a period of several days using both sunspotmaximum and sunspot-minimum parameters. Our results show large amounts of O²⁺ near the equator at sunspot maximum but relatively little at sunspot minimum, and emphasize the key role of the collisional process between O²⁺ and O⁺. It is the combined effects of O²⁺---O ⁺ collisions and thermal diffusion that lead to the large O²⁺ densities near the equator at sunspot maximum. Both of these mechanisms have less influence at sunspot minimum. At sunspot maximum the O⁺ layer acts as a collisional barrier below the O²⁺ production region preventing O²⁺ from sinking towards regions of high recombination rate. In this production region the effects of thermal diffusion are small and upward flow of O²⁺ results from the action of the O²⁺ pressure gradient and the polarization electric field. When the upward flowing O²⁺ reaches regions in which thermal diffusion has a strong influence it is accelerated to even higher altitudes. The O ⁺ barrier is so effective that the diurnal variation of the O⁺ layer is reflected in the diurnal variation of O²⁺ near the equator at sunspot maximum. Our sunspot maximum results also indicate that certain types of temperature profiles are more likely to enhance equatorial O²⁺ densities. The existence of large temperature gradients below 1000 km altitude does not help the flow of O²⁺ towards the equator. The associated changes in the O⁺ layer lead to more O²⁺-O ⁺collisions and a smaller O²⁺ thermal-diffusion coefficient, the latter being sensitive to the ratio n(H⁺)/n(O⁺).     

Changes in thermospheric molecular oxygen abundance inferred from twilight 6300 A airglow

When the local solar zenith angle, χ_L, is < 105° the 6300 A line is much stronger than expected on the basis of F region ionic recombination alone. Between 95 and 105° the additional intensity is quantitatively explained by production of O(¹D) from photolysis of O₂ in the Schumann-Runge continuum, (λλ 1300–1750 A) using current values for solar flux, atmospheric composition and quenching of O(¹D) by N₂. The Schumann-Runge (SR) component exhibits a large seasonal variation with a maximum in summer. We interpret this variation as implying a seasonal change in thermospheric O₂ abundance; the change seems largely to reflect a variation in O₂ density at the base of the diffusive regime although some contribution may come from changes in thermospheric temperature structure. Large changes in the SR component exist from day to day and with a 27 day period following a major magnetic storm. The photodissociation source becomes inadequate when x_l < 95°; at 90° more than half of the intensity comes from still another source which we identify as local photoelectron excitation of O atoms.     

Measurements of radio noise at 0.700 mc and 2.200 mc from a high-altitude rocket probe

Radio noise observations at frequencies of 0·700 Mc and 2·200 Mc were made at altitudes between 3000 and 11,000 km from a Blue Scout Jr. high-altitude rocket probe on 30 July 1963. A steady background flux of (7·5₋₃⁺⁶) × 10⁻¹⁹ W m⁻²)(c/s)⁻¹ at 0·700 Mc and (1·8^+1.0_−0.5 × 10⁻¹⁹ W m⁻² (c/s)⁻¹ at 2·200 Mc was observed. Assuming a galactic origin of the observed fluxes at both frequencies, the averaged sky brightnesses are b(0·700 Mc) = (6₋₃⁺⁵) × 10⁻²⁰ W m⁻² (c/s)⁻¹ sr⁻¹b(2·200 Mc) = (1.4^+1.0_−0.5 × 10⁻²⁰ W m⁻² (c/s)⁻¹ sr⁻¹ The observed brightness at 2·200 Mc is in reasonable agreement with the results of other observers. The apparent brightness at 0·700 Mc is, however, greater than was expected from previous observations. An alternative source of the 0·700 Mc flux in the terrestrial exosphere, as well as characteristics of several noise bursts observed during the flight, is briefly discussed.     

A study of F2 region night-time vertical ionization fluxes at millstone hill

Vertical fluxes of ionization in the F2 region have been measured by the incoherent scatter technique over Millstone Hill in 1969. The results obtained near midnight for the region above h_maxF2 have been examined to determine whether there is a significant flux of ionization from the magnetosphere to the ionosphere that serves to maintain the F-layer. It is found that H⁺ ions are a minor constituent over the altitude range in which useful measurements can be made, so that any conclusion must rest upon properly interpreting the observed O⁺ fluxes. By selecting periods when the layer did not appear to be decaying rapidly it was hoped to find cases where the O⁺ flux did not vary with altitude in the range 500 h 800 km (i.e. where losses are unimportant), since this would imply that the flux is of magnetospheric origin.

While three cases exhibited this behaviour, the majority exhibited a decrease in the O⁺ flux with height, indicating that the layer was descending. Attempts to correct for this were made, and the average flux from the magnetosphere was estimated as 3 × 10⁷ el/cm²/sec. This is in fair agreement with other recent estimates, and implies that at this latitude the ionosphere is not maintained solely by the magnetospheric flux. Moreover, large increases in flux that could give rise to nocturnal increases in the total content of the layer do not appear to have been seen.     

Studies of equatorial 630.0 nm airglow enhancements produced by a chemical release in the F-region

A sky-mapping filter photometer has been used to determine the 630.0 nm airglow enhancement produced by explosive release of 3 × 10²⁶ CO₂ molecules into the F-region at 320 km altitude on 8 September 1982 as part of project BIME. The enhancement is produced when COg molecules engage in atom transfer with the F-region O⁺ ions to form O₂⁺ ions, which subsequently dissociatively recombine with the ambient electrons to produce O(¹D) atoms to yield the 630.0 nm radiation. The morphology of the enhanced airglow region has been traced in a series of 630.0 nm intensity contour maps as a function of time, the enhancement reaching a central brightness of approximately 400 R about 2 min after release and a diameter of 250 km some 3 min after release. The measurements of central intensity and enhanced region radius as a function of time are compared with model calculations by Mendillo and Herniter of diffusive expansion of CO₂ molecules from either a point release or from an initial, extended volume. While peak intensities are reasonably reproduced, the measured decay of the 630.0 nm intensity and the growth in size of the enhanced region are rather different from the model predictions. The measured 200 m/s drift southeastward of the enhanced region is consistent with the motion of the neutral thermosphere determined from optical doppler shifts less than an hour earlier.     

Deactivation of N2A Σumolecules in the aurora

Recent rocket observations of the N₂ V-K (Vegard-Kaplan) system in the aurora have been reinterpreted using an atmospheric model based on mass spectrometer measurements in an aurora of similar intensity at the same time of year. In contrast to the original interpretation, we find that population by cascade from the C³Π_u and B³Π_g states in the A³Σ_u⁺v=0,1 levels, as calculated using recently measured electron excitation cross sections, accurately accounts for the observed relative emission rates (IV-K/12PG_0.0). In addition there is no need to change the production rate of A ³ Σ _u⁺ molecules relative to that of C³Π_uv=0 as a function of altitude in order to fit the profile of the deactivation probability to the atmospheric model. Quenching of A ³ Σ _u⁺ molecules at high altitudes is dominated by atomic oxygen. The rate constants for the v=0 and v=1 levels are 8 × 10⁻¹¹ cm³ sec⁻¹ and 1.7 × 10⁻¹⁰ cm³ sec⁻¹ respectively, as determined using the model atmosphere mentioned above. Recent observations with a helium cooled mass spectrometer suggest that conventional mass spectrometer measurements tend to underestimate the atomic oxygen relative concentration. The rate coefficients may therefore be too large by as much as a factor of 3. Below 130 Km we find that it is possible to account for the deactivation in bright auroras by invoking large nitric oxide concentrations, similar to those recently observed mass spectrometrically and using a rate constant of 8 × 10⁻¹¹ cm³ sec⁻¹ for both the v=1 levels. This rate constant is very nearly the same as that measured in the laboratory (7 × 10⁻¹¹ cm³ sec⁻¹). Molecular oxygen appears not to play a significant role in deactivating the lower A ³ Σ _u⁺ levels.     

Hydrogen atoms and ions in the thermosphere and exosphere

The distribution of atomic hydrogen in the thermosphere and exosphere is computed taking into account the upward flow which balances the escape flux. Because of the upward flow the number-density gradient is much steeper than it would be in a static atmosphere. Attention is drawn to the fact that the ratio of the amount of hydrogen above the 100 or 110km levels to the amount of hydrogen above the 200 or 300 km levels is a sensitive measure of the temperature of the exosphere. The evidence on the absolute abundance of atomic hydrogen is examined. It is concluded that the number density at the 120km level is probably about 5 × 10⁵/cm³. The Ly. absorption line at this level is beyond the linear part of the curve of growth.

Consideration is also given to the steady-state distributions of O⁺ and H⁺ ions. In the lower part of the exosphere the number density of O⁺ ions falls with increase in altitude (the associated scale height being twice that of the O atoms) and the number density of H⁺ ions rises at the same rate (as was first pointed out by Dungey). The altitude at which the number densities of O⁺ and H⁺ ions become equal is calculated on various assumptions regarding the temperature and hydrogen content of the exosphere. It is found to be about 1200 km when the temperature is 1250° K and the hydrogen content corresponds to the number density cited near the end of the preceding paragraph. The gradient of the predicted electrondensity distribution at several Earth radii is much less than that deduced from whistler studies.

The passage from charge transfer to diffusive equilibrium is discussed in an Appendix.     

Observation and Study of the CO, CO, HCO and N2H Molecular Lines Towards IRAS 02232+6138

Using the 13.7 m millimeter-wave telescope at the Qinghai Station of Purple Mountain Observatory, we have made observations of ¹³CO, C¹⁸O, HCO⁺ and N₂H⁺ molecular lines towards IRAS 02232+6138. As the excitation density of the probe molecule increases from ¹³CO to HCO⁺, the size of the cloud core associated with IRAS 02232+6138 decreases from 2.40 pc to 0.54 pc, and the virial mass of the cloud core decreases from 2.2 × 10³M to 5.1 × 10²M. A bipolar molecular outflow is found towards IRAS 02232+6138. Using the power function n(r) ∝ r⁻ to fit the spatial density structure of the cloud core, we obtain the power-law index  = 2.3 − 1.2; and we find that, as the probed density increases, the power function becomes more flat. The abundance ratio of ¹³CO to C¹⁸O is 12.4 ± 6.9, comparable with the values 11.8 ± 5.9 for dark clouds and the values 9.0–15.6 for massive cores. The abundance of N₂H⁺ molecules is 3.5 ± 2.5 × 10⁻¹⁰, consistent with the value 1.0 − 5.0 × 10⁻¹⁰ for dark cloud cores and the value 1.2 − 12.8 × 10⁻¹⁰ for massive cores. The abundance of HCO⁺ molecules is 0.9 ± 0.5 × 10⁻⁹, close to the value 1.6 − 2.4 × 10⁻⁹ for massive cores. An increase of HCO⁺ abundance in the outflow region was not found. Combining with the IRAS data, the luminosity-mass ratio of the cloud core is obtained in the range 37–163(L/M). Based on the IRAS luminosity, it is estimated that a main-sequence O7.5 star is probably embedded in the IRAS 02232+6138 cloud core.     

The winter anomaly in ionospheric absorption and the D-region ion chemistry

A detailed analysis of the D-region ion composition measurements performed by Zbinden et al. (1975), during a winter day of high ionospheric absorption, has been carried out. The study examines the interactive mesosphere-D-region processes which occur in such anomalous conditions and their implication for water cluster ion chemistry. Two clustering regimes for NO⁺ have been observed in the data. Association with N₂ is identified as the dominant process below 76 km. Between 76 and 78 km altitude the effective loss rate of NO⁺ drops by two orders of magnitude. Above 77 km, the three-body reaction NO⁺ + CO₂+M→NO⁺CO₂+M seems to be the main NO⁺ loss. A mesospheric temperature profile could be derived from the ion composition data. This indicates the presence of a strong inversion above 76 km altitude. The wavelike structure obtained, is shown to be consistent with in situ winter temperature measurements. The sharp suppression of the N₂ association reaction could, thus, be explained by an increase in the collisional break-up of the NO⁺N₂ ion because of the enhanced temperature. In conclusion, our study indicates that, besides the increase in the production of NO⁺ and O₂⁺, due to an enhancement in the minor ionizable constituents, an additional thermal mesosphere-D-region interaction seems necessary to explain this winter anomalous ion composition data.     

Electron excitation and auroral emission parameters

Auroral luminosities of the main emission lines in the aurora have been calculated for excitation by an isotopic primary electron flux with spectra of the form J(E) = AE exp (−E/E₁) + B(E₂)E exp (−E/E₁). The variation of emissions from O and N₂⁺ with height are shown, as are the variations of column integrated intensities and pertinent intensity ratios with the characteristic energy E₂, this leading to a method of estimating the electron spectrum from ground observation.     

Ionospheric conditions

A general analysis of ionospheric conditions has been made in the light of possible ionic reactions occurring in the upper atmosphere. Data obtained on various parameters, such as ionic production and recombination, show that precise knowledge of the spectral distribution of solar radiation is needed and that other experimental determinations on dissociative recombinations are required.

The ionic complexity of the ionosphere is underlined by describing how the atomic ions O⁺ and N⁺ react with N₂, O₂ and NO molecules. The behavior of the molecular ions N⁺₂, O⁺₂and NO⁺depends on a group of simultaneous processes involving charge transfers and ionatom interchanges which are more important than dissociative recombinations. The altitude distribution of ions is exemplified by discussing the relative importance of various loss coefficients in the D-, E- and F-regions. It is seen that molecular nitrogen ions are subject to important charge transfer processes, that nitric oxide ions are always final products destroyed only by dissociative recombination. Additionally, the entire production of atomic oxygen ions is related to the photoionization of molecular nitrogen. Some information is also given on possible anomalies in the ratio of O⁺₂ and NO⁺ densities in the lower ionosphere. From the lack of sufficient experimental information on ionic processes it is shown that a precise analysis of ionospheric behavior remains highly speculative.     

Dynamics of the O H2O charge-transfer reaction and its implications for space-borne measurements

O⁺(⁴S) + H₂O charge-transfer cross-section and product-ion time-of-flight measurements are presented over a center-of-mass collision energy range of 0.2–15 eV. The results are obtained with a newly constructed guided-ion beam experiment. The measured energy dependence of the charge-transfer crosssection agrees well with previous measurements and ADO model predictions of Bates [Chem. Phys. Lett. 82, 396 (1981) Proc. R. Soc. Lond. A384, 289 (1982) Chem. Phys. Lett. 111, 428 (1984)] at low collision energies, but exhibits significant differences at collision energies above 2 eV. The product kinetic energy analysis shows that most of the product ions are produced with near-thermal kinetic energies. At low collision energies, a significant backscattered channel is observed that is associated with complex formation. This channel exhibits a cross-section of approximately 1.4 Ųat a collision energy of 2.65 eV, corresponding to a laboratory ion energy of 5 eV.     

Excitation of the Aπu state of N by electrons

Absolute values of the emission cross sections for five vibrational bands in the Meinel system of N₂⁺,A²π_u to X²Σ_g⁺, excited by electron impact are presented. From these, a value was obtained for the total excitation cross section of the A²π_u state at 100 eV of 26·5 × 10⁻¹⁸ cm². The results are compared with those of other workers and with theory. Collisional transfer of the excitation energy from the levels of the A²π_u state was also observed with a transfer cross section of approximately 10⁻¹⁴ cm².     

Doppler profiles of the 5577 Å airglow

We discuss the altitude and intensity of the nocturnal green line emission resulting from O₂⁺ recombination. The Doppler profile of this emission is markedly non-thermal, the width being characteristic of the energy at which the O(¹S) atoms are produced. A simple theory is formulated which predicts the profile of this line. Experimental evidence on airglow line profiles is reviewed and it is found that the effect predicted here has not yet been observed. However a deliberate search for this effect should yield immediate results.     

Oxygen isotopes in the martian atmosphere: Implications for the evolution of volatiles

Non-thermal escape of oxygen by recombination of exospheric O₂⁺ combined with diffusive separation of gases at lower altitude provides a mechanism through which the Martian atmosphere may be enriched in ¹⁸O relative to ¹⁶O. Measurement of the abundance of ¹⁸O relative to ¹⁶O together with a determination of the turbopause may be used to develop important constraints on the history of Martian volatiles. Models for the interpretation of these data are developed and discussed in light of present information.