Crustal Composition of China Continent Constrained from Heat Flow Data and Helium Isotope Ratio of Underground Fluid

Based on conservation of energy principle and heat flow data in China continent, the upper limit of 1.3 μW/m3 heat production is obtained for continental crust in China. Furthermore, using the data of heat flow and helium isotope ratio of underground fluid, the heat productions of different tectonic units in China continent are estimated in range of 0.58–1.12 μW/m3 with a median of 0.85 μW/m3. Accordingly, the contents of U, Th and K2O in China crust are in ranges of 0.83–1.76 μg/g, 3.16–6.69 μg/g, and 1.0%–2.12%, respectively. These results indicate that the abundance of radioactive elements in the crust of China continent is much higher than that of Archean crust; and this fact implies China’s continental crust is much evolved in chemical composition. Meanwhile, significant lateral variation of crustal composition is also exhibited among different tectonic units in China continent. The crust of eastern China is much enriched in incompatible elements such as U, Th and K than that of western China; and the crust of orogenic belts is more enriched than that of platform regions. It can also be inferred that the crusts of eastern China and orogenic belts are much felsic than those of western China and platform regions, respectively, derived from the positive correlation between the heat production and SiO2 content of bulk crust. This deduction is consistent with the results derived from the crustal seismic velocity data in China. According to the facts of the lower seismic velocity of China than the average value of global crust, and the higher heat production of China continent compared with global crust composition models published by previous studies, it is deduced that the average composition models of global continent crust by Rudnick and Fountain (1995), Rudnick and Gao (2003), Weaver and Tarney (1984), Shaw et al. (1986), and Wedepohl (1995) overestimate the abundance of incompatible elements such as U, Th and K of continental crust.     

Element Abundances of China‘s Continental Crust and Its Sedimentary Layer and Upper Continental Crust

China’s continental crust (CCC) has an average thickness of 47km, with the upper continental crust (CUCC) being 31 km and the sedimentary layer(CSL) 5 km in thickness. The CCC, CUCC and CSL measure 12.437 × 10⁻¹⁷, 8.005 × 10⁻¹⁷ and 1.146 × 10¹⁷ metric tons in mass, respectively. The mass ratio of the upper continental crust to the lower one is 1.8:1. The element abundances were calculated for the CCC, CUCC and CSL respectively in terms of the chemical compositions of 2246 samples of various types and some complementary trace element data. The total abundance of 13 major elements accounts for 99.6% of the CCC mass while the other minor elements only account for 0.4%. REE characteristics, the abundance ratios of element pairs and the amounts of ore-forming elements are also discussed in the present paper.     

Lithium isotopic composition and concentration of the upper continental crust

The Li isotopic composition of the upper continental crust is estimated from the analyses of well-characterized shales, loess, granites and upper crustal composites (51 samples in total) from North America, China, Europe, Australia and New Zealand. Correlations between Li, δ⁷Li, and chemical weathering (as measured by the Chemical Index of Alteration (CIA)), and δ⁷Li and the clay content of shales (as measured by Al₂O₃/SiO₂), reflect uptake of heavy Li from the hydrosphere by clays. S-type granites from the Lachlan fold belt (-1.1 to -1.4‰) have δ⁷Li indistinguishable from their associated sedimentary rocks (-0.7 to 1.2‰), and show no variation in δ⁷Li throughout the differentiation sequence, suggesting that isotopic fractionation during crustal anatexis and subsequent differentiation is less than analytical uncertainty (±1‰, 2σ). The isotopically light compositions for both I- and S-type granites from the Lachlan fold belt (-2.5 to + 2.7 ‰) and loess from around the world (-3.1 to + 4.5‰) reflect the influence of weathering in their source regions. Collectively, these lithologies possess a limited range of Li isotopic compositions (δ⁷Li of −5‰ to + 5‰), with an average (δ⁷Li of 0 ± 2‰ at 1σ) that is representative of the average upper continental crust. Thus, the Li isotopic composition of the upper continental crust is lighter than the average upper mantle (δ⁷Li of + 4 ± 2‰), reflecting the influence of weathering on the upper crustal composition. The concentration of Li in the upper continental crust is estimated to be 35 ± 11 ppm (2σ), based on the average loess composition and correlations between insoluble elements (Ti, Nb, Ta, Ga and Al₂O₃, Th and HREE) and Li in shales. This value is somewhat higher than previous estimates (∼20 ppm), but is probably indistinguishable when uncertainties in the latter are accounted for.     

Sm／Nd Evolution of Upper Mantle and Continental Crust：Constraints on Gowth Rates of the Continental Crust

A new approach to the investigation of the Sm/Nd evolution of the upper mantle directly from the data on lherzolite xenoliths is described in this paper.It is demonstrated that the model age TCHUR of an unmetasomatic iherzolite zenolith ca represent the mean depletion age of its mantle source, thus presenting a correlation trend between f^Sm/Nd and the mean depletion age of the upper mantle from the data on xenoliths.This correlation trend can also be derived from the data on river suspended loads as well as from granitoids.Based on the correlation trend mentioned above and mean depletion ages of the upper mantle at various geological times, an evolution curve for the mean f^Sm/Nd value of the upper mantle through geological time has been established.It is suggested that the upwilling of lower mantle material into the upper mantle and the recycling of continental crust material during the Archean were more active ,thus maintaining fairly constantf^Sm/Nd and εNd values during this time period. Similarly ,an evolution curve for the mean f^Sm/Nd value of the continental crust through geological time has also been established from the data of continental crust material.In the light of both evolution curves for the upper mantle and continental crust ,a growth curve for the continental crust has been worked out ,suggesting that :(1)about 30%(in volume )of the present crust was present as the continental crust at 3.8 Ga ago ;(2)the growth rate was much lower during the Archean ;and (3)the Proterozoic is another major period of time during which the continental crust wsa built up .     

胶北太古宙早期锆石U-Pb定年及Hf同位素研究：华北克拉通古老陆壳增生及再循环的证据

古老陆壳物质的发现与鉴别是探索地球早期陆壳形成与演化历史的重要内容之一,锆石U-Pb年龄结合Hf同位素研究是该研究的重要手段。本文通过对胶北地体内一个长英质副片麻岩中的锆石开展系统的原位U-Pb定年和微量、稀土元素分析,获得了多个太古宙早期的锆石。根据这些锆石的阴极发光图像、Th/U比值及稀土元素球粒陨石标准化配分模式,它们具有典型岩浆锆石的特征,其中2个分析点给出了3413Ma和3400Ma(~3.4Ga)的锆石U-Pb年龄,7个分析点给出3547±19Ma(MSWD=1.16)的锆石U-Pb年龄,指示太古宙早期的陆壳岩浆事件;结合华北克拉通其它地区的类似研究结果,暗示华北克拉通可能曾经存在比现今出露面积更大的太古宙早期的古老陆壳。这些古老锆石的Hf同位素分析显示,它们的εHf(t)值在-6.19~0.95之间,平均为-2.54,两阶段Hf模式年龄在3737~4353Ma之间,平均值为~4.1Ga,远大于锆石的U-Pb年龄,指示华北克拉通存在~4.1Ga的地壳增生作用及古老陆壳(3.55Ga)的再循环。     

The geochemical composition of the terrestrial surface (without soils) and comparison with the upper continental crust

The terrestrial surface, the “skin of the earth”, is an important interface for global (geochemical) material fluxes between major reservoirs of the Earth system: continental and oceanic crust, ocean and atmosphere. Because of a lack in knowledge of the geochemical composition of the terrestrial surface, it is not well understood how the geochemical evolution of the Earth’s crust is impacted by its properties. Therefore, here a first estimate of the geochemical composition of the terrestrial surface is provided, which can be used for further analysis. The geochemical average compositions of distinct lithological classes are calculated based on a literature review and applied to a global lithological map. Comparison with the bulk composition of the upper continental crust shows that the geochemical composition of the terrestrial surface (below the soil horizons) is significantly different from the assumed average of the upper continental crust. Specifically, the elements Ca, S, C, Cl and Mg are enriched at the terrestrial surface, while Na is depleted (and probably K). Analysis of these results provide further evidence that chemical weathering, chemical alteration of minerals in marine settings, biogeochemical processes (e.g. sulphate reduction in sediments and biomineralization) and evaporite deposition are important for the geochemical composition of the terrestrial surface on geological time scales. The movement of significant amounts of carbonate to the terrestrial surface is identified as the major process for observed Ca-differences. Because abrupt and significant changes of the carbonate abundance on the terrestrial surface are likely influencing CO₂-consumption rates by chemical weathering on geological time scales and thus the carbon cycle, refined, spatially resolved analysis is suggested. This should include the recognition of the geochemical composition of the shelf areas, now being below sea level.     

中国东部地壳元素丰度与岩石平均化学组成研究

迄今我们习用的地壳化学元素丰度和岩石平均化学组成的文献值大多是收集的汇编数据,不少微量元素特别是贵金属等难测元素的丰度所依据的样品的代表性和测试质量难以考证,其值存在着颇大的不确定度。本研究立足于实测资料,在中国东部系统采集了各类火成岩和变质杂岩体及各时代的标准地层剖面岩石样品28253个,组合成2718个分析样。采用中子活化等15种可靠分析方法测试,以国家一级标准物质作质量监控。求得的华北地台地壳、中国东部上地壳和出露地壳及各类岩石的78种化学元素丰度,显著改善了地壳和岩石的化学元素丰度,填补了多种岩石微量元素丰度的空白。     

Heterogeneous magnesium isotopic composition of the upper continental crust

High-precision Mg isotopic data are reported for ∼100 well-characterized samples (granites, loess, shales and upper crustal composites) that were previously used to estimate the upper continental crust composition. Magnesium isotopic compositions display limited variation in eight I-type granites from southeastern Australia (δ²⁶Mg = −0.25 to −0.15) and in 15 granitoid composites from eastern China (δ²⁶Mg = −0.35 to −0.16) and do not correlate with SiO₂ contents, indicating the absence of significant Mg isotope fractionation during differentiation of granitic magma. Similarly, the two S-type granites, which represent the two end-members of the S-type granite spectrum from southeastern Australia, have Mg isotopic composition (δ²⁶Mg = −0.23 and −0.14) within the range of their potential source rocks (δ²⁶Mg = −0.20 and +0.15) and I-type granites, suggesting that Mg isotope fractionation during crustal anatexis is also insignificant. By contrast, δ²⁶Mg varies significantly in 19 A-type granites from northeastern China (−0.28 to +0.34) and may reflect source heterogeneity.Compared to I-type and S-type granites, sedimentary rocks have highly heterogeneous and, in most cases, heavier Mg isotopic compositions, with δ²⁶Mg ranging from −0.32 to +0.05 in nine loess from New Zealand and the USA, from −0.27 to +0.49 in 20 post-Archean Australian shales (PAAS), and from −0.52 to +0.92 in 20 sedimentary composites from eastern China. With increasing chemical weathering, as measured by the chemical index of alternation (CIA), δ²⁶Mg values show a larger dispersion in shales than loess. Furthermore, δ²⁶Mg correlates negatively with δ⁷Li in loess. These characteristics suggest that chemical weathering significantly fractionates Mg isotopes and plays an important role in producing the highly variable Mg isotopic composition of sedimentary rocks.Based on the estimated proportions of major rock units within the upper continental crust and their average MgO contents, a weighted average δ²⁶Mg value of −0.22 is derived for the average upper continental crust. Our studies indicate that Mg isotopic composition of the upper crust is, on average, mantle-like but highly heterogeneous, with δ²⁶Mg ranging from −0.52 to +0.92. Such large isotopic variation mainly results from chemical weathering, during which light Mg isotopes are lost to the hydrosphere, leaving weathered products (e.g., sedimentary rocks) with heavy Mg isotopes.     

Rate of growth of the preserved North American continental crust: Evidence from Hf and O isotopes in Mississippi detrital zircons

Detrital zircons from the Mississippi River have been analyzed for U-Th-Pb, Lu-Hf and O isotopes to constrain the rate of growth of the preserved North American continental crust. One hundred and forty two concordant zircon U/Pb dates on grains mounted in epoxy, obtained by Excimer laser ablation ICP-MS method, resolved six major periods of zircon crystallization: 0-0.25, 0.3-0.6, 0.95-1.25, 1.3-1.5, 1.65-1.95 and 2.5-3.0 Ga. These age ranges match the ages of the recognized lithotectonic units of the North American continent in the hinterland of the Mississippi River. Ninety-six zircons mounted on tape, which show no age zonation and were within 7.5% of concordance, were selected to represent the six U/Pb age time intervals and analyzed for Lu-Hf and O isotope by laser ablation MC-ICP-MS and SHRIMP II, respectively. The δ¹⁸O values of the zircons show a small step increase in the maximum δ¹⁸O values at the Archean-Proterozoic boundary from 7.5‰ in the Archean to 9.5‰, and rarely 13‰, in the Proterozoic and Phanerozoic. However, the average value of δ¹⁸O in zircons changes little with time, showing that the increase in the maximum δ¹⁸O values between 2.5 and 2.0 Ga, which can be attributed to an increase in the sediment content of the source regions of younger granitoids, is largely balanced by an increase in zircons with anomalously low δ¹⁸O, which can be attributed to hydrothermally altered crust in the granitoid source region.εHf_i values for the zircons range from 13.1 to −26.9. Zircons derived from juvenile crust, which we define as having mantle δ¹⁸O (4.5-6.5‰) and lying within error of the Hf depleted mantle growth curve, are rare or absent in the Mississippi basin. The overwhelming majority of zircons crystallized from melted pre-existing continental crust, or mantle-derived magmas that were contaminated by continental crust. The average time difference between primitive crust formation and remelting for each of the recognized lithotectonic time intervals, which is defined as crustal incubation time in this study, is 890 ± 460 Myr. There is also a suggestion that the crustal incubation time increases with decreasing age in the Mississippi basin, which is consistent with the declining role of radioactive heat production in the lower crust with time.The average Hf model age (1.94 Ga), weighted by fraction of zircons in the river load is in reasonable agreement with the Nd model age (1.7 Ga) for the Mississippi River. However, if the zircons are weighted by the area of North America covered by the six recognized periods of zircon crystallization the average model age is 2.35 Ga, which compares favorably with an area weighted Nd model age of 2.36 Ga. Our preferred approach is to use the measured O isotope values to constrain variations in the ¹⁷⁶Lu/¹⁷⁷Hf ratio of the granitic source region from which the zircons crystallized, making the assumption that zircons with mantle-like O isotopic ratios have higher ¹⁷⁶Lu/¹⁷⁷Hf than zircons with higher O isotope values. This method gives an average Hf model age of 2.53 Ga, which is 180 Myr older than the constant ¹⁷⁶Lu/¹⁷⁷Hf calculation.The area weighted zircon Hf model ages show two distinct periods of crust formation for the North American continent, 1.6-2.2 and 2.9-3.4 Ga. At least 50% of the preserved North American continental crust was extracted from the mantle by 2.9 Ga and 90% by 1.6 Ga. Two similar periods of crustal growth are also recognized in Gondwana (Hawkesworth C. J. and Kemp A. I. S. (2006) Using hafnium and oxygen isotopes in zircons to unravel the record of crustal evolution. Chem. Geol.226, 144-162.), suggesting that these may be periods of global continental crustal growth. However, we stress that more data from other continents are required before the hypothesis of episodic global continental growth can be accepted with confidence.     

Generalized geophysical model and dynamic properties of the continental crust

Detailed seismic investigations of the continental crust have produced evidence of definite regularities in the general layering of the consolidated crust despite its high degree of inhomogeneity. Three main layers may be resolved in the inner part of a continent: an upper layer with velocities of 5.8–6.4 km/s and a velocity gradient about 0.04–0.05 s⁻¹, an intermediate layer with velocities of 6.2–6.6 km/s and velocity gradient about zero, and a lower layer with velocities of 6.8–7.2 km/s and a high-velocity gradient of 0.05–0.1 s⁻¹. The intermediate layer is characteristically different not only because of its low average velocity gradient, but also because of its more pronounced horizontal layering, inversion zones, and its higher “transparency” and V_p/V_s ratio. The gravity and magnetic data have shown that basement inhomogeneities disappear at the top of the intermediate layer. Also there are few earthquakes in this layer. These pecularities may be interpreted as the result of partial melting (weakening) of rocks and their possible horizontal mobility inside this layer.Thus, dynamic models of tectonic processes must take into consideration the possible existence of a weak zone in the crust.     

Relative contributions of crust and mantle to the origin of the Bijli Rhyolite in a palaeoproterozoic bimodal volcanic sequence (<Emphasis Type="Italic">Dongargarh Group</Emphasis>), central India

New mineralogical, bulk chemical and oxygen isotope data on the Palaeoproterozoic Bijli Rhyolite, the basal unit of a bimodal volcanic sequence (Dongargarh Group) in central India, and one of the most voluminous silicic volcanic expressions in the Indian Shield, are presented. The Bijli Rhyolite can be recognized as a poorly sorted pyroclastic deposit, and comprises of phenocrystic K-feldspar + albite ± anorthoclase set in fine-grained micro-fragmental matrix of quartz-feldspar-sericite-chlorite-iron-oxide ± calcite. The rocks are largely metaluminous with high SiO₂, Na₂O + K₂O, Fe/Mg, Ga/Al, Zr, Ta, Sn, Y, REE and low CaO, Ba, Sr contents; the composition points to an ‘A-type granite’ melt. The rocks show negative Cs-, Sr-, Eu- and Ti- anomalies with incompatible element concentrations 2–3 times more than the upper continental crust (UCC). LREE is high (La/Yb ∼ 20) and HREE 20–30 times chondritic. δ¹⁸O_whole-rock varies between 4.4 and 7.8‰ (mean 5.87±1.26‰). The Bijli melt is neither formed by fractionation of a basaltic magma, nor does it represent a fractionated crustal melt. It is shown that the mantle-derived high temperature basaltic komatiitic melts/high Mg basalts triggered crustal melting, and interacted predominantly with deep crust compositionally similar to the Average Archaean Granulite (AAG), and a shallower crustal component with low CaO and Al₂O₃ to give rise to the hybrid Bijli melts. Geochemical mass balance suggests that ∼ 30% partial melting of AAG under anhydrous condition, instead of the upper continental crust (UCC) including the Amgaon granitoid gneiss reported from the area, better matches the trace element concentrations in the rocks. The similar Ta/Th of the rhyolites (0.060) and average granulite (0.065) vs. UCC (0.13) also support a deep crustal protolith. Variable contributions of crust and mantle, and action of hydrothermal fluid are attributed for the spread in δ¹⁸O^whole-rock values. The fast eruption of high temperature (∼ 900°C) rhyolitic melts suggests a rapid drop in pressure of melting related to decompression in an extensional setting.     

Seismic structure and rheology of the crust under mainland China

The crust and upper mantle in mainland China were relatively densely probed with wide-angle seismic profiling since 1958, and the data have provided constraints on the amalgamation and lithosphere deformation of the continent. Based on the collection and digitization of crustal P-wave velocity models along related wide-angle seismic profiles, we construct several crustal transects across major tectonic units in mainland China. In our study, we analyzed the seismic activity, and seismic energy releases during 1970 and 2010 along them. We present seismogenic layer distribution and calculate the yield stress envelopes of the lithosphere along the transects, yielding a better understanding of the lithosphere rheology strength beneath mainland China. Our results demonstrate that the crustal thicknesses of different tectonic provinces are distinctively different in mainland China. The average crustal thickness is greater than 65 km beneath the Tibetan Plateau, about 35 km beneath South China, and about 36–38 km beneath North China and Northeastern China. For the basins, the thickness is ~ 55 km beneath Qaidam, ~ 50 km beneath Tarim, ~ 40 km beneath Sichuan and ~ 35 km beneath Songliao. Our study also shows that the average seismic P-wave velocity is usually slower than the global average, equivalent with a more felsic composition of crust beneath the four tectonic blocks of mainland China resulting from the complex process of lithospheric evolution during Triassic and Cenozoic continent–continent and Mesozoic ocean–continent collisions. We identify characteristically different patterns of seismic activity distribution in different tectonic blocks, with bi-, or even tri-peak distribution of seismic concentration in South Tibet, which may suggest that crustal architecture and composition exert important control role in lithosphere deformation. The calculated yield stress envelopes of lithosphere in mainland China can be divided into three groups. The results indicate that the lithosphere rheology structure can be described by jelly sandwich model in eastern China, and crème brulee models with weak and strong lower crust corresponding to lithosphere beneath the western China and Kunlun orogenic belts, respectively. The spatial distribution of lithospheric rheology structure may provide important constraints on understanding of intra- or inter-plate deformation mechanism, and more studies are needed to further understand the tectonic process(es) accompanying different lithosphere rheology structures.     

大陆边缘弧岩浆成因与大陆地壳形成

大陆地壳如何形成是国际学术界长期关注并正在持续攻关的一个重大基础科学问题。活动陆缘弧的岩浆成因和密度分选过程是理解大陆地壳形成机制和演化过程的关键。北美白垩纪Cordilleran大陆边缘弧的形成可能经历了与底侵幔源岩浆有关的下地壳部分熔融和岩浆混合,或幔源初始玄武质岩浆的两阶段成分分异过程,以花岗质成分为主的北美内华达地区垂向地壳成分剖面结构可能与榴辉岩相残留体或堆晶岩的拆沉作用密切相关。目前并不清楚亚洲大陆南部以约200 Ma和约90 Ma两个时间断面为代表的中生代冈底斯弧,为何出现大量角闪石岩并具有玄武安山质的平均成分。探究中生代冈底斯弧的岩浆成因、地壳垂向成分结构和地壳形成机制可能有助于或多或少地解决这一问题。     

Granulite xenoliths from western Saudi Arabia: the lower crust of the late Precambrian Arbian-Nubian Shield

Mafic and intermediate granulite xenoliths, collected from Cenozoic alkali basalts, provide samples of the lower crust in western Saudi Arabia. The xenoliths are metaigneous two-pyroxene and garnet granulites. Mineral and whole rock compositions are inconsistent with origin from Red Sea rift-related basalts, and are compatible with origin from island arc calc-alkaline and low-potassium tholeiitic basalts. Most of the samples are either cumulates from mafic magmas or are restites remaining after partial melting of intermediate rocks and extraction of a felsic liquid. Initial⁸⁷Sr/⁸⁶Sr ratios are less than 0.7032, except for two samples at 0.7049. The Sm-Nd data yield T_DM model ages of 0.64 to 1.02 Ga, similar to typical Arabian-Nubian Shield upper continental crust. The isotopic data indicate that the granulites formed from mantle-derived magmas with little or no contamination by older continent crust. Calculated temperatures and pressures of last reequilibration of the xenoliths show that they are derived from the lower crust. Calculated depths of origin and calculated seismic velocities for the xenoliths are in excellent agreement with the crustal structure model of Gettings et al. (1986) based on geophysical data from western Saudi Arabia. Estimation of mean lower crustal composition, using the granulite xenoliths and the Gettings et al. (1986) crustal model, suggests a remarkably homogeneous mafic lower crust, and an andesite or basaltic andesite bulk composition for Pan-African juvenile continental crust.     

The Ivrea—Verbano and Strona-Ceneri Zones, Northern Italy: A cross-section of the continental crust—New evidence from seismic velocities of rock samples

Seismic velocities under confining pressures to 10 kbar have been measured for rocks of the Ivrea—Verbano and Strona—Ceneri Zones of northern Italy, a metamorphic complex thought to represent a cross-section of the continental crust and crust—mantle boundary. Laboratory-determined compressional wave velocities for schists and gneisses of the amphibolite facies found in the upper levels of the section (having an average density of 2.74 g/cm³) average 6.45 km/sec at pressures between 6 and 10 kbar. These increase with depth to values greater than 7.1 km/sec for amphibolites and rocks of the amphibolite—granulite facies transition and to 7.5 km/sec. (average density 3.06 g/cm³) in intermediate and mafic granulite facies rocks near the base of the section. Compressional wave velocities then abruptly increase to 8.5 km/sec in ultramafic complexes near the Insubric Line. Regional geophysical surveys show that P_g is 6.0 km/sec (density of 2.7 g/cm³), P* is 7.2–7.4 km/sec (density of 3.1 g/cm³) and P_n is 8.1 km/sec, values which are in agreement with the laboratory data when effects of temperature are taken into consideration. Estimated thicknesses of exposed rock units are in reasonable agreement with thicknesses determined for crustal layers in seismic refraction experiments. The agreement between the regional crustal structure and the laboratory-determined values of velocity and density provides strong evidence for the hypothesis that the rocks of this metamorphic complex represent a cross-section of the continental crust of the Po Basin.Using the Ivrea—Verbano and Strona—Ceneri sequence as a model of the continental crust, the crust of northern Italy is shown to consist of a thick series of metamorphic rocks with greenschist facies rocks occupying the uppermost levels. These grade downward into amphibolite facies gneisses and schists with occasional granitic intrusives. The Conrad discontinuity is marked by a change from silicic and intermediate amphibolite facies gneisses to intermediate and mafic granulite facies rocks in which hydrous minerals diminish in abundance and thus represents a distinct transition in terms of both composition and metamorphic grade. The lower crust is dominated by a heterogeneous series of mafic and metapelitic rocks in the granulite facies. Importantly, metasedimentary rocks of intermediate silica content found in the complex can have compressional wave velocities equivalent to velocities in mafic rocks suggesting that the lower continental crust everywhere is not necessarily mafic in composition. Ultramafic complexes near the Insubric Line may represent the upper mantle of the continent and their setting suggests that the continental crust-upper mantle boundary is sharp and is not isochemical.     

Crust-mantle interaction in continental arcs: inferences from the Mesozoic arc in the southwestern United States

Arc magmas ranging in composition from basaltic andesites to rhyolites and intrusive equivalents were emplaced into the western margin of the North American craton starting in Late Triassic time giving way to rift0related sedimentation in the Late Jurassic. The region of this study cuts across Proterozoic basements of contrasting Nd model ages, 1.7–1.8 Ga (average ɛ_Nd∼−11) in eastern Arizona and 2.0 to 2.3 GA (average ɛ_Nd∼−18) in western Arizona and eastern California (Bennett and DePaolo 1987). The Mesozoic rocks have initial ɛ_Nd of -3.4 to-6.4 in the eastern part of the study area and -7.1 to -9.2 in the western part. All of the rocks have elevated ⁸⁷Sr/⁸⁷Sr initial ratios (>0.706). Trends in initial ɛ_Nd values of Mesozoic arc rocks are directly correlated with the Nd model ages of the basement through which they passed. Simple two-component mixing calculations indicate that recycled continental crust in the arc magmas represents on average about 65%. A minimum of 35% mantle input into continental arc magmas, as recent as the Mesozoic, represents a significant contribution to the growth of the continental crust, in the absence of a return flow of continental material into the mantle of similar magnitude. In a detailed study in the Santa Rita Mountains. Arizona, there is a pattern of increase of ɛ_Nd with time: early basaltic andesites have more negative ɛ_Nd than later felsic rocks. A correlated pattern of depletion with time is also observed with trace element and major element data. We attribute this either to progressive hybridization of the lower crust by repeated injection of mantle magmas, or the progressive thinning of the continental crust during prolonged arc magmatism. The present data do not allow distinction between the two models. Progressive decrease in crustal contribution to arc magmas with time may be an important feature of continental arc evolution. Hybridization of the lower crust due to repeated injection of mantle melts during arc magmatism may help contribute to small-scale heterogeneities in lower crust inferred from seismic and xenolith data. Similarly, whether there is a well defined MOHO or sharp crust-mantle boundary in any given segment of the continental crust may in part depend on the extent of crust modification as a result of continental arc magmatism.     

Rheologic properties of the lithosphere and applications to passive continental margins

Thermal and petrologic models of the crust and upper mantle are used for calculating effective viscosities on the basis of constant creep rates. Viscosity—depth models together with pressure—depth models are calculated for continental and oceanic blocks facing each other at continental margins. It is found from these “static models” that the overburden pressure in the lower crust and uppermost mantle causes a stress which is directed from the ocean to the continent. The generally low viscosity of 10²⁰–10²³ poise in this region should permit a creep process which could finally lead to a “silent” subduction. In the upper crust static stresses act in the opposite direction, i.e. from the continent to the ocean, favouring tension which could produce normal faulting in the continent. Differences between observations and the results obtained from the static models are attributed to dynamical forces.     

Gold Content of Mantle-Derived Rocks from Eastern China and Its Implications

We have analyzed the gold content of 65 samples of mantle-derived xenoliths and their host rocks from eastern China, which is found to be inhomogeneous, falling in the ranges of 1.0×109-8.2×109 (averaging 3.8 ×10-9) and 0.2×10-9-5.3×10-9 (averaging 2.7×10-9) in the mantle-derived xenoliths and the host basalts respectively. Except the samples from Wanquan County of Hebei Province and Anding County of Hainan Province, the gold content is the highest on the margins of the North China platform and decreases spatially towards the north and south, and temporally the samples of the Tertiary have a higher gold content than those of the Quaternary. The gold content of the mantle-derived xenoliths and the host Paleozoic kimberlites is 3.8×10-9-180×109and 0.1×10-9-38.0×10-9 respectively, which are higher than that in the mantle-derived xenoliths in basalt and the host Cenozoic basalts. The mantle-derived xenoliths have a higher gold content than the host rocks, but their relativity is not very clear, su     

Magmatic evolution of the South Shetland Islands,Antarctica, and implications for continental crust formation

Lavas from the South Shetland Islands volcanic arc (northern Antarctic Peninsula) have been investigated in order to determine the age, petrogenesis and compositional evolution of a long-lived volcanic arc constructed on 32-km-thick crust, a thickness comparable with average continental crust. New ⁴⁰Ar–³⁹Ar ages for the volcanism range between 135 and 47 Ma and, together with published younger ages, confirm a broad geographical trend of decreasing ages for the volcanism from southwest to northeast. The migration pattern breaks down in Palaeogene time, with Eocene magmatism present on both Livingston and King George islands, which may be due to a change in both subduction direction and velocity after c. 60 Ma. The lavas range from tholeiitic to calc-alkaline, but there is no systematic change with age or geographic location. The compositions of lavas from the north-eastern islands indicate magma generation in a depleted mantle wedge with relatively low Sr and high Nd isotopic compositions and low U/Nb, Th/Nd and Ba/Nb ratios that was metasomatized by hydrous fluids from subducted basaltic oceanic crust. Lavas from the south-western islands show an additional sedimentary influence most likely due to fluid release from subducted sediments into the mantle wedge. Although magmatic activity in the South Shetland arc extended over c. 100 m.y., there is no evolution towards more enriched or evolved magmas with time. Few South Shetland arc lavas are sufficiently enriched with incompatible elements to provide a potential protolith for the generation of average continental crust. We conclude that even long-established subduction zones with magmatic systems founded on relatively thick crust do not necessarily form continental crustal building blocks. They probably represent only the juvenile stages of continental crust formation, and additional re-working, for example during subsequent arc-continental margin collision, is required before they can evolve into average continental crust.     

A damage model for the continuum rheology of the upper continental crust

In orogenic zones it is often considered appropriate to use a continuum rheology to model the deformation of the upper continental crust. In this paper we derive an applicable rheology utilizing fiber-bundle and continuum-damage models. We show that the results are identical and yield a power relation between stress σ and strain rate of the form σ= ^ρ−1. We constrain the applicable values of ρ utilizing Omori's law for the decay of aftershocks and conclude that ρ−1 is in the range of 5–15. With this strong nonlinear viscous rheology the behavior of the deforming upper crust approaches that of a perfect-plastic material.