On the surface composition of Io

The wavelength dependence of the reflectivity of Io indicates the presence of two materials on the surface of this satellite of Jupiter. These materials are sulfur and an unspecified material (R₁) which shows a wavelength dependence of its reflectivity for 0.3 μm < λ < 1.0 μm similar to the non-H₂O frost spectrum of the rings of Saturn. A 60/40 admixture of these two spectra matches the observed reflection spectrum of Io from 0.3μm–3 μm, if the spectrum of R₁ is featureless for λ > 1 μm. Sulfur will give rise to a posteclipse brightening. The variation with wavelength of the temperature dependence of the reflectivity of sulfur will allow an observational confirmation of the presence of sulfur on Io. The material R₁ should show a large geometrical albedo. The translucency of sulfur is consistent with the polarization-phase curve to Io. The material R₁ is also required to be translucent. The thermal conductivity of a cooled sulfur powder under vacuum was measured and found to agree with the value determined for the upper layer of Io from observations at 10 μm. It is shown that this agreement is not necessarily meaningful.     

Possible correlation of Io's posteclipse brightening with major solar flares

In 6 of the 7 instances where posteclipse brightening of Io has been reported by observers using blue filters, a major solar flare occurred within 10° of the sub-Jovian longitude in the 100-day interval prior to observation. In none of the 18 instances where no posteclipse brightening was observed did such a flare occur. It is proposed that a phenomenon associated with a major solar flare causes an increase in the trapped particle flux at Io's orbit by an order of magnitude. The posteclipse brightening may be caused by thermoluminescence of Io's surface material upon emergence. Alternatively, it is possible that the increase in trapped particle flux would warm the surface, creating a temporary atmosphere which would precipitate during eclipse cooling and vaporize in the period of warming after reemergence.     

A search for posteclipse brightening of Io in 1973. II

Four eclipse reappearances of Io were observed with an area-scanning photometer during the 1973 apparition of Jupiter. The results of these observations and of the ones reported in the preceding paper are discussed in the context of recent physical models for posteclipse brightening. An evaluation of the relative merits and deficiencies of all observational techniques which have been used to search for posteclipse brightening of Io leads to the conclusion that the reality of this phenomenon remains very much in doubt.     

Studies of proton-irradiated SO2 at low temperatures: Implications for lo

The infrared absorption spectrum from 3.3 to 27 μm (3030-370 cm^?) of SO₂ ice films has been measured at 20 and 88°K before and after 1-MeV proton irradiation. The radiation flux was chosen to simulate the estimated flux of Jovian magnetospheric 1-MeV protons incident on Io. After irradiation, SO₃ is identified as the dominant molecule synthesized in the SO₂ ice. This is also the case after irradiation of composite samples of SO₂ with sulfur, or disulfites. Darkening was observed in irradiated SO₂ ice and in irradiated S₈ pellets. Photometric and spectral measurements of the thermoluminescence of irradiated SO₂ have been made during warming. The spectrum appears as a broad band with a maximum at 4450 Å. Analysis of the luminescence data suggests that, at Ionian temperatures, irradiated SO₂ ice would not be a dominant contributor to posteclipse brightening phenomena. After warming to room temperature, a form of SO₃ remains along with a sulfate and S₈. Based on these experiments, it is reasonable to propose that small amounts of SO₃ may exist on the surface of Io as a result of irradiation synthesis in SO₂ frosts.     

Sulfur in vacuum: Sublimation effects on frozen melts,and applications to Io's surface and torus

A form of sulfur that is white at room temperature, shows almost no color change on cooling, and is fluffy in texture has been found in experiments on the effects of vacuum sublimation on solid sulfur. The white sulfur is a residual skin that forms on frozen sulfur in vacuum by differential evaporation of molecular species in the solid. S₈ ring sulfur is the dominant sublimation phase lost to the vacuum sink, and polymeric sulfur is the dominant residual phase. The microtexture of the fluffy sulfur layer is skeletal with an organized structure of filamentary components constructed of chains and clumps of submicron polyhedra. The layer is very porous (∼98%) and attains a thickness of ∼0.5 mm after 800 hr at 10⁻⁷ Torr (∼10⁻¹⁰ atm), and does not thicken much thereafter. Its color changes from that of the original melt freeze—yellow, tan, or brown depending on the prefreeze melt temperature—to white at room temperature. The UV/VIS reflectance spectrum (0.35 to 0.70 μm) of the original sulfur is greatly modified by formation of the vacuum surface layer: the blue absorption band edge moves toward the UV resulting in an increase in reflectivity in the range 0.42−0.46 μm as much as 400% and the UV reflectivity below 0.40 μm is reduced to one-third its original level to as low as 2%. Initially the changing band-edge position remains temperature sensitive, as in unmodified sulfur, shifting to shorter wavelengths with decreasing temperature, and returning to its precooled wavelength with temperature recovery; but once vacuum “maturity” is reached the temperature-induced excursion range of the absorption edge is reduced by an order of magnitude and is mostly in the UV whereas for ordinary sulfur (S₈) it is mostly in the blue. The sublimation rate from fresh frozen sulfur at initial exposure to high vacuum (∼10⁻⁷ Torr) is ∼3 × 10¹⁵ S cm⁻² sec⁻¹ at 300°K, increases steeply with temperature, decreases with higher vacuum pressure, and decreases with vacuum exposure time reaching an equilibrium flux of ∼3 × 10¹⁴ S cm⁻² sec⁻¹ after ∼1200 hr. For fresh frozen sulfur evaporating at ∼300°K and ∼10⁻⁷ Torr there occur significant spectral, color, and albedo effects in as little as 10 hr; samples become uniformly whitened within ∼100 hr, and progressive whitening and change in surface spectral properties continue for at least 1200 hr.This vacuum sulfur should exist in large quantity on Jupiter's satellite Io if there is solid free sulfur there that has solidified from a melt. A sulfur volcanism model for Io based on these findings is outlined. Color and spectra of different sulfur areas of Io may indicate relative crystallization age and cooling history. Concepts to be developed from this work on vacuum sulfur may help in understanding properties of Io's surface such as composition, texture, adsorbtivity, thermal inertia, photometry, and posteclipse brightening. The inferred flux of subliming sulfur from hotspots on Io is consistent with estimated turnover rates of the surface and is sufficient to supply the requisite sulfur to the Io plasma torus.     

Cassini/VIMS observation of an Io post-eclipse brightening event

During the Cassini-Jupiter flyby, VIMS observed Io at different phase angles, both in full sunlight and in eclipse. By using the sunlight measurements, we were able to produce phase curves in the visual through all the near infrared wavelengths covered by the VIMS instrument (0.85-5.1 μm). The phase angle spanned from ∼2° to ∼120°. The measurements, done just after Io emerged from Jupiter's shadow, show an increase of about 15% in Io's reflectance with respect to what would be predicted by the phase curve. This behavior is observed at wavelengths >1.2 μm. Moreover, just after emergence from eclipse an increase of about 25% is observed in the depth of SO₂ frost bands at 4.07 and 4.35 μm. At 0.879<λ<1.04 μm the brightening is 10-24%. Below λ=0.879 μm the brightening, if present, should be less than the precision of our measurements (∼5%). Apparently, these observations are not explained neither by a diverse spatial distribution of SO₂ on the Io' surface nor by atmospheric SO₂ condensation on the surface during the eclipse.     

Io's surface composition based on reflectance spectra of sulfur/salt mixtures and proton-irradiation experiments

The available full-disk reflectance spectra of Io in the range 0.3 to 2.5 μm have been interpreted by comparison with new laboratory spectra of a wide variety of natural and synthetic mineral phases in order to determine a surface compositional model for Io that is consistent with Io's other known chemical and physical properties. Our results indicate that the dominant mineral phases are sulfates and free sulfur derived from them, which points toward a low temperature and initially water-rich surface assemblage. Our current preferred mineral phase mixture that best matches the Io data and is simultaneously most consistent with other constraints, consists of a fine-grained particulate mixture of free sulfur (55 vol%), dehydrated bloedite [Na₂Mg(SO₄)₂·xH₂O] (30 vol%) ferric sulfate [Fe₂(SO₄)₃·xH₂O] (15 vol%), and trace amounts of hematite [Fe₂O₃]. Other salts may be present, such as halite and sodium nitrate, as well as clay minerals. Such a model is consistent with a probable pre- and post-accretion thermal history of Io-forming material and Io's observed Na emission and other properties. These results further support the evaporite surface hypothesis of Fanale et al'; while not precluding the presence of certain silicate phases such as montmorillonite.The average surface of Io's leading hemisphere appears to contain less free sulfur and more salts and to be finer grained than that of the trailing hemisphere. Since Io is immersed in Jupiter's magnetosphere, irradiation damage effects from low-energy proton bombardment were studied. Irradiation damage of lattices is estimated to be a relatively minor but operative process on the surface of Io; irradiation darkening by sulfate reduction to free sulfur and by F-center production in salts may be partly responsible for the differences in albedo of leading and trailing hemispheres and equatorial and polar regions of Io, but slight regional differences in relative intrinsic phase concentration on the surface may likewise account for these global variations in albedo.Possible unusual surface properties predicted by this model include: posteclipse darkening in certain wavelenghts, limb brightening in certain wavelengths, and unusual surface electrical properties. Further refinement of Io's surface composition model and better understanding of surface irradiation effects will be possible when observational data in the range 0.20 to 0.30 μm are obtained and when improved spectra in the range 0.30 to 5.0 μm are obtained having increased spectral, spatial, and temporal resolution.     

Eclipse reappearances of Io: Time-resolved spectroscopy (1.9-4.2 μm)

We obtained time-resolved, near-infrared spectra of Io during the 60-90 min following its reappearance from eclipse by Jupiter on five occasions in 2004. The purpose was to search for spectral changes, particularly in the well-known SO₂ frost absorption bands, that would indicate surface-atmosphere exchange of gaseous SO₂ induced by temperature changes during eclipse. These observations were a follow-on to eclipse spectroscopy observations in which Bellucci et al. [Bellucci et al., 2004. Icarus 172, 141-148] reported significant changes in the strengths of two strong SO₂ bands in data acquired with the VIMS instrument aboard the Cassini spacecraft. One of the bands (4.07 μm [ν₁ + ν₃]) observed by Bellucci et al. is visible from ground-based observatories and is included in our data. We detected no changes in Io’s spectrum at any of the five observed events during the approximately 60-90 min during which spectra were obtained following Io’s emergence from Jupiter’s shadow. The areas of the three strongest SO₂ bands in the region 3.5-4.15 μm were measured for each spectrum; the variation of the band areas with time does not exceed that which can be explained by the Io’s few degrees of axial rotation during the intervals of observation, and in no case does the change in band strength approach that seen in the Cassini VIMS data. Our data are of sufficient quality and resolution to show the weak 2.198 μm (4549.6 cm⁻¹) 4ν₁ band of SO₂ frost on Io for what we believe is the first time. At one of the events (June 22, 2004), we began the acquisition of spectra ∼6 min before Io reappeared from Jupiter’s shadow, during which time it was detected through its own thermal emission. No SO₂ bands were superimposed on the purely thermal spectrum on this occasion, suggesting that the upper limit to condensed SO₂ in the vertical column above Io’s surface was ∼4 × 10⁻⁵ g cm⁻².     

Unsteady flows in Io’s atmosphere caused by condensation and sublimation during and after eclipse: Numerical study based on a model Boltzmann equation

The behavior of Io’s atmosphere during and after eclipse is investigated on the basis of kinetic theory. The atmosphere is mainly composed of sulfur dioxide (SO₂) gas, which condenses to or sublimates from the frost of SO₂ on the surface depending on the variation of surface temperature (～90–114 K). The atmosphere may also contain a noncondensable gas, such as sulfur monoxide (SO) or oxygen (O₂), as a minor component. In the present study, an accurate numerical analysis for a model Boltzmann equation by a finite-difference method is performed for a one-dimensional atmosphere, and the detailed structure of unsteady gas flows caused by the phase transition of SO₂ is clarified. For instance, the following scenario is obtained. The condensation of SO₂ on the surface, starting when eclipse begins, gives rise to a downward flow of the atmosphere. The falling atmosphere then bounces upward when colliding with the lower atmosphere but soon falls again. This process of falling and bounce back of the atmosphere repeats during the eclipse, resulting in a temporal oscillation of the macroscopic quantities, such as the velocity and temperature, at a fixed altitude. For a pure SO₂ atmosphere, the amplitude of the oscillation is large because of a fast downward flow, but the oscillation decays rapidly. In contrast, for a mixture, the downward flow is slow because the noncondensable gas adjacent to the surface hinders the condensation of SO₂. The oscillation in this case is weak but lasts much longer than in the case of pure SO₂. The present paper is complementary to the work by Moore et al. (Moore, C.H., Goldstein, D.B., Varghese, P.L., Trafton, L.M., Stewart, B. [2009]. Icarus 201, 585–597) using the direct simulation Monte Carlo (DSMC) method.     

Cassini observations of Io's visible aurorae

More than 500 images of Io in eclipse were acquired by the Cassini spacecraft in late 2000 and early 2001 as it passed through the jovian system en route to Saturn (Porco et al., 2003, Science 299, 1541-1547). Io's bright equatorial glows were detected in Cassini's near-ultraviolet filters, supporting the interpretation that the visible emissions are predominantly due to molecular SO₂. Detailed comparisons of laboratory SO₂ spectra with the Cassini observations indicate that a mixture of gases contribute to the equatorial emissions. Potassium is suggested by new detections of the equatorial glows at near-infrared wavelengths from 730 to 800 nm. Neutral atomic oxygen and sodium are required to explain the brightness of the glows at visible wavelengths. The molecule S₂ is postulated to emit most of the glow intensity in the wavelength interval from 390 to 500 nm. The locations of the visible emissions vary in response to the changing orientation of the external magnetic field, tracking the tangent points of the jovian magnetic field lines. Limb glows distinct from the equatorial emissions were observed at visible to near-infrared wavelengths from 500 to 850 nm, indicating that atomic O, Na, and K are distributed across Io's surface. Stratification of the atmosphere is demonstrated by differences in the altitudes of emissions at various wavelengths: SO₂ emissions are confined to a region close to Io's surface, whereas neutral oxygen emissions are seen at altitudes that reach up to 900 km, or half the radius of the satellite. Pre-egress brightening demonstrates that light scattered into Jupiter's shadow by gases or aerosols in the giant planet's upper atmosphere contaminates images of Io taken within 13 minutes of entry into or emergence from Jupiter's umbra. Although partial atmospheric collapse is suggested by the longer timescale for post-ingress dimming than pre-egress brightening, Io's atmosphere must be substantially supported by volcanism to retain auroral emissions throughout the duration of eclipse.     

Sputtering of sulfur by kiloelectronvolt ions: Application to the magnetospheric plasma interaction with Io

Measurements of total yields, temperature dependences, mass spectra, and energy spectra of molecules sputtered from condensed sulfur (S₈) at low temperatures by keV ions are reported and results are given for Jovian plasma ion bombardment of Io. A change in the reflectance of the sulfur, which can be removed by annealing, is produced by the most penetrating ions and may be connected with the darker, colder polar regions on Io. The measured sputtering yields are much lower than those estimated earlier for room temperature sulfur films but are comparable to previous measurements of keV ion sputtering of SO₂ at low temperatures. The corrected mass spectrum indicates that ≈66% of the total yield corresponds to S₂ ejection while only 5 and 16% correspond to S and S₃, respectively. Therefore, if ions reach the surface of Io its atmosphere will have a non-negligible sulfur component of primarily S₂. The ejection of S and S₂ is temperature independent for temperatures characteristic of most of the surface of Io. The energy spectrum for S has an approximate 1/E² dependence at high ejection energies, whereas S₂ and S₃ fall off more rapidly. Assuming 50% coverage of both sulfur and SO₂ and a thin atmosphere (e.g., nightside and polar region) the direct sputter injection of sulfur atoms and molecules into the Jovian plasma torus and the indirect injection due to coronal processes are estimated. These injection rates for sulfur are compared to those for SO₂ showing that injection from sulfur deposits contributes 13% to the total mass injection rate of ∼2–3 × 10²⁹ amu/sec.     

Search for color changes and brightening of Io upon eclipse reappearance

Medium-resolution spectra were made of Io as it emerged from two eclipses in December 1975. In the wavelength range 4000–5800 Å, no spectral changes greater than the standard deviations were observed when the spectrum of Io just after reappearance was divided by the spectrum of Io 20 min later. No substantial increase in total brightness was observed over the same time interval. These observations were made at a time when the sub-Earth point was in Io's northern hemisphere; therefore, prediction of positive posteclipse brightening in this circumstance is not confirmed.     

Sulfur dioxide on Io: Spatial distribution and physical state

Observations of the 4-μm SO₂ band on Jupiter's satellite Io and laboratory measurements of SO₂ frost are presented. The observations confirm the existence of a large longitudinal variation in band strength but show no evidence of temporal changes. Comparison of the band position and shape in Io's spectrum with those in the laboratory frost's suggests that the bulk of the absorption on Io is due to frost, not adsorbed gas. The derived SO₂ coverage is large enough to require that SO₂ be present in most terrain types on Io and not just in the white plains unit. To reconcile the infrared observations that indicate large amounts of SO₂ with the ultraviolet observations of Voyager and IUE that show little, the SO₂ must be mixed intimately with the sulfur (or other material) so that at each wavelength the darker component dominates the spectrum.     

1-D DSMC simulation of Io's atmospheric collapse and reformation during and after eclipse

A one-dimensional Direct Simulation Monte Carlo (DSMC) model is used to examine the effects of a non-condensable species on Io's sulfur dioxide sublimation atmosphere during eclipse and just after egress. Since the vapor pressure of SO₂ is extremely sensitive to temperature, the frost-supported dayside sublimation atmosphere had generally been expected to collapse during eclipse as the surface temperature dropped. For a pure SO₂ atmosphere, however, it was found that during the first 10 min of eclipse, essentially no change in the atmospheric properties occurs at altitudes above ∼100 km due to the finite ballistic/acoustic time. Hence immediately after ingress the auroral emission morphology above 100 km should resemble that of the immediate pre-eclipse state. Furthermore, the collapse dynamics are found to be greatly altered by the presence of even a small amount of a non-condensable species which forms a diffusion layer near the surface that prevents rapid collapse. It is found that after 10 min essentially no collapse has occurred at altitudes above ∼20 km when a nominal mole fraction of non-condensable gas is present. Collapse near the surface occurs relatively quickly until a static diffusion layer many mean free paths thick of the non-condensable gas builds up which then retards further collapse of the SO₂ atmosphere. For example, for an initial surface temperature of 110 K and 35% non-condensable mole-fraction, the ratio of the SO₂ column density to the initial column density was found to be 0.73 after 10 min, 0.50 after 30 min, and 0.18 at the end of eclipse. However, real gas species (SO, O₂) may not be perfectly non-condensable at Io's surface temperatures. If the gas species was even weakly condensable (non-zero sticking/reaction coefficient) then the effect of the diffusion layer on the dynamics was dramatically reduced. In fact, if the sticking coefficient of the non-condensable exceeds ∼0.25, the collapse dynamics are effectively the same as if there were no non-condensable present. This sensitivity results because the loss of non-condensable to the surface reduces the effective diffusion layer size, and the formation of an effective diffusion layer requires that the layer be stationary; this does not occur if the surface is a sink. Upon egress, vertical stratification of the condensable and non-condensable species occurs, with the non-condensable species being lifted (or pushed) to higher altitudes by the sublimating SO₂ after the sublimating atmosphere becomes collisional. Stratification should affect the morphology and intensity of auroral glows shortly after egress.     

The ultraviolet absorber on Venus: Amorphous sulfur

The large backscattering cross section of the particles composing the upper clouds on Venus suggests that a small quantity of high refractive index material is present in the clouds. We propose that this material is elemental sulfur and that sulfur also accounts for the absorption of uv-visible radiation at wavelengths outside of the SO₂ absorption bands. A physical-chemical model of the clouds shows that sulfur, with a mass comparable to that of the observed Mode 1 particles, can be produced in oxygen-poor regions of the upper clouds and in rising air columns. Sulfur production from SO₂ can be rapid, which explains the observed correlation between SO₂ and the uv absorber. The sulfur is properly located to be the uv absorber uv absorber since its calculated concentration rapidly increases with depth in the upper clouds, but it is largely absent in the middle and lower clouds. Sulfur nucleation provides a means of generating the observed bimodal particle size distribution in the upper clouds. Chemical modeling shows that the sulfur vapor is rich in short-chain allotropes such as S₃ and S₄. These allotropes have absorption bands centered near 4000 and 5300 Å, respectively. We suggest that the sulfur particles on Venus are largely composed of S₈, but also contain a few percent of S₃ and S₄. Such particles could account for the wavelength dependence of the albedo of Venus and for the solar energy deposition profile in the clouds. These allotropes are metastable and relax to S₈ over periods of hours to days, providing a simple explanation for the relatively short lifetime of the uv absorber.     

No sulfur flows on Io

Physical and chemical properties of elemental sulfur are incompatible with the suggestion that the colored flows associated with volcanoes on Io are quenched unstable allotropes of sulfur. Either the volcanic flows are not sulfur, or some mechanism other than quenching is required to produce colored forms of sulfur in them. The properties of sulfur are unsuited to the production and survival of colored unstable allotropes on Io. The color of this object is probably due to some other material, possibly iron compounds.     

Io: Geochemistry of sulfur

The evidence from Voyager imaging, Earth-based spectral reflectivity studies, and thermal emission measurements combine to suggest an extremely fresh, volcanically recycled sulfur-rich crust for Io, with very shallow large-scale melting. Two present styles of volcanism are possible, depending on the thickness of local deposits of sulfur: shallow liquid sulfur magma generation with quiescent flooding, and high-temperature volcanism with violent eruption of a sulfur-iron magma driven by SO₂. Evolutionary considerations preclude direct derivation of Io's lithosphere from any metal-bearing chondritic source material. Metal-free C3V- or C2M-type parent material of either primary or secondary origin is the most plausible direct antecedent of the present sulfur-rich crust. Sulfates are almost certainly important constituents of the mantle, and can participate in the recycling of reduced, dense sulfide species to prevent total extraction of sulfur into the core.     

Spectral reflectance of solid sulfur trioxide (0.25–5.2 μm): Implications for Jupiter's satellite Io

We have measured the reflection spectrum of solid sulfur trioxide and we have compared this spectrum to the spectral geometric albedo of Jupiter's satellite Io. We find that the laboratory spectrum of solid SO₃ has very strong absorption features at 3.38, and 4.08 μm. The 3.38- and 3.70-μm absorptions are present very weakly (if indeed at all) in the spectral geometric albedo of Io. This suggests that solid SO₃, if present at all, could exist only as a very minor component of Io's surface. We note that studies involving particle bombardment of SO₂ (a known Io surface constituent) produce SO₃ (Moore, 1984, Icarus 31, 40–80). Sulfur trioxide, once formed on Io's surface, would be extremely stable; however, it would not be expected to accumulate to levels detectable from Earth-based instruments. While it may be possible that the constant resurfacing of Io by volcanic ejecta may cover any SO₃ formed, the area subject to such extensive resurfacing on short time scales (∼ 1 year) is at best ∼10%. Therefore, we would expect that condensed SO₂ remote from volcanos should develop a small but significant SO₃ concentration that could be detected by instruments such as the near-infrared mapping spectrometer on the Galileo spacecraft.     

S2O, polysulfuroxide and sulfur polymer on Io's surface?

To settle the question of disulfur monoxide and sulfur monoxide deposition and occurrence on Io's surface, we performed series of laboratory experiments reproducing the condensation of S₂O at low temperature. Its polymerization has been monitored by recording infrared spectra under conditions of temperature, pressure, mixing with SO₂ and UV-visible radiation simulating that of Io's surface. Our experiments show that S₂O condensates are not chemically stable under ionian conditions. We also demonstrate that SO and S₂O outgassed by Io's volcanoes and condensing on Io's surface should lead to yellow polysulfuroxide deposits or to white deposits of S₂O diluted in sulfur dioxide frost (i.e., S₂O/SO₂ < 0.1%). Thus S₂O condensation cannot be responsible for the red volcanic deposits on Io. Comparison of the laboratory infrared spectra of S₂O and polysulfuroxide with NIMS/Galileo infrared spectra of Io's surface leads us to discuss the possible identification of polysulfuroxide. We also recorded the visible transmission spectra of sulfur samples resulting from polysulfuroxide decomposition. These samples consist in a mixture of sulfur polymer and orthorhombic sulfur. Using the optical constants extracted from these measurements, we show that a linear combination of the reflectance spectra of our samples, the reflectance spectrum of orthorhombic S₈ sulfur and SO₂ reflectance spectrum, leads to a very good matching of Io's visible spectrum between 330 and 520 nm. We conclude then that Io's surface is probably mainly composed of sulfur dioxide and a mixture of sulfur S₈ and sulfur polymer. Some polysulfuroxide could also co-exist with these dominant components, but is probably restricted to some volcanic areas.     

Spectral reflectivities of the Galilean satellites and Titan, 0.32 to 0.86 micrometers

A spectrophotometric observational study of the Galilean satellites and Titan was carried out at 0.004-μm (40-Å) resolution over the spectral range 0.32 to 0.86 μm. A standard lunar area was used as a primary spectroscopic standard to establish the relative reflection spectra of the objects by ratioing the sky-corrected satellite spectra to the standard area on the Moon. J1 (Io) is found to have a spectral edge at 0.33 μm that has not been previously reported. The increase in reflectivity from 0.4 to 0.5 μm and the band at 0.56 μm are confirmed. A weak band at 0.56 μm is probable on J2 (Europa) and possible on J3 (Ganymede). J4 (Callisto) shows no spectral features that have not been previously reported. On Titan, no temporal variations in the methane bands greater than 2% were found, indicating that the effective path length in the Titan atmosphere did not change over the 3-month period of this study. A new absorption band of methane at 0.68 μm was found on Titan. We propose an extension of the evaporite model of Fanale et al. (1974, 1977) and the sulfur mixing models of Wamsteker et al. (1974) in which the primary constituent of the surface of J1 is elemental sulfur sublimated onto the surface by photodissociation of hydrogen sulfide outgassing from the interior. The sulfur is continually renewed by sublimation, sputtering, and redeposition. At low temperatures irradiation produces stable S₂, S₃, S₄, S₆, and long chain polymers. Some of these allotropes have an edge at 0.33 μm, a rising reflectance between 0.4 and 0.5 μm a band at 0.56 μm. All of these features are found in the spectrum of J1. We conclude that the lunar ratioing technique used in this study is well suited for determining the relative reflection spectra of solar system objects.