Venus: Mesospheric hazes of ice,dust, and acid aerosols

We speculate on the origin and physical properties of haze in the upper atmosphere of Venus. It is argued that at least four distinct types of particles may be present. The densest and lowest haze, normally seen by spacecraft, probably consists of a submicron sulfuric acid aerosol which extends above the cloud tops (at ～70 km) up to ～80 km; this haze represents an extension of the upper cloud deck. Measurements of the temperature structure between 70 and 120 km indicate that two independent water ice layers may occasionally appear. The lower one can form between 80 and 100 km and is probably the detached haze layer seen in high-contrast limb photography. This ice layer is likely to be nucleated on sulfuric acid aerosols, and is analogous to the nacreous (stratospheric) clouds on Earth. At the Venus “mesopause” near 120 km, temperatures are frequently cold enough to allow ice nucleation on meteoric dust or ambient ions. The resulting haze (which is analogous to noctilucent clouds on Earth) is expected to be extremely tenous, and optically invisible. On both Earth and Venus, meteoric dust is present throughout the upper atmosphere and probably has similar properties.     

Polarization studies of the Venus uv contrasts: Cloud height and haze variability

Polarimetry is able to show direct evidence for compositional differences in the Venus clouds. We present observations (collected during $\text{2}\text{1}\text{2}$ Venus years by the Pioneer Venus Orbiter) of the polarization in four colors of the bright and dark ultraviolet features. We find that the polarization is significantly different between the bright and dark areas. The data show that the “null” model of L. W. Esposito (1980, J. Geophys. Res.85, 8151–8157) and the “overlying haze” model of J. B. Pollack et al. (1980, J. Geophys. Res.85, 8223–8231) are insufficient. Exact calculations of the polarization, including multiple scattering and vertical inhomogeneity near the Venus cloud tops, are able to match the observations. Our results give a straightforward interpretation of the polarization differences in terms of known constituents of the Venus atmosphere. The submicron haze and uv absorbers are anticorrelated: for haze properties as given by K. Kawabata et al. (1980, J. Geophys. Res.85, 8129–8140) the excess haze depth at 9350 Å over the bright regions is Δτ_h = 0.03 ± 0.02. The cloud top is slightly lower in the dark features: the extra optical depth at 2700 Å in Rayleigh scattering above the darker areas is Δτ_R = 0.010 ± 0.005. This corresponds to a height difference of 1.2 ± 0.6 km at the cloud tops. The calculated polarization which matches our data also explains the relative polarization of bright and dark features observed by Mariner 10. The observed differential polarization cannot be explained by differential distribution of haze, if the haze aerosols have an effective size of 0.49 μm, as determined by K. Kawabata et al. (1982, submitted) for the aerosols overlying the Venus equator. We propose two models for the uv contrasts consistent with our results. In a physical model, the dark uv regions are locations of vertical convergence and horizontal divergence. In a chemical model, we propose that the photochemistry is limited by local variations in water vapor and molecular oxygen. The portions of the atmosphere where these constituents are depleted at the cloud tops are the dark uv features. Strong support for this chemical explanation is the observation that the number of sulfur atoms above the cloud tops is equal over both the bright and dark areas. The mass budget of sulfur at these altitudes is balanced between excess sulfuric acid haze over the bright regions and excess SO₂ in the dark regions.     

High altitude Venus haze from Pioneer Venus limb scans

High vertical resolution scans of the Venus limb made by the Pioneer Venus Orbiter Cloud Photopolarimeter at 365 nm and 690 nm wavelengths are used to investigate the level of the haze top, and haze particle properties and scale height. Haze particle vertical optical depth 0.01 occurs at altitude 80 to 85 km based on knowledge of instrument pointing. The lowest haze tops were observed close to subsolar longitudes but the data set supports a longitude dependence no more than a temporal variation. Single scattering computations for a spherical shell atmosphere show good agreement with observed intensities for particles smaller than 0.3 μm radius and refractive index less than 1.7, consistent with, but not limited to, concentrated sulfuric acid. Particle scale height in the 0.5 to 2 mbar pressure regions varies between 1 and 3 km over the season (12 of 92 days), latitude (15–45°N), and local time (0900–1800) ranges of the observations. Detached layers of haze are sometimes present. An average particle scale height of 2.2 km at 84 km altitude yields an eddy diffusion coefficient of 1.3 × 10⁵ cm² sec^?1.     

Vertical distribution of scattering hazes in Titan's upper atmosphere

Radial intensity scars of a Voyager 2 high phase angle image of Titan have been inverted to yield vertical extinction profiles at 1° intervals around the limb. A detached haze layer with peak particle number densities ～0.2 cm^?3 exists at all latitudes south of ～45°N, and at an altitude of 300–350 km. The optical depth 0.01 level lies at a radius of 2932 ± 5 km at the equator and at a radius of 2915 ± 10 km over the poles (altitudes of 357 ± 5 and 340 ± 10 km, respectively). In addition to the haze layer at 300–350 km, there is a small enhancement in the extinction at ～450 km which exists at all latitudes between 75°S and ～60°N.     

Liquid content of the lower clouds of venus as determined from mariner 10 radio occultation

S-band (13.06-cm) and X-band (3.56-cm) radio occulation data obtained during the flyby of Venus by Mariner 10 on February 5, 1974 were analyzed to obtain the effects of dispersive microwave absorption by the clouds of Venus. The received power profiles were first corrected for the effects of refraction in the atmosphere of Venus, programmed changes in the pointing direction of the high-gain antenna, and limit-cycle motion of the spacecraft attitude control system. The resulting excess attenuation profiles presumbaly due to cloud absorption have been inverted discretely to obtain profiles of absorption coefficient at the two wavelenghts. The ratios of the absorptivities are consistent with a sulfuric acid-water mixture as the constituent of the absorbing clouds, having a sulfuric acid concentration of 75 ± 25%. Three absorption peaks are evident in the profiles at altitudes of 68, 60, and 48 km. With a sulfuric acid concentration of 75%, the upper cloud has a peak liquid content of 0.08 g/m³, and an integrated content of 0.024 g/cm², which corresponds roughly to terrestrial stratus or altostratus clouds. The major absorption layer has a peak of 1.1 g/m³ at an altitude of 48 km, with an integrated content of 0.5 g/cm², similar to that of terrestrial cumulus and cumulonimbus clouds. The absorption ratios for the middle cloud at 60 km are not consistent with a sulfuric acid-water mixture.     

Comment on absorbing regions in the atmosphere of Venus as measured by radio occultation

Two recent papers, one by A.J. Kliore, C. Elachi, I.R. Patel, and J.B. Cimeno, Icarus37, 51-2- 72, 1979, and one by B. Lipa and G.L. Tyler, Icarus39, 192–208, 1979, reach fundamentally different conclusions concerning microwave absorption in the atmosphere of Venus, even though they are based on the same Mariner 10 radio occultation data. The Lipa and Tyler results are in general agreement with earlier Mariner 5 measurements analyzed by G. Fjeldbo, A.J. Kliore, and V.R. Eshleman, Astron. J.76, 123–140, 1971. We find that in the Kliore et al. treatment: (1) the effects of measurements and analysis uncertainties in the derived values of absorption are underestimated; (2) an incorrect formula is used for computation of the refractive effects needed to determine the absorption; (3) detailed features of a derived profile of absorption would have been created in an optically thin region by known motions of the spacecraft antenna, if its axial direction were biased about 0.5° from the computed directions; and (4) this particular angular bias is consistent with other available information about an apparent residual difference between true and reconstructed antenna pointing directions. We conclude that: (1) there is no credible evidence for measurable microwave absorption in the atmosphere of Venus at heights greater than 55 km for any of the wavelengths that have been used in radio occultation experiments, even though Kliore et al. indicate that there are significant amounts up to at least 70 km for both Mariner 10 wavelengths (13 and 3.6 cm); (2) absorption in the region 35 to 50 km has been reasonably well determined from the two concordant Mariner 5 and 10 analyses, but only at one wavelength (13 cm); and (3) improved instrumentation and careful planning and analysis will be required for the radio occultation technique to realize its potential for the study of absorbing regions in the atmospheres of Venus and the major planets.     

Morphology of the cloud tops as observed by the Venus Express Monitoring Camera

Since the discovery of ultraviolet markings on Venus, their observations have been a powerful tool to study the morphology, motions and dynamical state at the cloud top level. Here we present the results of investigation of the cloud top morphology performed by the Venus Monitoring Camera (VMC) during more than 3 years of the Venus Express mission. The camera acquires images in four narrow-band filters centered at 365, 513, 965 and 1010 nm with spatial resolution from 50 km at apocentre to a few hundred of meters at pericentre. The VMC experiment provides a significant improvement in the Venus imaging as compared to the capabilities of the earlier missions. The camera discovered new cloud features like bright “lace clouds” and cloud columns at the low latitudes, dark polar oval and narrow circular and spiral “grooves” in the polar regions, different types of waves at the high latitudes. The VMC observations revealed detailed structure of the sub-solar region and the afternoon convective wake, the bow-shape features and convective cells, the mid-latitude transition region and the “polar cap”. The polar orbit of the satellite enables for the first time nadir viewing of the Southern polar regions and an opportunity to zoom in on the planet. The experiment returned numerous images of the Venus limb and documented global and local brightening events. VMC provided almost continuous monitoring of the planet with high temporal resolution that allowed one to follow changes in the cloud morphology at various scales.We present the in-flight performance of the instrument and focus in particular on the data from the ultraviolet channel, centered at the characteristic wavelength of the unknown UV absorber that yields the highest contrasts on the cloud top. Low latitudes are dominated by relatively dark clouds that have mottled and fragmented appearance clearly indicating convective activity in the sub-solar region. At ～50° latitude this pattern gives way to streaky clouds suggesting that horizontal, almost laminar, flow prevails here. Poleward from about 60°S the planet is covered by almost featureless bright polar hood sometimes crossed by dark narrow (～300 km) spiral or circular structures. This global cloud pattern can change on time scales of a few days resulting in global and local “brightening events” when the bright haze can extend far into low latitudes and/or increase its brightness by 30%. Close-up snapshots reveal plenty of morphological details like convective cells, cloud streaks, cumulus-like columns, wave trains. Different kinds of small scale waves are frequently observed at the cloud top. The wave activity is mainly observed in the 65–80° latitude band and is in particular concentrated in the region of Ishtar Terra that suggests their possible orographic origin. The VMC observations have important implications for the problems of the unknown UV absorber, microphysical processes, dynamics and radiative energy balance at the cloud tops. They are only briefly discussed in the paper, but each of them will be the subject of a dedicated study.     

The abundance and vertical distribution of the unknown ultraviolet absorber in the venusian atmosphere from analysis of Venus Monitoring Camera images

Observations of Venus using the ultraviolet filter of the Venus Monitoring Camera (VMC) on ESA’s Venus Express Spacecraft (VEX) provide the best opportunity for study of the spatial and temporal distribution of the venusian unknown ultraviolet absorber since the Pioneer Venus (PV) mission. We compare the results of two sets of 125 radiative transfer models of the upper atmosphere of Venus to each pixel in a subset of VMC UV channel images. We use a quantitative best fit criterion based upon the notion that the distribution of the unknown absorber should be independent of the illumination and observing geometry. We use the product of the cosines of the incidence and emission angles and search for absorber distributions that are uncorrelated with this geometric parameter, finding that two models can describe the vertical distribution of the unknown absorber. One model is a well-mixed vertical profile above a pressure level of roughly 120 mb (～63 km). This is consistent with the altitude of photochemical formation of sulfuric acid. The second model describes it as a thin layer of pure UV absorber at a pressure level roughly around 24 mb (～71 km) and this altitude is consistent with the top of upper cloud deck. We find that the average abundance of unknown absorber in the equatorial region is 0.21 ± 0.04 optical depth and it decreases in the polar region to 0.08 ± 0.05 optical depth at 365 nm.     

Infrared photometry of Venus: Variation during 10 years?

The infrared flux of Venus has been observed with a narrowband filter (λ = 3.6 μm, Δλ = 0.08 μm) from 1982 through 1984, covering a range of the phase angle α from 27 to 94°. Normalized values of flux at the Venus-Earth distance of 1 AU were (4.0–5.4) × 10^?17W/cm²/cm^?1 and the α dependence of the data is rather weak. Furthermore, when the evening terminator of Venus was seen, lower values of flux were obtained in contrast with higher values at the morning terminator. The α dependence is quite different from that of J.V. Martonchik and R. Beer (1975, J. Atmos. Sci.32, 1151–1156). Since we cannot find any significant problem in the two observational methods, the difference might suggest an intrinsic time variation of haze particles during these 10 years in the upper haze layer of the Venus cloud.     

The structure and microphysical properties of the Venus clouds: Venera 9, 10, and 11 data

Data processing and interpretation of the nephelometer measurements made in the Venus atmosphere aboard the Venera 9, 10 and 11 landers in the sunlit hemisphere near the equator are discussed. These results were used to obtain the aerosol distribution and its microphysical properties from 62 km to the surface. The main aerosol content is found in the altitude range between 62 km (where measurements began) and 48 km, the location of the cloud region. Three prominent layers labeled as I (between 62 and 57 km), II (between 57 and 51 km) and III (between 51 and 48 km), each with different particle characteristics are discovered within the clouds. The measured light-scattering patterns can be intrepreted as having been produced by particles with effective radii from 1 to 2 μm depending on height and indices of refractivity from 1.45 in layer I to 1.42 in layer III. These values do not contradict the idea that the droplets are made of sulfuric acid. In layers II and III the particle size distribution is at least bimodal rather than uni-modal. The index of refraction is found to decrease to 1.33 in the lower part of layer II, suggesting a predominant abundance of larger particles of different chemical origin, and chlorine compounds are assumed to be relevant to this effect. In the entire heightrange of the Venera 9–11 craft descents, the clouds are rather rarefied and are characterized by a mean volume scattering coefficient σ ～ 2 × 10^?5 cm^?1 that corresponds to the mean meteorological range of visibility of about 2 km. The average mass content of condensate is estimated to be equal to 4 × 10^?9 g/cm³, and the total optical depth of clouds to τ ～ 35. Near the bottom of layer III clouds are strongly variable. In the subcloud atmosphere a haze was observed between 48 and 32 km; that haze is mainly made of submicron particles, r_eff ～ 0.1μm. The atmosphere below that is totally transparent but separate (sometimes possibly disappearing) layers may be present up to a height of 8 km above the surface. A model of this region with a very low particle density (N ? 2–3 cm^?3) strongly refractive large particles (r_eff ? 2.5 μm; 1.7 < n < 2.0) provided satisfactory agreement. The optical depth of aerosol in the atmosphere below the subcloud haze does not exceed 2.5.     

Theoretical interpretation of the 0.7820 μm CO2 band and 0.8226 μm H2O line on Venus

We have analyzed the P6, P8, and P10 lines in the 0.7820 μm CO₂ band of Venus using a scattering model. Our new results compare favorably with previous results from the 1.05 μm CO₂ band. We considered nonabsorbing and absorbing clouds. We found that the anisotropic scattering mean free path for both models at the 0.2atm level is between 0.55 and 0.73km, a range close to the value of 1 km for terrestrial hazes. We used our scattering models to synthesize the 0.8226 μm H₂O line, assuming that the clouds are composed of sulfuric acid drops, and found our nonabsorbing cloud required a sulfuric acid concentration of 82% by weight, while our thicker absorbing cloud required a concentration of 89%. A comparison of the variation of optical depth with height for our cloud models with the variation reported by Prinn (1973, Science182, 1132–1134) showed that, within a factor of 2, the variation for Prinn's thinnest cloud agreed with ours. Whitehill and Hansen (1973, Icarus20, 146–152) have recently confirmed the work of Regas et al. (1973a, J. Quant. Spectry. Radiative Transfer13, 461–463) which showed that two cloud layers are not required to explain the CO₂ phase variation of Venus. Prinn's recent photochemical study of sulfuric acid clouds further supports a single, continuous cloud layer in the line formation region instead of two cloud layers with an extensive clear region between. The single layer model appears more likely because the maximum particle density in Prinn's cloud occurs in the clear region between the two layers in the models of Hunt (1972, J. Quant. Spectry. Radiative Transfer12, 405–419) and Carleton and Traub (1972, Bull. Amer. Astron. Soc.4, 362.).     

Transmission of CO2 in the atmosphere of Venus for the spectral region near 7 microns

The transmission in the 7-μm “window” opf Venus was calculated for a 7-layer model atmosphere. The synthetic spectra show that radiation from the layer 20–30 km above the surface would reach the top of the atmosphere between 6.2 and 7.0 μm if there were no absorption besides the isotopic CO₂ bands; for the 7.0- to 8.2-μm region, the radiating level would be located 40–50 km above the surface of Venus. The brightness temperature for the entire region is 430°K; for the above two regions it is 494 and 341°K, respectively.     

A physical model of Titan's aerosols

Microphysical simulations of Titan's stratospheric haze show that aerosol microphysics is linked to organized dynamical processes. The detached haze layer may be a manifestation of 1 cm sec-1 vertical velocities at altitudes above 300 km. The hemispherical asymmetry in the visible albedo may be caused by 0.05 cm sec-1 vertical velocities at altitudes of 150 to 200 km, we predict contrast reversal beyond 0.6 micrometer. Tomasko and Smith's (1982, Icarus 51, 65-95) model, in which a layer of large particles above 220 km altitude is responsible for the high forward scattering observed by Rages and Pollack (1983, Icarus 55, 50-62), is a natural outcome of the detached haze layer being produced by rising motions if aerosol mass production occurs primarily below the detached haze layer. The aerosol's electrical charge is critical for the particle size and optical depth of the haze. The geometric albedo, particularly in the ultraviolet and near infrared, requires that the particle size be near 0.15 micrometer down to altitudes below 100 km, which is consistent with polarization observations (Tomasko and Smith 1982, West and Smith 1991, Icarus 90, 330-333). Above about 400 km and below about 150 km Yung et al.'s (1984, Astrophys. J. Suppl. Ser. 55, 465-506) diffusion coefficients are too small. Dynamical processes control the haze particles below about 150 km. The relatively large eddy diffusion coefficients in the lower stratosphere result in a vertically extensive region with nonuniform mixing ratios of condensable gases, so that most hydrocarbons may condense very near the tropopause rather than tens of kilometers above it. The optical depths of hydrocarbon clouds are probably less than one, requiring that abundant gases such as ethane condense on a subset of the haze particles to create relatively large, rapidly removed particles. The wavelength dependence of the optical radius is calculated for use in analyzing observations of the geometric albedo. The lower atmosphere and surface should be visible outside of regions of methane absorption in the near infrared. Limb scans at 2.0 micrometers wavelength should be possible down to about 75 km altitude.     

The detached haze layer in Titan's mesosphere

By comparing observations from the Cassini imaging system, UV spectrometer, and Huygens atmospheric structure instrument, we determine an apparent radius of ∼40 nm, an imaginary index <0.3 at 187.5 nm and a number density of ∼30 particles cm⁻³ for the detached haze layer at 520 km in Titan's mesosphere. We point out that the detached haze layer is coincident with a local maximum in the measured temperature profile and show that the temperature maximum is caused by absorption of sunlight in the detached haze layer. This rules out condensation as the source of the layer. The derived particle size is in good agreement with that estimated for the size of the monomers in the aggregate particles that make up the main haze layer. Calculations of the sedimentation velocity of the haze particles coupled with the derived number density imply a mass flux , which is approximately equal to the mass flux required to explain the main haze layer. Because the aerosol size and mass flux derived for the detached layer agree with those determined for the main layer, we suggest that the main haze layer in Titan's stratosphere is formed primarily by sedimentation and coagulation of particles in the detached layer. This implies that high-energy radical and ion chemistry in the thermosphere is the main source of haze on Titan.     

Are the clouds of venus sulfuric acid?

Water solutions of sulfuric acid, containing about 75% H₂SO₄ by weight, have a refractive index within 0.01 of the values deduced from polarimetric observations of the Venus clouds. These solutions remain liquid at the cloud temperature, thus explaining the spherical shape of the cloud particles (droplets). The equilibrium vapor pressure of water above such solutions is 0.01 that of liquid water or ice, which accounts for the observed dryness of the cloud region. Furthermore, H₂SO₄ solutions of such concentration have spectra very similar to Venus in the 8–13 μm region; in particular, they explain the 11.2 μm band. Cold sulfuric acid solutions also seem consistent with Venus spectra in the 3–4 μm region. The amount of acid required to make the visible clouds is quite small, and is consistent with both the cosmic abundance of sulfur and the degree of out-gassing of the planet indicated by known atmospheric constituents. Sulfuric acid occurs naturally in volcanic gases, along with known constituents of the Venus atmosphere such as CO₂, HCl, and HF ; it is produced at high temperature by reactions between these gases and common sulfate rocks. The great stability and low vapor pressure of H₂SO₄ and its water solutions explain the lack of other sulfur compounds in the atmosphere of Venus—a lack that is otherwise puzzling.Sulfuric acid precipitation may explain some peculiarities in Venera and Mariner data. Because sulfuric acid solutions are in good agreement with the Venus data, and because no other material that has been proposed is even consistent with the polarimetric and spectroscopic data, H₂SO₄ must be considered the most probable constituent of the Venus clouds.     

Venus cloud properties: Infrared opacity and mass mixing ratio

By using the Mariner 5 temperature profile and a homogeneous cloud model, and assuming that CO₂ and cloud particles are the only opacity sources, the wavelength dependence of the Venus cloud opacity is infrared from the infrared spectrum of the planet between 450 and 1250 cm^?1. Justification for applying the homogeneous cloud model is found in the fact that numerous polarization and infrared data are mutually consistent within the framework of such a model; on the other hand, dense cloud models are not satisfactory.Volume extinction coefficients varying from 0.5 × 10^?5 to 1.5 × 10^?5 cm^?1, depending on the wavelength, are determined at the tropopause level of 6110 km. By using all available data, a cloud mass mixing ratio of approximately 5 × 10^?6 and a particle concentration of about 900 particles cm^?3 at this level are also inferred. The derived cloud opacity compares favorably with that expected for a haze of droplets of a 75% aqueous solution of sulfuric acid.     

Sulfuric acid vapor and other cloud-related gases in the Venus atmosphere: Abundances inferred from observed radio opacity

Laboratory measurements of the microwave opacity of gaseous sulfuric acid under Venus atmospheric conditions indicate that it is an exceptionally strong absorber. They also suggest that its absorptivity has a surprisingly weak dependence on radio frequency, as compared with other common gaseous absorbers. Initial theoretical studies also indicate a large absorptivity and weak frequency dependence, although the measured opacity is several times the computed value, presumably due to deviations from Van Vleck-Weisskopf theory for pressures near and above about 1 atm. The absorbing characteristics of sulfuric acid vapor appear to reconcile what had been thought to be an inconsistency among measurements and deductions concerning the constituents of the atmosphere of Venus, and radio occultation, radar reflection, and radio emission measurements of its opacity. These and previous laboratory measurements of sulfur dioxide, water vapor, and carbon dioxide are used to model relative contributions to opacity as a function of height, in a way that is consistent with observations of the constituents and absorbing properties of the atmosphere. We conclude that sulfuric acid vapor is likely to be the principal microwave absorber in the 30- to 50-km-altitude range of the middle atmosphere of Venus. It would need to have a mixing ratio there of about 35 to 90 ppm if it were the sole absorber. Carbon dioxide, the predominant atmospheric gas, is the main absorber below about 30 km, while sulfur dioxide is an important but secondary absorber in both regions. Water vapor and cloud particulates appear to be only minor contributors to the total opacity. While gaseous sulfuric acid has not been directly measured in any of the in situ probe experiments (due to particular instrumental limitations), its presence at an abundance of the deduced order of magnitude is implied by these and other observations. We suggest that improved radio occultation measurements, in conjuction with high-resolution microwave emission observations and more detailed laboratory studies, could provide important data for investigating the sulfur compound chemistry in the atmosphere of Venus, and that the techniques and results may have application to the study of atmospheric conditions associated with acid rain on Earth.     

Venus Monitoring Camera for Venus Express

The Venus Express mission will focus on a global investigation of the Venus atmosphere and plasma environment, while additionally measuring some surface properties from orbit. The instruments PFS and SPICAV inherited from the Mars Express mission and VIRTIS from Rosetta form a powerful spectrometric and spectro-imaging payload suite. Venus Monitoring Camera (VMC)—a miniature wide-angle camera with 17.5° field of view—was specifically designed and built to complement these experiments and provide imaging context for the whole mission. VMC will take images of Venus in four narrow band filters (365, 513, 965, and 1000 nm) all sharing one CCD. Spatial resolution on the cloud tops will range from 0.2 km/px at pericentre to 45 km/px at apocentre when the full Venus disc will be in the field of view. VMC will fulfill the following science goals: (1) study of the distribution and nature of the unknown UV absorber; (2) determination of the wind field at the cloud tops (70 km) by tracking the UV features; (3) thermal mapping of the surface in the 1 μm transparency “window” on the night side; (4) determination of the global wind field in the main cloud deck (50 km) by tracking near-IR features; (5) study of the lapse rate and H₂O content in the lower 6–10 km; (6) mapping O₂ night-glow and its variability.     

Mars: Topographic control of clouds, 1907–1973

Mariner 9 high-resolution photos and topographic information were used to make a topographic analysis of “blue” and “red” cloud positions reported over a 66-year period in Lowell Observatory records. A sample of 77 “blue” cloud sites lay preferentially at the highest Martian elevations; 60% centered precisely on the seven major volcanic mountain peaks (unknown when the clouds were observed); another 16% lay on substantial slopes or contacts between cratered terrain and lower plains. The median altitude of blue cloud sites was 2.1 km above the global topographic median. These results agree with other evidence that most Earth-detected blue clouds are orographic uplift clouds, composed of condensates. Over half of 131 sporadic yellowish or red clouds were associated with blue clouds or volcanoes, and thus probably did not represent dust storm phenomena, contrary to a commonly held belief. Of 88 “possible dust clouds” (chosen by additional criteria), about two-thirds occur at borders between light and dark areas, in the light regions. These sites may have thin veneers of dust, and current depositional or denudational activity. Median altitude of “possible dust cloud” sites was 0.5 km below the global topographic median. Major dust storms begin in a few “core areas,” two of which associate with major basins Hellas and Isidis, probable reservoirs of mobile dust; but exact topographic control and causes of dust storms are unclear.     

Diurnal CO variations in the Venus mesophere from CO microwave spectra

Microwave spectra of carbon monoxide (¹²CO) in the mesosphere of Venus were measured in December 1978, May and December 1980, and January, September, and November 1982. These spectra are analyzed to provide mixing profiles of CO in the Venus mesosphere and best constrain the mixing profile of CO between ～ 100 and 80 km altitude. From the January 1982 measurement (which, of all our spectra, best constrains the abundance of CO below 80 km altitude) we find an upper limit for the CO mixing ratio below 80 km altitude that is two to three times smaller than the stratospheric (～65 km) value of 4.5 ± 1.0 × 10^?5 determined by P. Connes, J. Connes, L.D. Kaplan, and W. S. Benedict (1968, Astrophys. J.152, 731–743) in 1967, indicating a possible long-term change in the lower atmospheric concentration of CO. Intercomparison among the individual CO profiles derived from our spectra indicates considerable short-term temporal and/or spatial variation in the profile of CO mixing in the Venus mesosphere above 80 km. A more complete comparison with previously published CO microwave spectra from a number of authors specifies the basic diurnal nature of mesospheric CO variability. CO abundance above ～ 95 km in the Venus atmosphere shows approximately a factor of 2–4 enhancement on the nightside relative to the dayside of Venus. Peak nightside CO abundance above ～95 km occurs very near to the antisolar point on Venus (local time of peak CO abundance above ～95 km occurs at 0.6_?0.6^+0.7 hr after midnight on Venus), strongly suggesting that retrograde zonal flow is substantially reduced at an altitude of 100 km in the Venus mesosphere. In contrast, CO abundances between 80 and 90 km altitude show a maximum that is shifted from the antisolar point toward the morningside of Venus (local time of peak CO abundance between 80 and 90 km occurs at 8.5 ± 1.0 hr past midnight on Venus). The magnitude of the diurnal variation of CO abundance between 80 and 90 km is again, approximately a factor of 2–4. Disk-averaged spectra of Venus do not determine the exact form for the diurnal distribution of CO in the Venus mesosphere as indicated by comparison of synthetic spectra, based upon model distributions, and the measured spectra. However, the offset in phase for the diurnal variation for the >95 km and 80–90-km-altitude regions requires an asymmetric (in solar zenith angle) distribution.