Effects of Io ejecta on Europa

We examine the effects of Io ejecta on the surface and environment of Europa. We find that the observed sulfur on the trailing side of Europa, when interpreted as a deposit in equilibrium between implanation of, and sputtering by, corotating Io ejecta, implies a slow loss of material from Europa by sputtering. From this we infer that the spectrum of particles sputtered from water ice is soft. The quantity of observed sulfur and its confinement to the trailing hemisphere appear to exclude significant implantation and sputtering by energetic heavy ions. We also conclude that the contribution from Europa to the magnetospheric plasma (even at Europa itself) is negligible compared to the matter ejected from Io.     

Distribution of hydrate on Europa: Further evidence for sulfuric acid hydrate

Sulfuric acid hydrate has been proposed as an important species on Europa's surface, the acid being produced by radiolysis of surficial sulfur compounds. We investigated the spectral properties of disordered and crystalline forms of sulfuric acid and suggest that the hydration properties of Europa's hypothesized sulfuric acid lie between two end members: liquid sulfuric acid and its higher crystalline hydrates. The spectra of these end members are similar except for spectral shifts at the band edges. We measured the optical constants of sulfuric acid octahydrate and used these with simple radiative transfer calculations to fit Europa spectra obtained by Galileo's Near Infrared Mapping Spectrometer (NIMS). The global distribution of the hydrate that we associate here with hydrated sulfuric acid shows a strong trailing-side enhancement with a maximum fractional hydrate abundance of 90% by volume, corresponding to a sulfur atom to water molecule ratio of 10%. The hydrate concentration spatially correlates with the ultraviolet and visible absorption of the surface and with the sulfur dioxide concentration. The asymmetric global distribution is consistent with Iogenic plasma ion implantation as the source of the sulfur, possibly modified by electron irradiation and sputtering effects. The variegated distribution also correlates with geologic forms. A high spatial resolution image shows resolved lineae with less hydrate appearing within the lineae than in nearby crustal material. The low concentration of hydrated material in these lineae argues against their conveying sulfurous material to the surface from the putative ocean.     

Can redistribution of material by sputtering explain the hemispheric dichotomy of europa?

Sputtering and redeposition make up a significant geologic process on Europa and may contribute to the observed color differences between the leading and trailing hemispheres. Sputtering is particularly efficient on Europa as an erosive process, due to the high rate of ion bombardment from the Io plasma torus, together with Europa’s easily sputtered icy surface. We estimate the global average sputtering erosion rate on Europa at 14.7 mm Myr⁻¹. However, 42% to 86% of sputtered water molecules survive to redeposit onto the surface again. Due to gravitational escape and removal by electron-impact ionization, the number of redepositing particles cannot overcome sputtering erosion, and the global average result of sputtering is net erosion. However, neither sputtering nor redeposition is globally uniform, and differences in the global distributions of the two processes can result locally in net deposition.We propose that Europa’s hemispheric color dichotomy might be explained by net deposition on the leading hemisphere, which may obscure the non-ice signature by covering it with a thin water frost. To test this hypothesis, we have created a simulated model of the sputtering erosion/redeposition process on Europa. Our objectives are to determine the conditions under which net deposition occurs on the leading hemisphere and to evaluate the effects on this process of Jupiter’s gravity, of Europa’s rotation, and of the loss of water molecules to the jovian magnetosphere. We have followed the trajectories of hundreds of thousands of simulated sputtered water molecules in a Monte Carlo process, evolving their orbits under the gravity of both Europa and Jupiter. We have performed this model multiple times, in order to explore the effects of different assumptions of the global distribution of impacting ions, as well as of the sputtered particle ejection velocity. Based upon our results, we conclude that net deposition occurs under a wide range of conditions, making sputtering erosion and redeposition a plausible explanation for the hemispheric color dichotomy of Europa.     

The Physics and Chemistry of Sputtering by Energetic Plasma Ions

Energetic ions from the solar wind, local pick-up ions or magnetospheric plasma ions impact the atmospheres and surfaces of a number of solar system bodies. These energetic incident ions deposit energy in the gas or solid. This can lead to the ejection of atoms and molecules, a process referred to as sputtering. In this paper we first describe the physics and chemistry of atmospheric and surface sputtering. We then apply this to the production of a thin atmosphere on Europa by magnetospheric ion bombardment of Europa's surface and show that Europa loses more Na atoms than it receives from the Jupiter magnetosphere. The loss of atmosphere from Mars in earlier epochs by pick-up ion sputtering of that atmosphere is also calculated. This revised version was published online in July 2006 with corrections to the Cover Date.     

Ganymede,Europa, Callisto,and Saturn's rings: Compositional analysis from reflectance spectroscopy

The reflectance spectra of Ganymede, Europa, Callisto, and Saturn's rings are analyzed using recent laboratory reflectance studies of water frost, water ice, and water and mineral mixtures. It is found that the spectra of the icy Galilean satellites are characteristic of water ice (e.g., ice blocks or possibly very large ice crystals ? 1 cm) or frost on ice rather than pure water frost, and that the decrease in reflectance at visible wavelengths is caused by other mineral grains in the surface. The spectra of Saturn's rings are more characteristic of water frost with some other mineral grains mixed in the frost but not on the surface. The impurities on all these objects are not in spectrally isolated patches but appear to be intimately mixed with the water. The impurity grains appear to have reflectance spectra typical of minerals containing Fe³⁺. Some carbonaceous chondrite meteorite spectra show the necessary spectral shape. Ganymede is found to have more water ice on the surface than previously thought (～90 wt%), as is Callisto (30–90 wt%). The surface of Europa has a vast frozen water surface with only a few percent impurities. Saturn's rings also have only a few percent impurities. The amount of bound water or bound OH for these objects is 5 ± 5 wt% averaged over the entire surface. Thus with the small amount of nonicy material present on these objects, no hydrated minerals can be ruled out. A new absorption feature is identified in Ganymede, Callisto, and probably Europa at 1.5 μm which is also seen in the spectra of Io but not in Saturn's rings. This feature has not been seen in laboratory studies and its cause is unknown.     

Spectral reflectivities of the Galilean satellites and Titan, 0.32 to 0.86 micrometers

A spectrophotometric observational study of the Galilean satellites and Titan was carried out at 0.004-μm (40-Å) resolution over the spectral range 0.32 to 0.86 μm. A standard lunar area was used as a primary spectroscopic standard to establish the relative reflection spectra of the objects by ratioing the sky-corrected satellite spectra to the standard area on the Moon. J1 (Io) is found to have a spectral edge at 0.33 μm that has not been previously reported. The increase in reflectivity from 0.4 to 0.5 μm and the band at 0.56 μm are confirmed. A weak band at 0.56 μm is probable on J2 (Europa) and possible on J3 (Ganymede). J4 (Callisto) shows no spectral features that have not been previously reported. On Titan, no temporal variations in the methane bands greater than 2% were found, indicating that the effective path length in the Titan atmosphere did not change over the 3-month period of this study. A new absorption band of methane at 0.68 μm was found on Titan. We propose an extension of the evaporite model of Fanale et al. (1974, 1977) and the sulfur mixing models of Wamsteker et al. (1974) in which the primary constituent of the surface of J1 is elemental sulfur sublimated onto the surface by photodissociation of hydrogen sulfide outgassing from the interior. The sulfur is continually renewed by sublimation, sputtering, and redeposition. At low temperatures irradiation produces stable S₂, S₃, S₄, S₆, and long chain polymers. Some of these allotropes have an edge at 0.33 μm, a rising reflectance between 0.4 and 0.5 μm a band at 0.56 μm. All of these features are found in the spectrum of J1. We conclude that the lunar ratioing technique used in this study is well suited for determining the relative reflection spectra of solar system objects.     

Sputtering of sulfur: Experiments and consequences for Io

Experimental results on the sputtering of sulfur by MeV He ions are presented. It is shown that, for most of an Io surface, supposedly covered by sulfur, sputtering dominates sublimation in removing material. Sputtering cannot, however, be the sole supply of neutral sulfur for the Io torus.     

Energy Distributions for Desorption of Sodium and Potassium from Ice: The Na/K Ratio at Europa

The sputtering and decomposition of the surface of Europa by fast ions and electrons lead to the production of an atomosphere containing sodium and potassium atoms. Here time-of-flight energy distributions are measured for Na and K sputtered from a vapor-deposited ice by 200-eV electrons. These data are then used in a Monte Carlo simulation for alkalis in Europa's atmosphere. Na/K ratios versus distance from Europa are calculated and compared to the recent observations in the range 6 to 18 Europan radii from the surface. Normalizing to the observations, the Na/K ratio for the loss rates is ∼27 and the ratio for the average surface source rates is ∼20. These ratios are very different from the Na/K ratio at Io and are larger than the Na/K ratio suggested for Europa's putative subsurface ocean, consistent with fractionation on freezing and upwelling of ocean material.     

Thermal segregation of water ice on the Galilean satellites

Consideration of the thermal sublimation of ice on the Galilean satellites suggests that dirty-ice surfaces are susceptible to a process of cold-trapping of water in local bright patches and its preferential removal from dark areas. The result may be very rapid (decade time scale) segregation on the surface into bright icy regions and regions covered by dark ice-free lag deposits. Ion sputtering and micrometeorite bombardment are probably insufficient to prevent this process at low latitudes on Ganymede and Callisto. Sputtering on Europa may prevent segregation, especially on the trailing side. Segregated regions must be mostly smaller than the kilometer resolution of the Voyager images, but larger than centimeter size.     

Habitats and taphonomy of Europa

Jupiter's moon Europa possesses an icy shell kilometers thick that may overlie a briny ocean. The inferred presence of water, tidal and volcanic energy, and nutrients suggests that Europa is potentially inhabited by some kind of life; indeed Europa is a primary target in the search for life in the Solar System although no evidence yet exists for any kind of life. The thickness of the icy crust would impose limits on life, but at least 15 broad kinds of habitats seem possible for Europa. They include several on the sea floor, at least 3 in the water column, and many in the ice itself. All of these habitats are in, or could be transported to, the icy shell where they could be exposed by geologic activity or impacts so they might be explored from the surface or orbit by future planetary missions. Taphonomic processes that transport, preserve, and expose habitats include buoyant ice removing bottom habitats and sediment to the underside of the ice, water currents depositing components of water column habitats on the ice bottom, cryovolcanoes depositing water on the surface, tidal pumping bringing water column and ice habitats to the near-surface ice, and subice freezing and diapiric action incorporating water column and bottom ice habitats into the lower parts of the icy shell. The preserved habitats could be exposed at or near the surface of Europa chiefly in newly-formed ice, tilted or rotated ice blocks, ridge debris, surface deposits, fault scarps, the sides of domes and pits, and impact craters and ejecta. Future exploration of Europa for life must consider careful targeting of sites where habitats are most likely preserved or exist close to the surface.     

Near-infrared spectra of the Galilean satellites: Observations and compositional implications

We have obtained reflectivity spectra of the trailing and leading sides of all four Galilean satellites with circular variable filter wheel spectrometers operating in the 0.7- to 5.5-μm spectral interval. These observations were obtained at an altitude of 41,000 ft from the Kuiper Airborne Observatory. Features seen in these data include a 2.9-μm band present in the spectra of both sides of Callisto; the well-known 1.5-μm and 2.0-μm combination bands and the previously more poorly defined 3.1-μm fundamental of water ice observed in the spectra of both sides of Europa and Ganymede; and features centered at 1.35 ± 0.1, 2.55 ± 0.1, and 4.05 ± 0.05 μm noted in the spectra of both sides of Io. In an effort to interpret these data, we have compared them with laboratory spectra as well as synthetic spectra constructed with a simple multiple-scattering theory. We attribute the 2.9-μm feature of Callisto's spectra primarily to bound water, with the product of fractional abundance of bound water and mean grain radius in micrometers equaling approximately 3.5 × 10^?1 for both sides of the satellite. The fractional amounts of water ice cover on the trailing side of Ganymede, its leading side, and the leading side of Europa were found to be 50 ± 15, 65 ± 15, and 85% or greater, respectively. The bare ground areas on Ganymede have reflectivity properties in the 0.7- to 2.5-μm spectral region comparable to those of Callisto's surface and also have significant quantities of bound water, as does Callisto. Interpretation of the spectrum for the trailing side of Europa is complicated by magnetospheric particle bombardment which causes a perceptible broadening of strong bands, but the ice cover on this side is probably comparable to that on the leading side. These irradiation effects may be responsible for much of the difference in the visual geometric albedos of the two sides of Europa. Minor, but significant, amounts of ferrous-bearing material (either ferrous salts or alkali feldspars but not olivines or pyroxenes) account for the 1.35-μm feature of Io. The two longer wavelength bands are most likely attributable to nitrate salts. Ferrous salts and nitrates can jointly also account for much of the spectral variation in Io's visible reflectivity, thereby eliminating the need to postulate large quantities of sulfur. The absence of noticeable features near 3-μm wavelength in Io's spectra leads to upper bounds of 10% on the fractional cover of water and ammonia ice and 10^?3 on the relative abundance of bound water and hydroxylated material on Io. The two sides of Io have similar compositions. We suggest that the systematic increase in fractional water ice cover from Callisto to Ganymede to Europa is bought about by variations in efficiencies of recoating the satellite's surface by interior water brought to the surface, and by the deposition of extrinsic dust. The most important component of the latter is debris, derived from the outer irregular satellites of Jupiter, which impacts the Galilean satellites at relatively low velocities. Europa has the largest water ice cover because its crust is thinnest and thus the frequency of water recoating is the greatest, and because it is farthest from the sources of low-velocity dust. While models which depict Io's surface as consisting primarily of very fine-grained ice are no longer viable, we are unable to definitively distinguish between the salt assemblage and alkali feldspar models. The salt model can better account for Io's reflectivity spectrum from 0.3 to 5 μm, but the absence of appreciable quantities of bound water and hydroxylated material may not be readily understood within the context of that model.     

The chemical nature of Europa surface material and the relation to a subsurface ocean

The surface composition of Europa is of special interest due to the information it might provide regarding the presence of a subsurface ocean. One source of this information is the infrared reflectance spectrum. Certain surface regions of Europa exhibit distorted H₂O vibrational overtone bands in the 1.5 and 2.0 μm region, as measured by the Galileo mission Near Infrared Mapping Spectrometer (NIMS). These bands are clearly the result of highly concentrated solvated contaminants. However, two interpretations of their identity have been presented. One emphasizes hydrated salt minerals and the other sulfuric acid, although each does not specifically rule out some of the other. It has been pointed out that accurate chemical identification of the surface composition must depend on integrating spectral data with geochemical models, and information on the tenuous atmosphere sputtered from the surface. It is also extremely important to apply detailed chemistry when interpreting the spectral data, including knowledge of mineral dissolution chemistry and the subsequent optical signatures of ion solvation in low-temperature ice. We present studies of flash frozen acid and salt mixtures as Europa surface analogs and demonstrate that solvated protons, metal cations and inorganic anions all influence the spectra and must all, collectively, be considered when assigning Europa spectral features. These laboratory data show best correlation with NIMS Europa spectra for multi-component mixtures of sodium and magnesium bearing sulfate salts mixed with sulfuric acid. The data provide a concentration upper bound of 50-mol% for MgSO₄ and 40-mol% for Na₂SO₄. This newly reported higher sodium and proton content is consistent with low-temperature aqueous differentiation and hydrothermal processing of carbonaceous chondrite-forming materials during the formation and early evolution of Europa.     

Spectral geometric albedos of the Galilean satellites from 0.24 to 0.34 micrometers: Observations with the international ultraviolet explorer

We present the results of an 8-year program of spectrophometry of the Galilean satellites of Jupiter that was undertaken using the International Ultraviolet Explorer (IUE) Spacecraft. The ultraviolet geometric albedos of all four satellites are low. This is consistent with the hypothesis that sulfurous materials escaping from the surface of Io are being distributed by magnetospheric processes to the surfaces of the other three objects. Although iron bearing silicates may also cause UV darkening, these materials also have spectral features in the visible region of the spectrum which are not found in the spectra of the Galilean satellites. For Io, we find that the ultraviolet geometric albedo is very low (P_uv ∼ 0.04). The trailing hemisphere has an albedo that is higher than that of the leading hemisphere. This is opposite of what is observed at visual wavelengths. The decrease of albedo shortward of 0.33 μm is consistent with groundbased observations (Nelson and Hapke, 1978) and the laboratory reflection spectrum of sulfur dioxide frost. The hemispheric albedo asymmetry is consistent with a variable distribution of the frost, it being present in greater abundance on Io's leading hemisphere. The strenght of this feature has not changed with respect to longitude over the8 years of this study. The phase coefficients and opposition surges at ultraviolet wavelenghts indicate that Io's surface regolith is very porous. Europa has the highest ultraviolet albedo of all the Galilean satellites (P_uv ∼ 0.2). This not inconsistent with the hypothesis of recent resurfacing. However, this albedo is not high enough to be consistent with a surface of pure water ice. We confirm a previously reported ultraviolet spectral asymmetry between Europa's leading and trailing hemispheres. The new data are consistent with the previous analyses which interpreted this as the spectral signature of sulfur ions from the Jovian magnetosphere which had been embedded preferentially on the trailing side of Europa's predominately water ice.surface. The opposition surge observed for Europa's trailing side is greater than that for the leading side. This implies that the trailing side is less compact than the leading side, perhaps due to gardening from the ion implantation process. Ganymede's ultraviolet albedo (P_uv ∼ 0.10) is lower than Europa's. Ganymede has an ultraviolet spectral asymmetry that is similar to Europa's for wavelenghts longer than 0.28 μm. However, at wavelengths shorter than 0.28 μm, the two objects have different opposite hemispherical spectral ratios, indicating that the same mechanism cannot be used to explain the ultraviolet spectral albedo of both objects. One possible explanation is that ozone is present in addition to sulfur embedded on Ganymede's surface. The ultraviolet albedo and opposite hemispherical spectral ratio of Calisto is spectrally flat, indicating that the surface is covered by a material that is spectrally absorbing in the ultraviolet but has no change in absorption at the ultraviolet wavelenghts. The orbital phase variation in the ultraviolet indicates that the absorber is assymmetrically distributed in longitude.     

Hydrated minerals on Europa’s surface: An improved look from the Galileo NIMS investigation

The surface composition of Europa is of great importance for understanding both the internal evolution of Europa and its putative ocean. The Near Infrared Mapping Spectrometer (NIMS) investigation on Galileo observed Europa and the other Galilean satellites from 0.7 to 5.2 μm with spatial resolution down to a few kilometers during flybys by the spacecraft as it orbited Jupiter. These data have been analyzed and results published over the life of the Galileo mission and afterward. One result was the discovery of hydrated minerals at some locations on Europa and Ganymede. The data are noisy, especially for Europa, due to radiation affecting the NIMS electronics and detectors, and other artifacts are also present. The NIMS data are now being reprocessed using the accumulated knowledge gained over the entire missions to remove noise spikes and compensate for some other defects in the data. We are analyzing these reprocessed data in an attempt to defined better the nature of the hydrate spectral features and improve their interpretation. We report here on analyses of two NIMS reprocessed observations for the 0.7-3-μm region. A revised hydrate spectrum is calculated and mapped in detail across two lineaments. The spectrum shows the expected distorted water features but little or no spectral structure in these features. A narrow, weak spectral feature appears at 1.344 μm, which is weakly correlated with lower albedo. Several other weak features may be present but are difficult to confirm in these limited data sets. The hydrate signature shows the greatest strength within and toward the center of the lineaments, confirming and strengthening the association of the hydrate with these endogenic features. This trend may indicate that the material in the lineaments is youngest toward the center and has more water frost coverage toward the edge. A small, visually dark, circular feature has a spectrum that shows both hydrate and crystalline water ice features and perhaps contains a hydrate different in spectral characteristics and perhaps composition than found in the lineament.     

The stability of water in Io

A variety of processes have been examined to determine their impact on water loss from Io and the formation of an anhydrous surface. Thermal escape, photolysis, and gas-phase charged particle interactions are shown to be unimportant in this regard. Recent laboratory experiments have shown that charged-particle sputtering is likely to be an effective mechanism for the removal of water ice from Io's surface. Vaporization of ice by meteoroid impacts may also be significant. The overall sputtering rate appears to be sufficiently high that the formation of a substantial regolith due to meteoroid bombardment will be prevented. However, meteoroid bombardment is probably capable of maintaining a thin (? 500 μm overturned surface layer from which all free water has been removed by sputtering. Alternatively, a thick anhydrous surface layer may have formed on Io as the result of primordial heating. The survival of such a layer to the present implies the absence of subsequent water evolution onto the surface of the satellite.     

Implications from Galileo Observations on the Interior Structure and Chemistry of the Galilean Satellites

Data from the recent gravity measurements by the Galileo mission are used to construct wide ranges of interior structure and composition models for the Galilean satellites of Jupiter. These models show that mantle densities of Io and Europa are consistent with an olivine-dominated mineralogy with the ratios of Mg to Fe components depending on mantle temperature for Io and on ice shell thickness for Europa. The mantle density and composition depend relatively little on core composition. The size of the core is largely determined by the core's composition with core radius increasing with the concentration of a light component such as sulfur. For Io, the range of possible core sizes is between 38 and 53% of the satellite's radius. For Europa, there is also a substantial effect of the thickness of the ice layer which is varied between 120 and 170 km on the core size. Core sizes are between 10 and 45% of Europa's radius. The core size of Ganymede ranges between one-quarter and one-third of the surface radius depending on its sulfur content and the thickness of the ice shell. A subset of the Ganymede models is consistent with an olivine-dominated mantle mineralogy. The thickness of the silicate mantle above the core varies between 900 and 1100 km. The outermost ice shell is about 900 km in thickness and is further subdivided by pressure-induced phase transitions into ice I, ice III, ice V, and ice VI layers. Callisto should be differentiated, albeit incompletely. It is proposed that this satellite was never molten at a large scale but differentiated through the convective gradual unmixing of the ice and the metal/rock component. Bulk iron-to-silicon ratios Fe/Si calculated for the inner pair of satellites, Io and Europa, are less than the CI carbonaceous chondrite value of 1.7±0.1, whereas ratios for the outer pair, Ganymede and Callisto, cover a broad range above the chondritic value. Although the ratios are uncertain, in particular for Ganymede and Callisto, the values are sufficiently distinct to suggest a difference in composition between these two pairs of satellites. This may indicate a difference in iron-silicon fractionation during the formation of both classes of satellites in the protojovian nebula.     

Librations of the Galilean satellites: The influence of global internal liquid layers

The four Galilean satellites are thought to harbor one or even two global internal liquid layers beneath their surface layer. The iron core of Io and Ganymede is most likely (partially) liquid and also the core of Europa may be liquid. Furthermore, there are strong indications for the existence of a subsurface ocean in Europa, Ganymede, and Callisto. Here, we investigate whether libration observations can be used to prove the existence of these liquid layers and to constrain the thickness of the overlying solid layers. For Io, the presence of a small liquid core increases the libration of the mantle by a few percent with respect to an entirely solid Io and mantle libration observations could be used to determine the mantle thickness with a precision of several tens of kilometers given that the libration amplitude can be measured with a precision of 1 m. For Europa, Ganymede, and Callisto, the presence of a water ocean close to the surface increases by at least an order of magnitude the ice shell libration amplitude with respect to an entirely solid satellite. The shell libration depends essentially on the shell thickness and to a minor extent on the density difference between the ocean and the ice shell. The possible presence of a liquid core inside Europa and Ganymede has no noticeable influence on their shell libration. For a precision of several meters on the libration measurements, in agreement with the expected accuracy with the NASA/ESA EJSM orbiter mission to Europa and Ganymede, an error on the shell thickness of a few tens kilometers is expected. Therefore, libration measurements can be used to detect liquid layers such as Io’s core or water subsurface oceans in Europa, Ganymede, and Callisto and to constrain the thickness of the overlying solid surface layers.     

Sulfuric Acid Production on Europa: The Radiolysis of Sulfur in Water Ice

Europa's surface is chemically altered by radiolysis from energetic charged particle bombardment. It has been suggested that hydrated sulfuric acid (H₂SO₄·nH₂O) is a major surface species and is part of a radiolytic sulfur cycle, where a dynamic equilibrium exists between continuous production and destruction of sulfur polymers S_x, sulfur dioxide SO₂, hydrogen sulfide H₂S, and H₂SO₄·nH₂O. We measured the rate of sulfate anion production for cyclo-octal sulfur grains in frozen water at temperatures, energies, and dose rates appropriate for Europa using energetic electrons. The measured rate is G_Mixture(SO₄²⁻)=f_Sulfur (r₀/r)^βG₁ molecules (100 eV)⁻¹, where f_Sulfur is the sulfur weight fraction, r is the grain radius, r₀=50 μm, β≈1.9, and G₁=0.4±0.1. Equilibrium column densities N are derived for Europa's surface and follow the ordering N(H₂SO₄) » N(S)>N(SO₂)>N(H₂S). The lifetime of a sulfur atom on Europa's surface for radiolysis to H₂SO₄ is τ(−S)=120(r/r₀)^β years. Rapid radiolytic processing hides the identity of the original source of the sulfurous material, but Iogenic plasma ion implantation and an acidic or salty ocean are candidate sources. Sulfate salts, if present, would be decomposed in <3800 years and be rapidly assimilated into the sulfur cycle.     

S2O, polysulfuroxide and sulfur polymer on Io's surface?

To settle the question of disulfur monoxide and sulfur monoxide deposition and occurrence on Io's surface, we performed series of laboratory experiments reproducing the condensation of S₂O at low temperature. Its polymerization has been monitored by recording infrared spectra under conditions of temperature, pressure, mixing with SO₂ and UV-visible radiation simulating that of Io's surface. Our experiments show that S₂O condensates are not chemically stable under ionian conditions. We also demonstrate that SO and S₂O outgassed by Io's volcanoes and condensing on Io's surface should lead to yellow polysulfuroxide deposits or to white deposits of S₂O diluted in sulfur dioxide frost (i.e., S₂O/SO₂ < 0.1%). Thus S₂O condensation cannot be responsible for the red volcanic deposits on Io. Comparison of the laboratory infrared spectra of S₂O and polysulfuroxide with NIMS/Galileo infrared spectra of Io's surface leads us to discuss the possible identification of polysulfuroxide. We also recorded the visible transmission spectra of sulfur samples resulting from polysulfuroxide decomposition. These samples consist in a mixture of sulfur polymer and orthorhombic sulfur. Using the optical constants extracted from these measurements, we show that a linear combination of the reflectance spectra of our samples, the reflectance spectrum of orthorhombic S₈ sulfur and SO₂ reflectance spectrum, leads to a very good matching of Io's visible spectrum between 330 and 520 nm. We conclude then that Io's surface is probably mainly composed of sulfur dioxide and a mixture of sulfur S₈ and sulfur polymer. Some polysulfuroxide could also co-exist with these dominant components, but is probably restricted to some volcanic areas.