The albedo of Titan

The irradiance of Titan has been measured from 0.50 to 1.08μ in 30 Å band-passes spaced 0.01–0.02μ apart. Geometric albedos have been computed at the wavelenghts of measurement using a standard solar flux distribution after Labs and Neckel. The maximum value of p_λ(0) is 0.37 at 0.68, 0.75, and 0.834μ, the minimum value, in the centers of the strongest methane absorption bands, is 0.10 at 0.887 and 1.012μ.The brightness of Titan at the time of the present measurements has been compared with that of previous modern photoelectric measurements. Within the apparent consistency of the different photoelectric systems, the brightness of Titan appears to undergo changes with time.A provisional curve of the geometric albedo from 0.30 to 4.0μ has been made by combining the present results with those of other authors, i.e., relative measurements of Titan from 0.30 to 0.50μ, and measurements of Jupiter and Saturn from 1.08 to 4.00μ. The latter are used to estimate the strengths of the methane absorption bands of Titan in that spectral range. The bolometric geometric albedo, $\text{p}{}^1\text{(0)}$, is computed to be 0.21. A variety of current measurements of Titan indicate a substantial atmosphere, suggesting a value of the phase integral $\text{q}\text{= 1.30 ± 0.20}$. The bolometric Bond albedo, $\text{A}{}^1$, is then 0.27 ± 0.04, giving an effective radiative temperature T_e= 84 ± 2°K.The absorption band contours of Titan have been compared with those of Jupiter and Saturn at the same resolution. The bands of the planets are known to be due primarily to methane, and they show a very regular relationship, with those of Saturn being consistently deeper and wider. For Titan, the strengths of the bands are equal or less than those of Jupiter in the band centers, while the wings are stronger than those of Saturn.Previous photoelectric and photographic spectra have been examined for evidence of temporal variation of the methane path length in the atmosphere of Titan. Differences in measurement techniques prohibit detection of small differences. The only potential differences beyond experimental uncertainties are those of Kuiper (1944) and Harris (mid-fifties). Taking Kuiper's results at face value, Titan appears to have a shorter methane path length in 1972. Harris's results can be reconciled only by the doubtful hypothesis of an almost complete absence of methane at that time.     

Experimental laboratory simulation of Titan’s atmosphere: aerosols and gas phase

The discovery that Titan, the largest satellite of Saturn, has an atmosphere and that methane is a significant constituent of it, was the starting point for a systematic study of Titan’s atmospheric organic chemistry. Since then, the results from numerous ground-based observations and two flybys of Titan, by Voyager I and II, have led to experimental laboratory simulation studies and photochemical and physical modeling. All these works have provided a more detailed picture of Titan. We report here a continuation of such a study performing an experimental laboratory simulation of Titan’s atmospheric chemistry, and considering the two physical phases involved: gases and aerosols. Concerning the gaseous phase, we report the first detection of C₄N₂ and we propose possible atmospheric abundances for 70 organic compounds on Titan’s upper atmosphere. Concerning the solid phase, we have characterized aerosol analogues synthesized in conditions close to those of Titan’s environment, using elemental analysis, pyrolysis, solubility studies and infrared spectroscopy.     

On inhomogeneous scattering models of Titan's atmosphere

The spectrum of Titan from 4800 to 11 000 Å has many CH₄ absorption bands which cover a range of intensities of several orders of magnitude. Yet even the strongest of these bands in Titan's spectrum has considerable residual central intensity. Some investigators have concluded that these strong CH₄ bands must be highly saturated, but recent laboratory measurements of the bands made at room temperature show that curve-of-growth saturation is very small. At the presumed low pressures and temperatures in Titan's atmosphere, we show that saturation is very dependent on the band model parameters. However, in either a simple reflecting layer model or in a homogeneous scattering model saturation cannot be the principal cause of the filling in of these strong CH₄ bands if our best estimates of the band model parameters are correct. We find that an inhomogeneous scattering model atmosphere with fine “Axel dust” above most ot the CH₄ gas is needed to fill in the band centers. The calculated spectrum of one particular model of this class is compared to observations of Titan. Our essential conclusion is that Titan does have most of its scattering particles above most of the CH₄ gas which has an abundance of at least 2 km-am. This large abundance of CH₄ is necessary to produce the 6420-Å feature recently discovered in Titan's spectrum.     

Experimental simulation of Titan's atmosphere: Detection of ammonia and ethylene oxide

For several years now, an experimental simulation of Titan's atmosphere has been on going at LISA. A cold plasma is established in a gas mixture representative of the atmosphere of the satellite. In these experiments, more than 70 organic compounds have been identified, including the first identification in this type of experimental simulation of C₄N₂ already detected in its solid form on Titan, which suggests that the setup correctly mimics the chemistry of Titan's atmosphere.We have carried out the first experimental simulation including O-containing compounds in order to study the influence of the presence of CO on the chemical behavior of Titan's atmosphere. With the help of gas chromatography–mass spectrometry (GC–MS) and infrared spectroscopy (IRS) we can thus determine which minor species still undetected in Titan's atmosphere are likely to be present and understand the complex chemistry of the atmosphere of this satellite. Surprisingly we have identified unpredicted O-containing gaseous compounds, mainly ethylene oxide (also named oxirane, C₂H₄O). This molecule has been observed in the interstellar medium by observation in the millimeter region (Astrophys. J. 489 (1997) 553; Astron. Astrophys. 337 (1998) 275). On the contrary, the predicted O-compounds (formaldehyde and methanol) have not been identified in this experiment. Furthermore, we have identified NH₃ in the gaseous products with an initial mixture of N₂ (98%) and CH₄ (2%).The paper describes the experimental device used in this work, in particular the IRS and GC–MS techniques. We also comment the results related to the detection of the O-containing compounds and NH₃ and their implications on our knowledge of the chemistry of Titan's atmosphere and on the retrieval of the future Titan data expected from Cassini-Huygens.     

Photochemical processes on Titan: Irradiation of mixtures of gases that simulate Titan's atmosphere

Photochemical reaction pathways in Titan's atmosphere were investigated by irradiation of the individual components and the mixture containing nitrogen, methane, hydrogen, acetylene, ethylene, and cyanoacetylene. The quantum yields for the loss of the reactants and the formation of products were determined. Photolysis of ethylene yields mainly saturated compounds (ethane, propane, and butane) while photolysis of acetylene yields the same saturated compounds as well as ethylene and diacetylene. Irradiation of cyanoacetylene yields mainly hydrogen cyanide and small amounts of acetonitrile. When an amount of methane corresponding to its mixing ratio on Titan was added to these mixtures the quantum yields for the loss of reactants decreased and the quantum yields for hydrocarbon formation increased indicative of a hydrogen atom abstraction from methane by the photochemically generated radicals. GC/MS analysis of the products formed by irradiation of mixtures of all these gases generated over 120 compounds which were mainly aliphatic hydrocarbons containing double and triple bonds along with much smaller amounts of aromatic compounds like benzene, toluene and phenylacetylene. The reaction pathways were investigated by the use of ¹³C acetylene in these gas mixtures. No polycyclic aromatic compounds were detected. Vapor pressures of these compounds under conditions present in Titan's atmosphere were calculated. The low molecular weight compounds likely to be present in the atmosphere and aerosols of Titan as a result of photochemical processes are proposed.     

Limits on the size of aerosols from measurements of linear polarization in Titan’s atmosphere

The Descent Imager/Spectral Radiometer (DISR) instrument on the Huygens probe into the atmosphere of Titan yielded information on the size, shape, optical properties, and vertical distribution of haze aerosols in the atmosphere of Titan [Tomasko, M.G., Doose, L., Engel, S., Dafoe, L.E., West, R., Lemmon, M., Karkoschka, E., 2008. Planet. Space Sci. 56, 669-707] from photometric and spectroscopic measurements of sunlight in Titan’s atmosphere. This instrument also made measurements of the degree of linear polarization of sunlight in two spectral bands centered at 491 and 934 nm. Here we present the calibration and reduction of the polarization measurements and compare the polarization observations to models using fractal aggregate particles which have different sizes for the small dimension (monomer size) of which the aggregates are composed. We find that the Titan aerosols produce very large polarizations perpendicular to the scattering plane for scattering near 90° scattering angle. The size of the monomers is tightly constrained by the measurements to a radius of 0.04 ± 0.01 μm at altitudes from 150 km to the surface. The decrease in polarization with decreasing altitude observed in red and blue light is as expected by increasing dilution due to multiple scattering at decreasing altitudes. There is no indication of particles that produce small amounts of linear polarization at low altitudes.     

Photochemistry of the atmosphere of Titan: comparison between model and observations

The photochemistry of simple molecules containing carbon, hydrogen, nitrogen, and oxygen atoms in the atmosphere of Titan has been investigated using updated chemical schemes and our own estimates of a number of key rate coefficients. Proper exospheric boundary conditions, vertical transport, and condensation processes at the tropopause have been incorporated into the model. It is argued that he composition, climatology, and evolution of Titan's atmosphere are controlled by five major processes: (a) photolysis and photosensitized dissociation of CH4; (b) conversion of H to H2 and escape of hydrogen; (c) synthesis of higher hydrocarbons; (d) coupling between nitrogen and hydrocarbons; (e) coupling between oxygen and hydrocarbons. Starting with N2, CH4, and H2O, and invoking interactions with ultraviolet sunlight, energetic electrons, and cosmic rays, the model satisfactorily accounts for the concentrations of minor species observed by the Voyager IRIS and UVS instruments. Photochemistry is responsible for converting the simpler atmospheric species into more complex organic compounds, which are subsequently condensed at the tropopause and deposited on the surface. Titan might have lost 5.6 x 10(4), 1.8 x 10(3), and 4.0 g cm-2, or the equivalent of 8, 0.25, and 5 x 10(-4) bars of CH4, N2, and CO, respectively, over geologic time. Implications of abiotic organic synthesis on Titan for the origin of life on Earth are briefly discussed.     

Absolute absorption coefficient of C6H2 in the mid-UV range at low temperature; implications for the interpretation of Titan atmospheric spectra

The interpretation of mid-UV albedo spectra of planetary atmospheres, especially that of Titan, is the main goal of the SIPAT (Spectroscopie uv d'Interet Prebiologique dans l'Atmosphere de Titan) research program. This laboratory experiment has been developed in order to systematically determine the absorption coefficients of molecular compounds which are potential absorbers of scattered sunlight in planetary atmospheres, with high spectral resolution, and at various temperatures below room temperature. From photochemical modelling and experimental simulations, we may expect triacetylene (C6H2) to be present in the atmosphere of Titan, even though it has not yet been detected. We present here the first determination of the absolute absorption coefficient of that compound in the 200-300 nm range and at two temperatures (296 K and 233 K). The temperature dependence of the C6H2 absorption coefficient in that wavelength range is compared to that previously observed in the case of cyanoacetylene (HC3N). We then discuss the implications of the present results for the interpretation of Titan UV spectra, where it appears that large uncertainities can be introduced either by the presence of trace impurities in laboratory samples or by the variations of absorption coefficients with temperature.     

Experimental simulation of Titan's organic chemistry at low temperature

A wide range of experiments has already been carried out to simulate the chemical evolution of Titan. Such experiments can provide useful information on the possible nature of minor constituents, mostly organic, likely to be present in Titan's atmosphere. Indeed, all but one of the organic compounds already detected in Titan's atmosphere have been identified in simulation experiments. The exception, C4N2, as well as other compounds expected in Titan from theoretical modeling, such as other N-organics, mainly CH2N2, and polyynes, namely C6H2, have never been detected in experimental simulation. It turned out that these compounds were thermally unstable, and the temperature conditions used during the simulation experiments (including conditions used for chemical analysis) were not appropriate. We have recently started a new program of simulation experiments using temperature conditions close to those of Titan's environment, more compatible with the build-up and detection of organics only stable at low temperature. Spark discharge of N2-CH4 gas mixtures was carried out at low temperature in the range of 100-150 K. The analysis of the obtained products was performed through FTIR, GC and GC-MS techniques. GC-peak identification was done owing to its mass spectrum and, in most cases, by comparison of the retention time and of the mass spectrum with standards. We report here the first detection in Titan's simulation experiments of C6H2. Its abundance is a few 10(-2) relative to C4H2. We also report a tentative identification of HC5N (to be confirmed by use of standard) with an abundance of a few 10(-2) relative to HC3N. The possible presence of HC5N suggested by our work provides the occurrence of very novel pathways in the formation of Titan's organic aerosols, involving not only C and H but also N atoms.     

Temperature dependence of HC3N,C6H2, and C4N2 mid-UV absorption coefficients. Application to the interpretation of Titan's atmospheric spectra

Three organic compounds (HC₃N, C₆H₂, and C₄N₂) relevant of Titan's atmosphere have been studied within the framework of the SIPAT (Spectroscopie UV d'Intérêt Prébiologique dans l'Atmosphère de Titan) program. Since this facility is still unable to reach the very low temperatures (170 K) of Titan's high atmosphere, spectra have to be obtained at several absorption-cell temperatures, and the data extrapolated towards lower temperatures. Previously published HC₃N and C₆H₂ absorption coefficient data are reviewed, while new spectroscopic data are presented on C₄N₂. Integrated intensity calculations over the vibrational bands are performed apart from the background continuum. Thus, only the band contrast is considered here. While, the temperature dependence of the hot-band integrated intensity follows a Boltzmann distribution, we have enhanced the fit through an empirical parametrisation to account for the observed temperature dependence of the C₄N₂ and HC₃N absorption coefficients, and to extrapolate those data to the low temperature conditions of Titan's high atmosphere. Finally, we discuss the implications of the results to possible detection by remote sensing observations of these minor compounds in Titan's atmosphere.     

Composition of Titan''s surface from Cassini VIMS

Titan's bulk density along with Solar System formation models indicates considerable water as well as silicates as its major constituents. This satellite's dense atmosphere of nitrogen with methane is unique. Deposits or even oceans of organic compounds have been suggested to exist on Titan's solid surface due to UV-induced photochemistry in the atmosphere. Thus, the composition of the surface is a major piece of evidence needed to determine Titan's history. However, studies of the surface are hindered by the thick, absorbing, hazy and in some places cloudy atmosphere. Ground-based telescope investigations of the integral disk of Titan attempted to observe the surface albedo in spectral windows between methane absorptions by calculating and removing the haze effects. Their results were reported to be consistent with water ice on the surface that is contaminated with a small amount of dark material, perhaps organic material like tholin. We analyze here the recent Cassini Mission's visual and infrared mapping spectrometer (VIMS) observations that resolve regions on Titan. VIMS is able to see surface features and shows that there are spectral and therefore likely compositional units. By several methods, spectral albedo estimates within methane absorption windows between 0.75 and 5 μm were obtained for different surface units using VIMS image cubes from the Cassini-Huygens Titan T_a encounter. Of the spots studied, there appears to be two compositional classes present that are associated with the lower albedo and the higher albedo materials, with some variety among the brighter regions. These were compared with spectra of several different candidate materials. Our results show that the spectrum of water ice contaminated with a darker material matches the reflectance of the lower albedo Titan regions if the spectral slope from 2.71 to 2.79 μm in the poorly understood 2.8-μm methane window is ignored. The spectra for brighter regions are not matched by the spectrum of water ice or unoxidized tholin, in pure form or in mixtures with sufficient ice or tholin present to allow the water ice or tholin spectral features to be discerned. We find that the 2.8-μm methane absorption window is complex and seems to consist of two weak subwindows at 2.7 and 2.8 μm that have unknown opacities. A ratio image at these two wavelengths reveals an anomalous region on Titan that has a reflectance unlike any material so far identified, but it is unclear how much the reflectances in these two subwindows pertain to the surface.     

Benzene and aerosol production in Titan and Jupiter's atmospheres: a sensitivity study

Benzene has recently been observed in the atmosphere of Jupiter, Saturn and also Titan. This compound is required as a precursor for larger aromatic species (PAHs) that may be part of aerosol particles. Several photochemical models have tried to reproduce the observed quantities of benzene in the atmospheres of Jupiter (both low- and high-latitudes regions), Saturn and Titan. In this present work, we have conducted a sensitivity study of benzene and PAHs formation, using similar photochemical schemes both for Titan and Jupiter (low-latitudes conditions). Two different photochemical schemes are used, for which the modeled composition fairly agrees with observational constraints, both for Jupiter and Titan. Some disagreements are specific to each atmospheric case, which may point to needed improvements, especially in kinetic data involved in the corresponding chemical cycles. The observed benzene mole fraction in Titan's stratosphere is reproduced by the model, but in the case of Jupiter, low-latitudes benzene abundance is only 3% of the observed column density, which may indicate a possible influence of latitudinal transport, since abundance of benzene is much higher in auroral regions. Though, the photochemical scheme of C₆ compounds at temperature and pressure conditions of planetary atmospheres is still very uncertain. Several variations are therefore done on key reactions in benzene production. These variations show that benzene abundance is mainly sensitive to reactions that may affect the propargyl radical. The effect of aerosol production on hydrocarbons composition is also tested, as well as possible heterogenous recombination of atomic hydrogen in the case of Titan. PAHs are a major pathway for aerosol production in both models. The mass production profiles for aerosols are discussed for both Titan and Jupiter. Total production mass fluxes are roughly three times the one expected by observational constraints in both cases. Such comparative studies are useful to bring more constraints on photochemical models.     

Earth-Based Support for the Titan Saturn System Mission

The Titan Saturn System Mission (TSSM) concept is composed of a TSSM orbiter provided by NASA that would carry two Titan in situ elements provided by ESA: the montgolfière and the probe/lake lander. One overarching goal of TSSM is to explore in situ the atmosphere and surface of Titan. The mission has been prioritized as the second Outer Planets Flagship Mission, the first one being the Europa Jupiter System Mission (EJSM). TSSM would launch around 2023–2025 arriving at Saturn 9 years later followed by a 4-year science mission in the Saturn system. Following delivery of the in situ elements to Titan, the TSSM orbiter would explore the Saturn system via a 2-year tour that includes Enceladus and Titan flybys before entering into a dedicated orbit around Titan. The Titan montgolfière aerial vehicle under consideration will circumnavigate Titan at a latitude of ~20° and at altitudes of ~10 km for a minimum of 6 months. The probe/lake lander will descend through Titan’s atmosphere and land on the liquid surface of Kraken Mare (~75° north latitude). As for any planetary space science mission, and based on the Cassini–Huygens experience, Earth-based observations will be synergistic and enable scientific optimization of the return of such a mission. Some specific examples of how this can be achieved (through VLBI and Doppler tracking, continuous monitoring of atmospheric and surface features, and Direct-to-Earth transmission) are described in this paper.     

The role of photochemical processes in evolution of the isotopic composition of the atmosphere of Titan

Molecular nitrogen, the main component of the modern atmosphere of Titan, may have formed without significant changes in the nitrogen and hydrogen isotopic composition from the clathrate hydrate of ammonia NH₃ · H₂O_SLD, which is the main accreted form of nitrogen. The most preferable transformation mechanism of NH₃ · H₂O_SLD into atmospheric N₂ is its thermal decomposition in the interior of Titan rather than the photochemical decomposition of ammonia in the upper atmosphere of early Titan. The photolysis of ammonia does not lead to a change in the isotopic composition of nitrogen, as all the nitrogen remains in Titan’s atmosphere. The photolysis of NH does not lead to a change in the isotopic composition of nitrogen in Titan’s atmosphere. Fractionation of hydrogen and nitrogen isotopes during the impacts of comets with Titan does not seem to be significant either. It will be possible to determine the dissociative fractionation factor, the original ratio ¹⁴N/¹⁵N, and the mass of Titan’s original atmosphere when fractionation of nitrogen isotopes in Titan’s atmosphere is examined in additional theoretical and experimental studies that take into account processes occurring during the formation of a system of Saturn’s satellites.     

Titan's 5 micrometers spectral window: carbon monoxide and the albedo of the surface

We have measured the spectrum of Titan near 5 micrometers and have found it to be dominated by absorption from the carbon monoxide 1-0 vibration-rotation band. The position of the band edge allows us to constrain the abundance of CO in the atmosphere and/or the location of the reflecting layer in the atmosphere. In the most likely case, 5 micrometers radiation is reflected from the surface and the mole fraction of CO in the atmosphere is qCO=10(+10/-5) ppm, significantly lower than previous estimates for tropospheric CO. The albedo of the reflecting layer is approximately 0.07(+0.02/-0.01) in the 5 micrometers continuum outside the CO band. The 5 micrometers albedo is consistent with a surface of mixed ice and silicates similar to the icy Galilean satellites. Organic solids formed in simulated Titan conditions can also produce similar albedos at 5 micrometers.     

Spectral reflectivities of the Galilean satellites and Titan, 0.32 to 0.86 micrometers

A spectrophotometric observational study of the Galilean satellites and Titan was carried out at 0.004-μm (40-Å) resolution over the spectral range 0.32 to 0.86 μm. A standard lunar area was used as a primary spectroscopic standard to establish the relative reflection spectra of the objects by ratioing the sky-corrected satellite spectra to the standard area on the Moon. J1 (Io) is found to have a spectral edge at 0.33 μm that has not been previously reported. The increase in reflectivity from 0.4 to 0.5 μm and the band at 0.56 μm are confirmed. A weak band at 0.56 μm is probable on J2 (Europa) and possible on J3 (Ganymede). J4 (Callisto) shows no spectral features that have not been previously reported. On Titan, no temporal variations in the methane bands greater than 2% were found, indicating that the effective path length in the Titan atmosphere did not change over the 3-month period of this study. A new absorption band of methane at 0.68 μm was found on Titan. We propose an extension of the evaporite model of Fanale et al. (1974, 1977) and the sulfur mixing models of Wamsteker et al. (1974) in which the primary constituent of the surface of J1 is elemental sulfur sublimated onto the surface by photodissociation of hydrogen sulfide outgassing from the interior. The sulfur is continually renewed by sublimation, sputtering, and redeposition. At low temperatures irradiation produces stable S₂, S₃, S₄, S₆, and long chain polymers. Some of these allotropes have an edge at 0.33 μm, a rising reflectance between 0.4 and 0.5 μm a band at 0.56 μm. All of these features are found in the spectrum of J1. We conclude that the lunar ratioing technique used in this study is well suited for determining the relative reflection spectra of solar system objects.     

A Saturnian gas ring and the recycling of Titan's atmosphere

Atoms which escape Titan's atmosphere are unlikely to possess escape velocity from Saturn, and can orbit the planet until lost by ionization or collision with Titan. It is predicted that a toroidal ring of between ～1 and ～10³ atoms or molecules cm^?3 exists around Saturn at a distance of about 10 times the radius of the visible rings. This torus may be detectable from Earth-orbit and detection of nondetection of it may provide some information about the presence or absence of a Saturnian magnetic field, and the exospheric temperature and atmospheric escape rate of Titan. It is estimated that, if Titan has a large exosphere, ～97% or more of the escaping atoms can be recaptured by Titan, thereby decreasing the effective net atmospheric loss rate by up to two orders of magnitude. With such a reduction in atmospheric loss rates, it becomes more plausible to suggest that satellites previously thought too small to retain an atmosphere may have one. It is suggested that Saturn be examined by Lyman-α and other observations to search for the gaseous torus of Titan. If successful, these could then be extended to other satellites.The effect of a hypothetical Saturnian magnetosphere on the atmosphere of Titan is investigated. It is shown that, if Saturn has a magnetic field comparable to Jupiter's (～10 G at the planetary surface), the magnetospheric plasma can supply Titan with hydrogen at a rate comparable to the loss rates in some of the models of Trafton (1972) and Sagan (1973). A major part of the Saturnian ionospheric escape flux (～ 10²⁷ photoelectrons sec^?1) could perhaps be captured by Titan. At the upper limit, this rate of hydrogen input to the satellite could total ～0.1 atm pressure over the lifetime of the solar system, an amount comparable to estimates of the present atmospheric pressure of Titan.     

Estimated impact shock production of N2 and organic compounds on early Titan

Bombardment of Titan by Uranus-Neptune planetesimals and/or fragments of a disrupted Hyperion progenitor supplied more than enough energy to drive vigorous atmospheric shock chemistry. Chemical equilibrium modeling of the shock products in simulated atmospheres indicates that impact energy has produced large amounts of N₂ and organic compounds over Titan's history. The mole fraction of organic compounds in the shocked gas mixture (T = 1200−2500°K, P = 10⁻¹−10³bar) reaches a maximum of approximately 3% in a current Titan mixture and 12% in a primordial CH₄, NH₃-rich mixture. Atmospheric water mixing ratio controls the organic yield in shock reactions, but its limiting effect may have been reduced by cold-trapping of water in a cooling atmosphere. Kinetic inhibition of graphite formation in the shocked gas enhanced the yield of radicals and organic. The resulting mixture of carbonaceous soot and condensed hydrocarbons subsequently settled onto the surface; the depth of the generated layer was on the order of hundreds of meters. Impact shock energy was capable of converting massive amounts of NH₃ to N₂ early in Titan history—over twice the present atmospheric and 1.5 times the total ocean-atmospheric inventory of N₂. Shock conversion of NH₃ into N₂ bypasses the difficulties of other schemes of N₂ production and may have been of singular importance in Titan's atmospheric evolution.     

Ionization by cosmic rays of the atmosphere of Titan

Cosmic ray radiation is the main mechanism for ionizing the lower atmosphere of Titan. Their higher penetration power, in comparison with solar photons, allows cosmic rays to penetrate deep into the atmosphere of Titan, ionizing the neutral molecules and generating an ionosphere with an electron density peak, placed at around 90 km, similar in magnitude to the ionospheric peak produced by solar radiation in the upper atmosphere. In the lower atmosphere, the electron density profile, in the absence of a magnetic field, depends mainly on the modulation of cosmic rays by the solar wind and on the nature of the ionizable particles. We present here the first results of a new numerical model developed to calculate the concentration of electrons and most abundant ions in the Titan lower atmosphere. The present knowledge of Titan’s atmosphere permits us to include new neutral and ionic species, such as oxygen derivates, in a more detailed ion-chemistry calculation than previous lower ionospheric models of Titan. The electron density peaks at 90 km with a magnitude of 2150 cm⁻³. The ion distribution obtained predicts that cluster cations and hydrocarbon cations are the most abundant ions below and above the electron density peak, respectively. We also discuss the effect of solar activity at the distance of the Saturn orbit on the spectrum of the cosmic particles. We obtain that from solar minimum to solar maximum the ionization rate at the energy deposition peak changes by a factor of 1.2 at 70 km, and by a factor of 2.6 at altitudes as high as 400 km. The electron density at the concentration peak changes by a factor of 1.1 at 90 km, and by a factor of 1.6 at 400 km.     

Polycyclic aromatic hydrocarbons in the atmospheres of Titan and Jupiter

Polycyclic aromatic hydrocarbons (PAHs) are important components of the interstellar medium and carbonaceous chondrites, but have never been identified in the reducing atmospheres of the outer solar system. Incompletely characterized complex organic solids (tholins) produced by irradiating simulated Titan atmospheres reproduce well the observed UV/visible/IR optical constants of the Titan stratospheric haze. Titan tholin and a tholin generated in a crude simulation of the atmosphere of Jupiter are examined by two-step laser desorption/multiphoton ionization mass spectrometry. A range of two- to four-ring PAHs, some with one to four alkylation sites are identified, with net abundance approximately 10(-4) g g-1 (grams per gram) of tholins produced. Synchronous fluorescence techniques confirm this detection. Titan tholins have proportionately more one- and two-ring PAHs than do Jupiter tholins, which in turn have more four-ring and larger PAHs. The four-ringed PAH chrysene, prominent in some discussions of interstellar grains, is found in Jupiter tholins. Solid state 13C NMR spectroscopy suggests approximately equal to 25% of the total C in both tholins is tied up in aromatic and/or aliphatic alkenes. IR spectra indicate an upper limit in both tholins of approximately equal to 6% by mass in benzenes, heterocyclics, and PAHs with more than four rings. Condensed PAHs may contribute at most approximately 10% to the observed detached limb haze layers on Titan. As with interstellar PAHs, the synthesis route of planetary PAHs is likely to be via acetylene addition reactions.