An auroral F-region study using in situ measurements by the Atmosphere Explorer-C satellite

On 14 July 1974 the Atmosphere Explorer-C satellite flew through an aurora at F-region altitudes just after local midnight. The effects of the particle influx are clearly evident in the ion densities, the 6300 Å airglow, and the electron and ion temperatures. This event provided an opportunity to study the agreement between the observed ion densities and those calculated from photochemical theory using in situ measurements of such atmospheric parameters as the neutral densities and the differential electron energy spectra obtained along the satellite track. Good agreement is obtained for the ions O₂⁺, NO⁺ and N₂⁺ using photochemical theory and measured rate constants and electron impact cross sections. Atomic nitrogen densities are calculated from the observed [NO⁺]/[O₂⁺] ratio. In the region of most intense electron fluxes (20 erg cm⁻² sec⁻¹) at 280 km, the N density is found to be between 2 and 7 × 10⁷ cm⁻³. The resulting N densities are found to account for approx. 60% of the production of N⁺ through electron impact on N and the resonant charge exchange of O⁺(²P) with N(⁴S). This reaction also provides a significant source of O(¹S) in the aurora at F-region altitudes. In the region of intense fast electron influx, the reaction with atomic nitrogen is found to be the main loss of O⁺(²P).     

The winter anomaly in ionospheric absorption and the D-region ion chemistry

A detailed analysis of the D-region ion composition measurements performed by Zbinden et al. (1975), during a winter day of high ionospheric absorption, has been carried out. The study examines the interactive mesosphere-D-region processes which occur in such anomalous conditions and their implication for water cluster ion chemistry. Two clustering regimes for NO⁺ have been observed in the data. Association with N₂ is identified as the dominant process below 76 km. Between 76 and 78 km altitude the effective loss rate of NO⁺ drops by two orders of magnitude. Above 77 km, the three-body reaction NO⁺ + CO₂+M→NO⁺CO₂+M seems to be the main NO⁺ loss. A mesospheric temperature profile could be derived from the ion composition data. This indicates the presence of a strong inversion above 76 km altitude. The wavelike structure obtained, is shown to be consistent with in situ winter temperature measurements. The sharp suppression of the N₂ association reaction could, thus, be explained by an increase in the collisional break-up of the NO⁺N₂ ion because of the enhanced temperature. In conclusion, our study indicates that, besides the increase in the production of NO⁺ and O₂⁺, due to an enhancement in the minor ionizable constituents, an additional thermal mesosphere-D-region interaction seems necessary to explain this winter anomalous ion composition data.     

Ozone, climate and biospheric environment in the ancient oxygen-poor atmosphere

To study the climatological role of ozone in the Precambrian atmosphere and the consequences of its reduction for the ultraviolet environment of the early biosphere, a coupled one-dimensional radiative-convective and photochemical model has been developed. Oxygen levels between 10⁻⁵ and 1 time the present atmospheric level (PAL) are considered. It is shown that when the ice-albedo feedback is taken into account, relatively important temperature decreases are associated with the ozone changes linked to the progressive decrease of the oxygen level from 1 PAL to smaller values.

A similar study is performed for enhanced atmospheric CO₂ pressures (P_co2). In these conditions, the ozone column is increased at low O₂ concentrations with respect to the P_co2 = 1 PAL case. Consequently, the larger CO₂ concentration in the ancient atmosphere could have contributed to strengthen the ultraviolet screening of ozone. The surface temperature response to the ozone decrease, as well as the thermal profiles are also analyzed in these CO₂-rich models. A possible evolutionary scenario of atmospheric O₂ and CO₂ is discussed.

The consequences of these calculations for the ultraviolet environment of the primitive biosphere is discussed with a quantitative model calculating bacterial surviving rates. According to this model, the minimum ozone column being tolerable by unprotected bacteria would fall between 1 × 10¹⁸ and 4 × 10¹⁸ cm⁻², depending on the bacterial species considered and corresponding to an O₂ level somewhat lower than 10⁻² PAL. For the coccoid blue-green alga Agmenellum quadruplicatum, this minimum ozone column would be of 4.5 × 10¹⁸, a value which is only slightly less than the presently observed column in the spring time ozone hole of Antarctica.     

Rocket measurements of the 6300 Å and 3914 Å dayglow features

Rocket results are presented on the OI 6300 Å line and on the N₂⁺ 3914 Å band in the dayglow. An altitude range of 78–335 km is covered. Theoretical interpretations are given, using results of simultaneous measurements of electron density and electron temperature. The apparent brightness of the 6300 Å line at the base of the emitting region is found to be 13 kR, of which 5.5 kR are ascribed to excitation through the Schumann-Runge dissociation of O₂ by the solar UV radiations, 0.55 kR to the dissociative recombination of O₂⁺ and NO⁺ ions, and 0.03 kR to the excitation of O by thermal electrons. An additional source of excitation above 280 km is suggested. The deactivation of O(¹D) by O₂(X³Σ_g⁻) is found to be appreciable below 200 km, and its rate coefficient is estimated to be 2 × 10⁻¹⁰ cm³/sec. The apparent brightness of the 3914 Å band at the base of the emitting region is found to be 6.5 kR, decreasing to 3.2 kR at 330 km. Assuming that fluorescent scattering of solar radiation is the mechanism involved the distribution of N₂⁺ ions is calculated. The rate coefficients for the loss of these ions are hence calculated.     

Properties of energetic water-group ions in the extended pick-up region surrounding comet Giacobini-Zinner

The properties of energetic (65–95 keV) cometary water-group ions in the extended solar wind pick-up region surrounding comet Giacobini-Zinner are examined using data from the EPAS instrument on the ICE spacecraft. In the outer part of this region, extending from cometocentric distances of several hundred thousand to a few million kilometres (the limit of pick-up ion detectability), it is found that large modulations of the ion flux occur (with J_MAX/J_MIN 10²-10³) which are related to the direction of the magnetic field. It is also found that the ions stream in a direction which is intermediate between the directions of the solar wind flow and the E × B drift, and that ions are present at energies somewhat above the local pick-up energy. These properties indicate that the waves which are excited by the unstable “ring-beam” pick-up ion velocity distributions do result in significant scattering of the ions in this region, both in pitch angle and in energy, but that they have insufficient amplitude to scatter the ions into near isotropy in the solar wind frame. Closer to the comet (but still upstream from the bow shock), the ion flux modulations are considerably reduced in amplitude and the ions respond less to the E × B drift, indicating that the ions are scattered nearer to isotropy in this region. Inbound, this transition takes place relatively abruptly at a distance of 4 × 10⁵ km in association with an increase in the solar wind speed, after which the ion flux increases, and ceases to be modulated by the field direction, while the streaming direction is continuously antisolar and unmodulated by the direction of the E × B drift. Outbound, weak vestiges of the ring-beam ion anisotropy are present in the region immediately upstream from the bow shock (at −1 × 10⁵ km), but these become more marked at distances in excess of t4 × 10⁵ km, increasing gradually with increasing distance from the comet. It is shown that the evolution of the ion properties is qualitatively consistent with expectations based on quasi-linear diffusion of the ions by the magnetosonic waves observed during the encounter.     

Studies of the motion of equatorial 630.0 nm airglow depletions

An all-sky-mapping filter photometeer has been used to study equatorial 630.0 nm nightglow intensity depletions. A generally eastward drift of the ～ 0m/sec. At times two airglow depletions moving at different velocities were observed simultaneously; in one case they merged. Simultaneous interferometric determinations of doppler shifts in the 630.0 nm line indicated that the velocity of the neutral atmosphere does not appear to be correlated with the drift of the airglow depletions. The results are compared with other observations.     

The upper ionospheres of Jupiter and Saturn

We use a 1-D chemical diffusive model, in conjunction with the measured neutral atmospheric structure, to analyze the Voyager RSS electron density, n_e, profiles for the ionospheres of Jupiter and Saturn. As with previous studies we find serious difficulties in explaining the n_e measurements. The model calculates ionospheres for both Jupiter and Saturn with n_e peaks of 10 times the measured peaks at altitudes which are 900–1000 km lower than the altitude of peaks in the RSS electron densities. Based on our knowledge of neutral atmospheric structure, ionization sources, and known recombination mechanisms it seems that, vibrational excitation of H₂ must play some role in the conversion of slowly radiatively recombining H⁺ ions to the relatively more rapidly recombining H₂⁺ and H₃⁺ ions. In addition, vertical ion flow induced by horizontal neutral winds or electric fields probably also play some role in maintaining the plasma peaks observed both for Jupiter and Saturn to be at high altitudes. For the ionosphere of Saturn, the electron densities are affected by a putative influx of H₂O molecules, Φ_H2O, from the rings. To reproduce the RSS V2 exit n_e results model requires an influx of Φ_H2O 2 × 10⁷ molecules cm⁻² s⁻¹ without invoking H_2f vibrational excitation. To maintain the model n_e peak at the measured altitude vertical plasma drift maintained by meridional winds or vertical electric fields is required. The amounts of H₂O are consistent with earlier estimates of Connerney and Waite (1984) and do not violate any observational constraints.     

Negative ion composition and sulfuric acid vapour in the upper stratosphere

The nature of negative ions in the altitude region 42–45 km has been investigated by means of a balloon borne mass spectrometer. Apart from the NO₃⁻ and HSO₄⁻ clusters, ions with different cores, which can be identified as CO₃⁻, HCO₃⁻, Cl⁻ and ClO₃⁻ were observed. The spectra have been used to estimate the sulfuric acid number density at 45.2 and 42.3 km altitude.     

N2 emission in the twilight

About a year's observations of the N₂⁺ band (3914 Å) at Kitt Peak (latitude 32°) are reported. Morning intensities are the same throughout the year, but there is a strong winter maximum in the evening. It is suggested that the additional ionization is produced by photoelectrons from the magnetic conjugate point. Heights are estimated by the zenith-horizon method, which gives 235 km for the constant component and 350 km during the evening enhancement. The intensity variation through twilight is therefore entirely due to changes of the N₂⁺ concentration; each ion scatters light at a constant rate. The rotational distribution resembles that for a temperature of 1600°K, much higher than the temperature of the atmosphere. It is suggested that part of the ions may be produced by charge transfer from metastable O⁺(²D). N₂⁺ concentrations resulting from photoionization are calculated; they give a fair account of the observed horizon intensities, but not the zenith. Non-local electrons from higher in the atmosphere are suggested as a possible extra source; alternatively, the zenith measurements may be perturbed by scattered horizon light. The band intensity in the nightglow cannot be measured; the upper limit is 1 R.     

Properties of the infrared dark cloud G79.2+0.38

The MSX infrared dark cloud G79.2+0.38 has been observed over a 11′×′ region simultaneously in the J=1-0 rotational transition lines of the ¹²CO and its isotopic molecules ¹³CO and ¹⁸CO. The dense molecular cores defined by the C¹⁸O line are found to be associated with the two high-extinction patches shown in the MSX A-band image. The two dense cores have the column density N (H₂) (5 – 12) × 10²² cm⁻² and the mean number density n (3 ± 1) × 10⁴ cm⁻³. Their sizes are 1.7 and 1.2 pc in ¹³CO(1-0) line, 1.2 and 0.6 pc in C¹⁸O(1-0) line, respectively. The masses of these cloud cores are estimated to be in the range from 2 × 10² to 2 × 10³ M. The profile of radial mean density of the cloud core can be described by the exponential function ¯n(p) p^{−0.34±0.02}. Compared with the cases of typical optical dark clouds, the abundances of the CO isotopic molecules ¹³CO and C¹⁸O in this MSX infrared dark cloud appear to be depleted by a factor of 4–11, but at present there is no evidence for any obvious variation of the relative abundance ratio X_13/18 between ¹³CO and C¹⁸O with the column density.     

Analysis of the variation in inclination of Intercosmos 13 Rocket, 1975-22B

The orbit of Intercosmos 13 rocket (1975-22B) has been determined at 103 epochs between 30 April 1975 and 10 April 1980 from almost 7000 observations. One hundred and three values of inclination have been determined and corrections incoporated for the effects due to zonal harmonic, lunisolar and tesseral harmonic perturbations, precession, and solid Earth tides. The modified data have been analysed to yield values of the atmospheric rotation rate, Λ rev day⁻¹, viz. Λ = 0.94 ± 0.10 at an average height of 322 ± 6 km and Λ = 1.27 ± 0.02 at 288 km. Analysis of the inclination near 14th-order resonance has indicated lumped harmonic values 10^{9 1.0}_1.4 = − 76.13 ± 12.47, 10^{9 1,0}₁₄ = − 29.89 ± 32.64, 10^{9 −1.2}₁₄ = − 63.11 ± 15.44 10^{9 −1.2}₁₄ = − 32.52 ± 26.96, for inclination 82.952°.     

Eddy mixing and circulation at ionospheric levels

The rates of heat input into the mesosphere and lower thermosphere are calculated and compared with the heat losses. The worldwide average eddy diffusion coefficient required to maintain continuity in the heat budget is calculated and found to vary from about 10⁷ cm²/sec at 120 km down to about 10⁵ cm²/sec at 60 km. From the global asymmetry in heating at the solstice, it is concluded that a systematic pattern of vertical velocities prevails ranging from less than 1 cm/sec in the mesosphere up to 10 cm/sec near 120 km, upward over the summer polar region and downward over the winter polar region. This can be balanced by a wind system towards the winter polar region with velocities near 1 m/sec at 60 km increasing to 30 m/sec at 120 km. Such a wind system provides an explanation for the helium bulge in the upper thermosphere over the winter polar region.     

Doppler profiles of the 5577 Å airglow

We discuss the altitude and intensity of the nocturnal green line emission resulting from O₂⁺ recombination. The Doppler profile of this emission is markedly non-thermal, the width being characteristic of the energy at which the O(¹S) atoms are produced. A simple theory is formulated which predicts the profile of this line. Experimental evidence on airglow line profiles is reviewed and it is found that the effect predicted here has not yet been observed. However a deliberate search for this effect should yield immediate results.     

A measurement of the O2 ultra-violet nightglow emission

New measurements of the Herzberg I emission height profile in the night airglow are reported and indicate a peak emission height near 96 km in agreement with previous measurements. Using an atomic oxygen concentration profile determined from the oxygen green line profile measured on the same rocket it is concluded that the O₂(A³Σ_u⁺) state is not excited in the direct three body recombination of atomic oxygen. It is suggested that the excitation mechanism is a two step process, similar to the Barth mechanism for the atomic oxygen green lineand that the excited intermediate state is C³Δ_u.     

On the discovery of CO nighttime emissions on Titan by Cassini/VIMS: Derived stratospheric abundances and geological implications

We present a quantitative analysis of CO thermal emissions discovered on the nightside of Titan by Baines et al. [2005. The atmospheres of Saturn and Titan in the near-infrared: First results of Cassini/VIMS. Earth, Moon, and Planets, 96, 119–147]. in Cassini/VIMS spectral imagery. We identify these emission features as the P and R branches of the 1-0 vibrational band of carbon monoxide (CO) near 4.65 μm. For CH₃D, the prominent Q branch of the ν₂ fundamental band of CH₃D near 4.55 μm is apparent. CO₂ emissions from the strong v₃ vibrational band are virtually absent, indicating a CO₂ abundance several orders of magnitude less than CO, in agreement with previous investigations. Analysis of CO emission spectra obtained over a variety of altitudes on Titan's nightside limb indicates that the stratospheric abundance of CO is 32±15 ppm, and together with other recent determinations, suggests a vertical distribution of CO nearly constant at this value from the surface throughout the troposphere to at least the stratopause near 300 km altitude. The corresponding total atmospheric content of CO in Titan is 2.9±1.5×10¹⁴ kg. Given the long lifetime of CO in the oxygen-poor Titan atmosphere (0.5–1.0 Gyr), we find a mean CO atmospheric production rate of 6±3×10⁵ kg yr⁻¹. Given the lack of primordial heavy noble gases observed by Huygens [Niemann et al., 2005. The abundances of constituents of Titan's atmosphere from the GCMS on the Huygens probe. Nature, 438, 779–784], the primary source of atmospheric CO is likely surface emissions. The implied CO/CH₄ mixing ratio of near-surface material is 1.8±0.9×10⁻⁴, based on an average methane surface emission rate over the past 0.5 Gyr of 1.3×10⁻¹³ gm cm⁻² s⁻¹ as required to balance hydrocarbon haze production via methane photolysis [Wilson and Atreya, 2004. Current state of modeling the photochemistry of Titan's mutually dependent atmosphere and ionosphere. J. Geophys. Res. 109, E06002 Doi:10.1029/2003JE002181]. This low CO/CH₄ ratio is much lower than expected for the sub-nebular formation region of Titan and supports the hypothesis [e.g., Atreya et al., 2005. Methane on Titan: photochemical-meteorological-hydrogeochemical cycle. Bull. Am. Astron. Soc. 37, 735] that the conversion of primordial CO and other carbon-bearing materials into CH₄-enriched clathrate-hydrates occurs within the deep interior of Titan via the release of hydrogen through the serpentinization process followed by Fischer–Tropsch catalysis. The time-averaged predicted emission rate of methane-rich surface materials is 0.02 km³ yr⁻¹, a value significantly lower than the rate of silicate lava production for the Earth and Venus, but nonetheless indicative of significant active geological processes reshaping the surface of Titan.     

Photometric measurements of the O2 U.V. nightglow

Measurements of the O₂(A³Σ − X³Σ) Herzberg system in the night airglow have been made with the ESRO TD-1 satellite in the wavelength range 2400–3100 A. The slant emission rate varies from 3.5 to 15 kR, indicating an irregular structure of the atomic oxygen near the turbopause. A statistical maximum intensity is found near the tropic in the winter hemisphere. The intensity profile is consistent with excitation by three-body recombination of oxygen atoms. The observed total emission rate can be accounted for by reasonable atomic oxygen densities and an O₂(A³Σ) production efficiency of about 20% if quenching by N₂ occurs at the rate deduced from laboratory and other airglow measurements.     

Twilight effects of solar ionizing radiation

The absorption of solar ionizing radiation during twilight is investigated. Ion production rates are obtained as a function of altitude and twilight intensities and altitude profiles of emissions arising from the fluorescence of solar ionizing radiation are calculated for various solar depression angles. For an atmosphere with an exospheric temperature of 750°K, the predicted overhead intensity from fluorescence of the O⁺(²P — ²D) lines at 7319–7330 diminishes from 175 R at dusk to 10 R at a solar depression angle of 10°. The predicted overhead intensities from fluorescence of the N₂⁺ Meinel and first negative systems are respectively about 175 R and 20 R at dusk diminishing to respectively 1.5 R and 0.1 R at a solar depression angle of 10°.

It is suggested that a charge transfer reaction of O⁺²D in N₂ is a significant source of N₂⁺ ions. This reaction offers a possible explanation for the high apparent rotational temperatures in the first negative system observed by Broadfoot and Hunten. Other excitation and ionization mechanisms are briefly discussed.     

Deactivation of N2A Σumolecules in the aurora

Recent rocket observations of the N₂ V-K (Vegard-Kaplan) system in the aurora have been reinterpreted using an atmospheric model based on mass spectrometer measurements in an aurora of similar intensity at the same time of year. In contrast to the original interpretation, we find that population by cascade from the C³Π_u and B³Π_g states in the A³Σ_u⁺v=0,1 levels, as calculated using recently measured electron excitation cross sections, accurately accounts for the observed relative emission rates (IV-K/12PG_0.0). In addition there is no need to change the production rate of A ³ Σ _u⁺ molecules relative to that of C³Π_uv=0 as a function of altitude in order to fit the profile of the deactivation probability to the atmospheric model. Quenching of A ³ Σ _u⁺ molecules at high altitudes is dominated by atomic oxygen. The rate constants for the v=0 and v=1 levels are 8 × 10⁻¹¹ cm³ sec⁻¹ and 1.7 × 10⁻¹⁰ cm³ sec⁻¹ respectively, as determined using the model atmosphere mentioned above. Recent observations with a helium cooled mass spectrometer suggest that conventional mass spectrometer measurements tend to underestimate the atomic oxygen relative concentration. The rate coefficients may therefore be too large by as much as a factor of 3. Below 130 Km we find that it is possible to account for the deactivation in bright auroras by invoking large nitric oxide concentrations, similar to those recently observed mass spectrometrically and using a rate constant of 8 × 10⁻¹¹ cm³ sec⁻¹ for both the v=1 levels. This rate constant is very nearly the same as that measured in the laboratory (7 × 10⁻¹¹ cm³ sec⁻¹). Molecular oxygen appears not to play a significant role in deactivating the lower A ³ Σ _u⁺ levels.     

Nightside ionosphere of Venus

Venera 9, 10 measurements of the nightside ionospheric profile and the night airglow were used for investigating ionosphere formation processes. The upper ionospheric layer may be formed by HeI 584 Å radiation; the lower layer by meteorite ionization. Upper limits on the electron energy flux, <4 × 10⁸eV cm⁻² s⁻¹, the helium ion flux <10⁷ cm⁻² s⁻¹, the nitric oxide mixing ratio, <1.5 × 10⁻⁴ and the atomic sulphur mixing ratio, <10⁻⁶, are deduced for ionospheric altitudes.     

Observation and Study of the CO, CO, HCO and N2H Molecular Lines Towards IRAS 02232+6138

Using the 13.7 m millimeter-wave telescope at the Qinghai Station of Purple Mountain Observatory, we have made observations of ¹³CO, C¹⁸O, HCO⁺ and N₂H⁺ molecular lines towards IRAS 02232+6138. As the excitation density of the probe molecule increases from ¹³CO to HCO⁺, the size of the cloud core associated with IRAS 02232+6138 decreases from 2.40 pc to 0.54 pc, and the virial mass of the cloud core decreases from 2.2 × 10³M to 5.1 × 10²M. A bipolar molecular outflow is found towards IRAS 02232+6138. Using the power function n(r) ∝ r⁻ to fit the spatial density structure of the cloud core, we obtain the power-law index  = 2.3 − 1.2; and we find that, as the probed density increases, the power function becomes more flat. The abundance ratio of ¹³CO to C¹⁸O is 12.4 ± 6.9, comparable with the values 11.8 ± 5.9 for dark clouds and the values 9.0–15.6 for massive cores. The abundance of N₂H⁺ molecules is 3.5 ± 2.5 × 10⁻¹⁰, consistent with the value 1.0 − 5.0 × 10⁻¹⁰ for dark cloud cores and the value 1.2 − 12.8 × 10⁻¹⁰ for massive cores. The abundance of HCO⁺ molecules is 0.9 ± 0.5 × 10⁻⁹, close to the value 1.6 − 2.4 × 10⁻⁹ for massive cores. An increase of HCO⁺ abundance in the outflow region was not found. Combining with the IRAS data, the luminosity-mass ratio of the cloud core is obtained in the range 37–163(L/M). Based on the IRAS luminosity, it is estimated that a main-sequence O7.5 star is probably embedded in the IRAS 02232+6138 cloud core.