Physical and anthropogenic effects on observed long-term nutrient changes in the Irish Sea

The trend in Irish Sea nutrient concentrations over the last four decades has been considered to reflect changes in anthropogenic loading. Comparison of a long-term database for the Menai Strait, North Wales, with an established historic data set for the Cypris station, Isle of Man, indicates that climate also has a significant influence on observations of nutrient concentrations. Data are presented detailing long-term shifts in nitrate, phosphate and silicate measurements since the 1960s at these two fixed sampling sites in the Irish Sea. Broad systematic changes observed in all three nutrients over the decades show a rise from the 1960s through to the 1980s, followed generally by an overall decline in the 1990s. Decadal-scale salinity changes occur in the opposite sense to nutrient changes. Anthropogenic inputs from freshwater cannot fully account for observed nutrient trends, neither is there evidence for shifts in nutrient concentrations in oceanic waters over the past four decades. Climatically forced movement in the geographical position of the freshwater/seawater mixing zone over a decadal time scale could, however, give rise to the observed shifts in nutrient concentration and salinity. This cannot alter nutrient concentration and salinity per se, but causes the measurements taken at fixed sampling sites to fluctuate inversely over this time scale. It is concluded that there is complex interplay between anthropogenic loading and climate affecting the distribution of nutrients in the Irish Sea.     

A comparison of the temperature coefficients of electrical conductivity of Atlantic and Pacific seawaters

The Practical Salinity Scale 1978 (PSS) defines the relationship among salinity, electrical conductivity, temperature, and pressure. Strictly speaking, the PSS is only applicable to waters with the same relative chemical composition as standard seawater. We have tested the predictions of the PSS for samples of Atlantic and Pacific waters. The results indicate that the PSS is valid for these natural seawaters over the defined temperature range of the scale.     

盐度定义狭义性与广义性

通过理论分析和实验验证,论述了“实用盐标”、“氯度盐标”定义的狭义性及应用范围,指出电导法和氯度法测定保守性质样品,数据正确;而测定非保守性质样品,测定值偏离绝对盐度S_a.笔者建议的“密度盐标”属于广义性质,可广泛应用于保守和非保守性质样品.密度盐标具有的优点是:(1)不受样品组成变化影响,只与溶液质量和浮力有关,测定值有高度可靠性与重现性;(2)测定大洋水盐度与现有实用盐度值相同,测定工业水盐度较实用盐度、氯度盐度值更接近绝对盐度S_a;(3)在已知溶质情况下,应用溶液膨胀系数和物质偏摩尔体积校正系数可统一溶质浓度与盐度的换算关系.     

Detection of Intermediate Mediterranean Waters in the Atlantic Ocean by ARGO Floats Data

Peculiarities of the spatial distribution of intermediate Mediterranean waters (MW), which are the main source to maintain the heat and salt budgets at depths of 600–1500 m in the Atlantic Ocean, have been studied using the ARGO floats measurements database. About 75000 temperature and salinity profiles recorded by 900 ARGO floats in 2005–2014 in the Atlantic Ocean for latitudes from 20° to 50° N were used. To process these data, we used the ARGO-Based Model for Investigation of the Global Ocean (AMIGO). This technique allowed us for the first time to obtain a complete set of oceanographic characteristics up to a depth of 2000 m for different time averaging intervals (month, season, years). Joint analysis of the temperature, salinity, and velocity distributions at 700–1000 m depths made it possible to revise the distribution of MW and their penetration into the western part of the ocean across the Mid-Atlantic Ridge (MAR). It is shown that at depths of 700 and 1000 m, the Mid-Atlantic Ridge is a barrier to advective propagation of salty waters (>35.5 PSU) to the west and is transparent to fragments of destroyed intrathermocline lenses (ITL) with lower salinity (<35.4 PSU). In the Atlantic region, from 20° to 35° N and from 30° to 70° W, individual lens profiles with an anomalous salinity distribution were sought using ARGO measurements to detect ITL and its separate fragments. About 24 000 measurements from 370 ARGO floats were analyzed, and only about 3% of them showed weak salinity anomalies at 800–1200 m depths. No ITL were found from these observations. Analysis of long-term drifting of individual floats recording temperature and salinity profiles with anomalous layers made it possible to study the nature of MW transport through the MAR.     

应用镭-226解读南极普里兹湾表层水的来源与运移

中国第22次南极科学考察航次(2005年12月至2006年1月)期间,利用Mn-纤维富集大体积表层海水中的Ra同位素,并通过222Rn直接射气法测量226Ra的比活度,结果表明,普里兹湾表层水的226Ra比活度变化为0.92~2.09 Bq/m3,平均值为1.61 Bq/m3,在深海区域表现出226Ra含量高的特征。从空间分布看,表层水226Ra比活度呈现出由湾内向湾外增加的反常态势,反映出不同Ra含量水团的混合影响2。26Ra比活度与盐度的关系证实研究海域表层水的Ra含量主要受三种端元水体的混合所控制:其一为具有镭含量高、盐度高特征的南极夏季表层水;其二为低镭、低盐特征的冰融水;其三为高盐、中等镭含量的普里兹湾中深层水,该水体的226Ra纯粹由海底沉积物间隙水向上扩散所维持。结合S-226Ra示踪体系及上述三端元混合模型,计算出各组成水体的比例并描绘出它们的空间分布。南极夏季表层水的份额由湾外向湾内逐渐降低,并且在68°E断面向南影响范围较大;冰融水的比例由湾内向湾外降低,并且在湾内东部的高温水体中具有最大贡献;普里兹湾中深层水中受沉积物镭来源影响比较显著的区域出现在湾内西北部,其影响向湾外逐渐降低。冰融水与普里兹湾中深层水份额分别于普里兹湾湾顶东、西部出现高值的分布特征证实埃默里冰架前沿海流东进、西出的运移规律。     

Statistical structure of spatial variability of the ocean thermohaline fields from argo profiling data, 2005–2007

The means, variances, and three-dimensional spatial covariances of the ocean temperature and salinity anomalies in the upper 1400 m layer have been estimated using data of the Argo profiling floats from 2005 to 2007. The results of data processing suggest the continuation of general warming of the ocean waters noted in a number of papers based on earlier data. A pronounced geographical and vertical nonuniformity characterizes this warming but, as a whole, it is mostly distinct in the upper 100 m layer both in the tropics and midlatitudes. For the first time, the unique characteristics of the Argo observing system allowed us to obtain previously unfeasible estimates of the spatial statistics for salinity field. In particular, it has been demonstrated that the spatial structure of salinity anomalies is similar to those of temperature, excluding the case of the near-surface layer.     

Ultraviolet absorption/salinity correlation as an index of pollution in inshore sea waters

Ultraviolet absorption spectra of fresh and marine waters along the southern coast of Viti Levu, Fiji, are recorded. Variations in the magnitude of the absorption from streams deyoid of human influence limit the use of such measurements as a sensitive index of organic pollution. However, where there is a significant difference between the absorption magnitudes of adjacent streams, these can be individually identified in coastal waters by concurrent absorption and salinity measurements. Such measurements characterise water masses in inshore waters, and indicate the origin of their freshwater components. Consequently the method has particular relevance in sea areas influenced by fresh waters with enhanced ultraviolet absorbance due to organic pollution.     

The effect of manganese oxide scavenging on molybdenum in saanich inlet,British Columbia

A simple colorimetric method was developed for determining molybdenum in seawater by solvent extraction of its dithiolate and was then applied during a nine month study of Saanich Inlet. This inlet is a fjord on the coast of Vancouver Island, British Columbia, in which the bottom waters alternate between a weakly oxygenated and anoxic state. Results are given for the concentrations of dissolved and suspended molybdenum, suspended manganese, dissolved oxygen and of salinity measurements. Salinity-molybdenum correlations demonstrate that the deep waters are deficient in molybdenum, a conclusion consistent with reports that the sediments deposited in the reducing zone are enriched with molybdenum precipitated from the anoxic bottom waters. Suspended manganese, which occurs in large amounts as a result of the oxidative precipitation of dissolved Mn(II) diffusing from anoxic waters, has a distribution that is directly correlated to that of suspended molybdenum and which tends to be inversely related to that of dissolved molybdenum, suggesting that molybdenum is being coprecipitated with manganese oxides. Such a hypothesis is supported by the fact that the average molybdenum to manganese weight ratio of suspended matter closely approximates that of local manganese nodules, and by a mathematical analysis of the distribution data which includes development of a model for scavenging. Computations using the model relationships indicate that manganese oxide scavenging tends to concentrate molybdenum in the reducing waters where the anoxic processes responsible for its deposition in the sediments become operative. Additional calculations based upon current estimates of oceanic residence times suggest that manganese-oxide scavenging operating on an oceanic scale could be removing approximately 10% of the molybdenum being added to the oceans.     

Geochemistry of rare earth elements in the dissolved,acid-soluble and residual phases in surface waters of the Changjiang Estuary

The concentrations of rare earth elements in the dissolved, acid-soluble and residual phases in surface waters of the Changjiang Estuary were determined using ICP-MS. The main purposes of the study are to understand the estuarine geochemistry of rare earth elements and to explore water-particle interactions in the Changjiang estuarine mixing zone. The results show that there are two distinct processes operating on dissolved rare earth elements in the estuary: large scale removal at low salinities due to salt-induced coagulation and remarkable release at mid to high salinities. These processes result in modification of the effective river water flux and the systematical fractionation of the dissolved rare earth elements toward the East China Sea. The increase in concentration of dissolved rare earth elements in the mid to high salinity waters of the Changjiang Estuary suggests a sediment source in the mixing zone of the estuary, which is located over a shallow, broad shelf where there is extensive physical contact between bottom sediment and estuarine waters. Acid-soluble rare earth elements, the concentrations of which also dropped sharply in the low salinity region, appear to be controlled by salt-induced coagulation process and intense deposition of suspended particulate matter in the low salinity region. In the mid to high salinities, all acid-soluble rare earth element concentrations increase slightly with increasing salinity, suggesting that resuspension of sediments occurred. In contrast, the residual rare earth element concentrations are relatively constant with salinity variation in the Changjiang estuarine surface waters.     

入海河流河口及其近海水域盐度分析方法浅析

在水质监测及水环境调查中,盐度分析工作是一个重要环节,根据现行的《水质分析国家标准》,《海洋调查规范》地表水及生活用水的盐度分析一般采用前者,而海洋水样则采用后者,对于长江口及其近海水域既有适用《水质分析国家标准》（ＴＢ１１８９６－８９）的区段,又有适用《海洋调查规范》的区域,亦有两种都不适用的部分配 长江口盐度分析方法的研究,阐述了该区域进行水样盐度分析的各种方法的适用范围及提高效率保证成果质量     

Distributions of Water Masses and Currents in Tachibana Bay, West of Ari-ake Sound, Kyushu, Japan

We have investigated the water mass distribution and circulation in Tachibana Bay, which is located in the junction area between Ari-ake Sound and Amakusa-Nada in western Kyushu, Japan. This was done to clarify the mechanism by which ghost shrimp larvae, originating from a sandflat of Amakusa-Shimoshima Island, are transported. Temperature and salinity data repeatedly obtained over the area of Tachibana Bay show that relatively low salinity water lies over northern part of the bay, while high salinity water lies over southern part of the bay. The location of the low salinity water margin tends to depend on the amount of rainfall several days before the observation. A large amount of rainfall makes a clear boundary between low and high salinity waters. Current velocity data indicate an eastward mean flow just north of Tomioka, northern tip of Amakusa-Shimoshima Island, and a clockwise mean flow approaching the Tomioka Bay sandflat, which should be suitable for the on-shore transport of the ghost shrimp postlarvae. Current measurements with shipboard ADCP just west of Hayasaki Strait, at the entrance of Ari-ake Sound, show that a westward tidal residual current tends to incline to the north, with evidence of a density current in the northern part of the western Hayasaki Strait.     

Long-term moored array measurements of currents and hydrography over Georges Bank: 1994–1999

In conjunction with the GLOBEC (Global Ocean Ecosystems Dynamics) program, measurements of moored currents, temperature and salinity were made during 1994–1999 at locations in 76 m of water along the southern flank of Georges Bank and at the Northeastern Peak. The measurements concentrate on the biologically crucial winter and spring periods, and coverage during the fall is usually poorer.Current time series were completely dominated by the semidiurnal M₂ tidal component, while other tidal species (including the diurnal K₁ component) were also important. There was a substantial wind-driven component of the flow, which was linked, especially during the summer, to regional–scale response patterns. The current response at the Northeast Peak was especially strong in the 3–4 days period band, and this response is shown to be related to an amplifying topographic wave propagating eastward along the northern flank. Monthly mean flows on the southern flank are southwestward throughout the year, but strongest in the summertime. The observed tendency for summertime maximum along-bank flow to occur at depth is rationalized in terms of density gradients associated with a near-surface freshwater tongue wrapping around the Bank.Temperature and salinity time series demonstrate the presence, altogether about 25% of the time, of a number of intruding water masses. These intrusions could last anywhere from a couple days up to about a month. The sources of these intrusions can be broadly classified as the Scotian Shelf (especially during the winter), the Western Gulf of Maine (especially during the summer), and the deeper ocean south of Georges Bank (throughout the year). On longer time scales, the temperature variability is dominated by seasonal temperature changes. During the spring and summer, these changes are balanced by local heating or cooling, but wintertime cooling involves advective lateral transports as well. Salinity variations have weak, if any, seasonal variability, but are dominated by interannual changes that are related to regional- or basin-scale changes.All considered, Georges Bank temperature and salinity characteristics are found to be highly dependent on the surrounding waters, but many questions remain, especially in terms of whether intrusive events leave a sustained impact on Bank waters.     

A demonstration of the hydrographic partition of the Benguela upwelling ecosystem at 26°40'S

Continuous CTD data from a series of recent cruises show that the distribution of the water mass characteristics in the central Benguela region from the Orange River mouth (28°38'S) to alvis Bay (22°57'S) is discontinuous in the central and intermediate waters at about the latitude of Lüderitz (26°40'S), Namibia. The central and intermediate water masses at the shelf edge and shelf break north of the Lüderitz upwelling cell have a high salinity relative to the potential temperature compared to similar waters south of the upwelling cell. It is shown that the feed waters for the wind-induced upwelling on the shelf to the north and south of the Lüderitz discontinuity are different in character and source. The distribution of the water masses shows that the shelf-edge poleward undercurrent provides low-oxygen water from different regions in the Atlantic Ocean to be upwelled onto the shelf. North of th Lüderitz upwelling cell, the central and intermediate waters come from the oxygen-depleted Angola Basin, whereas south of the discontinuity those waters are from the interior of the adjacent Cape Basin, which is less oxygen-deficient. This has implications for the dispersion of low-oxygen water and the triggering of anoxic events, and consequences for the biota on the shelf, including commercially important fish species.     

A year in the physical oceanography of the Chukchi Sea: Moored measurements from autumn 1990–1991

Year-long time-series of temperature, salinity and velocity from 12 locations throughout the Chukchi Sea from September 1990 to October 1991 document physical transformations and significant seasonal changes in the throughflow from the Pacific to the Arctic Ocean for one year. In most of the Chukchi, the flow field responds rapidly to the local wind, with high spatial coherence over the basin scale—effectively the ocean takes on the lengthscales of the wind forcing. Although weekly transport variability is very large (ca. -2 to ), the mean flow is northwards, opposed by the mean wind (which is southward), but presumably forced by a sea-level slope between the Pacific and the Arctic, which these data suggest may have significant variability on long (order a year) timescales. The high flow variability yields a significant range of residence times for waters in the Chukchi (i.e. one to six months for half the transit) with the larger values applicable in winter.Temperature and salinity (TS) records show a strong annual cycle of freezing, salinization, freshening and warming, with sizable interannual variability. The largest seasonal variability is seen in the east, where warm, fresh waters escape from the buoyant, coastally trapped Alaskan Coastal Current into the interior Chukchi. In the west, the seasonally present Siberian Coastal Current provides a source of cold, fresh waters and a flow field less linked to the local wind. Cold, dense polynya waters are observed near Cape Lisburne and occasional upwelling events bring lower Arctic Ocean halocline waters to the head of Barrow Canyon. For about half the year, at least at depth, the entire Chukchi is condensed into a small region of TS-space at the freezing temperature, suggesting ventilation occurs to near-bottom, driven by cooling and brine rejection in autumn/winter and by storm-mixing all year.In 1990–1991, the ca. 0.8 Sv annual mean inflow through Bering Strait exits the Chukchi in four outflows—via Long Strait, Herald Valley, the Central Channel, and Barrow Canyon—each outflow being comparable (order 0.1–0.3 Sv) and showing significant changes in volume and water properties (and hence equilibrium depth in the Arctic Ocean) throughout the year. The clearest seasonal cycle in properties and flow is in Herald Valley, where the outflow is only weakly related to the local wind. In this one year, the outflows ventilate above and below (but not in) the Arctic halocline mode of 33.1 psu. A volumetric comparison with Bering Strait indicates significant cooling during transit through the Chukchi, but remarkably little change in salinity, at least in the denser waters. This suggests that, with the exception of (in this year small) polynya events, the salinity cycle in the Chukchi can be considered as being set by the input through Bering Strait and thus, since density is dominated by salinity at these temperatures, Bering Strait salinities are a reasonable predictor of ventilation of the Arctic Ocean.     

Sensitivity of a global ocean model to increased run-off from Greenland

We study the reaction of a global ocean–sea ice model to an increase of fresh water input into the northern North Atlantic under different surface boundary conditions, ranging from simple restoring of surface salinity to the use of an energy balance model (EBM) for the atmosphere. The anomalous fresh water flux is distributed around Greenland, reflecting increased melting of the Greenland ice sheet and increasing fresh water export from the Arctic Ocean. Depending on the type of surface boundary condition, the large circulation reacts with a slow-down of overturning and gyre circulations. Restoring of the total or mean surface salinity prevents a large scale redistribution of the salinity field that is apparent under mixed boundary conditions and with the EBM. The control run under mixed boundary conditions exhibits large and unrealistic oscillations of the meridional overturning. Although the reaction to the fresh water flux anomaly is similar to the response with the EBM, mixed boundary conditions must thus be considered unreliable. With the EBM, the waters in the deep western boundary current initially become saltier and a new fresh water mass forms in the north-eastern North Atlantic in response to the fresh water flux anomaly around Greenland. After an accumulation period of several decades duration, this new North East Atlantic Intermediate Water spreads towards the western boundary and opens a new southward pathway at intermediate depths along the western boundary for the fresh waters of high northern latitudes.     

Hypoxia by degrees: Establishing definitions for a changing ocean

The marked increase in occurrences of low oxygen events on continental shelves coupled with observed expansion of low oxygen regions of the ocean has drawn significant scientific and public attention. With this has come the need for the establishment of better definitions for widely used terms such as “hypoxia” and “dead zones”. Ocean chemists and physicists use concentration units such as ??molO₂/kg for reporting since these units are independent of temperature, salinity and pressure and are required for mass balances and for numerical models of ocean transport. Much of the reporting of dead zone occurrences is in volumetric concentration units of mlO₂/l or mgO₂/l for historical reasons. And direct measurements of the physiological state of marine animals require reporting of the partial pressure of oxygen (pO₂) in matm or kPa since this provides the thermodynamic driving force for molecular transfer through tissue. This necessarily incorporates temperature and salinity terms and thus accommodates changes driven by climate warming and the influence of the very large temperature range around the world where oxygen limiting values are reported. Here we examine the various definitions used and boundaries set and place them within a common framework. We examine the large scale ocean pO₂ fields required for pairing with pCO₂ data for examination of the combined impacts of ocean acidification and global warming. The term “dead zones”, which recently has received considerable attention in both the scientific literature and the press, usually describes shallow, coastal regions of low oxygen caused either by coastal eutrophication and organic matter decomposition or by upwelling of low oxygen waters. While we make clear that bathyal low oxygen waters should not be confused with shallow-water “dead zones”, as deep water species are well adapted, we show that those waters represent a global vast reservoir of low oxygen water which can readily be entrained in upwelling waters and contribute to coastal hypoxia around the world and may be characterized identically. We examine the potential for expansion of those water masses onto continental shelves worldwide, thereby crossing limits set for many not adapted species.     

Temporal and spatial distribution of dissolved copper, lead, zinc and cadmium in the Changjiang Estuary and its adjacent waters

Heavy metal concentrations were measured in the Changjiang Estuary and its adjacent waters. Results from a systematic survey in April 2002 to March 2003 indicate that the ranges of the concentrations of dissolved copper, lead, zinc and cadmium in the study waters are 1.01 - 6.86, 0. 10 - 0.39,3.17 - 9.12 and 0.011 - 0. 049 μg/dm^3 , respectively. Similar to zinc, the behavior of dissolved copper was essentially conservative, but high scatter has been observed for high salinity samples, which can be attributed to the decomposition or mineralization of organic matter by bacteria. Dissolved lead may have active behavior with an addition at high salinity. Overall concentrations of dissolved cadmium increase with salinity. The mean values of these dissolved metals calculated for the surface waters were higher than those for the middle and bottom ones. External inputs of dissolved heavy metals to the surface waters were the likely explanation for these higher values. The maximum seasonal average values of dissolved copper and zinc were found in summer, reflecting higher amounts of riverine input in this season. In contrast, the maximum seasonal average values of dissolved lead and copper were found in winter and the lowest ones in summer, respectively, which might be asso- ciated with a combination of low concentration with heterogeneous scavenging. Concentrations of these dissolved metals found for the Changjiang Estuary fall in the range observed for the other estuaries but are noticeably higher than those from uncontaminated rivers, except for cadmium. Compared with observations for the Changjiang Estuary in the last two decades, it is clear that the Changjiang estuarine waters has been contaminated with copper, lead, zinc and cadmium during China＇ s industrialization, but concentrations of them have decreased in the last few years.     

Effect of changes in the composition of seawater on the density–salinity relationship

Over the next 5–10 years, the WOCE hydrographic program will generate reliable hydrographic data for the world oceans. The resultant conductivity salinity, temperature, and pressure data will generate calculated densities that will be used to examine mixing along constant density surfaces. Changes in the composition of deep waters due to the breakdown of plant material can effect the calculated densities at a given conductivity salinity. The increases in SiO₂, nitrate, alkalinity, and TCO₂ (or pH) can change the density of seawater as well as the conductivity. For studies of the salinity and density fields over small spatial scales, these changes will be small, but for large scale and ocean to ocean studies the differences can be significant. The density calculations based on the salinity determined from conductivity need to be adjusted for the offsets due to changes in the composition of seawater. This report describes how this correction should be made using existing information.     

Antarctic Intermediate Water variability in the northern New Zealand region

In the region between 30°S and northern New Zealand, vertical salinity profiles through the core of the Antarctic Intermediate Water (AAIW) show a high degree of spatial and temporal variability, and this variability is much larger than that found in nearby ocean areas. Characteristic features are interleaving of salinity layers and large changes in the salinity minimum between adjacent stations. Quantifying the changes through the calculation of an intrusion index highlights the degree of variability and the importance of boundary mixing along the New Zealand slope. However, the main cause of the variability is the meeting and mixing of higher salinity AAIW, arriving from the north‐west (having travelled around the subtropical gyre) with lower salinity AAIW arriving by more direct entry from the north‐east. These waters meet in the region through the action of the meso‐scale eddy field. Present data indicate that where strong salinity interleaving occurs, the length scales are of the order of 10 km and the time scales are of the order of a few days. Resolution of the processes at work will require studies on finer scales than presently available.     

Cessation and partial reversal of deep water freshening in the northern North Atlantic: observation-based estimates and attribution

Recent decadal salinity changes in the Greenland-Scotland overflow-derived deep waters are quantified using CTD data from repeated hydrographic sections in the Irminger Sea. The Denmark Strait Overflow Water salinity record shows the absence of any net change over the 1980s–2000s; changes in the Iceland–Scotland Overflow Water (ISOW) and in the deep water column (σ₀ > 27.82), enclosing both overflows, show a distinct freshening reversal in the early 2000s. The observed freshening reversal is a lagged consequence of the persistent ISOW salinification that occurred upstream, in the Iceland Basin, after 1996 in response to salinification of the northeast Atlantic waters entrained into the overflow. The entrainment salinity increase is explained by the earlier documented North Atlantic Oscillation (NAO)-induced contraction of the subpolar gyre and corresponding northwestward advance of subtropical waters that followed the NAO decline in the mid-1990s and continued through the mid-2000s. Remarkably, the ISOW freshening reversal is not associated with changes in the overflow water salinity. This suggests that changes in the NAO-dependent relative contributions of subpolar and subtropical waters to the entrainment south of the Iceland–Scotland Ridge may dominate over changes in the Nordic Seas freshwater balance with respect to their effect on the ISOW salinity.