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1.
We performed a petrologic, geochemical, and oxygen isotopic study of the lowest FeO ordinary chondrite (OC), Yamato (Y) 982717. Y 982717 shows a chondritic texture composed of chondrules and chondrule fragments, and mineral fragments set in a finer grained, clastic matrix, similar to H4 chondrites. The composition of olivine (Fa11.17 ± 0.48 (1σ)) and low‐Ca pyroxene (Fs11.07 ± 0.98 (1σ)Wo0.90 ± 0.71(1σ)) is significantly more magnesian than those of typical H chondrites (Fa16.0‐20, Fs14.5‐18.0), as well as other known low‐FeO OCs (Fa12.8‐16.7; Fs13‐16). However, the bulk chemical composition of Y 982717, in particular lithophile and moderately volatile elements, is within the range of OCs. The bulk siderophile element composition (Ni, Co) is within the range of H chondrites and distinguishable from L chondrites. The O‐isotopic composition is also within the range of H chondrites. The lack of reduction textures indicates that the low olivine Fa content and low‐Ca pyroxene Fs content are characteristics of the precursor materials, rather than the result of reduction during thermal metamorphism. We suggest that the H chondrites are more compositionally diverse than has been previously recognized.  相似文献   

2.
A mineralogical and chemical analysis has been performed on the largest mass (8750 g) of the Girgenti, Italy, meteorite, from the collection of the Smithsonian Institution, Washington, D.C. The mineralogical composition is olivine, Fa24–25; hypersthene, Fs21 –22; plagioclase, An12; maskelynite; whitlockite; nickel-iron; troilite; chromite and ilmenite. Girgenti is a severly metamorphosed stone, whose total iron content (23.5%) is somewhat higher than the average for hypersthene chondrites.  相似文献   

3.
The principal data are collected about the fall and the distribution of the fragments of the Valdinizza, Italy, meteorite. A complete individual, weighing 872 g, preserved in the United States National Museum, Washington, D. C., is described in some detail. The mineralogical composition is olivine, Fa25; hypersthene, Fs23; plagioclase, An10; maskelynite; nickel-iron; troilite; chromite; ilmenite and possibly a phosphate mineral. Valdinizza is a fairly typical hypersthene chondrite, belonging to the type 6 chondrites of Van Schmus and Wood (1967); its structure shows evidence of a period of high-temperature recrystallization; interesting features of shock-metamorphism are notable, the microtexture deformations suggesting a high level of stress  相似文献   

4.
Abstract— Mass balance calculations were performed to constrain the precursor mineralogy of fine-grained, aqueously altered materials in CM carbonaceous chondrites. The bulk composition of unaltered fine-grained CM materials was estimated and then used to calculate phase proportions for several different initial assemblages. All starting assemblages contain relic, unaltered Fe-poor phases observed in CM chondrites, plus iron sulfides. The original sources of Fe are uncertain, because most primary Fe-rich phases were aqueously altered. Four endmember assemblages are considered by adding Fe metal, Fa50, Fa100, or FeO-rich amorphous materials to the Fe-poor phases. These represent the Fe-bearing phases in CM and/or other chondritic classes. Results indicate that the precursor CM assemblage may have contained a maximum of either ~10 vol% Fe metal, 57 vol% Fa50, ~28 vol% Fa100, or 37.0 vol% FeO-rich amorphous materials. Additional calculations were performed in which Fe metal was added to the various FeO-bearing assemblages. These reveal a strong positive correlation between the forsterite/(forsterite + enstatite) ratio and the amount of FeO-bearing phases that coexist with metal. If forsterite was more abundant than low-Ca pyroxene in the accreted CM materials, then these materials must have also contained significant amounts of FeO-rich phases (e.g., at least 36 vol% Fa50, 10 vol% Fa100, or 17 vol% FeO-bearing glasses). Calculated mineral proportions suggest that intact calcium-aluminum-rich inclusions (CAIs) represent only about one-half of the original CAI budget, which is consistent with previous hypotheses that the initial CAI contents of CM and CO chondrites were similar. Some similarities exist between the primary CM assemblages calculated here and the mineralogies of other chondrite classes, but the initial CM materials do not appear to be represented in our meteorite inventory.  相似文献   

5.
Abstract— A crusted stone weighing 3.10 kg was found in 1983 near Tabbita in south central New South Wales (ca. 34°03′S, 145°50′E), Australia. Compositions of the ferro-magnesian silicates (olivine Fa24.6; orthopyroxene Fs20.9) show that the meteorite belongs to the L-group of chondrites. Uniformity of silicate compositions and the presence of abundant crystalline plagioclase feldspar (An10.8Ab81.7Or7.5) show that the meteorite belongs to petrologic type 6. Silicates that display undulose extinction, and the absence of any thermal effects induced by shock indicate that Tabbita is shock facies c. Tabbita is distinct from several other L6 chondrites found in the same general area.  相似文献   

6.
The Loop meteorite was found in 1962 in Gaines County, Texas, at a location very close to that where the Ashmore chondrite was found in 1969. The two specimens were assumed to be fragments of the same meteorite. The Loop meteorite is a type L6 chondrite composed of olivine (Fo75.4Fa24.6), orthopyroxene (En77.6Wo1.5Fs20.9), clinopyroxene (En47.5Wo45.1Fs7.4), plagioclase (Ab84.3Or5.5An10.2), Fe-Ni metal, troilite, and chromite. Fe-Ni metal is represented by kamacite (5.8-6.4 wt % Ni, 0.88-1.00 wt % Co), taenite (30.0–52.9 wt % Ni, 0.16-0.34 wt % Co), and plessite (16.8–28.5 wt % Ni, 0.38-0.54 wt % Co). Native copper occurs as rare inclusions in Fe-Ni metal. Both chondrules and matrix have similar mineral compositions. The mineral chemistry of the Loop meteorite is quite different from that of the Ashmore, which was classified as an H5 chondrite by Bryan and Kullerud (1975). Therefore, the Ashmore and Loop meteorites are two different chondrites, even though they were recovered from the same geographic location.  相似文献   

7.
Microprobe analyses of the major silicates in Clovis (no. 1), New Mexico, establish it as an H3 chondrite. Inclusions identified in Clovis are: breccia fragments; angular and vesicular chondrule or rock fragments composed almost entirely of glass and olivine (Fa12–22); chondrules, composed principally of pyroxene (Fs2–33) and olivine (Fa1–28); and Ca, Al and Ti-rich inclusions. These refractory enriched inclusions, similar in composition to those found in some carbonaceous chondrites, are rare in ordinary chondrites but in this study were observed in Sharps, Virginia (H3), Gobabeb, South Africa (H4), Dimmitt, Texas (H4), Weston, Connecticut (H4–6) and Clovis. Sodium, known to rim similar inclusions in carbonaceous chondrites, also occurs in the interiors of inclusions observed in this study, sometimes in moderate amounts. The Na distribution is regarded as primary and is not attributable, at least in total, to secondary Na extraction from the host matrix.  相似文献   

8.
Abstract— Petrographic and mineralogic studies of amoeboid olivine inclusions (AOIs) in CO3 carbonaceous chondrites reveal that they are sensitive indicators of parent‐body aqueous and thermal alteration. As the petrologic subtype increases from 3.0 to 3.8, forsteritic olivine (Fa0–1) is systematically converted into ferroan olivine (Fa60–75). We infer that the Fe, Si and O entered the assemblage along grain boundaries, forming ferroan olivine that filled fractures and voids. As temperatures increased, Fe+2 from the new olivine exchanged with Mg+2 from the original AOI to form diffusive haloes around low‐FeO cores. Cations of Mn+2, Ca+2 and Cr+3 were also mobilized. The systematic changes in AOI textures and olivine compositional distributions can be used to refine the classification of CO3 chondrites into subtypes. In subtype 3.0, olivine occurs as small forsterite grains (Fa0–1), free of ferroan olivine. In petrologic subtype 3.2, narrow veins of FeO‐rich olivine have formed at forsterite grain boundaries. With increasing alteration, these veins thicken to form zones of ferroan olivine at the outside AOI margin and within the AOI interior. By subtype 3.7, there is a fairly broad olivine compositional distribution in the range Fa63–70, and by subtype 3.8, no forsterite remains and the high‐Fa peak has narrowed, Fa64–67. Even at this stage, there is incomplete equilibration in the chondrite as a whole (e.g., data for coarse olivine grains in Isna (CO3.8) chondrules and lithic clasts show a peak at Fa39). We infer that the mineral changes in AOI identified in the low petrologic types required aqueous or hydrothermal fluids whereas those in subtypes ?3.3 largely reflect diffusive exchange within and between mineral grains without the aid of fluids.  相似文献   

9.
The mineralogical and chemical compositions of meteorites from the Motta di Conti, Vercelli, Italy, shower (February 29, 1868) have been determined. Microprobe analyses, of olivine (Fa19,6) and orthopyroxene (Fs17,8), as well as the bulk chemical composition, particularly the ratios of SiO2/MgO (1.50), Fe°/Ni° (11.03), Fetotal/SiO2 (0.81), Fe°/Fetotal (0.70) and the content of Fetotal (28.60%) classify the meteorite as an H-group chondrite. The percentage of total metallic nickel-iron (22.06%) is somewhat higher than the average in H-group chondrites. The texture of our stone shows evidence of metamorphism. The integration between matrix and chondrules is advanced and may suggest a high petrographic grade, but the identification of several microscopic features (e.g. small grains of monoclinic twinned pyroxene, FeNi-FeS intergrowths, globules and mosaic) leads to the conclusion that a variety of petrographic types (4–6) are present. Metamorphic equilibration in chondrites is discussed and a preliminary hypothesis for H4–6 chondrites is suggested.  相似文献   

10.
According to its petrography, uniform olivine, Fa23.8, and pyroxene, Fs20.4, a total iron content of 22.9 wt % Fe, 16.4 wt % FeO and an FeO/FeO + MgO ratio of 24.7 mol %, the Tambakwatu is a veined, intermediate hypersthene (Cia) or L6 chondrite.  相似文献   

11.
The Homewood meteorite is a slightly weathered find of 325 grams discovered in 1970 about 64 km southwest of Winnipeg, Manitoba. It consists of olivine (Fa25.4; 43.8 normative wt. percent), orthopyroxene (Fs23.3; 28.5 percent), kamacite and taenite (7.5 percent), troilite (5.6 percent), maskelynite (8.3 percent), chromite (1.0 percent), whitlockite (0.7 percent) and minor patchy Ca pyroxene. Bulk chemical analysis yielded Fetotal 21.60 wt. percent, Fe/SiO20.55, SiO2/MgO 1.53 and FeO/Fetotal 0.29. Barred olivine, radiating pyroxene and porphyritic chondrules, all with ill-defined outlines, occur in the meteorite. Most chemical and mineralogical features characterize the Homewood meteorite as an L6 (hypersthene) chondrite. The presence of maskelynite, the undulatory extinction, extensive fracturing and pervasive mosaicism of olivine, and the poor definition of chondrule outlines suggest that the Homewood meteorite has been shocked in the range of 300–350 kbar.  相似文献   

12.
The Kramer Creek, Colorado, chondrite was found in 1966 and identified as a meteorite in 1972. Bulk chemical analysis, particularly the total iron content (20.36%) and the ratio of Fetotal/SiO2 (0.52), as well as the compositions of olivine (Fa21.7) and orthopyroxene (Fs18.3) place the meteorite into the L-group of chondrites. The well-defined chondritic texture of the meteorite, the presence of igneous glass in the chondrules and of low-Ca clinopyroxene, as well as the slight variations in FeO contents of olivine (2.4% MD) and orthopyroxene (5.6% MD) indicate that the chondrite belongs to the type 4 petrologic class.  相似文献   

13.
In the summer of 1984, two meteorites fell in the northern part of Honshu, Japan; Aomori, at 1:50 p.m. on June 30, and Tomiya, at 1:35 p.m. on August 22. Coordinates of the falls of the Aomori and the Tomiya are at 140°47.1'E., 40°48.6'N., and 140°51.9'E., 38°22.0'N., respectively. Results of chemical analyses of major elements, ratios of Fetotal/SiO2 (0.546 and 0.803) and Femetal/Fetotal (0.332 and 0.581), and molar compositions of olivines (Fa25 and Fa19) indicate that the Aomori and the Tomiya are typical L- and H-group ordinary chondrites, respectively. In the Aomori, chondrules are present as relicts in the well-recrystallized matrix. Olivine and pyroxene are homogeneous in composition, and coarse clear feldspar, up to 100 micrometers in size, is well developed in the chondrules and matrix. Though the Aomori is a petrologic type 6 based on its texture and mineralogy, it includes a few grains of multiple twinned clinobronzite which is rarely observed in highly equilibrated ordinary chondrites. In the Tomiya, chondrules possess a fine-grained mesostasis, and both orthopyroxene and clinobronzite are noticeable in thin sections. Plagioclase is mostly microcrystalline, but is also sparsely present as tiny, visible grains. Thus, the Tomiya was classified to be petrologic type between 4 and 5. The deformation texture of olivine, pyroxene and plagioclase indicates that both meteorites were shocked by 0.2-0.25 Mb. In conjunction with the discussion of the frequency of meteorite-falls, all observed falls of meteorites in Japan are tabulated in this paper.  相似文献   

14.
Abstract Al-Jimshan is a highly weathered 11.45 kg chondrite that was found in 1955 in the Rub' al Khali Desert, Saudi Arabia (20*42′N, 52*50E) about 240 km south-east of the town of al-Hadidah. The main mass is now at UCLA. Based on texture and mineral composition (olivine Fa17.7 ± 0.4; pyroxene Fs15.7 ± 1.0 Wo13 ± 0.4), al-Jimshan is classified as an H4 chondrite of shock stage S2. The Bir-Hadi and ad-Dahbubah H chondrites, which also were found in the Rub'al Khali (Holm, 1962), are probably not paired with al-Jimshan. They are classified as H5, shock stage S3 (Fa18.1 ± 0.5, n = 10; Fs16.0 ± 0.6, Wo1.1 ± 0.4, n = 9) and H5, shock stage S2 (Fa17.9 ± 0.3, n = 10; FS15.5 ± 0.2 Wo1.0 ± 0.4, n = 10), respectively.  相似文献   

15.
Abstract— We report in situ measurements of O‐isotopic compositions of magnetite and primary and secondary olivine in the highly unequilibrated oxidized CV chondrites Kaba and Mokoia. In both meteorites, the magnetite and the secondary olivine (fayalite, Fa90–100) have O‐isotopic compositions near the terrestrial fractionation (TF) line; the mean Δ17O (= δ17O‐0.52 × δ18O) value is about ?1%‰. In contrast, the compositions of nearby primary (chondrule), low‐FeO olivines (Fa1–2) are well below the TF line; Δ17O values range from ?3 to ?9%‰. Krot et al. (1998) summarized evidence indicating that the secondary phases in these chondrites formed by aqueous alteration in an asteroidal setting. The compositions of magnetite and fayalite in Kaba and Mokoia imply that the O‐isotopic composition of the oxidant was near or somewhat above the TF line. In Mokoia the fayalite and magnetite differ in δ18O by ~20%‰, whereas these same materials in Kaba have virtually identical compositions. The difference between Mokoia magnetite and fayalite may indicate formation in isotopic equilibrium in a water‐rich environment at low temperatures, ~300 K. In contrast, the similar compositions of these phases in Kaba may indicate formation of the fayalite by replacement of preexisting magnetite in dry environment, with the O coming entirely from the precursor magnetite and silica. The Δ17O of the oxidant incorporated into the CV parent body (as phyllosilicates or H2O) appears to have been much (7–8%‰) lower than that in that incorporated into the LL parent body (Choi et al, 1998), which suggests that the O‐isotopic composition of the nebular gas was spatially or temporally variable.  相似文献   

16.
The Colony meteorite is an accretionary breccia containing several millimeter-to centimeter-size chondritic clasts embedded in a chondritic host. Colony is one of the least equilibrated CO3 chondrites; it has an unrecrystallized texture and contains compositionally heterogeneous olivine and low-Ca pyroxene, kamacite with low Ni and Co and high Cr, amoeboid inclusions with low FeO and MnO, a fine-grained silicate matrix with very high FeO, and numerous small chondrules with clear pink glass. However, Colony differs from normal CO chondrites in several respects: Although Al, Sc, V, Cr, Ir, Fe, Au and Ga abundances are consistent with a CO chondrite classification, certain lithophiles (Mg and Mn), siderophiles (Ni and Co) and chalcophiles (Se and Zn) are depleted by factors of 10–40%. The shape of Colony's thermoluminescence (TL) glow curve is similar to that of Allan Hills A77307 (another unequilibrated chondrite with CO3 petrological characteristics) and different from those of normal CO chondrites. [ALHA77307 also resembles Colony in having low Mg, Mn, Ni and Co, compared to normal CO chondrites, but it possesses CO-CV levels of Se and Zn and nearly CV levels of Cd.] Colony is badly weathered; it contains 22.7 wt.% Fe2O3 and 5.7 wt.% H2O. Recalculating the analysis on an H2O-free basis with all Fe2O3, NiO and CoO converted to metal, yields an inferred original metallic Fe, Ni abundance of ~ 19 wt.%. This is similar to that of Kainsaz (an unweathered CO3 fall), but much higher than that of all other CO3 chondrites (< 6.3 wt.%). Although it is possible that Colony and either ALHA77307 or Kainsaz constitute distinct CO3 chemical subgroups, the weathered nature of Colony and ALHA77307 preclude the drawing of firm conclusions. Nevertheless, it is clear that CO3 chondrites vary more in compositional and petrological properties than was previously recognized.  相似文献   

17.
Madiun is a white, veined olivine-hypersthene, L6 chondrite. It can be classed as such on the basis of its petrography and chemistry, uniform olivine (Fa24.2) and pyroxene (Fs21,2) end total iron content of 23.7 wt % Fe.  相似文献   

18.
Pecora Escarpment 91002: A member of the new Rumuruti (R) chondrite group   总被引:1,自引:0,他引:1  
Abstract— Pecora Escarpment (PCA)91002 is a light/dark-structured chondrite breccia related to Carlisle Lakes and Rumuruti; the meteorite contains ~10–20 vol% equilibrated (type ?5 and ?6) clasts within a clastic groundmass, much of which was metamorphosed to type-3.8 levels. The olivine compositional distribution forms a tight cluster that peaks at Fa38–40; by contrast, low-Ca pyroxene compositions are highly variable. Opaque phases identified in PCA91002 and its paired specimen, PCA91241, include pyrrhotite, pentlandite, pyrite, chromite, ilmenite, metallic Cu and magnetite. The majority of the rock is of shock stage S3-S4; there are numerous sulfide-rich shock veins and 50-μm plagioclase melt pockets. Instrumental neutron activation analysis shows that, unlike Carlisle Lakes and ALH85151, PCA91002 exhibits no Ca enrichment or Au depletion; because PCA91002 is relatively unweathered, it seems probable that the Ca and Au fractionations in Carlisle Lakes and ALH85151 were caused by terrestrial alteration. The Rumuruti-like (formerly Carlisle-Lakes-like) chondrites now include eight separate meteorites. Their geochemical and petrographic similarities suggest that they constitute a distinct chondrite group characterized by unfractionated refractory lithophile abundances (0.95 ± 0.05x CI), high bulk Δ17O, a low chondrule/groundmass modal abundance ratio, mean chondrule diameters in the 400 ± 100 μm range, abundant NiO-bearing ferroan olivine, sodic plagioclase, titanian chromite, abundant pyrrhotite and pentlandite and negligible metallic Fe-Ni. We propose that this group be called R chondrites after Rumuruti, the only fall. The abundant NiO-bearing ferroan olivine grains, the occurrence of Cu-bearing sulfide, and the paucity of metallic Fe-Ni indicate that R chondrites are highly oxidized. It is unlikely that appreciable oxidation took place on the parent body because of the essential lack of plausible oxidizing agents (e.g., magnetite or hydrated silicates). Therefore, oxidation of R chondrite material must have occurred in the nebula. A few type-I porphyritic olivine chondrules containing olivine grains with cores of Fa3–4 composition occur in PCA91002; these chondrules probably formed initially as metallic-Fe-Ni-bearing objects at high nebular temperatures. As temperatures decreased and more metallic Fe was oxidized, these chondrules accreted small amounts of oxidized material and were remelted. The ferroan compositions of the >5-μm olivine grains in the R chondrites reflect equilibration with fine-grained FeO-rich matrix material during parent body metatnorphism.  相似文献   

19.
The formation of the high‐pressure compositional equivalents of olivine and pyroxene has been well‐documented within and surrounding shock‐induced veins in chondritic meteorites, formed by crystallization from a liquid‐ or solid‐state phase transformation. Typically polycrystalline ringwoodite grains have a narrow range of compositions that overlap with those of their olivine precursors, whereas the formation of iron‐enriched ringwoodite has been documented from only a handful of meteorites. Here, we report backscattered electron images, quantitative wavelength‐dispersive spectrometry (WDS) analyses, qualitative WDS elemental X‐ray maps, and micro‐Raman spectra that reveal the presence of Fe‐rich ringwoodite (Fa44‐63) as fine‐grained (500 nm), polycrystalline rims on olivine (Fa24‐25) wall rock and as clasts engulfed by shock melt in a previously unstudied L5 chondrite, Dhofar 1970. Crystallization of majorite + magnesiowüstite in the vein interior and metastable mineral assemblages within 35 μm of the vein margin attest to rapid crystallization of a superheated shock melt (>2300 K) from 20─25 GPa to ambient pressure and temperature. The texture and composition of bright polycrystalline ringwoodite rims (Fa44‐63; MnO 0.01─0.08 wt%) surrounding dark polycrystalline olivine (Fa8‐14; MnO 0.56─0.65 wt%) implies a solid‐state transformation mechanism in which Fe was preferentially partitioned to ringwoodite. The spatial association between ringwoodite and shock melt suggests that the rapidly fluctuating thermal regimes experienced by chondritic minerals in contact with shock melt are necessary to both drive phase transformation but also to prevent back‐transformation.  相似文献   

20.
Abstract— We have measured O‐isotopic ratios in a variety of olivine grains in the CO3 chondrite Allan Hills (ALH) A77307 using secondary ion mass spectrometry in order to study the chondrule formation process and the origin of isolated olivine grains in unequilibrated chondrites. Oxygen‐isotopic ratios of olivines in this chondrite are variable from δ17O = ?15.5 to +4.5% and δ18O = ?11.5 to +3.9%, with Δ17O varying from ?10.4 to +3.5%. Forsteritic olivines, Fa<1, are enriched in 16O relative to the bulk chondrite, whereas more FeO‐rich olivines are more depleted in 16O. Most ratios lie close to the carbonaceous chondrite anhydrous minerals (CCAM) line with negative values of Δ17O, although one grain of composition Fa4 has a mean Δ17O of +1.6%. Marked O‐isotopic heterogeneity within one FeO‐rich chondrule is the result of incorporation of relic, 16O‐rich, Mg‐rich grains into a more 16O‐depleted host. Isolated olivine grains, including isolated forsterites, have similar O‐isotopic ratios to olivine in chondrules of corresponding chemical composition. This is consistent with derivation of isolated olivine from chondrules, as well as the possibility that isolated grains are chondrule precursors. The high 16O in forsteritic olivine is similar to that observed in forsterite in CV and CI chondrites and the ordinary chondrite Julesburg and suggests nebula‐wide processes for the origin of forsterite that appears to be a primitive nebular component.  相似文献   

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