CHEMICAL VARIATIONS AMONG L-GROUP CHONDRITES,II. CHEMICAL DISTINCTIONS BETWEEN L3 AND LL3 CHONDRITES

New chemical analyses of the Krymka and Manych chondrites and a review of data for other low-iron type 3 chondrites show that the ratio of metallic to total iron varies widely in LL3 chondrites and is an imperfect basis for distinguishing between these meteorites and L3 chondrites. More reliable chemical criteria — total Fe/Mg and Ni/Mg ratios, and Fe-S relationships — indicate that Krymka, Manych, Carraweena and Bishunpur are LL3 chondrites rather than samples of an iron-poor subgroup of the L-group.     

CHEMICAL VARIATIONS AMONG L-GROUP CHONDRITES,III. MAJOR ELEMENT VARIATION IN L6 CHONDRITES

Bulk chemical and mineral analyses of five L6 chondrites of shock facies d to f bring the number of L6 falls analyzed by Jarosewich to 20 and enable us: 1) to examine the chemical effects of shock melting in chondrites of the same petrologic type that presumably sample a limited stratigraphic range in their parent body; and 2) to seek depth-related chemical variations by comparing the compositions of L3 and melt-free L6 chondrites. The mean Fe/Mg, Si/Mg, S/Mg and Ni/Mg ratios of melt-free L6 chondrites (shock facies a to c) are virtually identical to those of L3 chondrites, suggesting that L-group material had the same bulk composition early (L6) and late (L3) in the accretion of the parent body. Wider variations of S/Mg and Ni/Mg in L6 chondrites may signify that L6 material was less well mixed than L3, or that some mobilization of metal and troilite occurred at shock intensities (facies c) too low to melt silicates. L6 chondrites that experienced shock melting of silicates (facies d to f) show wide variations of Fe/Mg, Si/Mg, S/Mg and Ni/Mg. It appears that most of the major element variation in the L-group is tertiary (shock-related) rather than primary (nebular, accretionary) or secondary (metamorphic). There is some evidence that L-group chondrites comprise two subgroups with different Fe/S ratios, but these subgroups are now poorly defined and their significance is unknown.     

CHEMICAL VARIATIONS AMONG L-GROUP CHONDRITES I. THE AIR,APT AND TOURINNES-LA-GROSSE (L6) CHONDRITES

Petrographic, mineralogical and bulk chemical data are presented for three of approximately 25 L-group chondrites with which we are attempting to define and interpret major element chemical variations in the L-group. Two of these unbrecciated L6 chondrites - Aïr and Apt - have olivine and feldspar characteristics that testify to shock pressures of approximately 240–260 kb; they contain sparse veins and pockets of glass. The third, Tourinnes-la-Grosse, experienced a lower shock pressure and lacks such evidence of melting.     

HIGH POSSIL AND STRATHMORE—A STUDY OF TWO L6 CHONDRITES

High Possil and Strathmore are the first (1804) and last (1917) meteorite falls, respectively, of the three recorded in Scotland. Olivine compositions and total Fe contents in High Possil (Fa_25.2; 21.35 wt %) and Strathmore (Fa_25.3; 20.6 wt %) confirm their classification as L-group chondrites (Mason, 1963), and the presence of abundant plagioclase feldspar shows that both chondrites belong to petrologic type 6. Both chondrites display thermal and mechanical alteration attributable to moderate shock-loading appropriate to facies c (High Possil) and c-d (Strathmore) (Dodd and Jarosewich, 1979). Incipient shock-melting of metal and troilite in both chondrites is the first described from Lc chondrites, and differences in the responses of metallic and silicate minerals to shock-loading are discussed.     

THE CHEMICAL COMPOSITION OF MAJOR ELEMENTS AND HEAVY TRACE METALS IN CHONDRITES PARAMBÙ AND MARILIA

The chemical composition of the newly observed fallen chondrites Parambù, 1967, and Marilia, 1971, was determined. Wet chemical methods were used for major elements analyses and the abundances of heavy trace elements from tungsten to uranium were determined by spark source mass spectrometry. The chemical composition confirmed the classification of Marilia as an H-group chondrite by Avanzo et al. (1973): Parambù was classified as an LL-group chondrite.     

ADELAIDE AND BENCH CRATER — MEMBERS OF A NEW SUBGROUP OF THE CARBONACEOUS CHONDRITES

The composition and mineralogy of Bench Crater and a new carbonaceous chondrite (Adelaide) are compared. They, Kakangari and possibly certain carbonaceous xenoliths from other meteorites constitute a distinct chemical subgroup of the carbonaceous chondrites characterized primarily by a calcium-to-aluminium ratio (atomic) of about 0.5. It is proposed to call this group the Kakangari (CK) group     

PLASMA CHEMISTRY OF METEORITES—I. CLEANSING AND REDUCTION OF THE ODESSA IRON METEORITE

Three small samples of the Odessa, Texas iron meteorite, two surrounded by sandy soil, were introduced into a hydrogen plasma. The soil was effectively cleansed from the iron surfaces, being substantially destroyed with only a fine dust remaining. The appearance of the iron meteorite samples indicated that the terrestrial oxidation was reversed, probably to magnetite, Fe₃O₄, and metallic iron.     

THE METEORITIC SHOWER OF PARAMBU,CEARA STATE,BRAZIL: — MINERALOGY AND PETROLOGY

The fall of a meteorite shower in Parambú, Ceará State, Brazil, is described. Parambú is an L-group chondrite (Urey and Craig, 1953). The mineralogical composition is olivine Fa₂₈. ortho- and clinopyroxenes, plagioclase, maskelynite, whitlockite, nickel-iron, troilite, chromite, and ilmenite. The structure of Parambú is characteristically polymict and shows an advanced brecciation. Interesting features of metamorphism are notable, with good evidence of shock.