On the relationship between the Apollo 16 ancient regolith breccias and feldspathic fragmental breccias,and the composition of the prebasin crust in the Central Highlands of the Moon

Abstract Two types of texturally and compositionally similar breccias that consist largely of fragmental debris from meteorite impacts occur at the Apollo 16 lunar site: Feldspathic fragmental breccias (FFBs) and ancient regolith breccias (ARBs). Both types of breccia are composed of a suite of mostly feldspathic components derived from the early crust of the Moon and mafic impact-melt breccias produced during the time of basin formation. The ARBs also contain components, such as agglutinates and glass spherules, indicating that the material of which they are composed occurred at the surface of the Moon as fine-grained regolith prior to lithification of the breccias. These components are absent from the FFBs, suggesting that the FFBs might be the protolith of the ARBs. However, several compositional differences exist between the two types of breccia, making any simple genetic relationship implausible. First, clasts of mafic impact-melt breccia occurring in the FFBs are of a different composition than those in the ARBs. Also the feldspathic “prebasin” components of the FFBs have a lower average Mg/Fe ratio than the corresponding components of the ARBs; the average composition of the plagioclase in the FFBs is more sodic than that of the ARBs; and there are differences in relative abundances of rare earth elements. The two breccia types also have different provenances: the FFBs occur primarily in ejecta from North Ray crater and presumably derive from the Descartes Formation, while the ARBs are restricted to the Cayley plains. Together these observations suggest that although some type of fragmental breccia may have been a precursor to the ARBs, the FFBs of North Ray crater are not a significant component of the ARBs and, by inference, the Cayley plains. The average compositions of the prebasin components of the two types of fragmental breccia are generally similar to the composition of the feldspathic lunar meteorites. With 30–31% Al₂O₃, however, they are slightly richer in plagioclase than the most feldspathic lunar meteorites (～29% Al₂O₃), implying that the crust of the early central nearside of the Moon contained a higher abundance of highly feldspathic anorthosite than typical lunar highlands, as inferred from the lunar meteorites. The ancient regolith breccias, as well as the current surface regolith of the Cayley plains, are more mafic than (1) prebasin regoliths in the Central Highlands and (2) regions of highlands presently distant from nearside basins because they contain a high abundance (～30%) of mafic impact-melt breccias produced during the time of basin formation that is absent from other regoliths.     

Some things we can infer about the Moon from the composition of the Apollo 16 regolith

Abstract— Characteristics of the regolith of Cayley plains as sampled at the Apollo 16 lunar landing site are reviewed and new compositional data are presented for samples of <1 mm fines (“soils”) and 1–2 mm regolith particles. As a means of determining which of the many primary (igneous) and secondary (crystalline breccias) lithologic components that have been identified in the soil are volumetrically important and providing an estimate of their relative abundances, more than 3 × 10⁶ combinations of components representing nearly every lithology that has been observed in the Apollo 16 regolith were systematically tested to determine which combinations best account for the composition of the soils. Conclusions drawn from the modeling include the following. At the site, mature soil from the Cayley plains consists of 64.5% ± 2.7% components representing “prebasin” materials: anorthosites, feldspathic breccias, and a small amount (2.6% ± 1.5% of total soil) of nonmare, mafic plutonic rocks, mostly gabbronorites. On average, these components are highly feldspathic, with average concentrations of 31–32% Al₂O₃ and 2–3% FeO and a molar Mg/(Mg + Fe) ratio of 0.68. The remaining 36% of the regolith is syn- and postbasin material: 28.8% ± 2.4% mafic impact-melt breccias (MIMBs, i.e., “LKFM” and “VHA basalts”) created at the time of basin formation, 6.0% ± 1.4% mare-derived material (impact and volcanic glass, crystalline basalt) with an average TiO₂ concentration of 2.4%, and 1% postbasin meteoritic material. The MIMBs are the principal (80–90%) carrier of incompatible trace elements (rare earths, Th, etc.) and the carrier of about one-half of the siderophile elements and elements associated with mafic mineral phases (Fe, Mg, Mn, Cr, Sc). Most (71%) of the Fe in the present regolith derives from syn- and postbasin sources (MIMBs, mare-derived material, and meteorites). Thus, although the bulk composition of the Apollo 16 regolith is nominally that of noritic anorthosite, the noritic part (the MIMBs) and the anorthositic part (the prebasin components) are largely unrelated. There is compositional evidence that 3–4% of the soil is Th-rich material such as that occurring at the Apollo 14 site, and one fragment of this type was found among the small regolith particles studied here. If regolith such as that represented by the Apollo 16 ancient regolith breccias was a protolith of the present regolith, such regolith cannot exceed ～71% of the present regolith; the rest must be material added or redistributed since closure of the ancient regolith breccias. The postclosure material includes the mare-derived material and the Apollo-14-like component. Compositions of all mature surface soils from Apollo 16, even those collected 4 km apart on the Cayley plains, are very similar, which is in stark contrast to the wide compositional range of the lithologies of which the soil is composed. This uniformity indicates that the ratio of MIMBs to feldspathic prebasin components is not highly variable in the megaregolith over distances of a few kilometers, that there are no large, subsurface concentrations of “pure” mafic impact-melt breccia, and that the intimate mixing is inherent to the Cayley plains at a gross scale. Thus, the mixing of mafic impact-melt breccias and feldspathic prebasin components must have occurred during formation and deposition of the Cayley plains; such uniformity could not have been achieved by small postdeposition impacts into a stratified megaregolith. Using this conclusion as one constraint, and the known distribution of Th on the lunar surface as another, and the assumption that the Imbrium impact is primarily responsible for formation of the Cayley plains, arguments are presented that the Apollo 16 MIMBs derive from the Imbrium region, and, consequently, that one-fourth of the Apollo 16 regolith is primary Imbrium ejecta in the form of mafic impact-melt breccias.     

Impact history of the Apollo 17 landing site revealed by U‐Pb SIMS ages

Secondary ion mass spectrometry (SIMS) U‐Pb ages of Ca‐phosphates from four texturally distinct breccia samples (72255, 76055, 76015, 76215) collected at the Apollo 17 landing site were obtained in an attempt to identify whether they represent a single or several impact event(s). The determined ages, combined with inferences from petrologic relationships, may indicate two or possibly three different impact events at 3920 ± 3 Ma, 3922 ± 5 Ma, and 3930 ± 5 Ma (all errors 2σ). Searching for possible sources of the breccias by calculating the continuous ejecta radii of impact basins and large craters as well as their expected ejecta thicknesses, we conclude that Nectaris, Crisium, Serenitatis, and Imbrium are likely candidates. If the previous interpretation that the micropoikilitic breccias collected at the North Massif represent Serenitatis ejecta is correct, then the average ²⁰⁷Pb/²⁰⁶Pb age of 3930 ± 5 Ma (2σ) dates the formation of the Serenitatis basin. The occurrence of zircon in the breccias sampled at the South Massif, which contain Ca‐phosphates yielding an age of 3922 ± 5 Ma (2σ), may indicate that the breccia originated from within the Procellarum KREEP terrane (PKT) and the Imbrium basin appears to be the only basin that could have sourced them. However, this interpretation implies that all basins suggested to fall stratigraphically between Serenitatis and Imbrium formed within a short (<11 Ma) time interval, highlighting serious contradictions between global stratigraphic constraints, sample interpretation, and chronological data. Alternatively, the slightly older age of the two micropoikilitic breccias may be a result of incomplete resetting of the U‐Pb system preserved in some phosphate grains. Based on the currently available data set this possibility cannot be excluded.     

Lithologic distribution and geologic history of the Apollo 17 site: The record in soils and small rock particles from the highland massifs

Abstract— Through analysis by instrumental neutron activation (INAA) of 789 individual lithic fragments from the 2 mm–4 mm grain-size fractions of five Apollo 17 soil samples (72443, 72503, 73243, 76283, and 76503) and petrographic examination of a subset, we have determined the diversity and proportions of rock types recorded within soils from the highland massifs. The distribution of rock types at the site, as recorded by lithic fragments in the soils, is an alternative to the distribution inferred from the limited number of large rock samples. The compositions and proportions of 2 mm–4 mm fragments provide a bridge between compositions of <1 mm fines, and types and proportions of rocks observed in large collected breccias and their clasts. The 2 mm–4 mm fraction of soil from South Massif, represented by an unbiased set of lithic fragments from station-2 samples 72443 and 72503, consists of 71% noritic impact-melt breccia, 7% incompatible-trace-element-(ITE)-poor highland rock types (mainly granulitic breccias), 19% agglutinates and regolith breccias, 1% high-Ti mare basalt, and 2% others (very-low-Ti (VLT) basalt, monzogabbro breccia, and metal). In contrast, the 2 mm–4 mm fraction of a soil from the North Massif, represented by an unbiased set of lithic fragments from station-6 sample 76503, has a greater proportion of ITE-poor highland rock types and mare-basalt fragments: it consists of 29% ITE-poor highland rock types (mainly granulitic breccias and troctolitic anorthosite), 25% impact-melt breccia, 13% high-Ti mare basalt, 31% agglutinates and regolith breccias, 1% orange glass and related breccia, and 1% others. Based on a comparison of mass-weighted mean compositions of the lithic fragments with compositions of soil fines from all Apollo 17 highland stations, differences between the station-2 and station-6 samples are representative of differences between available samples from the two massifs. From the distribution of different rock types and their compositions, we conclude the following: (1) North-Massif and South-Massif soil samples differ significantly in types and proportions of ITE-poor highland components and ITE-rich impact-melt-breccia components. These differences reflect crudely layered massifs and known local geology. The greater percentage of impact-melt breccia in the South-Massif light-mantle soil stems from derivation of the light mantle from the top of the massif, which apparently is richer in noritic impact-melt breccia than are lower parts of the massifs. (2) At station 2, the 2 mm–4 mm grain-size fraction is enriched in impact-melt breccias compared to the <1 mm fraction, suggesting that the <1 mm fraction within the light mantle has a greater proportion of lithologies such as granulitic breccias which are more prevalent lower in the massifs and which we infer to be older (pre-basin) highland components. (3) Soil from station 6, North Massif, contains magnesian troctolitic anorthosite, which is a component that is rare in station-2 South-Massif soils. (4) Compositional differences between poikilitic impact-melt breccias from the two massifs suggest broad-scale heterogeneity in impact-melt breccia interpreted by most investigators to be ejecta from the Serenitatis basin. We have found rock types not previously recognized or uncommon at the Apollo 17 site. These include (1) ITE-rich impact-melt breccias that are compositionally distinct from previously recognized “aphanitic” and “poikilitic” groups at Apollo 17; (2) regolith breccias that are free of mare components and poor in impact melt of the types associated with the main melt-breccia groups, and that, if those groups derive from the Serenitatis impact, may represent the pre-Serenitatis surface; (3) several VLT basalts, including an unusual very-high-K basaltic breccia; (4) orange-glass regolith breccias; (5) aphanitic-matrix melt breccias at station 6; (6) fragments of alkali-rich composition, including alkali anorthosite, and monzogabbro; (7) one fragment of 72275-type KREEP basalt from station 3; (8) seven lithic fragments of ferroan-anorthositic-suite rocks; and (9) a fragment of metal, possibly from an L chondrite. Some of these lithologies have been found only as lithic fragments in the soils and not among the large rock samples. In contrast, we have not found among the 2 mm–4 mm lithic fragments individual samples of certain lithologies that have been recognized as clasts in breccias (e.g., dunite and spinel troctolite). The diversity of lithologic information contained in the lithic fragments of these soils nearly equals that found among large rock samples, and most information bearing on petrographic relationships is maintained, even in such small samples. Given a small number of large samples for “petrologic ground truth,” small lithic fragments contained in soil “scoop” samples can provide the basis for interpreting the diversity of rock types and their proportions in remotely sensed geologic units. They should be considered essential targets for future automated sample-analysis and sample-return missions.     

High resolution U‐Pb ages of Ca‐phosphates in Apollo 14 breccias: Implications for the age of the Imbrium impact

Previous age estimates of the Imbrium impact range from 3770 to 3920 Ma, with the latter being the most commonly accepted age of this basin‐forming event. The occurrence of Ca‐phosphates in Apollo 14 breccias, interpreted to represent ejecta formed by this impact, provides a new opportunity to date the Imbrium event as well as refining the impact history of the Moon. We present new precise U‐Pb analyses of Ca‐phosphates from impact breccia sample 14311 that are concordant and give a reliable weighted average age of 3938 ± 4 Ma (2σ). Comparison with previously published U‐Pb data on phosphate from Apollo 14 samples indicate that all ages are statistically similar and suggest phosphates could have been formed by the same impact at 3934 Ma ± 3 Ma (2σ). However, this age is older than the 3770 to 3920 Ma range determined for other samples and also interpreted as formed during the Imbrium impact. This suggests that several impacts occurred during a 20–30 Ma period around 3900 Ma and formed breccias sampled by the Apollo missions.     

The granulitic impactite suite: Impact melts and metamorphic breccias of the early lunar crust

Abstract— An important and poorly understood group of rocks found in the ancient lunar highlands is called “feldspathic granulitic impactites.” Rocks of the granulite suite occur at most of the Apollo highlands sites as hand samples, rake samples, clasts in breccias, and soil fragments. Most lunar granulites contain 70–80% modal plagioclase, but they can range from anorthosite to troctolite and norite. Previous studies have led to different interpretations for the thermal history of these rocks, including formation as igneous plutons, long-duration metamorphism at high temperatures, and short-duration metamorphism at low temperatures. This paper reports on a study of 24 polished thin sections of lunar granulites from the Apollo 15, 16, and 17 missions. We identify three different textural types of granulitic breccias: poikilitic, granoblastic, and poikilitic-granoblastic breccias. These breccias have similar equilibration temperatures (1100 ± 50 °C), as well as common compositions. Crystal size distributions in two granoblastic breccias reveal that Ostwald ripening took place during metamorphism. Solid-state grain growth and diffusion calculations indicate relatively rapid cooling during metamorphism (0.5 to 50 °C/year), and thermal modeling shows that they cooled at relatively shallow depths (<200 m). In contrast, we conclude that the poikilitic rocks formed by impact melting, whereas the poikilitic-granoblastic rocks were metamorphosed and may have partially melted. These results indicate formation of lunar granulites in relatively small craters (30–90 km in diameter), physically associated with the impact-melt breccia pile, and possibly from fine-grained fragmental precursor lithologies.     

“New” lunar meteorites: Impact melt and regolith breccias and large‐scale heterogeneities of the upper lunar crust

Abstract— We have analyzed nine highland lunar meteorites (lunaites) using mainly INAA. Several of these rocks are difficult to classify. Dhofar 081 is basically a fragmental breccia, but much of its groundmass features a glassy‐fluidized texture that is indicative of localized shock melting. Also, much of the matrix glass is swirly‐brown, suggesting a possible regolith derivation. We interpret Dar al Gani (DaG) 400 as an extremely immature regolith breccia consisting mainly of impact‐melt breccia clasts; we interpret Dhofar 026 as an unusually complex anorthositic impact‐melt breccia with scattered ovoid globules that formed as clasts of mafic, subophitic impact melt. The presence of mafic crystalline globules in a lunar material, even one so clearly impact‐heated, suggests that it may have originated as a regolith. Our new data and a synthesis of literature data suggest a contrast in Al₂O₃‐incompatible element systematics between impact melts from the central nearside highlands, where Apollo sampling occurred, and those from the general highland surface of the Moon. Impact melts from the general highland surface tend to have systematically lower incompatible element concentration at any given Al₂O₃ concentration than those from Apollo 16. In the case of Dhofar 026, both the bulk rock and a comparatively Al‐poor composition (14 wt% Al₂O₃, 7 μg/g Sm) extrapolated for the globules, manifest incompatible element contents well below the Apollo 16 trend. Impact melts from Luna 20 (57°E) distribute more along the general highland trend than along the Apollo 16 trend. Siderophile elements also show a distinctive composition for Apollo 16 impact melts: Ni/Ir averaging ?1.8x chondritic. In contrast, lunaite impact‐melt breccias have consistently chondritic Ni/Ir. Impact melts from Luna 20 and other Apollo sites show average Ni/Ir almost as high as those from Apollo 16. The prevalence of this distinctive Ni/Ir ratio at such widely separated nearside sites suggests that debris from one extraordinarily large impact may dominate the megaregolith siderophile component of a nearside region 2300 km or more across. Highland polymict breccia lunaites and other KREEP‐poor highland regolith samples manifest a strong anticorrelation between Al₂O₃ and mg. The magnesian component probably represents the chemical signature of the Mg‐suite of pristine nonmare rocks in its most “pure” form, unaltered by the major KREEP‐assimilation that is so common among Apollo Mg‐suite samples. The average composition of the ferroan anorthositic component is now well constrained at Al₂O₃ ?29–30 wt% (implying about 17–19 wt% modal mafic silicates), in good agreement with the composition predicted for flotation crust over a “ferroan” magma ocean (Warren 1990).     

Compositional evidence regarding the influx of interplanetary materials onto the lunar surface

Siderophilic element/Ir ratios are higher in mature lunar soils from highlands sites than in those from mare sites. We infer that the population of materials responsible for the early intense bombardment of the Moon had high ratios, and that the population responsible for the essentially constant flux has low ratios. No group of chondrites has siderophile/Ir ratios identical to those in the mare or highlands soils; CM chondrites are the most similar, and CM-like materials may account for a major fraction of Earth-crossing materials during the past 3.7 b.y.Siderophile/Ir ratios may be used to determine the amount of highlands regolith in soils or breccias from the mare-highlands interface areas (Apollo 15 and 17), and to infer the time of formation of highlands breccias whose sideropbiles originated in mature soils. Arguments are summarized against the viewpoint that the siderophiles in most highlands breccias originated in basin-forming projectiles. Differences in mature soil siderophile concentrations at Apollo 14 and 16 indicate a substantially greater concentration at the latter site immediately following the Imbrium event.Siderophile concentrations are used to estimate mean regolith depths at the landing sites; as relative values these are more precise than estimates based on seismic or crater observations. The longlived flux is calculated to be 2.9 g cm^–2 b.y.^–1 averaged over the past 3.7 b.y. A consideration of the relationship between mass fluence and time indicates that the mass flux decreased with a half-life of about 40 m.y. immediately following the Imbrium event.     

Petrography,mineralogy, and geochemistry of lunar meteorite Sayh al Uhaymir 300

Abstract— We report here the petrography, mineralogy, and geochemistry of lunar meteorite Sayh al Uhaymir 300 (SaU 300). SaU 300 is dominated by a fine‐grained crystalline matrix surrounding mineral fragments (plagioclase, pyroxene, olivine, and ilmenite) and lithic clasts (mainly feldspathic to noritic). Mare basalt and KREEPy rocks are absent. Glass melt veins and impact melts are present, indicating that the rock has been subjected to a second impact event. FeNi metal and troilite grains were observed in the matrix. Major element concentrations of SaU 300 (Al₂O₃ 21.6 wt% and FeO 8.16 wt%) are very similar to those of two basalt‐bearing feldspathic regolith breccias: Calcalong Creek and Yamato (Y‐) 983885. However, the rare earth element (REE) abundances and pattern of SaU 300 resemble the patterns of feldspathic highlands meteorites (e.g., Queen Alexandra Range (QUE) 93069 and Dar al Gani (DaG) 400), and the average lunar highlands crust. It has a relatively LREE‐enriched (7 to 10 x CI) pattern with a positive Eu anomaly (?11 x CI). Values of Fe/Mn ratios of olivine, pyroxene, and the bulk sample are essentially consistent with a lunar origin. SaU 300 also contains high siderophile abundances with a chondritic Ni/Ir ratio. SaU 300 has experienced moderate terrestrial weathering as its bulk Sr concentration is elevated compared to other lunar meteorites and Apollo and Luna samples. Mineral chemistry and trace element abundances of SaU 300 fall within the ranges of lunar feldspathic meteorites and FAN rocks. SaU 300 is a feldspathic impact‐melt breccia predominantly composed of feldspathic highlands rocks with a small amount of mafic component. With a bulk Mg# of 0.67, it is the most mafic of the feldspathic meteorites and represents a lunar surface composition distinct from any other known lunar meteorites. On the basis of its low Th concentration (0.46 ppm) and its lack of KREEPy and mare basaltic components, the source region of SaU 300 could have been within a highland terrain, a great distance from the Imbrium impact basin, probably on the far side of the Moon.     

The spatial and temporal distribution of lunar mare basalts as deduced from analysis of data for lunar meteorites

In this work we analyze data for lunar meteorites with emphasis on the spatial and temporal distribution of lunar mare basalts. The data are mostly from the Lunar Meteorite Compendium (http://www-curator.jsc.nasa.gov/antmet/lmc/contents.cfm cited hereafter as Compendium) compiled by Kevin Righter, NASA Johnson Space Center, and from the associated literature. Analysis of the data showed that (i) a significant part of the lunar meteorite source craters are not larger than hundreds of meters in diameter; (ii) cryptomaria seem to be rather abundant in lunar highlands; (iii) the ratios of lunar meteorites belonging to three broad petrologic groups (mare basalt/gabbro, feldspatic highland breccias, and mingled breccias which are a mixture of mare and highland components) seem to be roughly proportional to the areal distribution of these rocks on the lunar surface; and (iv) the meteorite mare basalt ages show a range from ～2.5 to 4.3 Ga and fill the gaps in the Apollo/Luna basalt age distribution. The ages of mare basalt clasts from mingled breccias seem to be systematically higher than those of “normal” mare basalts, which supports the suggestion that mingled breccias originated mostly from cryptomaria.     

Origin and transportation history of lunar breccia 14311

In this paper, we compare the U‐Pb zircon age distribution pattern of sample 14311 from the Apollo 14 landing site with those from other breccias collected at the same landing site. Zircons in breccia 14311 show major age peaks at 4340 and 4240 Ma and small peaks at 4110, 4030, and 3960 Ma. The zircon age patterns of breccia 14311 and other Apollo 14 breccias are statistically different suggesting a separate provenance and transportation history for these breccias. This interpretation is supported by different U‐Pb Ca‐phosphate and exposure ages for breccia 14311 (Ca‐phosphate age: 3938 ± 4 Ma, exposure age: ~550–660 Ma) from the other Apollo 14 breccias (Ca‐phosphate age: 3927 ± 2 Ma, compatible with the Imbrium impact, exposure age: ~25–30 Ma). Based on these observations, we consider two hypotheses for the origin and transportation history of sample 14311. (1) Breccia 14311 was formed in the Procellarum KREEP terrane by a 3938 Ma‐old impact and deposited near the future site of the Imbrium basin. The breccia was integrated into the Fra Mauro Formation during the deposition of the Imbrium impact ejecta at 3927 Ma. The zircons were annealed by mare basalt flooding at 3400 Ma at Apollo 14 landing site. Eventually, at approximately 660 Ma, a small and local impact event excavated this sample and it has been at the surface of the Moon since this time. (2) Breccia 14311 was formed by a 3938 Ma‐old impact. The location of the sample is not known at that time but at 3400 Ma, it was located nearby or buried by hot basaltic flows. It was transported from where it was deposited to the Apollo 14 landing site by an impact at approximately 660 Ma, possibly related to the formation of the Copernicus crater and has remained at the surface of the Moon since this event. This latter hypothesis is the simplest scenario for the formation and transportation history of the 14311 breccia.     

Multiple lithic clasts in lunar breccia Northwest Africa 7948 and implication for the lithologic components of lunar crust

This study presents the petrography, mineralogy, and bulk composition of lunar regolith breccia meteorite Northwest Africa (NWA) 7948. We identify a range of lunar lithologies including basaltic clasts (very low-titanium and low-titanium basalts), feldspathic lithologies (ferroan anorthosite, magnesian-suite rock, and alkali suite), granulites, impact melt breccias (including crystalline impact melt breccias, clast-bearing impact melt breccias, and glassy melt breccias), as well as regolith components (volcanic glass and impact glass). A compositionally unusual metal-rich clast was also identified, which may represent an impact melt lithology sourced from a unique Mg-suite parent rock. NWA 7948 has a mingled bulk rock composition (Al₂O₃ = 21.6 wt% and FeO = 9.4 wt%) and relatively low concentrations of incompatible trace elements (e.g., Th = 1.07 ppm and Sm = 2.99 ppm) compared with Apollo regolith breccias. Comparing the bulk composition of the meteorite with remotely sensed geochemical data sets suggests that the sample was derived from a region of the lunar surface distal from the nearside Th-rich Procellarum KREEP Terrane. Our investigations suggest that it may have been ejected from a nearside highlands-mare boundary (e.g., around Mare Crisium or Orientale) or a cryptomare region (e.g., Schickard-Schiller or Mare smythii) or a farside highlands-mare boundary (e.g., Mare Australe, Apollo basin in the South Pole–Aitken basin). The distinctive mineralogical and geochemical features of NWA 7948 suggest that the meteorite may represent lunar material that has not been reported before, and indicate that the lunar highlands exhibit wide geological diversity.     

Morphology and structure of the taurus-littrow highlands (Apollo 17): evidence for their origin and evolution

The Taurus-Littrow region (Apollo 17 landing area) is located in the northeastern quadrant of the Moon in the mountainous area on the southeastern rim of the Serenitatis basin. The highlands in the Taurus-Littrow region can be divided into three broad terrain types. (1)Littrow massifs - massive, 10-20 km diam, steep-sloped (20°–30°), highland blocks often bordered by linear graben-like valleys. (2)Littrow sculptured hills - a series of closely spaced 1-5 km diam domical hills occupying broad highland plateaus which have been cratered and block faulted. Sculptured hill units stretch along the eastern edge of Serenitatis from the Apollo 17 area north to Posidonius. (3)Vitruvius front and plateau - a long irregular but generally north-trending scarp (occasionally rising over 2 km above the surrounding terrain) and its associated uplifted plateau to the east. This terrain is composed of hills ranging from 2-7 km diam, whose morphology is intermediate between the sculptured hills and the massifs. It is concluded that the highland units in the Taurus-Littrow region are primarily related to the origin of the Serenitatis basin because of their marked similarity to more well-preserved basin-related deposits in the younger Imbrium and Orientale basins: (1) the massifs and sculptured terra are morphologically similar to the Imbrium basin-related Montes Alpes and Alpes Formation, (2) the relative geographic position of the Taurus-Littrow highlands and Montes Alpes/Alpes Formation is the same, forming the second ring and spreading distally, and (3) the structures are similar in orientation and development (e.g., massifs are related to radial and concentric structure; Alpes Formation/sculptured terra are not). Interpretation of the massifs and sculptured hills as Serenitatis impact-related deposits lessens the possible role of highland volcanism in the origin and evolution of the Taurus-Littrow terrain, although extensive pre-Serenitatis volcanism cannot be ruled out. The preserved morphology of the sculptured hills suggests that the thickness of post-Serenitatis large basin ejecta (from Imbrium, for instance) is small, compared to the total highland section. This implies that the primary contributions to the highland stratigraphy are from Serenitatis and pre-Serenitatis events. The highland surface, however, may be dominated by ejecta from the latest nearby large event (formation of the Imbrium basin). Structural elements mapped in the Taurus-Littrow area include lineaments, the Vitruvius structural front, two types of grabens, and scarps. The majority of lineaments, as well as some grabens, appear to be related to a dominant NW trend and subordinate N and NE trends. These trends are interpreted to be related to a more regional lunar grid pattern which formed in the area prior to the origin of the Serenitatis basin, causing distinct structural inhomogeneities in the highland terrain. The Serenitatis event produced radial and concentric structures predominantly influenced by this pre-existing trend. Younger grabens are generally circumferential to the Serenitatis basin and appear to be related to readjustment of Serenitatis-produced structures; those that are oblique to Serenitatis follow the pre-Serenitatis structural grain. No obvious structural elements can be correlated with the post-Serenitatis, Nectaris and Crisium basins. It is believed that the origin and hence the geographic concentration of the Littrow massifs is related to the fact that Serenitatis radials in the massif area coincide with lines of pre-existing structural weakness along a general lunar grid direction (NW). Pre-existing structurally weak lunar grid trends seem to have been structurally reactivated by Serenitatis radials, causing preferential uplift of large blocks in this area. Elsewhere in the region radials would be oblique to this direction. Since Serenitatis and Imbrium radials coincide in the massif area, the post-Serenitatis Imbrium event may have reactivated Serenitatis radial fractures, possibly rejuvenating the massif terrain. The geologic and tectonic history of the Taurus-Littrow highlands began prior to the origin of Serenitatis in Tectonic Interval I. The strong NW trending structural elements are believed to have formed as part of a global stress pattern (possibly shear) sometime during this period of probable crustal formation and fragmentation. Tectonic Interval II was initiated by the origin of the Serenitatis basin. The basic topography and morphology of the region and most large grabens resulted from this event and their orientations show that they were controlled at least in part by the pre-existing grid. No other large basins forming during this interval appear to have had a major effect on the area. Tectonic Interval III is dominated by the formation of narrow grabens following structural patterns circumferential to the Serenitatis basin and tangential to it where they coincide with pre-existing grid directions. Serenitatis isostatic rebound or early mare fill may have produced this stress system. The scarp in the vicinity of the Apollo 17 landing site is the youngest obvious structural element.     

The comparative behavior of apatite‐zircon U‐Pb systems in Apollo 14 breccias: Implications for the thermal history of the Fra Mauro Formation

Abstract— We report secondary ion mass spectrometry (SIMS) U‐Pb analyses of zircon and apatite from four breccia samples from the Apollo 14 landing site. The zircon and apatite grains occur as cogenetic minerals in lithic clasts in two of the breccias and as unrelated mineral clasts in the matrices of the other two. SIMS U‐Pb analyses show that the ages of zircon grains range from 4023 ± 24 Ma to 4342 ± 5 Ma, whereas all apatite grains define an isochron corresponding to an age of 3926 ± 3 Ma. The disparity in the ages of cogenetic apatite and zircon demonstrates that the apatite U‐Pb systems have been completely reset at 3926 ± 3 Ma, whereas the U‐Pb system of zircon has not been noticeably disturbed at this time. The apatite U‐Pb age is slightly older than the ages determined by other methods on Apollo 14 materials highlighting need to reconcile decay constants used for the U‐Pb, Ar‐Ar and Rb‐Sr systems. We interpret the apatite age as a time of formation of the Fra Mauro Formation. If the interpretation of this Formation as an Imbrium ejecta is correct, apatite also determines the timing of Imbrium impact. The contrast in the Pb loss behavior of apatite and zircon places constraints on the temperature history of the Apollo 14 breccias and we estimate, from the experimentally determined Pb diffusion constants and an approximation of the original depth of the excavated samples in the Fra Mauro Formation, that the breccias experienced an initial temperature of about 1300–1100 °C, but cooled within the first five to ten years.     

On the origin of the lunar smooth-plains

Before the Apollo 16 mission, the material of the Cayley Formation (a lunar smooth plains) was theorized to be of volcanic origin. Because Apollo 16 did not verify such interpretations, various theories have been published that consider the material to be ejecta of distant multiringed basins. Results presented in this paper indicate that the material cannot be solely basin ejecta. If smoothplains are a result of formation of these basins or other distant large craters, then the plains materials are mainly ejecta of secondary craters of these basins or craters with only minor contributions of primary-crater or basin ejecta. This hypothesis is based on synthesis of knowledge of the mechanics of ejection of material from impact craters, photogeologic evidence, remote measurements of surface chemistry, and petrology of lunar samples. Observations, simulations, and calculations presented in this paper show that ejecta thrown beyond the continuous deposits of large lunar craters produce secondary-impact craters that excavate and deposit masses of local material equal to multiples of that of the primary crater ejecta deposited at the same place. Therefore, the main influence of a large cratering event on terrain at great distances from such a crater is one of deposition of more material by secondary craters, rather than deposition of ejecta from the large crater. Examples of numerous secondary craters observed in and around the Cayley Formation and other smooth plains are presented. Evidence is given for significant lateral transport of highland debris by ejection from secondary craters and by landslides triggered by secondary impact. Primary-crater ejecta can be a significant fraction of a deposit emplaced by an impact crater only if the primary crater is nearby. Other proposed mechanisms for emplacement of smooth-plains formations are discussed, and implications regarding the origin of material in the continuous aprons surrounding large lunar craters is considered. It is emphasized that the importance of secondary-impact cratering in the highlands has in general been underestimated and that this process must have been important in the evolution of the lunar surface.     

The bombardment history of the Moon as recorded by 40Ar‐39Ar chronology

New petrography and ⁴⁰Ar‐³⁹Ar ages have been obtained for 1–3 mm sized rock fragments from Apollo 16 Station 13 soil 63503 (North Ray crater ejecta) and chips from three rocks collected by Apollo 16 and Apollo 17 missions. Selection of these samples was aimed at the old ⁴⁰Ar‐³⁹Ar ages to understand the early history of the lunar magnetic field and impact flux. Fifteen samples were studied including crustal material, polymict feldspathic fragmental breccias, and impact melts. The impact ages obtained range between approximately 3.3 and 4.3 billion years (Ga). Polymict fragmental breccia 63503,1 exhibits the lowest signs of recrystallization observed and a probable old relic age of 4.547 ± 0.027. The plateau age of 4.293 ± 0.044 Ga obtained for impact melt rock 63503,13 represents the oldest known age for such a lithology. Possibly, this age represents the minimum age for the South Pole‐Aitken (SPA) Basin. In agreement with literature data, these results show that impact ages >3.9 Ga are found in lunar rocks, especially within soil 63503. Impact exhumation of deep‐seated warm crustal material onto the lunar surface is considered to explain the common 4.2 Ga ages obtained for weakly shocked samples from soil 63503 and Apollo 17. This would directly imply that one or more basin‐forming events occurred at that time. Some rock fragments showing none to limited petrologic features indicate thermal annealing. These rocks may have lost Ar while resident within the hot‐ejecta of a large basin. Concurrent with previous studies, these results lead us to advocate for a complex impact flux in the inner solar system during the initial approximately 1.3 Ga.     

Lunar meteorite Queen Alexandra Range 93069: A lunar highland regolith breccia with very low abundances of mafic components

Abstract— Lunar meteorite QUE 93069 found in Antarctica is a mature, anorthitic regolith breccia with highland affinities that was ejected from the Moon <0.3 Ma ago. The frequency distribution of mineral and lithic clasts gives information about the nature of the regolith and subregolith basement near the ejection site as well as about the abundances of rock types shocked to different degrees prior to the breccia formation. Thin section QUE 93069,37 consists of 67.5 vol% fine-grained (<～130 μm) constituents and 32.5 vol% mineral and lithic clasts and an impact melt vein. The most abundant types of these clasts are intragranularly recrystallized anorthosites and plagioclases (together 26.3 vol%) and feldspathic fine-grained to microporphyritic crystalline melt breccias (21.9 vol%). Mafic crystalline melt breccias are extremely rare (1.3 vol%). Granulitic lithologies are 10.4 vol%, recrystallized feldspathic melt breccias are 15.0 vol%, and glasses are 3.5 vol%. The impact melt vein cutting across the entire thin section was probably formed subsequent to the lithification process of the bulk rock at pressures below 20 GPa, because the bulk rock never experienced a higher peak shock pressure. Lunar meteorite QUE 93069 has a higher abundance of clear glass, occurring within melt spherules, glassy fragments, and an impact melt vein than lunar meteorites ALHA81005, Y-791197, Y-82192/3, Y-86032, or MAC 88104/5. The high abundance of melt spherules indicates that this lunar meteorite contains the highest content of typical regolith components. Mafic crystalline melt breccias are much rarer in QUE 93069 than in all other lunar highland regolith breccias. The extremely low abundance of mafic components may constrain possible areas of the Moon, from which the breccia was derived. The source area of QUE 93069 must be a highland terrain lacking significant mafic impact melts or mare components.     

Petrology,chemistry, and isotopic compositions of the lunar highland regolith breccia Dar al Gani 262

Abstract— Lunar meteorite Dar al Gani 262 (DG 262)—found in the Libyan part of the Sahara—is a mature, anorthositic regolith breccia with highland affinities. The origin from the Moon is undoubtedly indicated by its bulk chemical composition; radionuclide concentrations; noble gas, N, and O isotopic compositions; and petrographic features. Dar al Gani 262 is a typical anorthositic highland breccia similar in mineralogy and chemical composition to Queen Alexandra Range (QUE) 93069. About 52 vol% of the studied thin sections of Dar al Gani 262 consist of fine-grained(100 μm) constituents, and 48 vol% is mineral and lithic clasts and impact-melt veins. The most abundant clast types are feldspathic fine-grained to microporphyritic crystalline melt breccias (50.2 vol%; includes recrystallized melt breccias), whereas mafic crystalline melt breccias are extremely rare (1.4 vol%). Granulitic lithologies are 12.8 vol%, intragranularly recrystallized anorthosites and cataclastic anorthosites are 8.8 and 8.2 vol%, respectively, and (devitrified) glasses are 2.7 vol%. Impact-melt veins (5.5 vol% of the whole thin sections) cutting across the entire thin section were probably formed subsequent to the lithification process of the bulk rock at pressures below 20 GPa, because the bulk rock never experienced a higher peak shock pressure. Mafic crystalline melt breccias are very rare in Dar al Gani 262 and are similar in abundance to those in QUE 93069. The extremely low abundance of mafic components and the bulk composition may constrain possible areas of the Moon from which the breccia was derived. The source area of Dar al Gani 262 must be a highland terrain lacking significant mafic impact melts or mare components. On the basis of radionuclide activities, an irradiation position of DG 262 on the Moon at a depth of 55–85 g/cm³and a maximum transit time to Earth <0.15 Ma is suggested. Dar al Gani 262 contains high concentrations of solar-wind-implanted noble gases. The isotopic abundance ratio ⁴⁰Ar/³⁶Ar < 3 is characteristic of lunar soils. The terrestrial weathering of DG 262 is reflected by the occurrence of fractures filled with calcite and by high concentrations of Ca, Ba, Cs, Br, and As. There is also a large amount of terrestrial C and some N in the sample, which was released at low temperatures during stepped heating. High concentrations of Ni, Co, and Ir indicate a significant meteoritic component in the lunar surface regolith from which DG 262 was derived.     

AN EXAMPLE OF A THERMALLY METAMORPHOSED AGGLUTINATE

A single fragment from an Apollo 16 soil appears to be a soil agglutinate that has experienced thermal metamorphism. Its texture is similar to that observed in many of the samples of recrystallized polymict breccias collected in the lunar highlands. Debris blankets, consisting largely of mineral and lithic clasts and derived from highland bedrock by major impacts, are less likely than agglutinate-rich soil from the highland megaregolith to be the progenitor of this class of recrystallized rocks.     

Geochemistry and petrology of lunar meteorite Queen Alexandra Range 94281, a mixed mare and highland regolith breccia,with special emphasis on very-low-titanium mafic components

Abstract— Queen Alexandra Range (QUE) 94281, a lunar meteorite recently discovered in Antarctica, is a glassy-matrix, clast-rich regolith breccia containing a mixture of mafic, volcanic-glass and gabbroic constituents and a diverse set of highland constituents. In thin section, the clast assemblage is dominated by coarse mineral debris from a shallow intrusive or hypabyssal setting, or from deep within a thick mare flow. Abundant coarse-grained pyroxene clasts have fine-scale exsolution lamellae and compositions similar to pyroxenes of known lunar very-low-Ti (VLT) basalts and other lunar meteorites of basaltic composition. Pyroxene compositions follow Fe-enrichment extending to hedenbergite, which is associated with fayalite and cristobalite, indicating slow cooling. We refer to the protolith of the crystalline VLT component as VLT gabbro. Fragments of pyroclastic glasses that have high Fe and low Ti concentrations, similar to the pyroclastic green glasses known from Apollo samples, are common. Lithic clasts include abundant subrounded, glassy to cryptocrystalline, aluminous (～17–30 wt% Al₂O₃) KREEP-poor melt breccias of highland origin and a variety of other feldspathic impactites. On the basis of composition of our subsamples, QUE 94281 consists of ～54 wt% mafic or “mare” components and 46 wt% feldspathic or “highland” components. The bulk composition of QUE 94281 is similar to that of Yamato (Y) 793274, but QUE 94281 has slightly greater concentrations of some siderophile elements and slightly lower concentrations of those elements contributed mainly by mafic constituents. Differences in siderophile element concentrations are consistent with longer surface exposure of QUE 94281. Minor differences in trace element variations of subsamples of the two meteorites suggest subtle differences in the composition of their highland constituents. Nonetheless, the overall similarity of compositions supports the possibility that they were ejected from the same source region on the Moon. The crystalline VLT component of QUE 94281 differs from those known from Apollo 17 and Luna 24 VLT lithologies and from that of basaltic breccia Elephant Moraine (EET) 87521. The VLT-gabbro component and the ferroan VLT volcanic glasses in QUE 94281 have compositions that may be petrogenetically related by derivation from a common picritic parent composition, represented by an ultramafic glass found in QUE 94281.