首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 15 毫秒
1.
Abstract— A new grouplet of primitive, metal‐rich chondrites, here called the CB (C, carbonaceous; B, bencubbinite) chondrites, has been recognized. It includes Bencubbin, Weatherford, Hammadah al Hamra (HH) 237 and Queen Alexandra Range (QUE) 94411, paired with QUE 94627. Their mineral compositions, as well as their oxygen and nitrogen isotopic compositions, indicate that they are closely related to the CR and CH chondrites, all of which are members of the more inclusive CR clan. CB chondrites have much greater metal/silicate ratios than any other chondrite group, widely increasing the range of metal/silicate fractionation recorded in solar nebular processes. They also have the greatest moderately volatile lithophile element depletions of any chondritic materials. Metal has compositional trends and zoning patterns that suggest a primitive condensation origin, in contrast with metal from other chondrite groups. CB chondrites, as well as other CR clan chondrites, have much heavier nitrogen (higher 15N/14N) than that in other chondrite groups. The primitive characteristics of the CB chondrites suggest that they contain one of the best records of early nebular processes. Another chondrite, Grosvenor Mountains 95551, is petrographically similar to the CB chondrites, but its mineral and oxygen and nitrogen isotope compositions indicate that it formed from a different nebular reservoir.  相似文献   

2.
Abstract— Petrographic and bulk compositional data suggest the existence of a new grouplet of carbonaceous chondrites consisting of Coolidge and Loongana 001. Coolidge is a carbonaceous chondrite find from Kansas, USA, previously considered a metamorphosed CV chondrite. Loongana 001 is a recent find from Western Australia. It has a high matrix/chondrule modal abundance ratio, 1–2 vol% refractory inclusions and high refractory lithophile abundance ratios (~1.35x CI), indicating that it is a carbonaceous chondrite. Coolidge and Loongana 001 have many compositional and petrographic similarities. They have refractory element abundances in the range of CV chondrites, significantly higher than those in the CR chondrites. They have similar volatile element abundance patterns showing low volatile element abundances relative to both CR and CV chondrites. Coolidge and Loongana 001 have similar chondrule dimensions and shapes, oxidation states and opaque mineral assemblages. They are also similar in petrologic type (3.8–4) and shock stage (S2). Although both Coolidge and Loongana 001 may be related to the CV clan, they are not CV chondrites, nor are they formed by metamorphism of a CV precursor. They are distinctly different in composition from CV chondrites and their chondrules are smaller and have a much lower abundance of coarse-grained chondrule rims. Coolidge and Loongana 001 constitute a distinct carbonaceous chondrite grouplet.  相似文献   

3.
Abstract— NWA 2526 is a coarse‐grained, achondritic rock dominated by equigranular grains of polysynthetically twinned enstatite (?85 vol%) with frequent 120° triple junctions and ?10–15 vol% of kamacite + terrestrial weathering products. All other phases including troilite, daubreelite, schreibersite, and silica‐normative melt areas make up 相似文献   

4.
Abstract– The insoluble organic matter (IOM) of an unequilibrated enstatite chondrite Sahara (SAH) 97096 has been investigated using a battery of analytical techniques. As the enstatite chondrites are thought to have formed in a reduced environment at higher temperatures than carbonaceous chondrites, they constitute an interesting comparative material to test the heterogeneities of the IOM in the solar system and to constrain the processes that could affect IOM during solar system evolution. The SAH 97096 IOM is found in situ: as submicrometer grains in the network of fine‐grained matrix occurring mostly around chondrules and as inclusions in metallic nodules, where the carbonaceous matter appears to be more graphitized. IOM in these two settings has very similar δ15N and δ13C; this supports the idea that graphitized inclusions in metal could be formed by metal catalytic graphitization of matrix IOM. A detailed comparison between the IOM extracted from a fresh part and a terrestrially weathered part of SAH 97096 shows the similarity between both IOM samples in spite of the high degree of mineral alteration in the latter. The isolated IOM exhibits a heterogeneous polyaromatic macromolecular structure, sometimes highly graphitized, without any detectable free radicals and deuterium‐heterogeneity and having mean H‐ and N‐isotopic compositions in the range of values observed for carbonaceous chondrites. It contains some submicrometer‐sized areas highly enriched in 15N (δ15N up to 1600‰). These observations reinforce the idea that the IOM found in carbonaceous chondrites is a common component widespread in the solar system. Most of the features of SAH 97096 IOM could be explained by the thermal modification of this main component.  相似文献   

5.
We studied a thin section of Lewis Cliff (LEW) 87223, an unusual EL3-related, enstatite chondrite (EC) that has primary and secondary features not observed in other ECs. We studied its metal-rich nodules, possible shock features, and chondrules, eight of which are Al-rich chondrules (ARCs). LEW 87223 has petrologic and compositional features similar to EL3s. Enstatite is the dominant mineral; chondrule boundaries are well defined; Si content of metal (0.5–0.6 wt%) is consistent with typical EL3; it has Cr-bearing troilite, oldhamite, and alabandite; and its O-isotopic composition is similar to other ECs. However, metal abundance in LEW 87223 (~13 vol%) is slightly higher than in other EL3s and its metal nodules are texturally and mineralogically different from other ECs. Both high and low Ni metals are present, and its alabandite has higher Fe (27.8 wt% Fe) than in other EL3s. Silicates appear darkened in plane polarized light, largely due to reduction of Fe from silicate. A remarkable feature of LEW 87223 is the high abundance of ARCs, which contain Ca-rich plagioclase and varying amounts of Na-rich plagioclase along chondrule edges and as veins. This suggests Na metasomatism and the possibility of hydrothermal fluids, potentially related to an impact event. LEW 87223 expands the range of known EC material. It shows that ECs are more diverse and record a wider range of parent body processes than previously known. LEW 87223 is an anomalous EL3, potentially the first member of a new EC group should similar samples be discovered.  相似文献   

6.
7.
Abstract– Perryite [(Fe,Ni)x(Si,P)y], schreibersite [(Fe,Ni)3P], and kamacite (αFeNi) are constituent minerals of the metal‐sulfide nodules in the Sahara 97072 (EH3) enstatite chondrite meteorite. We have measured concentrations of Ni, Cu, Ga, Au, Ir, Ru, and Pd in these minerals with laser ablation, inductively coupled plasma mass spectrometry (ICP‐MS). We also measured their Fe, Ni, P, Si, and Co concentrations with electron microprobe. In kamacite, ratios of Ru/Ir, Pd/Ir, and Pd/Ru cluster around their respective CI values and all elements analyzed plot near the intersection of the equilibrium condensation trajectory versus Ni and the respective CI ratios. In schreibersite, the Pd/Ru ratio is near the CI value and perryite contains significant Cu, Ga, and Pd. We propose that schreibersite and perryite formed separately near the condensation temperatures of P and Si in a reduced gas and were incorporated into Fe‐Ni alloy. Upon further cooling, sulfidation of Fe in kamacite resulted in the formation of additional perryite at the sulfide interface. Still later, transient heating re‐melted this perryite near the Fe‐FeS eutectic temperature during partial melting of the metal‐sulfide nodules. The metal‐sulfide nodules are pre‐accretionary objects that retain CI ratios of most siderophile elements, although they have experienced transient heating events.  相似文献   

8.
Abstract— We report the mineralogy and oxygen isotopic compositions of FeO‐rich silicates in the Sahara 97159 EH3 chondrite. This component is referred to as FeO‐rich because it contains substantially more FeO than the characteristic FeO‐poor silicates in the highly reduced enstatite meteorites. These FeO‐rich silicates are mostly low‐Ca pyroxene (Fs5–35) and their compositions suggest an origin under more oxidizing conditions, like those for the ordinary chondrites. However, the mafic silicates in ordinary and carbonaceous chondrites are dominantly olivine, and the FeO‐rich silicates in the E chondrites are less commonly olivine. The oxygen isotopic compositions of the FeO‐rich silicates are indistinguishable from those of FeO‐poor silicates in Sahara 97159. These observations suggest that both the FeO‐rich silicates and the FeO‐poor silicates in EH chondrites formed from the same oxygen reservoir where redox conditions varied widely.  相似文献   

9.
Among the many ungrouped meteorites, Acfer 370, NWA 7135, and El Médano 301—probably along with the chondritic inclusion in Cumberland Falls and ALHA 78113—represent a homogeneous grouplet of strongly reduced forsterite‐rich chondrites characterized by common textural, chemical, mineralogical, and isotopic features. All of these meteorites are much more reduced than OCs, with a low iron content in olivine and low‐Ca pyroxene. In particular, Acfer 370 is a type 4 chondrite that has olivine and low‐Ca pyroxene compositional ranges of Fa 5.2–5.8 and Fs 9.4–33.4, respectively. The dominant phase is low‐Ca pyroxene (36.3 vol%), followed by Fe‐Ni metal (16.3 vol%) and olivine (15.5 vol%); nevertheless, considering the Fe‐oxyhydroxide (due to terrestrial weathering), the original metal content was around 29.6 vol%. Finally, the mean oxygen isotopic composition Δ17O = +0.68‰ along with the occurrence of a silica phase, troilite, Ni‐rich phosphides, chromite, and oldhamite confirms that these ungrouped meteorites have been affected by strong reduction and are different from any other group recognized so far.  相似文献   

10.
Ar‐Ar isochron ages of EL chondrites suggest closure of the K‐Ar system at 4.49 ± 0.01 Ga for EL5 and 6 chondrites, and 4.45 ± 0.01 Ga for EL3 MAC 88136. The high‐temperature release regimes contain a mixture of radiogenic 40Ar* and trapped primordial argon (solar or Q‐type) with 40Ar/36ArTR ~ 0 , which does not affect the 40Ar budget. The low‐temperature extractions show evidence of an excess 40Ar component. The 40Ar/36Ar is 180–270; it is defined by intercept values of isochron regression. Excess 40Ar is only detectable in petrologic types >4/5. These lost most of their primordial 36Ar from low‐temperature phases during metamorphism and retrapped excess 40Ar. The origin of this excess 40Ar component is probably related to metamorphic Ar mobilization, homogenization of primordial and in situ radiogenic Ar, and trapping of Ar by distinct low‐temperature phases. Ar‐Ar ages of EH chondrites are more variable and show clear evidence of a major impact‐induced partial resetting at about 2.2 Ga ago or alternatively, prolonged metamorphic decomposition of major K carrier phases. EH impact melt LAP 02225 displayed the highest Ar‐Ar isochron age of 4.53 ± 0.01 Ga. This age sets a limit of about 25–45 Ma for the age bias between the K‐Ar and U‐Pb decay systems.  相似文献   

11.
Abstract— The enstatite chondrite reckling peak (rkp) a80259 contains feldspathic glass, kamacite, troilite, and unusual sets of parallel fine‐grained enstatite prisms that formed by rapid cooling of shock melts. Metallic Fe,Ni and troilite occur as spherical inclusions in feldspathic glass, reflecting the immiscible Fe‐Ni‐S and feldspathic melts generated during the impact. The Fe‐Ni‐S and feldspathic liquids were injected into fractures in coarse‐grained enstatite and cooled rapidly, resulting in thin (≤ 10 μm) semicontinuous to discontinuous veins and inclusion trails in host enstatite. Whole‐rock melt veins characteristic of heavily shocked ordinary chondrites are conspicuously absent. Raman spectroscopy shows that the feldspathic material is a glass. Elevated MgO and SiO2 contents of the glass indicate that some enstatite and silica were incorporated in the feldspathic melt. Metallic Fe,Ni globules are enclosed by sulfide and exhibit Nienrichment along their margins characteristic of rapid crystallization from a Fe‐Ni‐S liquid. Metal enclosed by sulfide is higher in Si and P than metal in feldspathic glass and enstatite, possibly indicating lower O fugacities in metal/sulfide than in silicate domains. Fine‐grained, elongate enstatite prisms in troilite or feldspathic glass crystallized from local pyroxene melts that formed along precursor grain boundaries, but most of the enstatite in the target rock remained solid during the impact and occurs as deformed, coarsegrained crystals with lower CaO, Al2O3, and FeO than the fine‐grained enstatite. Reckling Peak A80259 represents an intermediate stage of shock melting between unmelted E chondrites and whole‐rock shock melts and melt breccias documented by previous workers. The shock petrogenesis of RKPA80259 reflects the extensive impact processing of the enstatite chondrite parent bodies relative to those of other chondrite types.  相似文献   

12.
Al Haggounia 001 and paired specimens (including Northwest Africa [NWA] 2828 and 7401) are part of a vesicular, incompletely melted, EL chondrite impact melt rock with a mass of ~3 metric tons. The meteorite exhibits numerous shock effects including (1) development of undulose to weak mosaic extinction in low‐Ca pyroxene; (2) dispersion of metal‐sulfide blebs within silicates causing “darkening”; (3) incomplete impact melting wherein some relict chondrules survived; (4) vaporization of troilite, resulting in S2 bubbles that infused the melt; (5) formation of immiscible silicate and metal‐sulfide melts; (6) shock‐induced transportation of the metal‐sulfide melt to distances >10 cm; (7) partial resorption of relict chondrules and coarse silicate grains by the surrounding silicate melt; (8) crystallization of enstatite in the matrix and as overgrowths on relict silicate grains and relict chondrules; (9) crystallization of plagioclase from the melt; and (10) quenching of the vesicular silicate melt. The vesicular samples lost almost all of their metal during the shock event and were less susceptible to terrestrial weathering; in contrast, the samples in which the metal melt accumulated became severely weathered. Literature data indicate the meteorite fell ~23,000 yr ago; numerous secondary phases formed during weathering. Both impact melting and weathering altered the meteorite's bulk chemical composition: e.g., impact melting and loss of a metal‐sulfide melt from NWA 2828 is responsible for bulk depletions in common siderophile elements and in Mn (from alabandite); weathering of oldhamite caused depletions in many rare earth elements; the growth of secondary phases caused enrichments in alkalis, Ga, As, Se, and Au.  相似文献   

13.
Using the in-plane rotation of polished thin section, the X-ray diffraction patterns exhibiting a high degree of randomness similar to powder pattern were obtained for 10 CO3 chondrites, which distinguished 130 reflections of olivine in the chondrules from that in the matrix, and showed systematic differences among subtypes based on the full width at half maximum intensity of two olivine 130 peaks. A lower petrologic subtype is characterized by sharp and strong peaks for forsteritic olivines in type I chondrules and by a weak and broad peak for ferroan matrices, and the higher petrologic subtypes are characterized by sharp and strong peaks for recrystallized matrices and a weakened or absent peak of magnesian olivines. The systematic change in the split peak of olivine 130 was linked with the mean diffusion length of Mg-Fe in olivine phenocrysts in type I chondrules. Fe-Ni diffusion in metals was considered to estimate the peak temperature of CO3.0, near the surface on the parent body. The peak metamorphic temperatures were estimated to be ~600–910 K using the onion-shell model when the cooling time was 106–108 yr on the parent body. A weak peak for ferroan olivine of CO3.0 suggests the amorphous silicate in matrices. The modal abundance of the amorphous Fe-silicate for subtype 3.0 (15% for Allan Hills [ALH] 77307 and 9% for Yamato [Y]-81020) was also evaluated from the deviation in trend of the relative peak ratios of the Fe-rich (≥Fa25) and Mg-rich (<Fa25) olivines for subtypes. The existence of martensites was suggested for ALH 77307. Amorphous silicate in matrices is a more resistant primordial component that produced the CO3 chondrites than martensite.  相似文献   

14.
Abstract— Metal nodules are one of the major textural components of Kaidun sample #01.3.06 EH3-4. In terms of structure, the nodules are of three types: (1) globular, (2) zoned with a massive core and globular mantle, and (3) nodules with no internal structure. The size and composition of the globules in the nodules and grains of metal of the matrix are almost identical: no greater than 20 μm and Ni, 5.95; Si, 3.33 wt%. The nodules contain small (usually <5 μm) inclusions of SiO2; albitic glass; enstatite; roedderite; and a mixture of SiO2 and Na2S2. This is the first reported occurrence of a simple sulfide of an alkaline metal in nature. The formation of the inclusions appears to be related to condensation of material onto the surfaces of metal grains. The nodules appear to have formed by aggregation of separate grains (globules) of metal, with conservation of condensates on the grain surfaces as inclusions. The inclusions probably condensed over a significant temperature range from 1400 to 600 K. The aggregation of metal grains and formation of the nodules probably occurred simultaneously with condensation.  相似文献   

15.
In this work, we investigate macroscopic characteristics, magnetic susceptibility, mineralogy, and mineral composition of Al Haggounia 001. The samples were collected during eight field missions in the period between 2015 and 2019. In the strewn field of about 65 km in length, the specimens are found either on the surface or shallowly buried in loose sediments, which rules out the previous suggestions that this meteorite is a fossil meteorite. Macroscopically, the samples exhibit three major lithologies with various colors, porosities, and distributions of oxidized veins. The data obtained using transmitted and reflected light microscopy, scanning electron microscopy, and electron microprobe analysis confirm the macroscopic observations and show a heterogenous distribution of silicates and metal sulfides. Al Haggounia 001 is composed of enstatite, plagioclase, kamacite, taenite, schreibersite, daubreelite, troilite, graphite, sinoite, and silica polymorphs. We identified a new type of chondrules that are flattened and composed of rods of albite and enstatite, as well as elongated nodules of metal and sulfides, in addition to compression fractures in the form of subparallel veinlets. These features presumably reflect the deformation caused by shock. The magnetic susceptibility of Al Haggounia 001 (4.39 ± 0.20) is much lower than that of usual EH (5.48 ± 0.16) and EL (5.46 ± 0.04) chondrites but is in the range of E finds (5.05 ± 0.43). The thermomagnetic and hysteresis measurements are controlled by type, size, distribution of metal-sulfide nodules, arrangement of oxyhydroxide veins, and weathering. Al Haggounia 001 is an anomalous meteorite with a polymict nature. It records multiple events revealing its unique origin which expends the groups of enstatite chondrites and provides insights into the complex formation and evolution history of their parent body.  相似文献   

16.
We present petrologic and isotopic data on Northwest Africa (NWA) 4799, NWA 7809, NWA 7214, and NWA 11071 meteorites, which were previously classified as aubrites. These four meteorites contain between 31 and 56 vol% of equigranular, nearly endmember enstatite, Fe,Ni metal, plagioclase, terrestrial alteration products, and sulfides, such as troilite, niningerite, daubréelite, oldhamite, and caswellsilverite. The equigranular texture of the enstatite and the presence of the metal surrounding enstatite indicate that these rocks were not formed through igneous processes like the aubrites, but rather by impact processes. In addition, the presence of pre‐terrestrially weathered metal (7.1–14 vol%), undifferentiated modal abundances compared to enstatite chondrites, presence of graphite, absence of diopside and forsterite, low Ti in troilite, and high Si in Fe,Ni metals suggest that these rocks formed through impact melting on chondritic and not aubritic parent bodies. Formation of these meteorites on a parent body with similar properties to the EHa enstatite chondrite parent body is suggested by their mineralogy. These parent bodies have undergone impact events from at least 4.5 Ga (NWA 11071) until at least 4.2 Ga (NWA 4799) according to 39Ar‐40Ar ages, indicating that this region of the solar system was heavily bombarded early in its history. By comparing NWA enstatite chondrite impact melts to Mercury, we infer that they represent imperfect petrological analogs to this planet given their high metal abundances, but they could represent important geochemical analogs for the behavior and geochemical affinities of elements on Mercury. Furthermore, the enstatite chondrite impact melts represent an important petrological analog for understanding high‐temperature processes and impact processes on Mercury, due to their similar mineralogies, Fe‐metal‐rich and FeO‐poor silicate abundances, and low oxygen fugacity.  相似文献   

17.
The origin of Mercury's anomalous core and low FeO surface mineralogy are outstanding questions in planetary science. Mercury's composition may result from cosmochemical controls on the precursor solids that accreted to form Mercury. High temperatures and enrichment in solid condensates are likely conditions near the midplane of the inner solar protoplanetary disk. Silicate liquids similar to the liquids quenched in ferromagnesian chondrules are thermodynamically stable in oxygen-rich systems that are highly enriched in dust of CI-chondrite composition. In contrast, the solids surviving into the orbit of Mercury's accretion zone were probably similar to highly unequilibrated, anhydrous, interstellar organic- and presolar grain-bearing chondritic, porous interplanetary dust particles (C-IDPs). Chemical systems enriched in an assumed C-IDP composition dust produce condensates (solid+liquid assemblages in equilibrium with vapor) with super-chondritic atomic Fe/Si ratios at high temperatures, approaching 50% of that estimated for bulk Mercury. Sulfur behaves as a refractory element, but at lower temperatures, in these chemical systems. Stable minerals are FeO-poor, and include CaS and MgS, species found in enstatite chondrites. Disk gradients in volatile compositions of planetary and asteroidal precursors can explain Mercury's anomalous composition, as well as enstatite chondrite and aubrite parent body compositions. This model predicts high sulfur content, and very low FeO content of Mercury's surface rocks.  相似文献   

18.
Shock‐induced features are abundantly observed in meteorites. Especially, shock veins, including high‐pressure minerals, characterize many kinds of heavily shocked meteorite. On the other hand, no high‐pressure phases have been yet reported from enstatite chondrites. We studied a heavily shocked EH3 chondrite, Asuka 10164, containing a vein, which comprises fragments of fine‐grained silicate and opaque minerals, and chondrules. In this vein, we found a silica polymorph, coesite. This is the first discovery of a high‐pressure phase in enstatite chondrites. Other high‐pressure polymorphs were not observed in the vein. The assemblages and chemical compositions of minerals, and the occurrence of coesite indicate that the vein was subjected to the high‐pressure and temperature condition at about 3–10 GPa and 1000 °C. The host also experienced heating for a short time under lower temperature conditions, from ~700 to ~1000 °C, based on the opaque minerals typical of EH chondrites and textural features. Although the pressure condition of the vein in this chondrite is much lower than those in the other meteorites, our results suggest that all major meteorite groups contain high‐pressure polymorphs. Heavy shock events commonly took place in the solar system.  相似文献   

19.
Abstract— Here we present the results of a geochemical study of the projectile component in impactmelt rocks from the Lappajärvi impact structure, Finland. Main‐ and trace‐element analyses, including platinum group elements (PGEs), were carried out on twenty impact‐melt rock samples from different locations and on two shocked granite fragments. The results clearly illustrate that all the impact melt rocks are contaminated with an extraterrestrial component. An identification of the projectile type was performed by determining the projectile elemental ratios and comparing the corresponding element ratios in chondrites. The projectile elemental ratios suggest an H chondrite as the most likely projectile type for the Lappajärvi impact structure. The PGE composition of the highly diluted projectile component (?0.05 and 0.7 wt% in the impact‐melt rocks) is similar to the recent meteorite population of H chondrites reaching Earth. The relative abundance of ordinary chondrites, including H, L, and LL chondrites, as projectiles at terrestrial impact structures is most likely related to the position of their parent bodies relative to the main resonance positions. This relative abundance of ordinary chondrites suggests a strong bias of the impactor population toward inner Main Belt objects.  相似文献   

20.
Abstract— The Machinga, southern Malawi, Africa, L6 chondrite (observed fall, 22 January 1981) contains accessory phases of metal, troilite, chromite, and native Cu (which is associated with limonite and found in zones of aqueous alteration). Rare accessory phases are apatite and pentlandite, which are uncommon in L6 chondrites. Major mineral constituents (olivine, orthopyroxene, and plagioclase) indicate shock effects at a level of about 15–20 GPa shock pressure. The meteorite is thus classified to be of L6d type. Melt pockets of widely variable composition are abundant.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号