扬子地台西南缘传统型铂族矿产地质特征

传统型铂族矿产，系指与镁铁质岩浆成矿作用有关的铂族矿产资源。华力西运动时期，扬子地台西南缘沿超壳深断裂带发生的大陆裂谷作用，为来自上地幔的镁铁质(拉斑玄武岩质)岩浆的上涌和侵位提供了极为有利的前提条件。含铂基性超基性岩的时空分布，受到大陆裂谷作用的主要发生发展时期和裂谷活动带的控制。通过对典型矿床特征及其成矿作用的探讨，论述了扬子地台西南缘主要的铂族矿床类型；并从四维成矿的角度，阐述了对区域成矿规律的一些基本认识。     

Pre-Tertiary Orogenies in the Himalaya: A review of various evidences

Various sedimentary sequences of the Himalaya reflecting different tectonic cycles when compared with the ages of (i) unconformity, (ii) pre-Tertiary metamorphism, (iii) granites and (iv) pre-Tertiary deformations point to following pre-Tertiary Orogenies: (i) Sundernagar (Middle Precambrian), (ii) Shali (Vendian), (iii) Jasim-Kurgiakh (Ordovician), (iv) Blaini-Thidsi (Upper Paleozoic) and (v) Tal-Chikkim (Middle-Upper Cretaceous). Besides these, minor impulses identifiable are: (i) Bandel-2 (Middle Riphean), (ii) Tangze (Devonian), (iii) Infra Krol (Upper Permian), (iv) Tandi (? Callovian) and (v) Krol (Upper Jurassic - Lower Cretaceous). Due to paucity of deformation structures related to these earth movements, it is suggested that these were either (i) mainly epeirogenic, (ii) feebly orogenic or (iii) they produced folds which were coaxial with subsequent Himalayan folds hence indistinguishable from the latter.     

对于氟碳钡铈矿（Cordylite—Ce）成分与结构的质疑

本文讨论了氟碳钡铈矿的成分和结构问题。发现氟碳钡铈矿的成分、密度、折射率三者间的一致性参数很差,晶体结构与光性和空间群相矛盾,单个大阳离子的平均占有体积远大于同类矿物的平均占有体积,它的晶体结构与同类矿物不可类比。由于受当时条件的限制,在以往有关氟碳钡铈矿的成分和结构的资料中存在着一些明显的错误,有必要对其进行重新定义。其结构化学式应改为:(Na_(1-x),Ca_(0·5x))BaCe_2(CO_3)_4F。     

岩溶水锶元素水文地球化学特征

通过对桂林地区地下河系统不同类型岩溶水水样Sr2+ 含量和87 Sr /86 Sr 值分析,得到如下结论: ( 1)桂林地区岩溶水中Sr2+ 含量普遍较低,流经不同岩层的地下水Sr2+ 含量不同,岩溶水中Sr2+ 含量随着Ca2+ 含量的增大而增大,随着Mg2+含量的增大而减小;地下河水中的Sr2+ 含量始终介于表层岩溶带水、饱水带裂隙水、地表坡面流和外源水(如果存在外源水补给)的最大、最小值之间。( 2)流经不同岩层地下水的87 Sr /86 Sr值不同,流经砂岩层地下水87 Sr /86 Sr 值较高,其次为流经白云岩层和灰岩层的地下水;地下河水87 Sr /86 Sr 值也是介于表层岩溶带水、饱水带裂隙水、地表坡面流和外源水(如果有外源水补给)的最大、最小值之间。因此Sr2+和87 Sr /86 Sr能反映岩溶水形成的信息,是较理想的天然示踪剂,在岩溶水研究中具有很广阔的应用前景。      

北苏鲁仰口地区变辉长岩中锆石U-Pb定年、微量元素和Hf同位素特征及其地质意义

北苏鲁仰口地区出露超高压的变辉长岩.锆石阴极发光图像和其内部矿物包体激光拉曼测试的联合研究结果表明,变辉长岩锆石具有弱发光效应的岩浆韵律环带的核和被改造的强发光效应的边.岩浆韵律环带的核部保存大量而复杂的矿物包体,包括普通辉石(Cpx)+斜方辉石(Opx)+斜长石(P1)+石英(Qtz)+黑云母(Bt)+钛铁矿(Ilm)+磷灰石(Ap);边部保存的矿物包体则相对较少,包括普通辉石(Cpx)+斜方辉石(Opx)+斜长石(Pl)+磷灰石(Ap).尽管岩浆韵律环带核部的稀土元素总合量比被改造的锆石边部明显偏高,但二者稀土元素配分模式具有明显的相似性,主要表现为轻稀土相对亏损,而重稀土明显富集,相应的(La/Yb)N=0.00015～0.00039,并具有明显的负Eu异常(Eu/Eu*=0.20～0.26)、相对明显的正Ce异常(Ce/Ce*=71.5～147.4)和较高的Th/U比值(1.97～2.69).上述特征表明,仰口地区变辉长岩中的锆石均为继承性的岩浆锆石,而没有新生的变质锆石.LA-(MC)-ICP-MS锆石原位U-Pb定年和Lu-Hf同位素分析结果表明,两件锆石样品Y1和Y2的年龄数据所构成的不一致线显示了十分接近的上交点和下交点年龄.其上交点年龄分别为785±15Ma(2σ)和784±12Ma(2σ),应代表原岩的形成时代,表明变辉长岩的原岩与Rodinia超大陆裂解的岩浆事件存在密切的成因关系;而下交点年龄分别为226±24Ma(2σ)和228±26Ma(2σ),与苏鲁其它类型超高压岩石中含柯石英锆石微区记录的变质年龄十分吻合,应代表变辉长岩的超高压变质时代.岩浆结晶锆石的核部具有明显偏高的176Lu/177Hf(0.00044～0.00291)和176Yh/177Hf(0.0165～0.1168)比值,而176Hf/177Hf比值变化于0.281956～0.282048之间,相应的εHf(t)=-8.5～-14.0,tDM2=2.03～2.32Ga,表明仰口地区变辉长岩的原岩起源于古元古代时期的富集地幔或发生部分熔融的下地壳残留体.被改造的岩浆结晶锆石的边部则具有明显偏低的176Lu/177Hf(0.00029～0.00060)和176Yh/177Hf(0.0112～0.0200)比值,而176Hf/177Hf(t)比值变化于0.281953～0.282002之间,相应的εHf(t)=-10.2～-11.9,tDM2=2.12～2.21Ga.与岩浆结晶锆石核部相比,被改造的岩浆锆石边部的176Lu/177Hf、176Yb/177Hf、176Hf/177Hf(t)比值和εHf(t)和tDM2值的变化范围更小,表明中-新三叠纪的超高压变质作用使岩浆结晶锆石边部的Lu-Hf同位素体系发生调整,更趋向于均一化.     

秦巴北部商县—卢氏地区变质方解石—白云石地质压力计的研究

秦巴北部的商县-卢氏县地区广泛分布有区域变质的方解石-白云石共生矿物对,它们对于估计变质作用和断裂构造作用的温压条件,有着重要的意义。本文着重就该地区Fe~(2+)在方解石-白云石中的X_(Fe)~(Co)>X_(Fe)~(Dol)分配情况,提出新的计压方法。     

西秦岭南带志留纪笔石生物地层

西秦岭南带志留系已发现１４个笔石层位,划分为１０ 个笔石带,４ 个笔石层,它们分别是：下志留统８ 个笔石带,２ 个笔石层;中志留统２ 个笔石带;上志留统２ 个笔石层。     

Sorption behavior of nine chromium (III) organic complexes in soil

Sorption data were obtained with a Matawan soil and the following chromium (III) organic complexes: chromium (III) ascorbate, chromium (III) glutamate, chromium (III) histidine, chromium (III) mandelate, chromium (III) citrate, chromium (III) cysteine, chromium (III) serine, chromium (III) pyruvate and chromium (III) oxalate. The influence of pH (2–12), ionic strength (0.005–1 M) and concentration of sorbate (1–10 mg/L) on the extent of sorption was evaluated. The pH value did not influence the percent sorption at environmentally relevant pH 7. Ionic strength between 0.005 and 0.01 M KNO₃ did not influence the sorption. Sorption and desorption data obtained at pH 7, 0.01 M KNO₃ and 1–10 mg/L for each chromium (III) organic complex were analyzed using Freundlich and Langmuir models. The Freundlich model provided good fits for all of the chromium (III) organic complexes. Sorption data for chromium (III) glutamate, chromium (III) pyruvate, chromium (III) oxalate, chromium (III) cysteine, chromium (III) ascorbate and chromium (III) citrate were described well by the Langmuir model. Estimates for the saturated sorption capacities were 141, 70.9, 36.5, 35.5, 28.6 and 4.4 μg/g, respectively. It was not possible to desorb significant amounts of the previously sorbed chromium (III) organic complexes. At the same pH, ionic strength and solid:liquid ratio, the order of the observed sorption to the Matawan soil from highest to lowest was chromium (III) mandelate, chromium (III) glutamate, chromium (III) histidine, chromium (III) cysteine, chromium (III) serine, chromium (III) pyruvate, chromium (III) oxalate, chromium (III) ascorbate and chromium (III) citrate.     

中国金矿床工业类型

作为勘查和开发直接对象的含金地质体是金矿床工业价值的决定性要素,是金矿床地质特征的本质规定,也是人们最易识别和掌握的直观标志,以此作为金矿床工业类型的分类基础,划分出10类金矿床:（1）石英脉型;（2）糜棱岩型;（3）蚀变碎裂岩型;（4）冰长石-绢云母石英脉型;（5）角砾岩型;（6）矽卡岩型;（7）微细浸染型;（8）红土型;（9）铁帽型;（10）砂砾层型     

MORPHOLOGY, INTERNAL STRUCTURE, AND ORIGIN OF GLAUCONITE PELLETS

Glauconite pellets exhibit considerable variety in morphology and internal structure. Recognized morphological types are: (1) ovoidal or spheroidal; (2) tabular or discoidal; (3) mammillated; (4) ellipsoidal; (5) vermicular; (6) composite; and (7) fossil casts, internal molds, or replacements. Types of internal structures include: (1) random microcrystalline, (2) oriented microcrystalline, (3) micaceous, (4) organic (?) replacements, (5) coatings on detrital grains, and (6) fibroradiated rims. These characteristics can be used to interpret the origin and/or subsequent history of pellet types. Suggested origins include: (1) chemical precipitation, (2) expansion and alteration of detrital mica, (3) alteration of fecal pellets, (4) alteration of clay fillings of fossil tests, (5) mechanical aggregation, and (6) chemical replacement. Not all glauconite pellets exhibit diagnostic characteristics with regard to their genesis. Original morphologies may be obscured by abrasion (reworking) prior to final burial. Internal structures may be changed by recrystallization or other diagenetic processes. It is concluded that glauconite pellets have multiple origins. They can form from several different parent materials and by several different processes. Frequently, however, characteristics which might reveal the original nature of the pellets have been lost during reworking and diagenesis. Inasmuch as glauconite occurrences differ in kind and variety of pellets, recognition of pellet types and their distribution is potentially useful for stratigraphic correlation or environmental determinations.     

西藏冲江铜矿含矿岩体与非含矿岩体区分探讨

冲江铜矿位于世界三大斑岩成矿域的特提斯-喜马拉雅成矿域,其大地构造位置属冈底斯-念青唐古拉构造带的冈底斯陆缘火山-岩浆弧中部。矿区含矿岩体与非含矿岩体的岩性相同,很难通过肉眼或常规分析方法把它们区分开来。热释光测试结果表明,矿区岩石的热释光曲线有单峰和双峰两种,矿化主要发生在具单峰的似斑状二长花岗岩中。岩石矿化程度越强,热释光总积分强度值越小。另外,高岭土化对岩石天然热释光有叠加作用,具高岭土化的岩石明显具有更高的热释光值,且高岭土化与矿化成负相关。因此,热释光值可作为判断矿化的一个岩石标型。石英粒度统计也表明,含矿岩体的石英粒度曲线呈韵律式变化,而不含矿的岩石粒度曲线呈渐进式变化。故岩石中的石英粒度也可作为矿化的一个矿物标型。     

西藏狮泉河蛇绿混杂岩带——一个新的多岛弧盆系统的厘定及意义

狮泉河蛇绿混杂岩带的结构、性质、形成时间及与班-怒带的时空演化关系是青藏高原大地构造划分中亟待解决的问题。通过系统的地质调查工作，证实狮泉河带内存在完整的蛇绿岩带，并首次将其划分为4个蛇绿岩亚带，相互之间由3个呈平行分布的岛弧链分隔，从而构成一个早白垩世的多岛弧盆系统。狮泉河带闭合过程为岛弧造山过程，俯冲极向主要向北，构成冈底斯-腾冲陆块和喀喇昆仑-南羌塘-左贡陆块之间的晚燕山期结合带；它与班-怒带在时间上具有继承性，空间上由北向南迁移，并部分重叠，反映了由班-怒带向狮泉河带的转化是一种接力式的。上述发现对青藏高原大地构造单元划分、新特提斯洋构造演化的研究具有重要意义。     

Types and distribution of silver ore deposits in China

Silver is generally recovered as a by- and co-product along with Au, Pb, Zn, Cu, Sb, Bi, Hg, Sn and W from polymetallic and gold mines in China. Chinese silver deposits can be classified into five principal types according to host rocks. These types and their host rocks are: (1) marine volcanic-sedimentary rocks hosting (la) massive sulfide Pb-Zn-(Cu)-Ag ores and (1b) stratiform Ag-(Au) ores; (2) continental volcanic-sedimentary rocks containing (2a) various polymetallic-silver veins and/or stockworks, and (2b) Ag-(Au) veins in pyroclastic rocks; (3) rocks affected by metasomatic processes including (3a) complex Sn-polymetallic-Ag ores, (3b) Pb-Zn-(Cu)-Ag skarns, (3c) associated W-Ag quartz veins and/or skarns, and (3d) Ag-(Au) zones and veins in altered carbonate rocks; (4) metamorphic-intrusive rocks, principally Ag-(Au) veins in sheared and brecciated metamorphic rocks; and (5) sedimentary rocks including (5a) stratiform Pb-Zn-Ag ores in carbonate rocks, (5b) Ag-V mantos in black shales, and (5c) Cu-(Ag) layers in red sandstones. A sixth grouping includes gossans. The tectonic settings, geological features, and temporal and spatial distribution of these different types of silver occurrences indicate that silver mineralization reflects to a great extent the evolution of tectonic environments in China throughout geological time. Type 1 is generally developed in association with several fold belts from the Caledonian to Yanshanian orogens, while types 2, 3 and 4 correlate with rejuvenation of the eastern China continent during the Mesozoic period. The three subgroups of type 5 are recognized in different stages and various sedimentry and diagenetic environments during the development of paraplatforms and fold belts. Type 6 results from recent weathering of existing sulfide ores or protores. Editorial handling: DR     

Molecular-level modes of As binding to Fe(III) (oxyhydr)oxides precipitated by the anaerobic nitrate-reducing Fe(II)-oxidizing Acidovorax sp. strain BoFeN1

Sorption of contaminants such as arsenic (As) to natural Fe(III) (oxyhydr)oxides is very common and has been demonstrated to occur during abiotic and biotic Fe(II) oxidation. The molecular mechanism of adsorption- and co-precipitation of As has been studied extensively for synthetic Fe(III) (oxyhydr)oxide minerals but is less documented for biogenic ones. In the present study, we used Fe and As K-edge X-ray Absorption Near Edge Structure (XANES), extended X-ray Absorption Fine Structure (EXAFS) spectroscopy, Mössbauer spectroscopy, XRD, and TEM in order to investigate the interactions of As(V) and As(III) with biogenic Fe(III) (oxyhydr)oxide minerals formed by the nitrate-reducing Fe(II)-oxidizing bacterium Acidovorax sp. strain BoFeN1. The present results show the As immobilization potential of strain BoFeN1 as well as the influence of As(III) and As(V) on biogenic Fe(III) (oxyhydr)oxide formation. In the absence of As, and at low As loading (As:Fe ≤ 0.008 mol/mol), goethite (Gt) formed exclusively. In contrast, at higher As/Fe ratios (As:Fe = 0.020-0.067), a ferrihydrite (Fh) phase also formed, and its relative amount systematically increased with increasing As:Fe ratio, this effect being stronger for As(V) than for As(III). Therefore, we conclude that the presence of As influences the type of biogenic Fe(III) (oxyhydr)oxide minerals formed during microbial Fe(II) oxidation. Arsenic-K-edge EXAFS analysis of biogenic As-Fe-mineral co-precipitates indicates that both As(V) and As(III) form inner-sphere surface complexes at the surface of the biogenic Fe(III) (oxyhydr)oxides. Differences observed between As-surface complexes in BoFeN1-produced Fe(III) (oxyhydr)oxide samples and in abiotic model compounds suggest that associated organic exopolymers in our biogenic samples may compete with As oxoanions for sorption on Fe(III) (oxyhydr)oxides surfaces. In addition HRTEM-EDXS analysis suggests that As(V) preferentially binds to poorly crystalline phases, such as ferrihydrite, while As(III) did not show any preferential association regarding Fh or Gt.     

东喜马拉雅构造结岩体冷却的~(40)Ar/~(39)Ar年代学研究

对采自东喜马拉雅构造结核心地段雅鲁藏布大峡谷地区的13件标本中的20件矿物样品进行了系统的常规^40Ar／^39Ar年代学研究。数据显示,样品的（^40Ar／^39Ar）i值均接近尼尔值（295．5±5）,且绝大部分样品的坪年龄与其反等时线年龄在误差范围内一致。从数据统计结果来看,所测样品的^40Ar／^39Ar年龄大都集中在1．3Ma和2．5Ma左右,表明南迦巴瓦地区在上新世中期和更新世早期均经历了快速冷却抬升事件。本次测试的样品采自不同的高程及不同的构造单元,且样品原岩的成因及岩性各异,但沿着大峡谷由北向南不同地段的样品的不同矿物（角闪石、黑云母、白云母、钾长石）的^40Ar／^39Ar年龄相近,而同一样品中不同矿物的^40Ar／^39Ar年龄大小又并非完全按照矿物对氩同位素体系的封闭温度高低来分布,表明该地区在上新世以来的岩体冷却速率很大,以致该地区的矿物对氩同位素体系的封闭过程与处于缓慢冷却环境中的封闭过程明显不同。以本文报道的数据估算,南迦巴瓦地区的岩体在最近3Ma以来的冷却速率达120～240℃／Ma,岩体抬升速率达3．4—6．9mm／a。     

An iron isotope signature related to electron transfer between aqueous ferrous iron and goethite

We measured the Fe isotope fractionation during the reactions of Fe(II) with goethite in the presence and absence of a strong Fe(III) chelator (desferrioxamine mesylate, DFAM). All experiments were completed in an O₂-free glove box. The concentrations of aqueous Fe(II) ([Fe(II)_aq]) decreased below the initial total dissolved Fe concentrations ([Fe(II)_total], 2.15 mM) due to fast adsorption within 0.2 day. The concentration of adsorbed Fe(II) ([Fe(II)_ads]) was determined as the difference between [Fe(II)_aq] and the concentration of extracted Fe(II) in 0.5 M HCl ([Fe(II)_extr]) (i.e., [Fe(II)_ads] = [Fe(II)_extr] − [Fe(II)_aq]). [Fe(II)_ads] also decreased with time in experiments with and without DFAM, documenting that fast adsorption was accompanied by a second, slower reaction. Interestingly, [Fe(II)_extr] was always smaller than [Fe(II)_total], indicating that some Fe(II) was sequestered into a pool that is not HCl-extractable. The difference was attributed to Fe(II) incorporated into goethite structure (i.e., [Fe(II)_inc] = [Fe(II)_total] −[Fe(II)_extr]). More Fe(II) was incorporated in the presence of DFAM than in its absence at all time steps. Regardless of the presence of DFAM, both aqueous and extracted Fe(II) (δ^56/54Fe(II)_aq and δ^56/54Fe(II)_extr) became isotopically lighter than or similar to goethite (− 0.27‰) at day 7, implying that the isotope exchange occurred between bulk goethite and aqueous Fe. Consistently, the mass balance indicated that the incorporated Fe is isotopically heavier than extracted Fe. These observations suggested that (i) co-adsorption of Fe(II) with DFAM resulted in more pervasive electron transfer, (ii) the electron transfer from heavy Fe(II) in the adsorbed Fe(II) to light Fe(III) in goethite results in the fixation of heavy adsorbed Fe(III) on the surface and accumulation of Fe(II) within the goethite, and (iii) desorption of the reduced, light Fe from goethite does not necessarily occur at the same surface sites where adsorption occurred.     

Abiotic reduction of uranium by Fe(II) in soil

Structural Fe(II) has been shown to reduce several oxidized environmental contaminants, including NO₃, chlorinated solvents, Cr(VI), and U(VI). Studies investigating reduction of U(VI) by soils and sediments, however, suggest that abiotic reduction of U(VI) by Fe(II) is not significant, and that direct enzymatic reduction of U(VI) by metal-reducing bacteria is required for U(VI) immobilization as U(IV). Here evidence is presented for abiotic reduction and immobilization of U(VI) by structural Fe(II) in a redoximorphic soil collected from a hillside spring in Iowa. Oxidation of Fe(II) in the soil after reaction with U(VI) was demonstrated by Mössbauer spectroscopy and reduction of U(VI) by the pasteurized soil using U L_III-edge X-ray absorption spectroscopy (XAS). XAS indicates that both reduced U(IV) and oxidized U(VI) or U(V) are present after U(VI) interaction with the Fe(II) containing soil. The EXAFS data show the presence of a non-uraninite U(IV) phase and evidence of the oxidized U(V) or U(VI) fraction being present as a non-uranyl species. Little U(VI) reduction is observed by soil that has been exposed to air and oxidation of Fe(II) to goethite has occurred. Soil characterization based on chemical extractions, Mössbauer spectroscopy, and Fe K-edge XAS indicate that the majority of Fe(II) in the soil is structural in nature, existing in clay minerals and possibly a green rust-like phase. These data provide compelling evidence for abiotic reduction of U(VI) by structural Fe(II) from soil near Fe-rich oxic–anoxic boundaries in natural environments. The work highlights the potential for abiotic reduction of U(VI) by Fe(II) in reduced, Fe-rich environments.     

硅酸盐体系的化学平衡:(2)反应热力学

通过具体的应用实例,系统介绍了在矿物材料学研究中硅酸盐体系的多相平衡反应热力学的基本原理。对硅酸盐体系的典型多相平衡反应进行了热力学计算,包括:(1)微晶玻璃制备过程中的硅酸盐熔融反应;(2)霞石正长岩和高铝粉煤灰利用技术中的硅酸盐烧结反应;(3)S iO2-CaO-H2O体系和KA lS i3O8-CaO-H2O体系雪硅钙石、硬硅钙石的水热晶化反应;(4)高铝粉煤灰和霞石正长岩烧结产物的溶解反应;(5)Na[A l(OH)4]-A l(OH)3-H2O体系和Na2SO4-Ca(OH)2-H2O体系中α-A l(OH)3和CaSO4.2H2O的析晶反应。研究成果可望对矿物材料制备实验方案设计、工业生产过程优化及改进产品性能提供理论指导,同时为同类材料学研究提供借鉴。     

班公湖-怒江结合带西段多岛弧盆系时空结构初步分析

笔者依据班公湖地区1：25万喀纳幅、日土县幅、羌多幅地质填图和专题研究工作取得的阶段性成果,将班公湖带的多岛弧盆系时空结构厘定为3条蛇绿混杂岩亚带。该3条亚带为盆地所隔,从北而南依次为班公湖带北亚带、班摩掌侏罗纪弧间盆地、班公湖带中亚带、日土-巴尔穷侏罗纪—早白垩世复合弧后盆地和班公湖带南亚带等。初步认为班公湖-怒江特提斯洋经历了晚三叠—早侏罗世往北俯冲、中晚侏罗世早期向北、往南双向俯冲、早白垩世往南俯冲等3次俯冲消亡阶段;同时,讨论了在班公湖带研究中存在的问题及其在反演班公湖-怒江结合带西段构造演化和在找矿方面的意义,以及进一步研究方向。     

“海州式”磷矿床中磷灰石的矿物学研究

“海州式”磷矿床中的磷灰石主要由变质改造再活化、混合岩化交代重结晶而成，有微碳氟磷灰石、氟磷灰石两种，晶胞参数σ０＝９．３６５３－９．３８１９ｎｍ，Ｃ０＝６．８７９７－６．８９３６ｎｍ，晶体化学式为（Ｃａ５．００Ｆ３０．０２Ｓｒ０．０１ＴＲ０．０１）５．０４〔（Ｐ２．９９Ｃ０．０４）３．０３Ｏ１２〕Ｆ０．８０，（Ｃａ４．９４Ｆｅ０．０２Ｍｇ０．０２Ｓｒ０．０１ＴＲ０．０１）５．００〔（Ｐ２．９０〕