Complete and partial self-reversal of natural remanent magnetization of basaltic rocks from Lower Silesia,Poland

Summary Experiments of heating-cooling cycles in zero magnetic field were performed in order to study self-reversal of NRM in basaltic rocks from Lower Silesia. Complete self-reversal occurred in one sample containing titanomagnetite withT _c of 170°C and a small amount of a phase with higher Curie point. During consecutive heat treatments the phenomenon became less conspicuous. In three samples of higher oxidation level, containing several magnetic phases, only partial self-reversal of NRM occurred. For the most oxidized sample no changes of direction of NRM were observed. We suggest that the investigated phenomenon of self-reversal of NRM is due to a negative magnetic interaction between primary titanomagnetite and products of its oxidation. It seems that complete self-reversal can take place in a restricted state of oxidation.     

Origin of magnetic minerals and natural remanent magnetization of basaltic rocks from Lower Silesia,Poland

Summary Two groups of basaltic rocks with normal and reversed NRM were examined. It was found that in both groups the primary NRM, synchronous with the period of rock formation, is preserved. Relations of the primary NRM to the origin and the degree of oxidation of magnetic minerals were considered in detail.     

Geochemistry of some volcanic rocks from south-eastern sicily: Rare earth and other trace element distribution

Some trace element data for volcanic rocks found at different levels, from Tertiary to Holocene, in south-eastern Sicily (Iblean Plateau and Mt. Etna) are presented and discussed in the present paper in order to better the information about the origin and relationships of the various rock types. Four groups of volcanic rocks have been recognized on the basis of their major element chemistry: 1) low-K tholeiites, 2) associated alkali basalts to nephelinites of the Iblean Plateau (Upper Pliocene to Lower Pleistocene), 3) the basal subalkaline lavas of Mt. Etna, and 4) the alkalic suite rocks that make up the bulk of the volcano. The distribution of Rb, Sr, Ni, Cr, Co, Cu, REE, Th and Sc suggests:

1. an origin of the Iblean magmas by a different degree of partial melting of a Rb-poor and possibly slightly hetereogeneous mantle;
2. quite distinct source compositions for the Etnean magmas, relative to those of the Iblean area, on the basis of their Rb and Sr contents;
3. an origin of the alkalic rocks of Mt. Etna from independently generated magma(s) rather than by crystal fractionation of the Etnean subalkaline magmas or of a magma having the geochemical features of the Iblean alkali basalts; evidence for this is given by the distribution features of the incompatible elements showing an origin for these rocks from compositionally different parent magmas and/or an evolution under widely variable environmental conditions;
4. the primary character for the chemical differences observed in some of the Etnean subalkaline rocks that can be accounted for by different physico-chemical conditions at their source rather than by crystal fractionation processes.

     

Tectonic setting of basic volcanic rocks determined using trace element analyses

Analyses for Ti, Zr, Y, Nb and Sr in over 200 basaltic rocks from different tectonic settings have been used to construct diagrams in which these settings can usually be identified. Basalts erupted within plates (ocean island and continental basalts) can be identified using a Ti-Zr-Y diagram, ocean-floor basalts, and low-potassium tholeiites and calc-alkali basalts from island arcs can be identified using a Ti-Zr diagram (for altered samples) and a Ti-Zr-Sr diagram (for fresh samples). Y/Nb is suggested as a parameter for indicating whether a basalt is of tholeiitic or alkalic nature. Analyses of dykes and pillow lavas from the Troodos Massif of Cyprus are plotted on these diagrams and appear to the tholeiitic ocean-floor rocks.     

Volatile and trace elements in basaltic glasses from Samoa: Implications for water distribution in the mantle

We report volatile (H₂O, CO₂, F, S, Cl) and trace element data for submarine alkalic basalt glasses from the three youngest Samoan volcanoes, Ta'u, Malumalu and Vailulu'u. Most samples are visibly sulfide saturated, so have likely lost some S during fractionation. Cl / K ratios (0.04–0.15) extend to higher values than pristine MORBs, but are suspected to be partly due to source differences since Cl / K roughly varies as a function of ⁸⁷Sr / ⁸⁶Sr. There are no resolvable differences in the relative enrichment of F among sources, and compatibility of F during mantle melting is established to be nearly identical to Nd. Shallow degassing has affected CO₂ in all samples, and H₂O only in the most shallowly erupted samples from Vailulu'u. Absolute water contents are high for Samoa (0.63–1.50 wt.%), but relative enrichment of water compared to equally incompatible trace elements (Ce, La) is low and falls entirely below normal MORB values. H₂O / Ce (58–157) and H₂O / La (120–350) correlate inversely with ⁸⁷Sr / ⁸⁶Sr compositions (0.7045–0.7089). This leads us to believe that, because of very fast diffusion of hydrogen in mantle minerals, recycled lithospheric material with high initial water and trace element content will lose water to the drier ambient mantle during storage within the inner Earth. The net result is the counter-intuitive appearance of greater dehydration with greater mantle enrichment. We expect that subducted slabs will experience a two-stage dehydration history, first within subduction zones and then in the ambient mantle during long-term convective mixing.     

Variation trends in basaltic rocks of the canary islands

More than two hundred new analyses of basaltic rocks from the Canary Islands are presented. The available data show that the earlier successions have similar variation trends throughout the archipelago; these trends represent all the intermediate types between basic differentiates (oceanites, ankaramites) and more salic differentiates (trachy-basalts, hawaiites). In the more recent volcanic series, the study shows that there is a magmatic diversification with different variation trends in the Eastern than in the Central Canary Islands. In the latter the alkaline character becomes stronger in the successive periods of volcanic activity which have been established in each island. In the Eastern islands the basaltic evolution is, on the contrary, towards basaltic rocks with tholeiitic affinities.     

Numeric generalization of trends in rocks of basaltic composition

Relationship for the transformation of percentage values, plotted in a conventional regular tetrahedron, to 3-dimensional cartesian co-ordinates is derived to facilitate the calculation of statistical measures. Regression relationship is worked out using the recomputed values for six basalt compositions (data taken fromVemban, 1947) to numerically generalise the trend of crystallization.     

Chemical characteristics of some basaltic rocks of India

An analysis of the chemical characteristics of about 200 basaltic rocks of India indicate that the rocks of Pavagarh, Girnar, Rajmahal, Mundwara, Cuddapah and Panjal Trap form independent magmatic series of mixed type having entirely different chemical characteristics relative to the Deccan basalt. The tholeiitic and olivine or alkaline basalts do not seem to form independent magma types. The present study indicates that the rocks belonging to the above magma types coexist together and may represent differentiates of a single magma series.     

Major element frequency distribution of the Japanese Quaternary volcanic rocks

Published chemical analyses of the Japanese Quaternary volcanic rocks are being collected to build a comprehensive data file. About 1600 selected major element analyses which include all 13 components of the bulk chemistry of the lavas and pyroclastics are considered here. Care was taken to correct misprints in the published analyses through correspondence with the original authors or analysts. Analyses are weighted against the volume of the volcano on which rock the analyses are made. Total volume of the volcanic material thus treated in this paper amounts to 3900 km³ or about 80% of the total Quaternary volcanic materials. The volume-weighted histograms for the most components show a unimodal profile when the large-scale caldera-forming pyroclastic flow and fall deposits are disregarded. SiO₂ histogram shows a broad primary mode around 57 %. For many components, the large-scale pyroclastic deposits form a secondary mode at the positions corresponding to a felsic composition. This strongly suggests that the mode of generation and ascent of such calderaforming felsic magma is different from that of the ordinary cone- and dome-building basalt-andesite-dacite series of magmas. Number-of-analyses histograms for the same set of combinations reveals that number frequencies show quite similar profiles as those for the volume-weighted histograms for the Japanese Quaternary volcanics. The profiles of the histograms for the Northeast Japan arc is very much similar as those of the whole Japanese islands while those for Izu-Mariana and Southwest Japan arcs are different. The differences are due to the different proportions of the rocks belonging to tholeiitic, calc-alkalic and alkali rock series in each arc. The whole Japan histograms may be considered as a good representative of the chemical characteristics of the average Japanese Quaternary (less than the last half million years) volcanic rocks.     

Petrology and geochemistry of basaltic rocks of the Lau Basin

The Lau Basin is a marginal sea, located between the Tonga and Lau Ridges, in the southwestern Pacific. The basin is on the “inner” or concave side of the Tonga Trench-Arc system and is situated above the deep seismic zone dipping westward from the Tonga Trench. The Tonga Trench-Arc system is undoubtedly located above a zone of crustal shortening as evidenced by the deep seismicity and vulcanism. However, the geological and geophysical data give strong support to the contention that the Lau Basin has formed by crustal dilation.Rocks dredged from ridges and seamounts in the basin are sub-alkaline basalt. The average major element composition of least altered samples is: SiO₂ 48.8%, TiO₂ 1.2%, K₂O 0.18%, P₂O₅ 0.08%, H₂O+ 0.30%, Fe^III/Fe^II = 0.26,CaO/Al₂O₃ = 0.77. The data for Lau Basin basalt (LBB) show close similarity to data of typical oceanic ridge basalt (ORB). Trace element abundances (ppm): Ni 160, Cr 390, Sr 100, Ba < 31, Rb < 1 also resemble ORB values. K/Rb in a least altered and unfractionated sample is 860, Ba/Sr is 0.1, Ba/Rb is 8. Strontium isotope data show the only marked variance from ORB chemistry with LBB values ranging from ⁸⁷Sr/⁸⁶Sr=0.7020 to 0.7051. The low Sr abundances in the samples suggest the possibility of crustal Sr contamination to explain the radiogenic Sr enrichment. An alternate possibility is that the mantle source rocks were enriched in ⁸⁷Sr. Variation within dredge hauls and between dredge sites may be explained by low-pressure fractional crystallization of magmas separated from the mantle at about 50 km depth.The basin probably began to open in middle to late Miocene time either by the disruption of a single andesitic island arc by splitting along its axis or by dilation of the area between two closely spaced concentric arcs. Mantle counterflow in the asthenosphere above the downgoing oceanic lithosphere slab is the probable driving force for dilation and has provided a continuous supply of parent material for the basalt of the basin floor.     

Rare earth element and other trace element distribution,and the origin of the iblean magmas

In the Iblean region, southeast Sicily, a sequence of subaqueous and subaerial volcanics is interlayered in sedimentary levels, Upper Miocene to Lower Pleistocene in age. These rocks range from low-K tholeiites to basanites.Rare earth elements (REE) have been determined by instrumental neutron activation analysis in five samples, and other trace elements (Li, Rb, Sr, Co, Cr, Cu, Ni) by atomic absorption spectrophotometry in thirteen samples, already analyzed also for major elements.The tholeiites differ systematically from rocks of the alkalic suite for elements like Li, Sr and light REE (Sr < 200 ppm, Ce ? 15 ppm in the former; Sr > 500 up to 2000 ppm, Ce > 150 ppm in the latter), while Ni, Co, Cr and heavy REE ranges overlap in the two rock suites.The results agree in indicating different degrees of partial melting, probably at different levels in a heterogeneous mantle, as responsible for the origin of most of the rocks found in the Iblean region: the tholeiites should have been formed at relatively shallow depth by fusion of large proportions of a depleted mantle, while increasingly undersaturated volcanics of the alkalic suite have been probably generated at greater depth by partial melting of decreasing amounts of mantle material.     

Geochemistry of the Mesozoic basaltic rocks in southern Hunan Province

Southern Hunan Province is famous for its intensive rare, radioactive and other metal elements’ mineralizations. There is a relation between the basaltic rocks and mineralizations in space, time and ore-forming elements. The Jurassic-Cretaceous (204–81 Ma) basaltic rocks consists mainly of alkali-basalt and tholeiitic basalt formed in plate environment. Trace elements and Sr, Nd, Pb isotopic compositions show that the regional mantle source was metasomatized shortly before the partial melting. The alkali basalt and tholeiitic basalt might be 3%–5% and 10%–15% of the partial melting of the enriched mantle source respectively. Obviously the enrichment of the regional mantle played an important role in formation of the large and super-large deposits in southern Hunan Province.     

Minor and trace element distribution in melilite and pyroxene from the Allende meteorite

Melilite and pyroxene were separated from a coarsely crystalline chondrule in the Allende meteorite and analysed by microprobe and spark source mass spectrometer techniques. Elemental abundances in the bulk chondrule are consistent with a mixture of equal amounts of the two minerals, as observed microscopically. The lanthanide distributions are markedly different in the two minerals; relative to chondrite abundances, melilite shows progressive depletion of the lanthanides La-Sm, a positive Eu anomaly, and relatively constant abundances of the heavier lanthanides (Gd-Yb, and Y), whereas pyroxene shows progressive enrichment towards the heavier lanthanides, on which is superimposed a negative Eu anomaly. Both minerals, and the bulk chondrule, show unusual concentrations of the platinum metals, but the crystallographic site or sites of these metals remains to be determined.     

Electric conductivity of young basaltic rocks of Central and South-East Slovakia

Summary The electric conductivity of basaltic rocks of the final volcanic phase of the Alpine-Carpathian orogenesis was studied in the temperature interval of 200–1000°C. The results obtained are compared with the chemical and modal composition of the rocks and with the content of trace elements (Cr, Co, Ni, V). The statistical treatment of a set of 11 rocks types indicated that the electric conductivity is mostly affected by the modal composition of the rock in the temperature interval of 200–600°C, whereas the effect of trace elements can be seen distinctly in the interval of 600–1000°C.     

Bubble size distribution in magma chambers and dynamics of basaltic eruptions

In the shallow magma chambers of volcanoes, the CO₂ content of most basaltic melts is above the solubility limit. This implies that the chamber contains gas bubbles, which rise through the magma and expand. Thus, the volume of the chamber, its gas volume fraction and the gas flux into the conduit change with time in a systematic manner as a function of the size and number of gas bubbles. Changes in gas flux and gas volume are calculated for a bubble size distribution and related to changes in eruption regimes. Fire fountain activity, only present during the first quarter of the eruption, requires that the bubbles are larger than a certain size, which depends on the gas flux and on the bubble content[1]. As the chamber degasses, it loses its largest gas bubbles and the gas flux decreases, eventually suppressing the fire fountaining activity. Ultimately, an eruption stops when the chamber contains only a few tiny bubbles. More generally, the evolution of basaltic eruptions is governed by a dimensionless number, τ * ≈ τgΔρa_O²/(18μh_c), where τ = a characteristic time for degassing; a₀ = the initial bubble diameter; μ = the magma viscosity; and h_c = the thickness of the degassing layer. Two eruptions of the Kilauea volcano, Mauna Ulu (1969–1971) and Puu O'o (1983—present), provide data on erupted gas volume and the inflation rate of the edifice, which help constrain the spatial distribution of bubbles in the magma chamber: bubbles come mainly from the bottom of the reservoir, either by in situ nucleation long before the eruption or within a vesiculated liquid. Although the gas flux at the roof of the chamber takes similar values for both eruptions, the duration of both the fire fountaining activity and the entire eruption was 6 times shorter at Mauna Ulu than during the Puu O'o eruption. The dimensionless analysis explains the difference by a degassing layer 6 times thinner in the former than the latter, due to a 2 year delay in starting the Mauna Ulu eruption compared to the Puu O'o eruption.     

Geochemical characteristics of Cretaceous basaltic rocks in South China and constraints on Pacific plate subduction

The South China, including Yangzi Craton and the Cathaysian Block, belongs to the southern part of East Asia continent. It borders Pacific plate on the east side and Qinling-Dabie Orogen on the north side. During the middle-late Cretaceous, a number of downfaulted red basins (the terrestrial sedimentary basins in Fig. 1) and volcanic- sedimentary basins had been developed in South China[1,2], in which the con-temporaneous basaltic rocks were generally distributed (Fig. 1). Although the …     

Radioactive heat production in rocks and its relation to other petrophysical parameters

Summary Radioactive heat productionA is a scalar and isotropic petrophysical property independent of in situ temperature and pressure. Its value is usually expressed in HGU units (1 HGU=10^–13 cal/cm³ sec) and depends on the amounts of uranium, thorium and potassium.A varies with rock type over several orders of magnitude and reflects the geochemical conditions during rock formation (magmatic differentiation, sedimentation or metamorphism).In order to assign realistic thermal parameters to deeper-seated rocks correlations with seismic velocity (which can be determined from the surface) have been looked for. In the range characteristic for crystalline rocks of the crust (5–8 km/sec)A is strongly correlated with density and compressional wave velocityv _p:A decreases with increasingv _p orp. From this relationship it is now possible to estimate heat production values for any particular layer of a crustal section from measured seismic velocities. Contrary to earlier belief there is, as shown by experimental determinations, no correlation between heat productionA and thermal conductivityK in igneous and metamorphic rocks. In sediments however, especially in sand/shale sequences, a correlation betweenK andA is most likely: increasing clay mineral content, characterized by increasingA, causes the decrease ofK in these rocks.Contribution No. 111, Institute of Geophysics, Swiss Federal Institute of Technology, Zurich, Switzerland.     

Radioactive elements in sediments and altered rocks of the Kikhpinych long-lived volcanic center

Data on the concentration of radioactive elements in mineral sediments and hydrothermally altered rocks of the long-lived Kikhpinych volcanic center are presented. High concentrations of uranium (up to 31 g/t) and thorium (up to 46 g/t) relative to the average values for the dacites of Kamchatka and the Uzon-Geyser depression are found in white kaolinite clays of mud pots and in dacites of the Yuzhnoe Kikhpinych thermal field transformed into kaolinite clays. In this field and in the Severnoe thermal field (in the crater of Staryi Kikhpinych Volcano) high values of volume radon activity (VA Rn > 1000 kBq/m³) were recorded in subsoil air. These high concentrations of uranium and thorium in fresh mineral sediments and anomalous values of VA Rn in subsoil air of hydrothermally altered rocks are considered to have resulted from the mass transfer of radioactive elements by fluid flows of the hydrothermal system.     

Palaeomagnetic studies of Lower Jurassic rocks in England and Wales

Paleomagnetic data from late Lower Jurassic sediments from Dorset, Gloucestershire and Yorkshire confirm the existence of at least one interval of reversed geomagnetic polarity in Upper Toarcian time (about 175 m.y. ago). The mean pole position calculated from these data lies at 50°N, 37°E, but the field represented by this pole is believed to have been non-axial because of its incompatibility with Mesozoic faunal, palaeoclimatic and palaeomagnetic evidence throughout western Europe.Unstable remanent magnetization found in a large number of samples of various lithologies is shown to have originated during drilling. It is tentatively identified as partial TRM acquired during dissipation of heat from the drill tip. Alternative causes such as superficial contamination and vibration do not explain the majority of the observations.