An investigation of the spatial variability of the grain size composition of floodplain sediments

River floodplains have been widely recognized as important sinks for storing suspended sediment and associated contaminants transported by river systems. The grain size composition of floodplain deposits exerts an important influence on contaminant concentrations, and commonly exhibits significant spatial variability in response to the dynamic nature of overbank flow and sediment transport. Information on the spatial variability of the grain size composition of overbank deposits is therefore essential for developing an improved understanding of the processes controlling sediment transport on floodplains, and for investigating the fate of sediment-associated contaminants. Such information is also important for validating existing floodplain sedimentation models. This paper reports the results of a study aimed at investigating the spatial variability of the grain size composition of floodplain sediments at different spatial scales, through analysis of surface sediment samples representative of contemporary floodplain deposits collected from frequently inundated floodplain sites on five British lowland rivers. Significant lateral and downstream variations in the grain size composition of the sediment deposits have been identified in the study reaches. An attempt has been made to relate the observed spatial distribution of the grain size composition of the overbank deposits to the local floodplain geometry and topography. The importance of the particle size characteristics of the suspended sediment transported by the rivers in influencing the spatial variability of the grain size composition of the overbank sediments deposited on these floodplains is also considered. © 1998 John Wiley & Sons, Ltd.     

Effect of mining and related activities on the sediment trace element geochemistry of lake coeur D'Alene,idaho, USA. Part I: Surface sediments

During the summer of 1989 surface sediment samples were collected in Lake Coeur d'Alene, the Coeur d'Alene River and the St Joe River, Idaho, at a density of approximately one sample per square kilometre. Additional samples were collected from the banks of the South Fork of the Coeur d'Alene and the Coeur d'Alene Rivers in 1991. All the samples were collected to determine trace element concentrations, partitioning and distribution patterns, and to relate them to mining, mining related and discharge operations that have occurred in the Coeur d'Alene district since the 1880s, some of which are ongoing. Most of the surface sediments in Lake Coeur d'Alene north of Conkling Point and Carey Bay are substantially enriched in Ag, As, Cu, Cd, Hg, Pb, Sb and Zn relative to unaffected sediments in the southern portion of the lake near the St Joe River. All the trace element enriched sediments are extremely fine grained (mean grain sizes « 63 μm). Most of the enriched trace elements, based on both the chemical analyses of separated heavy and light mineral fractions and a two step sequential extraction procedure, are associated with an operationally defined Fe oxide phase; much smaller percentages are associated either with operationally defined organics/sulphides or refractory phases. The presence, concentration and distribution of the Fe oxides and heavy minerals indicates that a substantial portion of the enriched trace elements are probably coming from the Coeur d'Alene River, which is serving as a point source. Within the lake, this relatively simple point source pattern is complicated by a combination of (1) the formation of trace element rich authigenic Fe oxides that appear to have reprecipitated from material solubilized from anoxic bed sediments and (2) physical remobilization by currents and wind driven waves. The processes that have caused the trace element enrichment in the surface sediments of Lake Coeur d'Alene are likely to continue for the foreseeable future.     

Tidally-induced sediment transport patterns in the upper Bay of Fundy: A numerical study

The Minas Basin, the eastern end of the Bay of Fundy, is well known for its high tide ranges and strong tidal currents, which can be exploited to extract electricity power. The properties of the tidally-induced sediment transport in the Minas Basin, where significant changes in tidal processes may occur due to a recently proposed tidal power project, have been studied with a three-dimensional hydrodynamic model, an empirical bed load sediment transport model and surface sediment concentrations derived from the remotely-sensed images. The hydrodynamic model was evaluated against independent observational data, which include tidal elevation, tidal current (in the full water column and bottom layer), residual current profile and tidal asymmetry indicators. The evaluation shows that the model is in good agreement with the observations.The sediment transport includes two components, bed load and suspended particulate load. The bed load is calculated using the modelled bottom shear stress and the observed grain size data. The estimated features of bed load transport roughly agree with the observed patterns of the erosion and deposition in the Minas Basin and Cobequid Bay. The transport of the suspended load is estimated using the modelled velocity fields and the surface sediment concentration derived from remote-sensing images. The comparisons between the modelled results and the limited observations illustrate that the observed directions of suspended sediment transport are basically reproduced by the model. The modelled net suspended sediment input into the Minas Basin through Minas Passage is 2.4×10⁶ m³ yr^?1, which is comparable to the observed value of 1.6×10⁶ m³ yr^?1.The variations of the bed load and the suspended load in space and time are also presented. The total net transport, defined as the mean value of the sum of bed and suspended load transports during the tidal cycle, shows strong spatial variability. The magnitude of the transport flux ranges from 0.1 to 0.2 kg m^?1 s^?1 in Minas Channel and Minas Passage, 0.1 kg m^?1 s^?1 in Cobequid Bay, to 0.01 kg m^?1 s^?1 in the central Minas Basin and Southern Bight. In Minas Channel, the sediment transport follows the structure of the tidal residual circulation, which features a large anticlockwise gyre. The sediment in Minas Passage moves eastward and deposits into the central Minas Basin. However, the sediment from the eastern part of the Basin moves westward and deposits in the central Minas Basin as well. In the Cobequid Bay, sediment moves eastward and deposits in the upper bay.     

LINKS BETWEEN PROGLACIAL STREAM SUSPENDED SEDIMENT DYNAMICS,GLACIER HYDROLOGY AND GLACIER MOTION AT MIDTDALSBREEN,NORWAY

Two-hourly suspended sediment concentration variations observed during the summer of 1987 in the proglacial stream draining Midtdalsbreen, Norway are modelled using multiple regression and time series techniques. Suspended sediment fluctuations are influenced by stream discharge variations, diurnal hysteresis effects, medium-term sediment supply and transport variations and the recent suspended sediment concentration history of the stream. They do not appear to be influenced by seasonal exhaustion or rainfall variations. Possible reasons for this are discussed. Large positive residuals from the fitted models are major pulses of suspended sediment unrelated to discharge variations; these sediment flushes correlate with periods of enhanced glacier motion. They cannot be explained by enhanced sediment production by subglacial erosion, but are probably due to the tapping of subglacially stored sediment during sudden changes in the hydraulics and/or configuration of the subglacial hydrological system. Seasonal changes in the lag between glacier motion peaks and suspended sediment flushes suggest that the subglacial hydrological system evolves over the summer from a distributed to a more channelized configuration.     

Trace metals distribution pattern in floodplain sediments of a lowland river in relation to contemporary valley bottom morphodynamics

The distribution of trace metals in alluvial sediments depends on their natural background concentrations, and on the dynamics of contemporary depositional and erosional (mainly flood‐induced) processes. Geological and geochemical investigations were carried out in the valley of Vistula River near Magnuszew (central Poland). Sediment samples were collected from a depth of 35 cm and comprise sediments of all defined geomorphological features. Identification and geological interpretation of the morphodynamic sediment features was supported by aerial photographs and high‐resolution satellite images. These studies revealed that the distribution of trace metals is closely linked to the morphogenesis of the alluvial floodplain. The highest concentrations of Cu, Co, Zn, V, Cr and Ni were observed in crevasse‐splays deposits. By contrast, Sr, Pb and As were concentrated in deposits which fill oxbow lakes (partly infilled with organic deposits). The lowest concentrations of trace metals were detected in flood sediments deposited within erosional troughs. The geomorphological and sedimentological history of the fluvial features explains the pattern of heavy metal distribution on the current floodplain surface. Copyright © 2014 John Wiley & Sons, Ltd.     

A comparative study of three different learning algorithms applied to ANFIS for predicting daily suspended sediment concentration

The modeling and prediction of suspended sediment in a river are key elements in global water recourses and environment policy and management. In the present study, an Adaptive Neuro-Fuzzy Inference System model trained with the Levenberg-Marquardt learning algorithm is considered for time series modeling of suspended sediment concentration in a river. The model is trained and validated using daily river discharge and suspended sediment concentration data from the Schuylkill River in the United States. The results of the proposed method are evaluated and compared with similar networks trained with the common Hybrid and Back-Propagation algorithms, which are widely used in the literature for prediction of suspended sediment concentration. Obtained results demonstrate that models trained with the Hybrid and Levenberg-Marquardt algorithms are comparable in terms of prediction accuracy. However, the networks trained with the Levenberg-Marquardt algorithm perform better than those trained with the Hybrid approach.     

Recent increase of river–floodplain suspended sediment exchange in a reach of the lower Amazon River

We analyzed variation of channel–floodplain suspended sediment exchange along a 140 km reach of the lower Amazon River for two decades (1995–2014). Daily sediment fluxes were determined by combining measured and estimated surface sediment concentrations with river–floodplain water exchanges computed with a two‐dimensional hydraulic model. The average annual inflow to the floodplain was 4088 ± 2017 Gg yr^?1 and the outflow was 2251 ± 471 Gg yr^?1, respectively. Prediction of average sediment accretion rate was twice the estimate from a previous study of this same reach and more than an order of magnitude lower than an estimate from an earlier regional scale study. The amount of water routed through the floodplain, which is sensitive to levee topography and increases exponentially with river discharge, was the main factor controlling the variation in total annual sediment inflow. Besides floodplain routing, the total annual sediment export depended on the increase in sediment concentration in lakes during floodplain drainage. The recent increasing amplitude of the Amazon River annual flood over two decades has caused a substantial shift in water and sediment river–floodplain exchanges. In the second decade (2005–2014), as the frequency of extreme floods increased, annual sediment inflow increased by 81% and net storage increased by 317% in relation to the previous decade (1995–2004). Copyright © 2017 John Wiley & Sons, Ltd.     

Effect of mining and related activities on the sediment trace element geochemistry of Lake Coeur D'Alene,Idaho, USA part II: Subsurface sediments

During the summer of 1990, 12 gravity cores were collected in Lake Coeur d'Alene, Idaho at various depths and in a variety of depositional environments. All core subsamples were analysed to determine the bulk sediment chemistry; selected subsamples were analysed for trace element partitioning and ¹³⁷Cs activity. The purpose of these analyses was to determine the trace element concentrations and distributions in the sediment column and to try to establish a trace element geochemical history of the lake in relation to mining and mining-related discharge operations in the area. Substantial portions of the near-surface sediments in Lake Coeur d'Alene are markedly enriched in Ag, As, Cd, Hg, Pb, Sb and Zn, and slightly enriched in Cu, Fe and Mn. Variations in the thickness of the trace element-rich sediments, which range from more than 119 cm to as little as 17 cm, indicate that the source of much of this material is the Coeur d'Alene River. An estimated 75 million tonnes of trace element-rich sediments have been deposited on or in the lake bed. Estimated trace element masses in excess of those considered representative of background conditions range from a high of 468 000 tonnes of Pb to a low of 260 tonnes of Hg. The similarity between the trace element-rich surface and subsurface sediments with respect to their location, their bulk chemistry, their interelement relations and their trace element partitioning indicate that the sources and/or concentrating mechanisms causing the trace element enrichment in the lake sediments have probably been the same through-out their depositional history. Based on a Mt St Helens'ash layer from the 1980 eruption, ages estimated from ¹³⁷Cs activity and the presence of 80 discernible and presumably annual layers in a core collected near the Coeur d'Alene River delta indicate that deposition rates for the trace element-rich sediments have ranges from 2.1 to 1.3 cm/year. These data also indicate that the deposition of trace element-rich sediments began, at least in the Coeur d'Alene River delta, some time between 1895 and 1910, dates consistent with the onset of mining and ore processing activities that began in the area in the 1880s.     

The effect of mining and related activities on the sediment–trace element geochemistry of Lake Coeur d'Alene,Idaho, USA. Part III. Downstream effects: the Spokane River Basin

During 1998/1999, surface and subsurface sediment samples were collected along the entire length of the Spokane River from its outlet at the northern end of Lake Coeur d'Alene (CDA), Idaho, to Lake Roosevelt on the Columbia River, Washington. The study was conducted to determine if the trace element enrichments observed in Lake CDA and on the floodplain and in the CDA River extend through the Spokane River Basin (SRB). As in Lake CDA, surface sediments in the SRB are enriched in Pb, Zn, As, Cd, Sb and Hg relative to local background levels. Pb, Cd and Zn are the most elevated, with maximum enrichment occurring in the upper Spokane River in close proximity to Lake CDA. On average, enrichment decreases downstream, apparently reflecting both increased distance from the inferred source (the CDA River Basin), as well as increased dilution by locally derived but unenriched materials. Only Cd and Zn display marked enrichment throughout the SRB. Pb, Zn and Cd seem to be associated mainly with an operationally defined iron oxide phase, whereas the majority of the As and Sb seem to be matrix‐held. Subsurface sediments also are enriched in Pb, Zn, As, Cd, Sb and Hg relative to background levels. Based on ¹³⁷Cs and excess ²¹⁰Pb dating, trace element enrichment began in the middle part of the SRB (Long Lake) between 1900 and 1920. This is contemporaneous with similar enrichments observed in Lake CDA, as well as the completion of Long Lake Dam (1913). In the most downstream part of the basin (Spokane River Arm of Lake Roosevelt), enrichment began substantially later, between 1930 and 1940. The temporal difference in enrichment between Long Lake and the River Arm may reflect the latter's greater distance from the presumed source of the enrichment (the CDA River Basin); however, the difference is more likely the result of the completion of Grand Coulee Dam (1934–1941), which formed Lake Roosevelt, backed up the Spokane River, and increased water levels in the River Arm by about 30 m.     

Elemental composition and mineralogical characteristics of coastal marine sediments of Tutuila, American Samoa

Surface sediment samples were collected from 5 pristine coastal areas and 1 potentially contaminated coastal site on Tutuila, the main island of American Samoa, an isolated island group in the South Pacific Ocean. Samples were analysed for total element analysis (15 elements) and mineralogy. The results indicated no evidence of trace element contamination at any site, including Pago Pago Harbour. Inter-site variations could be explained assuming the sediments consisted predominantly of coralline sand and rubble with varying quantities of basaltic materials derived from local catchments.     

Sediment yield studies of headwater catchments in Sussex,S.E. England

The transport of sediment from six small (0.2 to 17.6 km²) headwater catchments is described. The catchments under investigation were located in relation to predominant lithological deposits within the Cretaceous rock succession; two of the areas were underlain by (Weald) clay, two by sandstone (Ashdown Sand and Tunbridge Wells Sand) and two by chalk. The climate of the region under investigation is temperate, with an average annual precipitation (850 mm) in excess of potential evapotranspiration (450 mm). The transport of suspended material from within the catchments was examined by collecting samples of the water-sediment mixture draining the areas, using hand held depth-integrating and permanently installed stage sampling systems. The results of the regularly maintained sampling programme, over a two-year period, are described. Attempts were made to both measure and compute bed load transport. Suspended sediment concentrations are compared between catchments and related to hydrological characteristics. The nature of the material in transit is examined. Sediment rating curves are derived for each of the headwater catchments, defining the relationship in the form y = Ax^b (where y = suspended sediment concentration (mg/1) and x = water discharge (m³/s)). Annual rating curves are used to derive annual suspended sediment loads by combination with water discharge data, using a log-incremental computerized approach. Multiple regression techniques have been used to examine annual loads in terms of hydrological and morphological characteristics of the headwater catchments. Based on the field information available, a generalized model for the relationship between suspended sediment concentration and water discharge is described. Finally, the derived annual loads from the headwater catchments are combined with both limited observations from the larger Sussex rivers and data available for other catchment investigations in the British Isles, to produce a series of prediction equations for catchment yield under temperate climatic conditions.     

In-channel surficial fine-grained sediment laminae. Part II: Chemical characteristics and implications for contaminant transport in fluvial systems

Samples of surficial fine-grained laminae (SFGL) were collected in three south-western Ontario rivers. Each sediment sample was subjected to a sequential extraction procedure designed to partition particulate metals (Cd, Pb, Cu, Zn) into five operationally defined fractions: (1) exchangeable; (2) bound to carbonates; (3) bound to Fe-Mn oxides; (4) bound to organic matter; and (5) residual. Particulate phosphus was sequentially extracted from the sediment samples into three fractions: (1) non-apatite inorganic P; (2) apatite P; and (3) organic P. The major accumulate phases of trace metals in SFGL are carbonates, Fe-Mn oxides and organic matter. The content of NAIP in SFGL ranged from 17 to 38% of total particulate P. Compared with suspended and bed sediments, levels of P and trace metals in SFGL were lower at the study sites. A conceptual overview of physical, chemical and biological processes influencing formation of SFGL and the potential role of this fine-grained sediment for contaminant transport in fluvial systems is presented.     

Relationship between bed shear stress and suspended sediment concentration:annular flume experiments

In this study,annular flume experiments were carried out,using the sediment samples collected from the lower part of the inter-tidal zone at Xiaoyangkou,Jiangsu coast,China.The Ariathurai-Partheniades equation was used to determine the bed shear stress,by evaluating variations in the suspended sediment concentration within the water column.The derived relation between the bed shear stress and suspended sediment concentration shows that,at various stages of seabed erosion, suspended sediment concentration increases rapidly when the flow velocity is increased,but the pattern of change in the bed shear stress does not follow suit.At low concentrations,bed shear stress initially increases markedly with increasing flow velocity.However,when the concentration reaches an apparently critical level around 0.55 kg m"3,the rate of change in the bed shear stress abruptly slows down,or becomes almost constant,in response to further increases in the flow velocity.Results of experiments indicate that,from a critical level onward,suspended sediment concentration has a strong influence on the bed shear stress.     

Particle size characteristics of suspended sediment in hillslope runoff and stream flow

This study examines the particle size characteristics of hillslope soils and fluvial suspended sediments in an agricultural catchment. Samples of surface runoff and stream flow were collected periodically and analysed for the size distributions of the effective (undispersed) sediment. This sediment was subsequently dispersed and the ultimate size distributions determined. The median effective particle size of stream suspended sediment was considerably coarser than the median ultimate particle size, indicating that most of the load included a substantial proportion of aggregates. Moreover, the proportion of fine material (i.e. silt and clay) increased, and the proportion of sand-sized material decreased, with increasing discharge. This decrease in sediment size with increased flow, which is contrary to the traditional assumption of a positive discharge/particle size relationship, is thought to reflect: (i) the influx of silt and clay, predominantly the former, originating on the catchment slopes and brought to the stream by overland flow along vehicle wheelings, roads and tracks; and (ii) erosion of fine material from the channel bed and banks. During large storms, however, the proportion of sand-sized sediment increased during the rising limb of the hydrograph, as a result of the entrainment of coarser source material from the valley floor during overbank flooding. The stream suspended sediment was finer than the catchment soils and considerably finer than material eroding from the catchment slopes during storms. The degree of clay and silt enrichment in the suspended sediments was largely the result of preferential deposition of the coarser fraction during the transport and delivery of sediment from its source to basin outlet. The data from this study confirm that a significant mode of sediment transport in fluvial systems is in the form of aggregates, and that the dispersed sediment size distribution is inappropriate for determining the transportability of sediment by flow. © 1997 by John Wiley & Sons, Ltd.     

Floodplain construction by recent,rapid vertical accretion: Waipaoa River,New Zealand

The rate of vertical accretion (typically 14–18 mm h⁻¹) during eight floods in the Waipaoa River basin, with recurrence intervals of 5 to 60 years, was determined by relating the floodplain stratigraphy at McPhail's bend to the 1948–1995 flood history. Overbank deposits remaining after a flood that occurred in March 1996 suggest a rate of vertical accretion of 15 mm h⁻¹. By contrast, because the flow velocity across the floodplain was too high to permit deposition from suspension, during the record flood of March 1988 the rate of vertical accretion was only 6 mm h⁻¹. The sequence of deposition is highly discontinuous, and the rapid vertical accretion is a response to a late 19th to early 20th century phase of deforestation in the headwaters that probably initiated a far greater change in suspended sediment yield than in discharge. Cross-section surveys conducted since 1948 indicate that the high suspended sediment load of the Waipaoa River also promoted in-channel deposition, which effected a progressive reduction in bankfull channel width although, due to the overbank deposition, channel capacity remained constant. © 1998 John Wiley & Sons, Ltd.     

Numerical modeling of bedload and suspended load contributions to morphological evolution of the Seine Estuary (France)

This numerical modeling study (i) assesses the influence of the sediment erosion process on the sediment dynamics and subsequent morphological changes of a mixed-sediment environment, the macrotidal Seine estuary, when non-cohesive particles are dominant within bed mixtures (non-cohesive regime), and (ii) investigates respective contributions of bedload and suspended load in these dynamics. A three dimensional (3D) process-based morphodynamic model was set up and run under realistic forcings (including tide, waves, wind, and river discharge) during a 1-year period. Applying erosion homogeneously to bed sediment in the non-cohesive regime, i.e., average erosion parameters in the erosion law (especially the erodibility parameter, E₀), leads to higher resuspension of fine sediment due to the presence of coarser fractions within mixtures, compared to the case of an independent treatment of erosion for each sediment class. This results in more pronounced horizontal sediment flux (two-fold increase for sand, +30% for mud) and erosion/deposition patterns (up to a two-fold increase in erosion over shoals, generally associated with some coarsening of bed sediment). Compared to observed bathymetric changes, more relevant erosion/deposition patterns are derived from the model when independent resuspension fluxes are considered in the non-cohesive regime. These results suggest that this kind of approach may be more relevant when local grain-size distributions become heterogeneous and multimodal for non-cohesive particles. Bedload transport appears to be a non-dominant but significant contributor to the sediment dynamics of the Seine Estuary mouth. The residual bedload flux represents, on average, between 17 and 38% of the suspended sand flux, its contribution generally increasing when bed sediment becomes coarser (can become dominant at specific locations). The average orientation of residual fluxes and erosion/deposition patterns caused by bedload generally follow those resulting from suspended sediment dynamics. Sediment mass budgets cumulated over the simulated year reveal a relative contribution of bedload to total mass budgets around 25% over large erosion areas of shoals, which can even become higher in sedimentation zones. However, bedload-induced dynamics can locally differ from the dynamics related to suspended load, resulting in specific residual transport, erosion/deposition patterns, and changes in seabed nature.     

The potential use of pollen in the identification of suspended sediment sources

Pollen and spores form a significant part of the suspended organic load of a New Forest stream. Flood concentrations reach 230 grains ml^?1 while baseflow carries under one grain ml^?1. Hydrographs from different seasons show differing hysteretic loops for pollen and spore concentrations against discharge and suspended sediment. These variations reflect not only factors of production, but the type and distance of the contributing sources. This investigation suggests that variations in flood pollen and spore concentrations may be used to trace such suspended sediment sources as: eroding bedrock, channel banks, or hillslopes under specific vegetation covers.     

Sediment routing analyses based on chronological changes in hillslope and riverbed morphologies

Recent studies of sediment delivery and budgets in the United States indicate that upland erosion rates at a given time may not explain contemporaneous sediment yields from a drainage basin. This suggests temporal discontinuities in sediment delivery associated with hillslope and channel storage processes. Integration of sediment production, storage and transport is essential to understand sediment routing in basins. We analysed each process chronologically using aerial photographs, monitoring data of sediment movement and annual tree-rings, and then compared estimated temporal changes in sediment production from hillslopes, floodplain disturbance areas and sediment transport in river channels. Toeslopes, floodplains and alluvial fans together contained 59 per cent of sediment eroded from uplands over the last 30 years. Monitoring results of riverbed changes showed that the volume of stored sediment on floodplains decreased exponentially with succeeding floods. The age distribution of floodplain deposits reflected the disturbance history of a river channel, and followed an exponential decrease with age. The results of this study may have important implications for sediment control plans for watersheds in steep regions.     

The mobilization and deposition of mud deposits in a coastal plain estuary

Muddy sediments with their potential for containing contaminants are commonly deposited and remobilized by tidal currents in estuarine environments. We examined the mobilization and subsequent redeposition of mud in a coastal plain estuary located in the southeastern United States. Time-series data for salinity, suspended sediment concentrations and quality (percent organic matter and pigment concentrations) were obtained over a 13-hour tidal cycle. We found that fast-settling mud particles are found during the highest tidal current speeds. Particle quality analyses suggest that all the material is of similar origin, and that phaeopigment can be used as a tracer of particles in this system. These particles settle onto the bed when current speeds approach slack conditions. We speculate that the quantity of mud mobilized during neap tide is less than during spring tide resulting in an opportunity for the mud to partially consolidate on the bottom and be removed from resuspension. We further speculate that the muddy sediments are mainly derived from fringing marshes in this estuary.     

Levels and patterns of polychlorinated dibenzo-p-dioxins, dibenzofurans and biphenyls in surface sediments from the western Baltic Sea (Arkona Basin) and the Oder River estuarine system

Surface sediment samples were collected from the western Baltic Sea (Arkona Basin) and the Oder River estuarine system in May and August 1995 and analysed for polychlorinated dibenzo-p-dioxins, dibenzofurans and biphenyls. Contents of PCDF (sum) and PCDD (sum) varied from 2.5 to 820.0 pg g⁻¹ dw and from 12.7 to 2991.0 pg g⁻¹ dw, respectively. PCB contents (sum of 23 congeners) ranged between < 130.0 and 16267.0 pg g⁻¹ dw. Only slight variations in PCDF/D and PCB contents on dry weight basis were found between the Oder River estuarine system and the open Baltic Sea. TOC-normalization of the data showed an approximately homogen PCDF/D distribution in the study area. The distribution pattern for PCDF/D and PCB may be attributed to high sediment dynamics combined with transport processes from the temporary sedimentation basin (Oderhaff) to the deeper parts of the Baltic Sea.