The effects of particle breakage and abrasion on the magnetic properties of two soils

As mineral magnetism is used as a tracer for sourcing river and dam sediments, changes in the magnetic properties that may occur during transport between the source and sink must be considered. Abrasion and breakage of particles will occur during transport. These processes were examined in simulation experiments with a granitic and a sedimentary soil. The effects of these processes on the magnetic properties of a granitic and a sedimentary soil were examined using a simulated breakage/abrasion experiment. Breakage and/or abrasion had substantial effects on the magnetic properties of both soils. All particle sizes were affected, but the magnitude varied through the size range of derived particles. The major effect was on the concentration of magnetic minerals, with differences between the concentrations in particle sizes of the original material and those generated by the experiments being as much as 20 times. The effect on the granite soil was to reduce the concentrations, i.e. derived material was less than original material; whereas for the sedimentary soil the derived particles had higher concentrations. The effect on magnetic grain size, as indicated by the magnetic ratios, was less than the effect on the mass magnetic properties, but still substantial for some ratios for some sizes. © 1998 John Wiley & Sons, Ltd.     

The Maude Weir sediments. 1. Desorption and sorption of phosphorus,and related changes in mineral magnetic properties after desorption

Algal blooms frequently occur in the Maude Weir in the Murrumbidgee River of NSW, which are related to the availability of nutrients, particularly phosphorus. A clayey sediment from the bottom released P to the water when kept under reducing conditions, but did not release P when the supernatant water was aerated. The same material, with and without aeration, sorbed P when resuspended in water containing 1 mg P L⁻¹. The resuspended anaerobic material adsorbed almost twice as much as the same material under aerobic conditions. Vigorous mixing, simulating transport breakage and abrasion, caused a substantial increase in sorption, with the effect being greater for the aerobic material. This was attributed to fragmentation of iron oxide aggregates formed during oxidation. Mineral magnetic properties, susceptibility and remanence ratios SIRM/χ, SIRM/ARM and IRMh%, of the material from the desorption experiment reflected changes in the chemical state of iron caused by oxidation and reduction. Copyright © 2000 John Wiley & Sons, Ltd.     

Major element chemistry of sediments from the Darling–Barwon river and its tributaries: implications for sediment and phosphorus sources

In 1991, one of Australia's longest rivers, the Darling–Barwon, experienced one of the world's largest recorded algal blooms. Nearly 1000 km of river were affected. At the time of the bloom phosphorus originating from anthropogenic sources was believed to be the principal cause. In this study we have used major element chemistry to examine the sources of sediment and sediment‐associated phosphorus delivered to the Darling–Barwon River. We show that the sediments are derived primarily from the sedimentary and granitic bedrock areas of the catchment, not the intensively farmed basalt areas. We also show that the sediment currently in transport in the Darling–Barwon does not originate from contemporary upland erosion, but is probably derived from lowland areas of the catchment that contain more weathered material. Phosphorus concentrations in the sediments are consistent with those in natural soils of the region, and evidence from two sediment cores indicates that phosphorus concentrations have not changed significantly in the last 200 years. The implications of these findings for algal growth control strategies are discussed. Copyright © 2000 John Wiley & Sons, Ltd.     

Fingerprinting upland sediment sources: particle size‐specific magnetic linkages between soils,lake sediments and suspended sediments

Accelerated erosion of fine‐grained sediment is an environmental problem of international dimensions. Erosion control strategies and targeting of mitigation measures require robust and quantitative identification of sediment sources. Here, we use magnetic ‘fingerprinting’ to characterize soils, and examine their affinity with and contribution to suspended sediments transported within two subcatchments feeding Bassenthwaite Lake, northwest England. A high‐resolution soil magnetic susceptibility survey was made using a field susceptometer (ZH Instruments, SM400 probe). Combining the spatial and vertical (down‐profile) soil magnetic data, a subset of soil profiles was selected for detailed, laboratory‐based magnetic remanence analyses. The magnetic properties of the catchment soils are highly particle size‐dependent. Magnetic analyses were performed on the 31–63 µm fraction, for particle size‐specific comparison both with the suspended sediments and lake sediments. Fuzzy cluster analysis groups the soil magnetic data into six clusters, apparently reflecting variations in parent material and horizon type, with three magnetically hard soils as unclassified outliers. Examination of the cluster affinity of the soils, suspended sediments and lake sediments indicates that topsoils of the upper Newlands Valley and subsoils around Keskadale Beck are a major source of the Newlands Beck suspended load, and the recent (post‐nineteenth century) sediments in the deep lake basin. Older lake sediments show strong affinity with a small number of the Derwent suspended sediments and one of the Glenderamackin soils. A large number of Derwent suspended sediments show no affinity with any of the soils or lake sediments, instead forming a coherent, discrete and statistically unclassified group, possibly resulting from mixing between the magnetically hard subsoils of the medium to high‐altitude Glenderamackin and Troutbeck areas and softer, lower altitude Glenderamackin soils. The lack of any affinity of these suspended sediments with the lake sediments may indicate deposition along the Derwent flood plain and/or in the shallow delta of Lake Bassenthwaite. Particle size‐specific magnetic fingerprinting is thus shown to be both highly discriminatory and quantitatively robust even within the homogeneous geological units of this catchment area. Such a methodological approach has important implications for small–large scale catchment management where sources of sediment arising from areas with uniform geology have been difficult to determine using other approaches, such as geochemical or radionuclide analyses. Copyright © 2009 John Wiley & Sons, Ltd.     

Effects of nitrate on phosphorus release: comparison of two Berlin lakes

After installation of phosphorus elimination plants at the inflows of the eutrophic Lake Tegel and Schlachtensee, phosphorus (P) loading declined by a factor of 40 and 100, respectively. This resulted in a pronounced reduction of phosphorus concentrations in the lake water, followed by a decline of chlorophyll‐a concentrations. However, for many years P release from sediments due to mineralization and desorption of sedimentary P continued. In Schlachtensee, the presence of nitrate above the sediment suppresses P release, because the Fe/P ratio is sufficient to provide enough aerobic sorption capacity. In Lake Tegel, some P release occurs even under aerobic conditions because of the low aerobic P sorption capacity of the sediments. There, nitrate could moderate the P release peaks which occur when the Fe‐P cycle at the sediment water interface is disturbed by precipitation of iron sulfide after reduction of sulfate during times of high mineralization intensity. The potentially mobile P pool in the sediments of both lakes is rather small, indicating that the P release could subside after sufficient reduction of the external P load in Lake Tegel and the disruption of the internal P cycle in Schlachtensee.     

太湖地区丘陵旱地土壤磷的吸持解吸特征

旱地土壤中流失的磷是地表水体中磷的重要来源,本文通过模拟实验对比太湖地区丘陵旱地土壤和水稻土对磷的吸持解吸特征,结果表明虽然旱地土壤对磷的固定能力略高于水稻土,但由于旱地土壤的有效磷水平普遍高于水稻土,因而前者磷的吸持饱和度（DPS）要大大高于后者,这就决定了旱地土壤中的磷被淋溶或以溶解态随径流流失的风险和数量也同于水稻土,磷吸持饱和度是土壤磷素水平和土壤固磷能力的综合指标,更能反映土壤固相中的磷进入液相的难易程序,可以作为评价水－土界面磷迁移能力 重要指标。     

Chemical characterization of individual particles from the nepheloid layer in the Atlantic Ocean

Particulate matter samples filtered from near-bottom, 30-liter water samples collected during the GEOSECS Atlantic cruise were analyzed by the Computer Evaluated Scanning Electron Microscope Image (CESEMI-2) system. This system permitted automated discrete particle analysis for the elements Al, Si, P, S, K, Ca, and Fe by energy-dispersive X-ray spectrometry and for particle size. Approximately 2000 particles in the size range 1–20 μm, representative of several milliliters of seawater, were analyzed per sample and yielded discrete size and chemical analysis of the major classes of particulate matter—opal, calcium carbonate, and clay—as well as some regularly occurring subclasses of clay and other minor classes.The distributional patterns of the major classes matched both in chemistry and abundance their general distributional patterns in sediments. Clay particles reflected high- and low-latitude sources; opal particles, patterns of diatom productivity; and carbonate, patterns of productivity as well as the calcite saturation chemistry of the water column. Superimposed on these features was evidence for long-range transport of particles in well-defined bottom water masses such as the Antarctic Bottom Water. Such transport is believed to occur through a series of resuspension events, in which case particle distributions match the properties of the sediments. Cases were found where near-bottom particles did not match the sediments, especially in quiescent environments.     

Characterization of phosphorus sorption on the sediments of Yangtze River Estuary and its adjacent areas

This paper studied the kinetics, isotherm and thermodynamics of phosphorus sorption onto the sediments of the Yangtze River estuary and its adjacent waters, as well as the sediments' compositions and physicochemical properties. The process could be described well by a two-compartment first order equation. The sorbed phosphorus mainly consisted of Ex-P and Fe-P, with Ex-P being the dominant. The equilibrium isotherms could be fitted well with a modified Langmuir equation. The calculations of the thermodynamic parameters indicated that the process was spontaneous and exothermic. The CEC and the fractions of clay, calcite and organic matter were correlated with the sorption parameters, while the surface proton charge of the sediments was significantly negatively correlated with them. Considering the kinetics and phosphorus forms changes during the process, the sorption in our study could be considered that the physical process plays an important role.     

Provenance of sandstones from the Wakino Subgroup of the Lower Cretaceous Kanmon Group, northern Kyushu, Japan

Abstract The Wakino Subgroup is a lower stratigraphic unit of the Lower Cretaceous Kanmon Group. Previous studies on provenance of Wakino sediments have mainly concentrated on either petrography of major framework grains or bulk rock geochemistry of shales. This study addresses the provenance of the Wakino sandstones by integrating the petrographic, bulk rock geochemistry, and mineral chemistry approaches. The proportions of framework grains of the Wakino sandstones suggest derivation from either a single geologically heterogeneous source terrane or multiple source areas. Major source lithologies are granitic rocks and high‐grade metamorphic rocks but notable amounts of detritus were also derived from felsic, intermediate and mafic volcanic rocks, older sedimentary rocks, and ophiolitic rocks. The heavy mineral assemblage include, in order of decreasing abundance: opaque minerals (ilmenite and magnetite with minor rutile), zircon, garnet, chromian spinel, aluminum silicate mineral (probably andalusite), rutile, epidote, tourmaline and pyroxene. Zircon morphology suggests its derivation from granitic rocks. Chemistry of chromian spinel indicates that the chromian spinel grains were derived from the ultramafic cumulate member of an ophiolite suite. Garnet and ilmenite chemistry suggests their derivation from metamorphic rocks of the epidote‐amphibolite to upper amphibolite facies though other source rocks cannot be discounted entirely. Major and trace element data for the Wakino sediments suggest their derivation from igneous and/or metamorphic rocks of felsic composition. The major element compositions suggest that the type of tectonic environment was of an active continental margin. The trace element data indicate that the sediments were derived from crustal rocks with a minor contribution from mantle‐derived rocks. The trace element data further suggest that recycled sedimentary rocks are not major contributors of detritus. It appears that the granitic and metamorphic rocks of the Precambrian Ryongnam Massif in South Korea were the major contributors of detritus to the Wakino basin. A minor but significant amount of detritus was derived from the basement rocks of the Akiyoshi and Sangun Terrane. The chromian spinel appears to have been derived from a missing terrane though the ultramafic rocks in the Ogcheon Belt cannot be discounted.     

Specific surface area as a maturity index of lunar fines

Mature surface fines have an equilibrium specific surface area of about 0.6 m²/g, the equivalent mean particle size being about 3 μm. The adsorption behavior of inert gases (reversible isotherms) indicates that the particles are also non-porous in the size range of pores 10–300Å. Apparently in mature soils there is a balance in the forces which cause fining, attrition, pore filling and growth of lunar dust grains. Immature, lightly irradiated soils usually have coarser grains which reduce in size as aging proceeds. The specific surface area, determined by nitrogen or krypton sorption at 77°K, is a valuable index of soil maturity.     

Effects of varying estuarine conditions on the sorption of phenanthrene to sediment particles of Yangtze Estuary

The sorption of phenanthrene on the Yangtze Estuary sediment was studied under varying conditions of particle size, sediment organic contents, salinity, and dissolved organic matter (DOM) concentrations. Small sediment particles showed higher trapping capacity for phenanthrene due to the higher organic contents associated. The organic carbon-based partition coefficient of phenanthrene to the Yangtze Estuary sediment was obtained as 7120 L/kg, lower than the values for other soils or sediments reported in previous studies. The magnitude and direction of the salt effect were complicated by the specific DOM studied. The sediment sorption capacity was greatly increased in saline water in the absence of DOM but decreased in the presence of DOM. Given the conditions in the Yangtze Estuary, the equilibrium sorption of phenanthrene would be decreased with increasing salinity. Overall, the nature and content of both sediment-bound and dissolved organic matter dominate the sorption of hydrophobic organic contaminants in the estuary.     

How the capacity of bedrock to collect dust and produce soil affects phosphorus bioavailability in the northern Appalachian Mountains of Pennsylvania

More above-ground biomass (kg m⁻²) grows in the northern Appalachian Mountains (USA) in forests on shale than on sandstone at all landscape positions other than ridgetops. This has been tentatively attributed to physical (rather than chemical) attributes of the substrates, such as elevation, particle size, and water capacity. However, shales have generally similar phosphorus (P) concentrations to sandstones and, in the Valley and Ridge province, they erode more quickly. This led us to hypothesize that faster replenishment of the lithogenic nutrient P in shale soils through erosion + soil production could instead control the differences in biomass. To test this, soils and foliage from 10 sites on shales and sandstones in the northern Appalachians from roughly the same elevation and aspect were analysed. We discovered that, when controlling for location, concentrations of bioavailable P in soils and P in foliage were higher and P resorbed from senescing red oak leaves was lower on slower-eroding sandstone than on faster-eroding shale. Lower resorption generally can be attributed to lower P limitation for trees. Further investigation of weathering and erosion on one of the sandstone–shale pairs within a larger, paired watershed study revealed that the differences in P concentrations in biomass and foliage between lithologies likely developed because sandstones act as ‘collectors’ that trap nutrients from residual and exogenous sources, while shales erode quickly and thus promote production of soil from bedrock that releases P to ecosystems. We concluded that the combined effects of differential rates of dust collection and erosion results in roughly equal biomass growing on sandstone and shale ridgetops. This work emphasizes the balance between a landscape's capacity to collect dust versus produce soil in controlling bioavailability of nutrients.     

From soil aggregates to riverine flocs: a laboratory experiment assessing the respective effects of soil type and flow shear stress on particles characteristics

Particles eroded from hillslopes and exported to rivers are recognized to be composite particles of high internal complexity. Their architecture and composition are known to influence their transport behaviour within the water column relative to discrete particles. To‐date, hillslope erosion studies consider aggregates to be stable once they are detached from the soil matrix. However, lowland rivers and estuaries studies often suggest that particle structure and dynamics are controlled by flocculation within the water column. In order to improve the understanding of particle dynamics along the continuum from hillslopes to the lowland river environment, soil particle behaviour was tested under controlled laboratory conditions. Seven flume erosion and deposition experiments, designed to simulate a natural erosive event, and five shear cell experiments were performed using three contrasting materials: two of them were poorly developed and as such can not be considered as soils, whilst the third one was a calcareous brown soil. These experiments revealed that soil aggregates were prone to disaggregation within the water column and that flocculation may affect their size distribution during transport. Large differences in effective particle size were found between soil types during the rising limb of the bed shear stress sequence. Indeed, at the maximum applied bed shear stress, the aggregated particles median diameter was found to be three times larger for the well‐developed soil than for the two others. Differences were smaller in the falling limb, suggesting that soil aggregates underwent structural changes. However, characterization of particles strength parameters showed that these changes did not fully turn soil aggregates into flocs, but rather into hybrid soil aggregate–floc particles. Copyright © 2013 John Wiley & Sons, Ltd.     

Using OSL to assess hypotheses related to the impacts of land use change with the early nineteenth century arrival of Europeans in south‐eastern Australia: an exploratory case study from Grabben Gullen Creek,New South Wales

A common explanation for intense soil erosion and gullying in SE Australia is the introduction by Europeans of new land use practices following their arrival in Australia in the late 18th century. Eucalyptus woodlands were cleared to introduce farming, and valley bottoms, characterized by chains of ponds with organic‐rich swampy meadow (SM) soils, were subsequently buried by thick deposits of ‘post‐settlement alluvium’ (PSA) generated by erosion in the catchment. In this study, optically stimulated luminescence (OSL) is used to evaluate the source(s) of the PSA in Grabben Gullen Creek (GGC), Australia. We use a portable OSL reader to measure total photon counts on bulk polymineral and polygrain‐size samples from nine profiles along the Creek. We use these luminescence signals as geotracers of sediment source(s) and transport pathways. We obtained higher luminescence signals in the PSA than in the SM sediments, suggesting different sources and fluvial transport conditions for these two widespread sedimentary units. Portable OSL reader data from soils in the GGC catchment that are potential sources for the SM sediments and PSA show that the high luminescence signals recorded in the PSA are similar to those from subsoil samples in granite soils, suggesting that the PSA was derived by gullying of granite subsoils. In the SM sediments, luminescence signals decrease upwards from the base of the profile, as expected in well‐reset fluvial deposits, but with one or more changes in gradient in the profile of photon counts with depth, most likely indicating changes in sediment deposition rates. To calculate deposition rates in the SM sediments, several samples were dated using OSL. The OSL ages produced low scatter in the equivalent doses, confirming the well‐reset nature of the grains composing the SM and indicating a process of sediment transport in dilute flows, as is interpreted from the portable OSL signals. Copyright © 2014 John Wiley & Sons, Ltd.     

Lithology‐controlled evolution of stream bed sediment and basin‐scale sediment yields in adjacent mountain watersheds,Idaho, USA

The composition, grain‐size, and flux of stream sediment evolve downstream in response to variations in basin‐scale sediment delivery, channel network structure, and diminution during transport. Here, we document downstream changes in lithology and grain size within two adjacent ~300 km² catchments in the northern Rocky Mountains, USA, which drain differing mixtures of soft and resistant rock types, and where measured sediment yields differ two‐fold. We use a simple erosion–abrasion mass balance model to predict the downstream evolution of sediment flux and composition using a Monte Carlo approach constrained by measured sediment flux. Results show that the downstream evolution of the bed sediment composition is predictably related to changes in underlying geology, influencing the proportion of sediment carried as bedload or suspended load. In the Big Wood basin, particle abrasion reduces the proportion of fine‐grained sedimentary and volcanic rocks, depressing bedload in favor of suspended load. Reduced bedload transport leads to stronger bed armoring, and coarse granitic rocks are concentrated in the stream bed. By contrast, in the North Fork Big Lost basin, bedload yields are three times higher, the stream bed is less armored, and bed sediment becomes dominated by durable quartzitic sandstones. For both basins, the geology‐based mass balance model can reproduce within ~5% root‐mean‐square error the composition of the bed substrate using realistic erosion and abrasion parameters. As bed sediment evolves downstream, bedload fluxes increase and decrease as a function of the abrasion parameter and the frequency and size of tributary junctions, while suspended load increases steadily. Variable erosion and abrasion rates produce conditions of variable bed‐material transport rates that are sensitive to the distribution of lithologies and channel network structure, and, provided sufficient diversity in bedrock geology, measurements of bed sediment composition allow for an assessment of sediment source areas and yield using a simple modeling approach. Copyright © 2016 John Wiley & Sons, Ltd.     

Measuring sheet erosion using synthetic color‐contrast aggregates

The bulk of eroded soils measured at the outlets of plots, slopes and watersheds are suspended sediments, splash‐induced sheet erosion. It is depending on rainfall intensity and antecedent soil moisture contents and contributes to a significant proportion of soil loss that usually is ignored in soil erosion and sediment studies. A digital image processing method for tracing and measuring non‐suspended soil particles detached/transported by splash/runoff was therefore used in the present study. Accordingly, fine mineral pumice grains aggregated with white cement and coloured with yellow pigment powder, with the same size, shape and specific gravity as those of natural soil aggregates, called synthetic color‐contrast aggregates, were used as tracers for detecting soil particle movement. Subsequently, the amount of non‐suspended soil particles detached and moved downward the slope was inferred with the help of digital image processing techniques using MATLAB R2010B software (Mathworks, Natick, Massachusetts, USA). The present study was conducted under laboratory conditions with four simulated rainfall intensities between 30–90 mm h^‐1, five antecedent soil moisture contents between 12–44 % v v^‐1 and a slope of 30%, using sandy loam soils taken from a summer rangeland in the Alborz Mountains, Northern Iran. A range of total transported soil between 90.34 and 1360.93 g m^‐2 and net splash erosion between 36.82 and 295.78 g m^‐2were observed. The results also showed the sediment redeposition ratio ranging from 87.27% [sediment delivery ratio (SDR) = 12.73%] to 96.39% (SDR = 3.61%) in various antecedent soil moisture contents of rainfall intensity of 30 mm h^‐1 and from 80.55% (SDR = 19.45%) to 89.42% (SDR = 10.58%) in rainfall intensity of 90 mm h^‐1. Copyright © 2013 John Wiley & Sons, Ltd.     

Laboratory and theoretical evaluation of impact of packing density,particle shape,and uniformity coefficient on erodibility of coarse-grained soil particles

Sedimentation – including erosion, transport, and deposition of coarse-grained particles – is a primary and growing environmental, engineering, and agricultural issue around the world. Soil erosion occurs when the hydrodynamic force induced by flowing water exceeds the geotechnical resistance of soils, as measured by critical shear stress for initiation of soil-particle motion. Even though various quantitative methods have been suggested with respect to different types of soil, the most widely accepted formula to estimate critical shear stress for coarse-grained soil is a direct function of the median grain size of the soil particles; however, the erosion resistance of soils also varies with other geotechnical properties, such as packing density, particle shape, and uniformity coefficient. Thus, in this study, a combined rolling–lift model for particle detachment was derived based on theoretical analysis. A series of experimental flume tests were conducted with specimens prepared with standard soil types, as well as laboratory-prepared mixtures of coarse-grained soil to validate the theoretical model and determine the effect of other geotechnical properties on the erosion characteristics of coarse grains, coupled with the effect of median particle size. The results indicated that the median grain size is the primary variable determining the resistance of coarse grains, but the critical shear stress also varies with the packing density of the soil matrix. In addition, angular particles show more erosion resistance than rounded particles, and the erosion potential of a soil decreased when the grain is well graded (higher value of uniformity coefficient). Additionally, regression analysis was performed to quantify the effect of each parameter on the critical shear stress of coarse grains. © 2020 John Wiley & Sons, Ltd.