Cenomanian–Turonian carbon isotope stratigraphy of the Western Canadian Sedimentary Basin

The Cenomanian–Turonian boundary was characterized by distinctive positive carbon isotope excursions that were related to the formation of widespread oceanic anoxia. High-resolution geochemical proxies (TOC, CaCO₃, δ¹³C_org, and δ¹³C_carb) obtained from bulk rock, planktic foraminifers, and inoceramids from four marine marlstone-dominated stratigraphic sections in the Western Canada Sedimentary Basin (WCSB) were used to establish a regional carbon isotope stratigraphic framework and to investigate paleoenvironmental variability in four different depositional settings. Compared to background δ¹³C_org, (<−27‰) and δ¹³C_carb (<2‰) values which were correlative to stable isotope excursions during Oceanic Anoxic Event (OAE) II worldwide, the δ¹³C_org (>24‰), and δ¹³C_carb (>4‰) derived from inoceramid prisms in the studied sections within WCSB, were elevated during the Late Cenomanian–Early Turonian. During this interval, TOC and CaCO₃ values which increased sporadically to >40% and 7%, respectively, were not consistent enough to be used for stratigraphic correlations. Based on the δ¹³C_org excursions, two bentonite beds were regionally correlated across this portion of the Western Interior Seaway (WIS). The eruption associated with the “Red” bentonite occurred approximately coeval with the maximum δ¹³C_org-excursion during OAE II in the Neocardioceras juddii Zone, whereas the “Blue” bentonite coincides with the termination of OAE II in the latest Watinoceras devonense zone. During the Late Cenomanian–Early Turonian in the WCSB, benthic foraminifers were sparse or totally absent, indicating the existence of fully anoxic bottom-water conditions. Planktic foraminifera were common in the well-oxygenated surface waters. A benthic oxic zone characterized by several agglutinated species occurs in the eastern part of the WSCB at the beginning of OAE II in the Sciponoceras gracile zone. The termination of the OAE II in the WCSB coincides with the first occurrence of small ammonites (Subprionocyclus sp.) in the western part of the basin.     

Characterization of C‐isotope variability in the Delhi Supergroup,northwestern India and the Mesoproterozoic ocean

Marine carbonate rocks of the Delhi Supergroup of northwestern India show little deviation in whole‐rock δ ¹³Ccarb and δ ¹⁸Ocarb values, which generally are around 0 and –10‰ respectively. These narrow ranges and almost constant δ ¹³Ccarb values persist despite close sampling through long sections. The data suggest that the global rate of organic carbon burial was probably constant during deposition of the Delhi Supergroup. The nearly invariant C isotopic profile of the Delhi Supergroup is similar to C isotopic profiles of Mesoproterozoic carbonates older than 1.3 Ga, as reported from different parts of world. Carbonate units on the western margin of the Delhi Supergroup however, have on average moderately positive δ ¹³C values (from 2 to +4.96‰). These high δ ¹³C carbonates may represent the Mesoproterozoic–Neoproterozoic transition (from ～1.25 to ～0.85 Ga), a period characterized by high positive δ ¹³C values globally.     

The Lagoon of Venice： geological setting,evolution and land subsidence

The paper deals with the geological setting, history and subsidence of the Venetian Plain. Major attention is paid to the Pleistocene-Holocene stratigraphic sequence in the Lagoon of Venice, in relation to its origin that datesback to 6-7 kyr BP. Geological land subsidence, which played an important role in the origin and the evolution of the lagoon, and anthropogenic subsidence, that has recently assumed a major importance for the Venetian environment, are discussed. Considering also the sealevel rise, 23 cm loss in land elevation has occurred in the last century, leading to increased flooding events and environmental problems that require protective works.     

Late Quaternary seismic stratigraphy and geological development of the south Vøring margin,Norwegian Sea

High-resolution seismic data and sediment cores show that an up to 280 m thick sedimentary sequence has been deposited on the south Vøring margin, off mid-Norway, the last ca 250 ka. The sedimentary succession has been divided into six seismic units, dominated by hemipelagic sediments. Five wedge-shaped massive sequences, of marine isotope stages 8, 6 and 2, interfinger the hemipelagic deposits on the upper slope. The wedge-shaped sequences represent glacigenic debris flows that have been fed by till transported to the shelf edge by grounded ice sheets during maximum glaciations. The hemipelagic units show well-defined depocentres, of various thicknesses, on the upper continental slope. Seismic facies interpretation indicates that the sediment distribution locally has been controlled by currents. Commonly, the hemipelagic units are characterised by parallel and continuous reflectors. However, the second youngest unit identified, deposited between 15.7 and 15.0 ¹⁴C ka BP, is acoustic transparent. We suggest that this unit has been sourced by along-slope transported meltwater plume deposits, released during the initial stage of the last deglaciation of the Norwegian Channel. The hemipelagic sedimentation rates have varied considerably throughout the studied time period. Until ca 21 ¹⁴C ka BP the rates did not exceed 1.4 m/kyr, whereas during the Last Glacial Maximum the rates increased and reached values of about 36 m/kyr before decreasing again at ca 15 ¹⁴C ka BP. Observation of iceberg scourings, of MIS 8 age, about 800 m below the present day sea level, suggest that the south Vøring margin has subsided by a rate of 1.2 m/kyr in the Late Quaternary.     

Age,evolution and regional setting of the Palaeoproterozoic Umba igneous suite in the Kolvitsa–Umba zone,Kola Peninsula: constraints from new geological,geochemical and U–Pb zircon data

The Umba igneous complex consists of an enderbite–charnockite suite, including porphyritic variety of charnockites, and a porphyritic granite. Both are intruded by irregular veins or minor bodies of later reddish granite. The porphyritic charnockites locally contains abundant xenoliths of country rocks and its contamination by sedimentary material is expressed by a minor content of garnet, that increases in amount in areas with sedimentary inclusions. The Umba igneous complex and the Umba block metasediments were deformed together during two episodes of deformation. The first one was a major episode of thrusting with the formation of a penetrative shear foliation (S₁), which dips gently eastwards, and a gently SE-plunging lineation. Coeval with this thrusting, the boundary between the Umba block and the Poriya Guba series in the southeast developed as a strike-slip shear zone, that juxtaposed the two blocks along a tectonic melange zone. The S₁-shearing deformed the enderbite–charnockite suite, and probably also the porphyritic granite, into plate-like, eastward-dipping bodies. Predating the shearing, the metasediments underwent high-grade metamorphism and anatexis leading to a high degree of partial melting. This anatexis is also found in the enderbite–charnockite suite, but in a much smaller scale and mainly in the marginal parts of the bodies. The second episode of deformation formed narrow localized extensional shear zones (S₂), which are developed in all rock units. The S₁-shearing in the tectonic melange zone occurred under high-pressure metamorphism during cooling at constant pressure (T=806–818°C, P=9.3–9.5 kbar) and then at decreasing pressure due to tectonic uplift. Both seem to have gone through the same deformation events as the metasediments. The S₂-extension occurred under decompression (P=7.5–8.0 kbar, T=860–840°C) caused by uplift or tectonic erosion of the thrust pile. Though indistinguishable in the field the enderbite–charnockite suite form a discontinuous suite with a trondhjemitic trend for the former, and a calc–alkaline trend for the latter. Geochemical study shows that the charnockite group is more strongly differentiated than the enderbite group and that magmatic differentiation in the charnockites were controlled by K-feldspar fractionation. The enderbites, on the other hand, lack differentiation and are considered to have crystallized rapidly from its magma source. The charnockites came from a different source that, judging from the high K/Rb ratio, formed at a deeper crustal level than the enderbites. Both members of the enderbite–charnockite suite formed due to subduction in an island arc setting, and Sm–Nd model ages of 2.1–1.9 Ga indicate that the Palaeoproterozoic suite has a juvenile character. Conventional U-Pb zircon dating of the porphyritic charnockite has given discordant ages of 1912.5±7.7 Ma, 1949±7 Ma and 1966±9. Our preferred interpretation is that the 1912.5±7.7 Ma age represents the age of intrusion, or maximum intrusion age of the charnockites, and that the 1949±7 Ma and 1966±9 Ma ages for the abraded type represent ages or mixed ages of inherited zircons from the contaminating Umba block metasediments. The youngest detrital zircons in these metasediments have similar ages. Their source could have been early magmatic arc intrusives, which were eroded shortly after their formation. If the Umba metasediments were deposited in a magmatic arc setting their initial deformation in an evolving arc may have provided the necessary heat flow for anatexis and high-grade peak metamorphism of the metasediments. Therefore, the intrusions of the enderbite–charnokite suite during the later evolution of the magmatic arc could have post-dated the peak of metamorphism, but still pre-date collision and thrusting leading to tectonic telescoping of the units, and thus explain the lower metamorphic grade in the Umba igneous complex compared to the metasediments. If the 1912.5±7.7 Ma age represents the maximum time of intrusion, the true intrusion age might be slightly younger.     

Zircons,age, and geological setting of rhyodacite–porphyry from the Bagrusha Complex (South Urals)

Before our studies, it was considered that the Bagrusha rhyolite–porphyry complex (BC) including veins and thin dykes occurring in the Kusa region among deposits presumably of the Satka and Avzyan Formations of the Lower and Middle Riphean, respectively. Based on the U–Pb SHRIMP and IDTIMS studies of zircons from rhyodacite—porphyry, we established the age of the BC formation of T₀ = 1348.6 ± 3.2 Ma for the first time. The age obtained is inconsistent with the idea on the Paleozoic age of the BC and the geological situation shown on geological maps of the region. The age (T₀ = 1348.6 ± 3.2 Ma) of rhyodacite–porphyry from the BC provides evidence for acid volcanism controlled by the Mashak (Middle Riphean) magmatic event in the region, and deposits hosting volcanic rocks of the BC cannot be younger than the base of the Middle Riphean, i.e., the Mashak Formation, which was not previously distinguished by researchers in the western part of the Kusa and Bakal–Satka regions. At the same time, it is possible that deposits hosting dykes and veins of the granite–rhyolite formation may have a Bakal (Lower Riphean) age.     

Impact lithologies – a key for reconstruction of rock-forming processes and a geological model of the Popigai crater,northern Siberia

The 100-km diameter Popigai impact crater (astrobleme), which formed 35.7?Ma ago as a result of the collision of an ordinary chondrite asteroid, was discovered in the 1970s. The impact site was studied in detail for nearly two decades, and various geological investigations were performed there. They included drilling of numerous wells (about 850), geophysical surveys, and investigations of impact breccias and impactites. This research was generally performed in connection with the identification of the unique resource of industrial impact diamonds, which were found in impact rocks for the first time in the world. The extensive research data acquired over 20–30 years include geological maps, collections of rock samples and thin sections, core samples, etc. All these materials are stored in the Russian Research Geological Institute in St Petersburg. Although a lot of data on the Popigai crater have already been published, the available materials and new analytical methods offer the opportunity to obtain some new data on mechanisms of rock-forming processes during an impact event, to improve existing geological models, and to compare in detail all these features to those established in other large craters on the Earth. Modelling of the physical processes of impact cratering has been extended and new data contribute significantly to the study of impact cratering and other problems of comparative planetology. In particular, many different hypotheses of rock-forming mechanisms are tested, especially those of impact melting of various target lithologies, homogenisation of huge volumes of melt products, and their mode of ejection, deposition, cooling, etc.     

Attenuated basin‐margin sequence stratigraphy of the Palaeoproterozoic Calvert and Isa Superbasins: The Fickling Group,southern Murphy Inlier,Queensland

Sedimentary rocks of the Palaeoproterozoic Calvert and Isa Superbasins are exposed across a large area of northern Australia. Despite the extent of the exposures there is little to indicate the nature of the basin margins as most outcrop boundaries are structurally or erosionally defined, or the margins, where preserved, are concealed beneath younger basins. The Murphy Inlier, which forms the boundary between the Mt Isa and McArthur Basins, is unique in that on its southern flanks a basin‐margin succession is well‐preserved as the Fickling Group. A detailed sequence‐stratigraphic analysis of outcrop sections and well logs, supplemented by seismic reflection profiles and SHRIMP U–Pb zircon ages, shows that all seven supersequences of the Isa Superbasin and one supersequence from the older Calvert Superbasin are represented in the Fickling Group. Through this high‐resolution sequence‐stratigraphic framework, it is possible to accurately correlate chronostratigraphically equivalent strata from the McNamara Group on the central Lawn Hill Platform to the Fickling Group on the southern Murphy Inlier. Each supersequence thins substantially from the McNamara Group (～11 km thick) to the Fickling Group (<1 km thick). The combined effects of truncation and onlap of sequences over the Murphy Inlier basement high are responsible for the thinning. Major time breaks of up to 25 million years occur between supersequences in the Fickling Group. Erosional hiatuses are often manifested at the base of supersequences as conglomerate beds composed of silicified detritus from older strata. Sequences in the Fickling Group were generally deposited in a proximal basin‐margin setting, while sequences in the McNamara Group were deposited in distal basin depocentres. The proximal depositional setting of Fickling Group sequences reduces the number of thick carbonaceous shale and siltstone intervals, which often host Zn–Pb–Ag and Cu deposits in the McNamara Group. Many host sequences from the McNamara Group are also absent in the Fickling Group due to truncation and onlap pinchout. Consequently, the economic potential of Palaeoproterozoic strata on the southern Murphy Inlier is less than equivalent strata from the central Lawn Hill Platform. Despite this, potential does exist for future discoveries of economic mineral deposits in the Mt Les Siltstone and Walford Dolomite units of the Fickling Group.     

The nappe-hosted Hoshbulak MVT Zn–Pb deposit,Xinjiang, China: A review of the geological,elemental and stable isotopic constraints

The Hoshbulak Zn–Pb deposit is located in South Tianshan, Xinjiang, China. The Zn–Pb orebody is tabular and stratoid in form and it is hosted in calcareous rocks of the Upper Devonian Tan'gaitaer Formation which were thrust over the Carboniferous system. The ores are mineralogically simple and composed mainly of sphalerite, galena, pyrite, calcite, dolomite and exhibit massive, banded, veinlets, colloidal, metasomatic, eutectic, concentric ring and microbial-like fabrics. The Co/Ni ratios of pyrite in the ores range from 0.46 to 0.90 by electron microprobe, which suggested that the Hoshbulak Zn–Pb mineralization was formed in a sedimentary environment. The REE patterns of the hydrothermal calcite coincide well with those of recrystallized micritic limestones, suggesting that the Hoshbulak Pb–Zn mineralization was closely genetically related to limestones of the Tan'gaitaer Formation. The C-, H- and O-isotopic compositions of hydrothermal calcite and dolomite in the ores yield δ¹³C(VPDB) values ranging from − 1.9‰ to + 2.6‰ (mean 0.79‰), δ¹⁸O(VSMOW) values from 22.41‰ to 24.67‰ (mean 23.04‰) and δD values from − 77‰ to − 102‰ for fluid inclusions. It is suggested that the ore-forming fluids, including CO₂, were derived from the calcareous strata of the Tan'gaitaer Formation in association with hydrocarbon brines. The δ³⁴S(VCDT) ranges from − 22.3‰ to − 8.5‰ for early ore-stage sulfides and from 5.9‰ to 24.2‰ with a cluster between 14.4‰ and 24.2‰ for the sulfides (pyrite, sphalerite, galena) in the main ore-stage. The ore sulfur may have been derived from evaporite rocks by thermochemical sulfate reduction (TSR) as the predominant mechanism for H₂S generation. The Pb-isotopic compositions of the sulfide minerals from the Hoshbulak ores yield ²⁰⁶Pb/²⁰⁴Pb ratios from 17.847 to 18.173, ²⁰⁷Pb/²⁰⁴Pb ratios from 15.586 to 15.873 and ²⁰⁸Pb/²⁰⁴Pb ratios from 37.997 to 38.905, which indicate that the metals were sourced mainly from the Tan'gaitaer Formation. We conclude that the genesis of the Hoshbulak Mississippi Valley-type deposit was closely related to thrust faulting in the South Tianshan orogen of China.     

Impact of bioturbation on reservoir quality and production – A review

Bioturbation is a typically small scale yet potentially significant geological process altering rock properties by reworking. For many years, bioturbation studies found application in exploration geology to estimate paleobathymetry, interpreting depositional environment and identifying key stratigraphic surfaces. These act as vital inputs to the geological models, for determination of source rock potential, reservoir quality and modeling of petroleum systems. Recently geologists extended the application of bioturbation studies to address production related challenges. Recognizing the bioturbation effects and incorporating them in reservoir simulation models can improve production predictions and enhanced oil recovery operations. This paper discusses bioturbation and its effects on reservoir quality, its performance and production.     

Basement framework and geodynamic evolution of the Palaeoproterozoic superbasins of north‐central Australia: An integrated review of geochemical,geochronological and geophysical data

A largely convergent setting is proposed for crustal, tectonic and basin evolution of the intracratonic regions of north‐central Australia between 1800 and 1575 Ma. The new geodynamic model contrasts with previous proposals of widespread extension during the Leichhardt, Calvert and Isa intervals. Local transtensional to extensional structures exist, but these are best explained by a combination of flexural, thermal and dynamic processes related to an active southern margin. The development of thick accumulations of sediments (superbasins) is linked geodynamically to interpreted active margin processes (subduction and magmatic arcs) in central Australia. A synthesis of geochemical data from the 1870–1575 Ma igneous units from the Arnhem, McArthur and Mt Isa regions of north‐central Australia confirms the intracratonic setting of these units and suggests that a long‐lived thermal anomaly was responsible for the generation of both mafic and felsic magmas. The geochemical characteristics suggest the igneous units are derived from the lithospheric mantle and are not typical rift‐ or plume‐related melts. A review of the U–Pb SHRIMP ages for the entire region demonstrates the minimum distribution of correlative igneous rocks was widespread. Exotic populations in the ²⁰⁷Pb/²⁰⁶Pb isotopic data provide insights into the nature and evolution of the crust throughout north‐central Australia. Archaean inheritance is found to be nearly ubiquitous. The data support the temporal subdivision of north‐central Australia into the Leichhardt (1800–1750 Ma), Calvert (1750–1690 Ma) and Isa (1690–1575 Ma) intervals which are marked by superbasins and concomitant episodes of igneous activity. A highly heterogeneous pre‐superbasin crust is interpreted from regional, newly processed geophysical data. The cratonic portion of north‐central Australia is interpreted to consist of three broad northwest‐trending belts or elements that are further distinguished into western, central and eastern geophysically distinct provinces. A map of the superbasin distribution is derived and integrated with structural and stratigraphic data to assess the evolution of the basins and the crust through time. The superbasin successions of north‐central Australia are synchronous and widespread, although not necessarily interconnected. The tectonic model incorporates dynamic tilting of the craton during episodes of subduction and transmission of compressive intraplate stresses through the craton during intervening episodes of orogeny. These processes resulted in flexure, strike‐slip deformation and a complex thermal structure. These mechanisms account for the subsidence and basin evolution that results in widespread ramp and strike‐slip basins. The model also accounts for the thermal history recorded by magmatic events. The proposed geodynamical model provides a unifying crustal evolution scenario for central and northern Australia for approximately 225 million years of the Proterozoic.     

Petrogenesis of the Wudaogou intermediate–mafic complex,NW China: zircon U–Pb dating,whole-rock and isotope geochemistry,and geological implications

The Wudaogou plutonic complex is located in the eastern Yanbian area of Jilin Province and consists of hornblende gabbros, gabbroic diorites, and quartz diorites that contain abundant dioritic microgranular xenoliths. Zircon U–Pb dating of gabbroic and quartz diorites yielded weighted mean ²⁰⁶Pb/²³⁸Pb ages of 263.5 ± 5.1 Ma (N = 12, mean squared weighted deviation (MSWD) = 0.78, probability = 0.66) and 262.0 ± 5.6 Ma (N = 10, MSWD = 0.50, probability = 0.87), respectively. These units are characterized by high Na₂O/K₂O (0.33–0.77) ratios and Al₂O₃ (15.05–18.91 wt%) concentrations and are large ion lithophile element (LILE) (light rare earth element (LREE), Rb, Ba, K, etc.) enriched and high field strength element (HFSE) (Nb, Ta, P, Ti) depleted. They also have initial ⁸⁷Sr/⁸⁶Sr values of 0.70192–0.70420 and ?_Nd(t) values of +1.9 to +4.7 with two-stage model ages (T_DM2) of 653–878 Ma. These characteristics indicate that these rocks formed from calc–alkaline magmas derived from partial melting of a mixture of juvenile crust formed attending the Neoproterozoic subduction of the Palaeo-Asian oceanic crust and lower crustal material. The dioritic xenoliths have whole-rock compositions that are similar to their host rocks, but with negative ?_Nd(t) values (?1.6 to ?4.3) and older T_DM2 ages (1166–1382 Ma), further indicating that this magmatic event involved older crustal material. Combining these data with existing knowledge of the crustal evolution of this area, we conclude that this complex formed in a post-collisional extensional setting during closure of the Palaeo-Asian Ocean.     

Iron and lithium isotope systematics of the Hekla volcano,Iceland — Evidence for Fe isotope fractionation during magma differentiation

In this study potential iron isotope fractionation by magmatic processes in the Earth's crust was systematically investigated. High precision iron isotope analyses by MC-ICP-MS were performed on a suite of rock samples representative for the volcanic evolution of the Hekla volcano, Iceland. The whole series of Hekla's rocks results from several processes. (i) Basaltic magmas rise and induce partial melting of meta-basalts in the lower part of the Icelandic crust. The resulting dacitic magma evolves to rhyolitic composition through crystal fractionation. During this differentiation the δ^56/54Fe_IRMM-014 values increase successively from 0.051 ± 0.021‰ for the primitive dacites to 0.168 ± 0.021‰ for the rhyolites. This increase can be described by a Rayleigh fractionation model using a constant bulk fractionation factor between all mineral phases (M) and the silicate liquid (L) of Δ^56/54Fe_M–L = ? 0.1‰. (ii) The basaltic magma itself differentiates by crystal fractionation to basaltic andesite composition. No Fe isotope fractionation was found in this series. All basalts and basaltic andesites have an average δ^56/54Fe_IRMM-014 value of 0.062 ± 0.042‰ (2SD, n = 9), identical to mean terrestrial basaltic values reported in previous studies. This observation is consistent with the limited removal of iron from the remaining silicate melt through crystal fractionation and small mineral-melt Fe isotope fractionation factors expected at temperatures in excess of 1050 °C. (iii) Andesites are produced by mixing of basaltic andesite with dacitic melts. The iron isotope composition of the andesites is matching that of the basaltic andesites and the less evolved dacites, in agreement with a mixing process. In the Hekla volcanic suite Li concentrations are positively correlated with indicators of magma differentiation. All Hekla rocks have δ⁷Li values typical for the upper mantle and demonstrate the absence of resolvable Li isotope fractionation during crystal fractionation. As a fluid-mobile trace element, Li concentrations and isotopes are a potential tracer of magma/fluid interaction. At Hekla, Li concentrations and isotope compositions do not indicate any extensive fluid exsolution. Hence, the heavy Fe isotope composition of the dacites and rhyolites can be predominately attributed to fractional crystallisation. Iron isotope analyses on single samples from other Icelandic volcanoes (Torfajökull, Vestmannaeyjar) confirm heavy Fe isotope enrichment in evolving magmas. Our results suggest that the iron isotope composition of highly evolved crust can be slightly modified by magmatic processes.     

Deposition and tectonic setting of the Palaeoproterozoic Castelo dos Sonhos metasedimentary formation,Tapajós Gold Province,Amazonian Craton,Brazil: age and isotopic constraints

The Castelo dos Sonhos Formation (CSF) represents a relic of a sedimentary basin located in the southeastern Tapajós Gold Province (TGP), at its boundary with the Iriri–Xingu Domain (IX), south of the Amazonian Craton. The formation comprises mature, coarse-grained metasandstones (quartz-arenites) intercalated with auriferous metaconglomerates with clasts of quartz and subordinately of banded iron formation, quartzite, schist, and felsic metavolcanic rocks. Lithology, planar, channelled, and large-scale cross-bedding suggest deposition in continental setting by the braided fluvial system associated with alluvial fans and subordinate aeolian dunes. The rocks underwent very low metamorphism and gently synformal folding, and were intruded by andesites and granitoids (2011–1918 Ma). U–Pb LA-ICP-MS zircon data indicate maximum depositional ages of 2050 Ma (metaconglomerate) and 2074, 2088, and 2104 Ma (metasandstones). Hence, deposition occurred at 2050–2011 Ma, slightly preceding or being coeval with the onset of the orogenic phase in TGP (2030–1956 Ma). The quartz-arenite composition, zircon U–Pb data, and negative εHf (?1.3 to ?13.0) and εNd (?2.9 to ?5.3) values indicate: (1) quartzose provenance, (2) prolonged transport and recycling of sedimentary sources, (3) multiple age peaks (2050–3700 Ma), with predominant sources of 2100 and 2750 Ma, and (4) long crustal residence time for the source rocks. Source areas were Rhyacian–Siderian orogenic belts to Mesoarchaean terranes of the Amazonian Craton located to the east, southeast, and northeast of TGP, along with Palaeoarchaean and Eoarchaean detrital zircons recycled from older sedimentary rocks. We interpret CSF as part of a larger foreland system related to the evolution of Rhyacian orogens, currently represented by the Bacajá and Santana do Araguaia domains. The present location of CSF in the easternmost TGP, close to its boundary with IX, is due to rifting (1.89–1.80 Ga) that produced the Uatumã Silicic Large Igneous Province (Uatumã SLIP), and the juxtaposition of the crustal domains is supported by gravity data.     

Fluid inclusion and carbon, oxygen, and strontium isotope study of the Polaris Mississippi Valley-type Zn–Pb deposit, Canadian Arctic Archipelago: implications for ore genesis

The Polaris deposit is one of the largest Mississippi Valley-type deposits in the world, with 22 million tonnes of ore at 14% Zn and 4% Pb contained in a single, compact orebody surrounded by dolomitized host rocks. Using detailed sampling of carbonates in the orebody and the dolostone halo, this paper aims to characterize the temporal and spatial evolution of the mineralizing system, and to understand the mechanisms that controlled the accumulation of this large, compact Zn–Pb deposit. Five types of dolomite have been distinguished, including three replacement (RD) and two pore-filling dolomites (PD). The paragenetic order is RD1, RD2, RD3, PD1, and PD2. Pore-filling calcite (PC) postdates all other minerals. In most cases, sulfides and dolomite did not co-precipitate, but sphalerite and galena largely overlap with RD3 and PD1. Various dolomites are dissolved or replaced by sulfide-precipitating fluids; sulfides in turn can be overgrown by dolomites. Colloform texture in sphalerite is widespread. Fluid inclusions were studied in RD3, PD1, PD2, sphalerite, and PC. The overall ranges of homogenization temperatures (T _h) and last ice-melting temperatures (T _m-ice) for fluid inclusions in dolomites and sphalerite are from 67 to 141 °C and from −46.7 to −27.0 °C, respectively, consistent with warm basinal brines with high salinities and Ca/Na ratios. Gas chromatographic analysis of these fluid inclusions indicates low concentrations of hydrocarbons (<0.06 mol%). C, O, and Sr isotopes were analyzed for all dolomites and PC, as well as for the fine-grained host limestone and early diagenetic calcite (SC–RC). The isotopic values of RD2, RD3, PD1, and PD2 cluster tightly and form largely overlapping domains. With respect to the host limestone, they are depleted in ¹⁸O, similar in δ¹³C, and slightly enriched in ⁸⁷Sr. There are no regular spatial variations for fluid inclusion and isotope data, indicating an overall geochemical homogeneity in the hydrothermal system. However, certain samples close to the fracture zones in the orebody with slightly elevated T _h and ⁸⁷Sr/⁸⁶Sr values and depleted δ¹⁸O values suggest that the fracture zone was the conduit for the hot brines. Based on the geological and geochemical characteristics of the deposit, we propose that sulfide precipitation at Polaris was caused by mixing of a reduced, metal-rich, sulfur-poor fluid with a reduced, metal-poor, sulfur-rich fluid at the site of mineralization. The metal-carrying fluid ascended along fractures from below the deposit and was hotter than the host rocks, whereas the reduced sulfur-carrying fluid was delivered to the site of mineralization laterally and was in thermal equilibrium with the host rocks. This model can readily explain the dissolution of dolomite during sulfide precipitation and the abundance of colloform sphalerite, as well as the low concentrations of hydrocarbons in fluid inclusions. Accepted: 20 December 1999     

LA-ICP-MS mineral chemistry of titanite and the geological implications for exploration of porphyry Cu deposits in the Jinshajiang – Red River alkaline igneous belt,SW China

The Jinshajiang–Red River alkaline igneous belt in the eastern Indian–Asian collision zone, of southwestern China, hosts abundant, economically important Cu–Mo–Au mineralization of Cenozoic age. Major- and trace-element compositions of titanites from representative Cu-mineralized intrusions determined by LA-ICP-MS show higher values for Fe₂O₃/Al₂O₃, ΣREE?+?Y, LREE/HREE, Ce/Ce*, (Ce/Ce*)/(Eu/Eu*), U, Th, Ta, Nb and Ga, and lower values for Al₂O₃, CaO, Eu/Eu*, Zr/Hf, Nb/Ta and Sr than those for titanites from barren intrusions. Different ΣREE?+?Y, LREE/HREE, U, Th, Ta and Nb values of titanites between Cu-mineralized and barren intrusions were controlled mainly by the coexisting melt compositions. However, different Sr concentrations and negative Eu anomalies of titanites between Cu-mineralized and barren intrusions were most probably caused by different degrees of crystallization of feldspar from melts. In addition, different Ga concentrations and positive Ce anomalies of titanites between Cu-mineralized and barren intrusions were most likely caused by different magmatic fO₂ conditions. Pronounced compositional differences of titanites between Cu-mineralized and barren intrusions can provide a useful tool to help discriminate between ore-bearing and barren intrusions at an early stage of exploration, and, thus, have a potential application in exploration for porphyry Cu deposits in the Jinshajiang – Red River alkaline igneous belt, and to other areas.     

Geology and tectonics of Japanese islands: A review – The key to understanding the geology of Asia

The age of the major geological units in Japan ranges from Cambrian to Quaternary. Precambrian basement is, however, expected, as the provenance of by detrital clasts of conglomerate, detrital zircons of metamorphic and sedimentary rocks, and as metamorphic rocks intruded by 500 Ma granites. Although rocks of Paleozoic age are not widely distributed, rocks and formations of late Mesozoic to Cenozoic can be found easily throughout Japan. Rocks of Jurassic age occur mainly in the Jurassic accretionary complexes, which comprise the backbone of the Japanese archipelago. The western part of Japan is composed mainly of Cretaceous to Paleogene felsic volcanic and plutonic rocks and accretionary complexes. The eastern part of the country is covered extensively by Neogene sedimentary and volcanic rocks. During the Quaternary, volcanoes erupted in various parts of Japan, and alluvial plains were formed along the coastlines of the Japanese Islands. These geological units are divided by age and origin: i.e. Paleozoic continental margin; Paleozoic island arc; Paleozoic accretionary complexes; Mesozoic to Paleogene accretionary complexes and Cenozoic island arcs. These are further subdivided into the following tectonic units, e.g. Hida; Oki; Unazuki; Hida Gaien; Higo; Hitachi; Kurosegawa; South Kitakami; Nagato-Renge; Nedamo; Akiyoshi; Ultra-Tamba; Suo; Maizuru; Mino-Tamba; Chichibu; Chizu; Ryoke; Sanbagawa and Shimanto belts.The geological history of Japan commenced with the breakup of the Rodinia super continent, at about 750 Ma. At about 500 Ma, the Paleo-Pacific oceanic plate began to be subducted beneath the continental margin of the South China Block. Since then, Proto-Japan has been located on the convergent margin of East Asia for about 500 Ma. In this tectonic setting, the most significant tectonic events recorded in the geology of Japan are subduction–accretion, paired metamorphism, arc volcanism, back-arc spreading and arc–arc collision. The major accretionary complexes in the Japanese Islands are of Permian, Jurassic and Cretaceous–Paleogene age. These accretionary complexes became altered locally to low-temperature and high-pressure metamorphic, or high-temperature and low-pressure metamorphic rocks. Medium-pressure metamorphic rocks are limited to the Unazuki and Higo belts. Major plutonism occurred in Paleozoic, Mesozoic and Cenozoic time. Early Paleozoic Cambrian igneous activity is recorded as granites in the South Kitakami Belt. Late Paleozoic igneous activity is recognized in the Hida Belt. During Cretaceous to Paleogene time, extensive igneous activity occurred in Japan. The youngest granite in Japan is the Takidani Granite intruded at about 1–2 Ma. During Cenozoic time, the most important geologic events are back-arc opening and arc–arc collision. The major back-arc basins are the Sea of Japan and the Shikoku and Chishima basins. Arc–arc collision occurred between the Honshu and Izu-Bonin arcs, and the Honshu and Chishima arcs.     

Structure and stratigraphy of the Teplá–Barrandian Neoproterozoic,Bohemian Massif: A new plate-tectonic reinterpretation

The Teplá–Barrandian unit (TBU) of the Bohemian Massif exposes a section across the once extensive Avalonian–Cadomian belt, which bordered the northern active margin of Gondwana during late Neoproterozoic. This paper synthesizes the state-of-the-art knowledge on the Cadomian basement of the TBU to redefine its principal component units, to revise an outdated stratigraphic scheme, and to interpret this scheme in terms of a recent plate-tectonic model for the Cadomian orogeny in the Bohemian Massif. The main emphasis of this paper is on an area between two newly defined fronts of the Variscan pervasive deformation to the NW and SE of the Barrandian Lower Paleozoic overlap successions. This area has escaped the pervasive Variscan (late Devonian to early Carboniferous) ductile reworking and a section through the Cadomian orogen is here superbly preserved.The NW segment of the TBU consists of three juxtaposed allochthonous belts of unknown stratigraphic relation (the Kralovice–Rakovník, Radnice–Kralupy, and Zbiroh–?árka belts), differing in lithology, complex internal strain patterns, and containing sedimentary and tectonic mélanges with blocks of diverse ocean floor (meta-)basalts. We summarize these three belts under a new term the Blovice complex, which we believe represents a part of an accretionary wedge of the Cadomian orogen.The SE segment of the TBU exposes the narrow Pi?ín belt, which is probably a continuation of the Blovice complex from beneath the Barrandian Lower Paleozoic, and a volcanic arc sequence (the Davle Group). Their stratigraphic relation is unknown. Flysch units (the ?těchovice Group and Svrchnice Formation) overlay the arc volcanics, and both units contain material derived from volcanic arc. The former was also sourced from the NW segment, whereas the latter contains an increased amount of passive margin continental material. In contrast to the Blovice complex, the flysch experienced only weak Cadomian deformation.The new lithotectonic zonation fits the following tectonic scenario for the Cadomian evolution of the TBU well. The S- to SE-directed Cadomian subduction beneath the TBU led to the involvement of turbidites, chaotic deposits, and 605 ± 39 Ma ocean floor in the accretionary wedge represented by the Blovice complex. The accretionary wedge formation mostly overlapped temporally with the growth of the volcanic arc (the Davle Group) at ~ 620–560 Ma. Upon cessation of the arc igneous activity, the rear of the wedge and some elevated portions of the arc were eroded to supply the deep-water flysch sequences of the ?těchovice Group, whereas the comparable Svrchnice Formation (~ 560 to < 544 Ma) was deposited in a southeasterly remnant basin close to the continental margin. The Cadomian orogeny in the TBU was terminated at ~ 550–540 Ma by slab breakoff, by final attachment of the most outboard ~ 540 Ma oceanic crust, and by intrusion of ~ 544–524 Ma boninite dikes marking the transition from the destructive to transform margin during the early/middle Cambrian.     

Hydrothermal alteration and associated mineralization in the Freda-Rebecca gold deposit – Bindura District, Zimbabwe

The Freda-Rebecca Mine is currently the largest gold producer in Zimbabwe. The ore deposit is hosted by two main shear systems crosscutting the Rebecca diorite and Bindura granodiorite (2.65 Ga) as well as Shamvaian metasediments, which are affected by contact metamorphism. Following the intrusion of the Bindura granodiorite, intensive hydrothermal alteration developed preferentially in the dioritic part of the igneous complex (Rebecca diorite). The hydrothermal alteration started with an extensive K-dominated hydrothermal metasomatism in the whole Rebecca diorite. It was followed by less penetrative hydrothermal alteration developed preferentially near shear zones and veinlets. Hydrothermal metasomatism caused microcline and biotite formation, prevailing in the Rebecca diorite. Two main stages of post-metasomatic hydrothermal alteration and mineralization were distinguished, based on spatial relationships between different minerals and some geochemical aspects. In the first stage, an actinolite-tourmaline-arsenopyrite mineralization formed, which is characterized by Ni-Co arsenopyrite associated with actinolite, tourmaline and quartz. The second, lower temperature stage gave a polyphase gold-rich mineralization that developed in four phases which are distinguished by different parageneses including: Phase 1. Actinolite, chlorite, clinozoisite/epidote, quartz, calcite, arsenopyrite, pyrite, pyrrhotite, chalcopyrite. Phase 2. Chlorite, epidote, calcite, gold, native Bi, Bi-Pb sulfides, galena, chalcopyrite, fahlore, pyrite, Fe-gersdorffite. Phase 3. Epidote, calcite, (Ni, Co, Fe) As S phases, Co-Fe-gersdorffite. Phase 4. Chlorite, calcite, quartz. The gold mineralization is exclusively associated with phase 2 and developed in three sulfide parageneses: – Gold + Bi-Pb sulfides + bismuth + chalcopyrite + galena, associated with chlorite (Au 1). – Gold + galena + pyrite, associated with calcite and chlorite (Au 2). – Gold + pyrite + Fe-gersdorffite, associated with epidote, chlorite and calcite (Au 3). The hydrothermal alteration and mineralization formed after the consolidation of the Rebecca diorite and Bindura granodiorite, most probably in the postmagmatic cooling stage. The mineralization was emplaced either synchronously or subsequently to the shear zones which crosscut the consolidated pluton. Not all shear zones are mineralized and different shear zones show different amounts of mineralization and hydrothermal alteration. Thus, it is suggested that during the cooling stage of the pluton and subsequent to the formation of the K-metasomatic zone (microcline + biotite), hydrothermal fluids preferentially followed just forming or pre-existing shear zones. It cannot be excluded that this process developed in a plutonic porphyry copper-like environment, in which the classically hydrothermal zonation did not form due to synchronous tectonic disturbance, which preferentially drives the hydrothermal flow along shear zones. Mineral parageneses and data from chlorite geothermometry indicate that the different stages and phases of hydrothermal alteration reflect cooling stages of the hydrothermal system, from >300 °C in the first stage to about 150 °C in the last phases. Received: 4 January 1999 / Accepted: 13 August 1999