Water balance analysis for the Tonle Sap Lake–floodplain system

The Tonle Sap Lake of Cambodia is the largest freshwater body of Southeast Asia, forming an important part of the Mekong River system. The lake has an extremely productive ecosystem and operates as a natural floodwater reservoir for the lower Mekong Basin, offering flood protection and assuring the dry season flow to the Mekong Delta. In light of the accelerating pace of water resources development within the Mekong Basin and the anticipation of potentially significant hydrological impacts, it is critical to understand the overall hydrologic regime of Tonle Sap Lake. We present here a detailed water balance model based on observed data of discharges from the lake's tributaries, discharge between Mekong and the lake through the Tonle Sap River, precipitation, and evaporation. The overland flow between the Mekong and lake was modelled with the EIA 3D hydrodynamic model. We found that majority (53.5%) of the water originates from the Mekong mainstream, but the lake's tributaries also play an important role contributing 34% of the annual flow, while 12.5% is derived from precipitation. The water level in the lake is mainly controlled by the water level in the Mekong mainstream. The Tonle Sap system is hence very vulnerable, from a water quantity point of view, to possible changes in the Mekong mainstream and thus, development activities in the whole Mekong basin. From a biogeochemical point of view, the possible changes in the lake's own catchment are equally important, together with the changes in the whole Mekong Basin. Based on our findings, we recommend of continuing the monitoring programmes in lake's tributaries and urgently starting of groundwater measurement campaign within the floodplain, and including the groundwater modelling to be part of the hydrodynamic models applied for the lake. Copyright © 2013 John Wiley & Sons, Ltd.     

A Tube Seepage Meter for In Situ Measurement of Seepage Rate and Groundwater Sampling

We designed and evaluated a “tube seepage meter” for point measurements of vertical seepage rates (q), collecting groundwater samples, and estimating vertical hydraulic conductivity (K) in streambeds. Laboratory testing in artificial streambeds show that seepage rates from the tube seepage meter agreed well with expected values. Results of field testing of the tube seepage meter in a sandy‐bottom stream with a mean seepage rate of about 0.5 m/day agreed well with Darcian estimates (vertical hydraulic conductivity times head gradient) when averaged over multiple measurements. The uncertainties in q and K were evaluated with a Monte Carlo method and are typically 20% and 60%, respectively, for field data, and depend on the magnitude of the hydraulic gradient and the uncertainty in head measurements. The primary advantages of the tube seepage meter are its small footprint, concurrent and colocated assessments of q and K, and that it can also be configured as a self‐purging groundwater‐sampling device.     

Quantification of TCE Co‐Oxidation in Groundwater Using a 14C–Assay

Bacteria that degrade natural organic matter in groundwater contain oxygenase enzymes that can co‐oxidize trichloroethene (TCE). This degradation pathway is promising for large dilute plumes, but its evaluation is limited because the density of the bacteria with oxygenase enzymes has not been correlated to field scale rates of degradation. A ¹⁴C–TCE assay was developed to determine pseudo first‐order rate constants for the aerobic co‐oxidation of TCE in groundwater. The assay involved incubating ¹⁴C–TCE in samples of groundwater contained in 160 mL serum bottles, and monitoring the accumulation of radiolabel in degradation products. A first‐order rate constant for co‐oxidation was extracted from the rate of accumulation of ¹⁴C in products, accounting for volumetric changes in the serum bottles due to sampling and subsequent changes to the distribution of TCE between the aqueous and gaseous phases. Of the groundwater samples evaluated from 19 wells at five sites, eight samples at three sites had ¹⁴C product accumulation rates that exceeded the accumulation rate in filter‐sterilized groundwater controls. First‐order rate constants ranged from 2.65 to 0.0066 year^?1, which is equivalent to half‐lives of 0.26 to 105 years. Groundwater samples from a few of the wells in which co‐oxidation occurred had volatile organic contaminants in addition to TCE; their presence may have induced the oxygenase enzymes that are needed for TCE co‐oxidation. ¹⁴CO₂ represented ~37% to 97% of the ¹⁴C products that accumulated; the balance of the products was soluble and non‐volatile.     

Data‐Driven Approach for Analyzing Hydrogeology and Groundwater Quality Across Multiple Scales

Recent trends of assimilating water well records into statewide databases provide a new opportunity for evaluating spatial dynamics of groundwater quality and quantity. However, these datasets are scarcely rigorously analyzed to address larger scientific problems because they are of lower quality and massive. We develop an approach for utilizing well databases to analyze physical and geochemical aspects of groundwater systems, and apply it to a multiscale investigation of the sources and dynamics of chloride (Cl^?) in the near‐surface groundwater of the Lower Peninsula of Michigan. Nearly 500,000 static water levels (SWLs) were critically evaluated, extracted, and analyzed to delineate long‐term, average groundwater flow patterns using a nonstationary kriging technique at the basin‐scale (i.e., across the entire peninsula). Two regions identified as major basin‐scale discharge zones—the Michigan and Saginaw Lowlands—were further analyzed with regional‐ and local‐scale SWL models. Groundwater valleys (“discharge” zones) and mounds (“recharge” zones) were identified for all models, and the proportions of wells with elevated Cl^? concentrations in each zone were calculated, visualized, and compared. Concentrations in discharge zones, where groundwater is expected to flow primarily upwards, are consistently and significantly higher than those in recharge zones. A synoptic sampling campaign in the Michigan Lowlands revealed concentrations generally increase with depth, a trend noted in previous studies of the Saginaw Lowlands. These strong, consistent SWL and Cl^? distribution patterns across multiple scales suggest that a deep source (i.e., Michigan brines) is the primary cause for the elevated chloride concentrations observed in discharge areas across the peninsula.     

Closed‐Form Approximations for Two‐Dimensional Groundwater Age Patterns in a Fresh Water Lens

Simple closed‐form approximations are presented for calculating the steady‐state groundwater age distribution in two‐dimensional vertical cross sections of idealized fresh water lenses overlying salt water, for aquifers that are vertically semi‐infinite and of finite thickness. The approximations are developed on the basis of existing one‐dimensional analytical solutions for travel‐time calculation in fresh water lenses and approximate streamline formulations. The two‐dimensional age distributions based on the closed‐form solutions match convincingly with numerical simulations. As expected, notable deviations from the numerical solution are encountered at the groundwater flow divide and when submarine groundwater discharge occurs. Ratios of recharge over hydraulic conductivities are varied to explore how the magnitude of the deviations changes, and it is found that the approximate closed‐form solutions perform well over a range of conditions found in natural systems.     

Field‐Scale Relationships Among Soil Properties and Shallow Groundwater Quality

It is important to understand the link between land surface/soil properties and shallow groundwater quality. To that end, soil properties and near‐water‐table groundwater chemistry of a shallow, unconfined aquifer were measured on a 100‐m grid on a 64‐ha irrigated field in southeastern North Dakota. Soil properties and hydrochemistry were compared via multivariate analysis that included product‐moment correlations and factor analysis/principal component analysis. Topographic low areas where the water table was in close proximity to the soil surface generally had higher apparent electrical conductivity (EC_a) and higher percent silt and clay than higher positions on the landscape. The majority of the groundwater was characterized by Ca‐ and Mg‐HCO₃ type water and was associated with topographic high areas with lower EC_a and net groundwater recharge. Small topographic depressions were areas of higher EC_a (net groundwater discharge) where salts that precipitated via evapotranspiration and evaporative discharge dissolved and leached to the groundwater during short‐term depression‐focused recharge events. At this site, groundwater quality and soil EC_a were related to surface topography. High‐resolution topography and EC_a measurements are necessary to characterize the land surface/soil properties and surficial groundwater quality at the field‐scale and to delineate areas where the shallow groundwater is most susceptible to contamination.     

Groundwater Resources and Their Role in Water Supply to Crimea

The processes of formation and distribution of the resources of fresh groundwater and surface water in the territory of Crimea Peninsula are considered. Water availability in the natural–historic and administrative regions of the republic is characterized. The proportions between different categories of groundwater resources are shown with their role in water supply to Crimea taken into account. The presentday development of groundwater resources is analyzed and the possible increase in water consumption meeting geoecological requirements is substantiated.     

Modeling Steady Sea Water Intrusion with Single‐Density Groundwater Codes

Steady interface flow in heterogeneous aquifer systems is simulated with single‐density groundwater codes by using transformed values for the hydraulic conductivity and thickness of the aquifers and aquitards. For example, unconfined interface flow may be simulated with a transformed model by setting the base of the aquifer to sea level and by multiplying the hydraulic conductivity with 41 (for sea water density of 1025 kg/m³). Similar transformations are derived for unconfined interface flow with a finite aquifer base and for confined multi‐aquifer interface flow. The head and flow distribution are identical in the transformed and original model domains. The location of the interface is obtained through application of the Ghyben‐Herzberg formula. The transformed problem may be solved with a single‐density code that is able to simulate unconfined flow where the saturated thickness is a linear function of the head and, depending on the boundary conditions, the code needs to be able to simulate dry cells where the saturated thickness is zero. For multi‐aquifer interface flow, an additional requirement is that the code must be able to handle vertical leakage in situations where flow in an aquifer is unconfined while there is also flow in the aquifer directly above it. Specific examples and limitations are discussed for the application of the approach with MODFLOW. Comparisons between exact interface flow solutions and MODFLOW solutions of the transformed model domain show good agreement. The presented approach is an efficient alternative to running transient sea water intrusion models until steady state is reached.     

Groundwater Quality Impacts from a Full‐Scale Integrated Constructed Wetland

The concept of integrated constructed wetlands (ICW) promotes in‐situ soils to construct and line wetland cells. The integrity of soil material, however, may provide a potential pathway for contaminants to flow into the underlying groundwater. This study assessed the extent of groundwater quality deterioration due to the establishment of a full‐scale ICW system treating domestic wastewater in Ireland. The ICW is located at Glaslough in Co. Monaghan, Ireland. It consists of two sedimentation ponds and a sequence of five shallow vegetated wetland cells. The ICW cells were lined with 500‐mm thick local subsoil material, which comprised a mixture of alluvium, organic soils, tills, and gravel. Groundwater samples and head data were collected from eight piezometers, which were installed around the ICW cells. The groundwater and wetland water samples were analysed for water quality parameters such as bulk organic matter, nutrients, and pathogens. Overall, the quality of groundwater underlying the ICW system recorded some contamination with bulk organic matter and some inorganic nutrients. Significantly higher contaminant concentrations were recorded in monitoring wells upgradient and near to the distal wetland cells than downgradient ones, which were near to the proximal cells. For the downgradient piezometers, concentrations seldomly exceeded the natural background levels. Detailed analyses through the application of chemometrics models indicated that the source of contamination was largely of geogenic origin. Findings suggest that ICW systems pose a minimal risk to the groundwater quality; the greatest risk was associated with the distal wetland cells.     

Monitoring of Impact of Ferti‐irrigation by Post‐methanated Distillery Effluent on Groundwater Quality

The impact assessment of molasses‐based distillery‐effluent irrigation on groundwater quality around village Gajraula in the district of Jyotiba Phule Nagar, Uttar Pradesh, India was studied by sampling groundwater on monthly intervals consecutively for summer, winter and monsoon seasons during 2006–2007 and water quality parameters, viz. pH, electrical conductivity (EC), chloride (Cl^?), sulphate (SO), nitrate (NO), chemical oxygen demand (COD), total solids (TS), total dissolved solids (TDS), sodium (Na⁺), potassium (K⁺), calcium (Ca²⁺), magnesium (Mg²⁺), zinc (Zn²⁺), iron (Fe³⁺), and total coliforms (TC) were monitored. Results depicted that the values of all parameters decreased with increasing depth of water table. Sulphate, nitrate and potassium contents were maximal in agricultural site during monsoon while EC, Cl^?, TS, TDS, Na⁺, Ca²⁺, Mg²⁺, Zn, and Fe were maximal in industrial sites during summer. Groundwater samples of residential site harboured maximum coliforms especially during monsoon, highlighting threat to groundwater. Significant positive correlation matrix between coliforms with nitrate, sulphate and potassium ions explained their survival on these nutrients. To overcome this, important measures emphasizing improvement in effluent treatment technology matching site‐specific characteristics are recommended for eco‐friendly ferti‐irrigation.     

1DTempPro V2: New Features for Inferring Groundwater/Surface‐Water Exchange

A new version of the computer program 1DTempPro extends the original code to include new capabilities for (1) automated parameter estimation, (2) layer heterogeneity, and (3) time‐varying specific discharge. The code serves as an interface to the U.S. Geological Survey model VS2DH and supports analysis of vertical one‐dimensional temperature profiles under saturated flow conditions to assess groundwater/surface‐water exchange and estimate hydraulic conductivity for cases where hydraulic head is known.     

Applying the HPT‐GWS for Hydrostratigraphy,Water Quality and Aquifer Recharge Investigations

The primary objective of this study was to evaluate use of the hydraulic profiling tool‐groundwater sampler (HPT‐GWS) log data as an indicator of water quality (level of dissolved ionic species) in an alluvial aquifer. The HPT‐GWS probe is designed for direct push advancement into unconsolidated formations. The system provides both injection pressure logs and electrical conductivity (EC) logs, and groundwater may be sampled at multiple depths as the probe is advanced (profiling). The combination of these three capabilities in one probe has not previously been available. During field work it was observed that when HPT corrected pressure (P_c) indicates a consistent aquifer unit then bulk formation EC can be used as an indicator of water quality. A high correlation coefficient (R ² = 0.93) was observed between groundwater specific conductance and bulk formation EC in the sands and gravels of the alluvial aquifer studied. These results indicate that groundwater specific conductance is exerting a controlling influence on the bulk formation EC of the coarse‐grained unit at this site, and probably many similar sites, consistent with Archie's Law. This simple relationship enables the use of the EC and P_c logs, with targeted water samples and a minimum of core samples, to rapidly assess groundwater quality over extended areas at high vertical resolution. This method was used to identify both a brine impacted zone at the base of the aquifer investigated and a groundwater recharge lens developing below storm water holding ponds in the upper portion of the same aquifer. Sample results for trace level, naturally occurring elements (As, Ba, U) further demonstrate the use of this system to sample for low level groundwater contamination.     

Assessment of Groundwater Quality at Yuncheng Basin: Denotation for the Water Management in China

Dramatic decreases in groundwater quality have raised widespread concerns about water supplies and ecological crises in China. In this study, hydrochemistry, stable isotopes, and graphical and multivariate statistical methods are integrated to identify hydrogeochemical processes controlling groundwater quality in the Yuncheng Basin, China. Our results show that groundwater with 21 variables (pH, temperature-T, total dissolved solid, major-trace elements, and stable isotopes) is chemically classified into three distinct clusters: fresh water [C1], brackish-saline water [C2], and saline water [C3]. Groundwater salinization is identified as the prime process in controlling groundwater quality for shallow groundwater and deep groundwater in the lowland areas. Large-scale As, F, or B contaminations found in groundwater are closely related to groundwater salinization, agricultural activity, and the exploration of geothermal water in the area. With respect to the risk of contamination, groundwater in the basin is spatially divided into the following: shallow groundwater with a high risk located in the north side of the Salt Lake, shallow groundwater with a moderate risk, and deep groundwater with a low to moderate risk. Nationally, the increasing demand on groundwater is threatened by a range of environmental and health pressures, including salinization and contaminations of nitrate, As, F, or B. Our study indicates that natural water-rock interactions and hydrogeological conditions are significant factors controlling these contaminations. Systematic management and regulation of existing groundwater resources are required to prevent further deterioration of groundwater resources. Policies should be made and implemented to ensure “green” exploitation of geothermal water.     

Homotopy Perturbation Method‐Based Analytical Solution for Tide‐Induced Groundwater Fluctuations

The groundwater variations in unconfined aquifers are governed by the nonlinear Boussinesq's equation. Analytical solution for groundwater fluctuations in coastal aquifers under tidal forcing can be solved using perturbation methods. However, the perturbation parameters should be properly selected and predefined for traditional perturbation methods. In this study, a new dimensional, higher‐order analytical solution for groundwater fluctuations is proposed by using the homotopy perturbation method with a virtual perturbation parameter. Parameter‐expansion method is used to remove the secular terms generated during the solution process. The solution does not require any predefined perturbation parameter and valid for higher values of amplitude parameter A/D, where A is the amplitude of the tide and D is the aquifer thickness.     

Field Investigation of Vapor‐Phase‐Based Groundwater Monitoring

The use of in‐field analysis of vapor‐phase samples to provide real‐time volatile organic compound (VOC) concentrations in groundwater has the potential to streamline monitoring by simplifying the sample collection and analysis process. A field validation program was completed to (1) evaluate methods for collection of vapor samples from monitoring wells and (2) evaluate the accuracy and precision of field‐portable instruments for the analysis of vapor‐phase samples. The field program evaluated three vapor‐phase sample collection methods: (1) headspace samples from two locations within the well, (2) passive vapor diffusion (PVD) samplers placed at the screened interval of the well, and (3) field vapor headspace analysis of groundwater samples. Two types of instruments were tested: a field‐portable gas chromatograph (GC) and a photoionization detector (PID). Field GC analysis of PVD samples showed no bias and good correlation to laboratory analysis of groundwater collected by low‐flow sampling (slope = 0.96, R² = 0.85) and laboratory analysis of passive water diffusion bag samples from the well screen (slope = 1.03; R² = 0.96). Field GC analysis of well headspace samples, either from the upper portion of the well or at the water‐vapor interface, resulted in higher variability and much poorer correlation (consistently biased low) relative to laboratory analysis of groundwater samples collected by low‐flow sample or passive diffusion bags (PDBs) (slope = 0.69 to 0.76; R² = 0.60 to 0.64). These results indicate that field analysis of vapor‐phase samples can be used to obtain accurate measurements of VOC concentrations in groundwater. However, vapor samples collected from the well headspace were not in equilibrium with water collected from the well screen. Instead, PVD samplers placed in the screened interval represent the most promising approach for field‐based measurement of groundwater concentrations using vapor monitoring techniques and will be the focus of further field testing.