Aerobic respiration in riparian exchange zones of regulated river corridors

River stage fluctuations drive surface water-groundwater exchanges within river corridors. This study evaluates how repeated daily stage fluctuations, representative of hydropeaking conditions, influence aerobic respiration of river-sourced dissolved organic carbon (DOC) in the riparian exchange zone using reactive flow and transport simulations. Over 50 hypothetical scenarios were modelled to evaluate how the duration of the daily flood signal, river DOC concentration, aquifer hydraulic conductivity and ambient groundwater flow condition affect the fate and transport of DOC and DO in the riparian aquifer. Time series subsurface snapshots highlight how the various factors influence the subsurface distribution of DOC and DO. The total mass of DOC respired per meter of river had a wide range depending on the parameters, spanning from 1.4 to 71 g over 24-h, with high hydraulic conductivity and losing ambient groundwater flow conditions favouring the largest amount of DOC respired. The ratio of DOC mass entering the riparian zone with the mass returning to the river showed that as little as 5% to as much as 76% of the DOC that enters the bank during stage fluctuations returns to the river. This return ratio is dependent on river DOC concentration, hydraulic conductivity and ambient groundwater flow. The results illustrate that stage variations due to river regulation can be a significant control on aerobic respiration in riparian exchange zones.     

Melt water driven stream and groundwater stage fluctuations on a glacier forefield (Dammagletscher,Switzerland)

In many mountain regions, large land areas with heterogeneous soils have become ice‐free with the ongoing glacier retreat. On these recently formed proglacial fields, the melt of the remaining glaciers typically drives pronounced diurnal stream level fluctuations that propagate into the riparian zone. This behaviour was measured on the Damma glacier forefield in central Switzerland with stage recorders in the stream and groundwater monitoring wells along four transects. In spite of the large groundwater stage variations, radon measurements in the near‐stream riparian zone indicate that there is little mixing between stream water and groundwater on daily time scales. At all four transects, including both losing and gaining reaches, the groundwater level fluctuations lagged the stream stage variations and were often damped with distance from the stream. Similar behaviours have been modelled using the diffusion equation in coastal regions influenced by tidal sea level variations. We thus tested the ability of such a model to predict groundwater level fluctuations in proglacial fields. The model reproduced several key features of the observed fluctuations at three of four locations, although discrepancies also arise due to non representative input data and model simplifications. Nevertheless, calibration of the model for the individual transects yielded realistic estimates of hydraulic diffusivities between the stream and groundwater monitoring wells. We conclude that studying diurnal groundwater fluctuations can provide important information about the subsurface hydrology of alpine watersheds dominated by glacier melt. Copyright © 2012 John Wiley & Sons, Ltd.     

Effects of riparian vegetation on stream bank subaerial processes in southwestern Virginia,USA

Riparian vegetation is frequently used for stream bank stabilization, but the effects of vegetation on subaerial processes have not been quantified. Subaerial processes, such as soil desiccation and freeze–thaw cycling, are climate‐related phenomena that deliver soil directly to the stream and make the banks more vulnerable to fluvial erosion by reducing soil strength. This study compares the impact of woody and herbaceous vegetation on subaerial processes by examining soil temperature and moisture regimes in vegetated stream banks. Soil temperature and water tension were measured at six paired field sites in southwestern Virginia, USA, for one year. Results showed that stream banks with herbaceous vegetation had higher soil temperatures and a greater diurnal temperature range during the summer compared to forested stream banks. Daily average summer soil water tension was 13 to 57 per cent higher under herbaceous vegetation than under woody vegetation, probably due to evapotranspiration from the shallow herbaceous root system on the bank. In contrast to summer conditions, the deciduous forest buffers provided little protection for stream banks during the winter: the forested stream banks experienced diurnal temperature ranges two to three times greater than stream banks under dense herbaceous cover and underwent as many as eight times the number of freeze–thaw cycles. During the winter, the stream banks under the deciduous forests were exposed to solar heating and night time cooling, which increased the diurnal soil temperature range and the occurrence of freeze–thaw cycling. Study results also indicated that freeze–thaw cycling and soil desiccation were greater on the upper stream bank due to thermal and moisture regulation of the lower bank by the stream. Therefore, subaerial erosion and soil weakening may be greater on the upper stream banks. Additional research is needed on the influence of subaerial processes on both subaerial and fluvial erosion. Copyright © 2006 John Wiley & Sons, Ltd.     

The importance of incorporating diurnally fluctuating stream discharge in stream temperature energy balance models

Although stream temperature energy balance models are useful to predict temperature through time and space, a major unresolved question is whether fluctuations in stream discharge reduce model accuracy when not exactly represented. However, high‐frequency (e.g., subdaily) discharge observations are often unavailable for such simulations, and therefore, diurnal streamflow fluctuations are not typically represented in energy balance models. These fluctuations are common due to evapotranspiration, snow pack or glacial melt, tidal influences within estuaries, and regulated river flows. In this work, we show when to account for diurnally fluctuating streamflow. To investigate how diurnal streamflow fluctuations affect predicted stream temperatures, we used a deterministic stream temperature model to simulate stream temperature along a reach in the Quilcayhuanca Valley, Peru, where discharge varies diurnally due to glacial melt. Diurnally fluctuating streamflow was varied alongside groundwater contributions via a series of computational experiments to assess how uncertainty in reach hydrology may impact simulated stream temperature. Results indicated that stream temperatures were more sensitive to the rate of groundwater inflow to the reach compared with the timing and amplitude of diurnal fluctuations in streamflow. Although incorporating observed diurnal fluctuations in discharge resulted in a small improvement in model RMSE, we also assessed other diurnal discharge signals and found that high amplitude signals were more influential on modelled stream temperatures when the discharge peaked at specific times. Results also showed that regardless of the diurnal discharge signal, the estimated groundwater flux to the reach only varied from 1.7% to 11.7% of the upstream discharge. However, diurnal discharge fluctuations likely have a stronger influence over longer reaches and in streams where the daily range in discharge is larger, indicating that diurnal fluctuations in stream discharge should be considered in certain settings.     

Nitrate attenuation in soil and shallow groundwater under a bottomland hedgerow in a European farming landscape

In many agricultural areas, hedgerows give rise to strong expectations of reducing the inputs of excess nitrate to the groundwater and rivers. This study aims to analyse the spatial and seasonal influences of a hedgerow on nitrate dynamics in the soil and groundwater. Nitrate (NO₃^?) and chloride (Cl^?) concentrations were measured with spatially dense sampling in the unsaturated soil and in the groundwater along a transect intersecting a bottomland oak (Quercus rubor) hedgerow after the growing season and during the dormant season. We explain NO₃^? dynamics by using Cl^? as an index of tree‐root extension and water transfer. At the end of the growing season, NO₃^? is entirely absorbed by the trees over a large and deep volume corresponding to the rooting zone, where, in contrast Cl^? is highly concentrated due to root exclusion. However, these observed patterns in the soil have no influence on the deep groundwater composition at this season. During the dormant season, water transfer processes feeding the shallow groundwater layer are different upslope and downslope from the hedgerow in relation to the thickness of the unsaturated zone. Upslope, the shallow groundwater is fed by rainwater infiltration through the soil which favours Cl^? dilution. Right under the hedge and downslope, the rapid ascent of the groundwater near the ground surface prevents rainwater input and Cl^? dilution. Under the hedgerow the highest concentrations of Cl^? coincide with the absence of NO₃^? in the shallow groundwater layer and with high concentrations of dissolved organic carbon. The absence of NO₃^? during the dormant season seems to be due to denitrification in the hedgerow rooting zone when it is rapidly saturated by groundwater. Copyright © 2011 John Wiley & Sons, Ltd.     

Landscape structure,groundwater dynamics,and soil water content influence soil respiration across riparian–hillslope transitions in the Tenderfoot Creek Experimental Forest,Montana

Variability in soil respiration at various spatial and temporal scales has been the focus of much research over the last decade aimed to improve our understanding and parameterization of physical and environmental controls on this flux. However, few studies have assessed the control of landscape position and groundwater table dynamics on the spatiotemporal variability of soil respiration. We investigated growing season soil respiration in a ～393 ha subalpine watershed in Montana across eight riparian–hillslope transitions that differed in slope, upslope accumulated area (UAA), aspect, and groundwater table dynamics. We collected daily‐to‐weekly measurements of soil water content (SWC), soil temperature, soil CO₂ concentrations, surface CO₂ efflux, and groundwater table depth, as well as soil C and N concentrations at 32 locations from June to August 2005. Instantaneous soil surface CO₂ efflux was not significantly different within or among riparian and hillslope zones at monthly timescales. However, cumulative integration of CO₂ efflux during the 83‐day growing season showed that efflux in the wetter riparian zones was ～25% greater than in the adjacent drier hillslopes. Furthermore, greater cumulative growing season efflux occurred in areas with high UAA and gentle slopes, where groundwater tables were higher and more persistent. Our findings reveal the influence of landscape position and groundwater table dynamics on riparian versus hillslope soil CO₂ efflux and the importance of time integration for assessment of soil CO₂ dynamics, which is critical for landscape‐scale simulation and modelling of soil CO₂ efflux in complex landscapes. Copyright © 2010 John Wiley & Sons, Ltd.     

Identification of groundwater recharge sources and processes in a heterogeneous alluvial aquifer: results from multi‐level monitoring of hydrochemistry and environmental isotopes in a riverside agricultural area in Korea

We evaluated sources and pathways of groundwater recharge for a heterogeneous alluvial aquifer beneath an agricultural field, based on multi‐level monitoring of hydrochemistry and environmental isotopes of a riverside groundwater system at Buyeo, Korea. Two distinct groundwater zones were identified with depth: (1) a shallow oxic groundwater zone, characterized by elevated concentrations of NO₃^? and (2) a deeper (>10–14 m from the ground surface) sub‐oxic groundwater zone with high concentrations of dissolved Fe, silica, and HCO₃^?, but little nitrate. The change of redox zones occurred at a depth where the aquifer sediments change from an upper sandy stratum to a silty stratum with mud caps. The δ¹⁸O and δ²H values of groundwater were also different between the two zones. Hydrochemical and δ¹⁸O? δ²H data of oxic groundwater are similar to those of soil water. This illustrates that recharge of oxic groundwater mainly occurs through direct infiltration of rain and irrigation water in the sandy soil area where vegetable cropping with abundant fertilizer use is predominant. Oxic groundwater is therefore severely contaminated by agrochemical pollutants such as nitrate. In contrast, deeper sub‐oxic groundwater contains only small amounts of dissolved oxygen (DO) and NO₃^?. The ³H contents and elevated silica concentrations in sub‐oxic groundwater indicate a somewhat longer mean residence time of groundwater within this part of the aquifer. Sub‐oxic groundwater was also characterized by higher δ¹⁸O and δ²H values and lower d‐excess values, indicating significant evaporation during recharge. We suggest that recharge of sub‐oxic groundwater occurs in the areas of paddy rice fields where standing irrigation and rain water are affected by strong evaporation, and that reducing conditions develop during subsequent sub‐surface infiltration. This study illustrates the existence of two groundwater bodies with different recharge processes within an alluvial aquifer. Copyright © 2009 John Wiley & Sons, Ltd.     

Fine‐scale characteristics of groundwater flow in a peatland

Fine‐scale dynamics of groundwater flow were studied in a 1·5 ha peatland in central New York. Measurements of the hydraulic head throughout a detailed network of piezometer clusters revealed spatial and temporal variability in the direction of groundwater flow at a very fine (within a few metres) scale of analysis. Within the small wetland, there were areas of groundwater recharge, discharge and lateral flow. Such patterns of groundwater flow frequently reversed or changed due to fluctuations of only a few centimetres in hydraulic head. Specific conductance, deuterium signatures and calcium concentrations of groundwater corroborated the groundwater flow patterns determined with hydraulic head measurements and illustrated the influence of source water chemistry and evaporation on different layers in the peat column. The control of peat chemistry by such fine‐scale groundwater flow may have important implications for plant community composition and diversity in groundwater‐fed peatlands. Copyright © 1999 John Wiley & Sons, Ltd.     

Diurnal dynamics of streamflow in an upland forested micro‐watershed during short precipitation‐free periods is altered by tree sap flow

Diurnal variations in streamflow are becoming acknowledged as a way of analysing how changing climatic conditions and land use affects watersheds but also as a way to understand watersheds as a whole. Yet not many studies from uplands below 900 mm mean annual precipitation zone are available from European countries. During the 2012 growing season, a sampling campaign took place in an upland forested micro‐watershed, Czech Republic (65 ha). Tree sap flow, rainfall and temperature were measured continuously, while streamflow at the discharge point and soil moisture were estimated from short‐term measurements. Short precipitation‐free periods lasting several days were identified for evaluation of trends in diurnal dynamics of both sap flow and streamflow. The results demonstrated that during these periods, the main factor altering streamflow was almost exclusively tree sap flow. A decrease in streamflow was observed during the day and an increase at night. The decline in sap flow after sunset was accompanied by a continuous increase in streamflow throughout the night up to its initial maximum in the morning. The amplitude in diurnal variations reached 18%. The observed time lag between the diurnal variations of sap flow and streamflow was approximately 2 h. Relatively low changes in diurnal dynamics of streamflow pointed out a strong regulatory role of the forest in buffering water discharge from the catchment. Copyright © 2015 John Wiley & Sons, Ltd.     

Microbial Mineralization of Dichloroethene and Vinyl Chloride under Hypoxic Conditions

Mineralization of ¹⁴C‐radiolabled vinyl chloride ([1,2‐¹⁴C] VC) and cis‐dichloroethene ([1,2‐¹⁴C] cis‐DCE) under hypoxic (initial dissolved oxygen (DO) concentrations about 0.1 mg/L) and nominally anoxic (DO minimum detection limit = 0.01 mg/L) was examined in chloroethene‐exposed sediments from two groundwater and two surface water sites. The results show significant VC and dichloroethene (DCE) mineralization under hypoxic conditions. All the sample treatments exhibited pseudo‐first‐order kinetics for DCE and VC mineralization over an extended range of substrate concentrations. First‐order rates for VC mineralization were approximately 1 to 2 orders of magnitude higher in hypoxic groundwater sediment treatments and at least three times higher in hypoxic surface water sediment treatments than in the respective anoxic treatments. For VC, oxygen‐linked processes accounted for 65 to 85% of mineralization at DO concentrations below 0.1 mg/L, and ¹⁴CO₂ was the only degradation product observed in VC treatments under hypoxic conditions. Because the lower detection limit for DO concentrations measured in the field is typically 0.1 to 0.5 mg/L, these results indicate that oxygen‐linked VC and DCE biodegradation can be significant under field conditions that appear anoxic. Furthermore, because rates of VC mineralization exceeded rates of DCE mineralization under hypoxic conditions, DCE accumulation without concomitant accumulation of VC may not be evidence of a DCE degradative “stall” in chloroethene plumes. Significantly, mineralization of VC above the level that could reasonably be attributed to residual DO contamination was also observed in several nominally anoxic (DO minimum detection limit = 0.01 mg/L) microcosm treatments.     

A Mathematical View of Water Table Fluctuations in a Shallow Aquifer in Brazil

Detailed monitoring of the groundwater table can provide important data about both short‐ and long‐term aquifer processes, including information useful for estimating recharge and facilitating groundwater modeling and remediation efforts. In this paper, we presents results of 4 years (2002 to 2005) of monitoring groundwater water levels in the Rio Claro Aquifer using observation wells drilled at the Rio Claro campus of São Paulo State University in Brazil. The data were used to follow natural periodic fluctuations in the water table, specifically those resulting from earth tides and seasonal recharge cycles. Statistical analyses included methods of time‐series analysis using Fourier analysis, cross‐correlation, and R/S analysis. Relationships could be established between rainfall and well recovery, as well as the persistence and degree of autocorrelation of the water table variations. We further used numerical solutions of the Richards equation to obtain estimates of the recharge rate and seasonable groundwater fluctuations. Seasonable soil moisture transit times through the vadose zone obtained with the numerical solution were very close to those obtained with the cross‐correlation analysis. We also employed a little‐used deep drainage boundary condition to obtain estimates of seasonable water table fluctuations, which were found to be consistent with observed transient groundwater levels during the period of study.     

Impacts of riparian zone plant water use on temporal scaling of groundwater systems

In this work, we study groundwater system temporal scaling in relation to plant water use and near‐river‐stage fluctuations in riparian zones where phreatophytes exist. Using detrended fluctuation analysis (DFA), we investigate the influence of regular diurnal fluctuations due to phreatophyte water use on temporal scaling properties of groundwater level variations. We found that groundwater use by phreatophytes, at the field site on the Colorado River, USA, results in distinctive crossovers (slope changes when the plots are fitted with straight lines) in the logarithm plots of root‐mean‐square fluctuations of the detrended water level time series versus time scales of groundwater level dynamics. For groundwater levels monitored at wells close to the river, we identified one crossover at ～1 day in the scaling characteristics of groundwater level variations. When time scale exceeds 1 day, the scaling properties decrease from persistent to close to 1/f noise, where f is the frequency. For groundwater levels recorded at wells further away from the river, the slope of the straight line fit (i.e. scaling exponent) is smallest when the time scale is between 1 and 3 days. When the time scale is < 1 day, groundwater variations become persistent. When the time scale is between 1 and 3 days, the variations are close to white noise, but return to persistent when the time scale is > 3 days. Copyright © 2011 John Wiley & Sons, Ltd.     

Denitrifying bacteria and hydrogeochemistry in a natural wetland adjacent to farmlands in Chiba,Japan

This study combined bacterial incubation and hydrogeochemical methods to investigate denitrification in the surface water, top soil (0–20 cm), and shallow groundwater of the Ochi wetland in Japan. Surface water was rich in nitrate (40 mg/l) and denitrifying bacteria (700 per ml). Three functional zones in the wetland were identified in the top soil and shallow groundwater. In the upstream portion of the wetland (Zone I), the counts of denitrifying bacteria in top soil increased from 5200 to 14 970 per ml and nitrate decreased from 25·4 to 1·8 mg/l. Organic carbon concentrations decreased as sulfate increased from 4·0 to 9·6 mg/l in this zone. In the middle‐stream of the wetland (Zone II), all concentrations of major anions, iron, organic carbon, and total nitrogen content in top soil were relatively constant, but the counts of denitrifying bacteria increased up to 70 200 per ml. In the downstream portion of the wetland (Zone III), complete removal of nitrate resulted in sharp reduction of counts of denitrifying bacteria. Correspondingly, dissolved oxygen (DO), organic carbon, and total nitrogen increased in this zone. Counts of denitrifying bacteria were lower in shallow groundwater than in top soil; nitrate concentrations in shallow groundwater were also very low in this zone. DO and the oxidation/reduction potential data suggest that groundwater flows to the surface along an extended flow path, thus providing nitrate for the denitrifying community. Copyright © 2011 John Wiley & Sons, Ltd.     

Effects of bedrock groundwater discharge on spatial variability of dissolved carbon,nitrogen, and phosphorous concentrations in stream water within a forest headwater catchment

The quantitative evaluation of the effects of bedrock groundwater discharge on spatial variability of stream dissolved organic carbon (DOC), dissolved inorganic nitrogen (DIN) and dissolved inorganic phosphorous (DIP) concentrations has still been insufficient. We examined the relationships between stream DOC, DIN and DIP concentrations and bedrock groundwater contribution to stream water in forest headwater catchments in warm-humid climate zones. We sampled stream water and bedrock springs at multiple points in September and December 2013 in a 5 km² forest headwater catchment in Japan and sampled groundwater in soil layer in small hillslopes. We assumed that stream water consisted of four end members, groundwater in soil layer and three types of bedrock groundwater, and calculated the contributions of each end member to stream water from mineral-derived solute concentrations. DOC, DIN and DIP concentrations in stream water were compared with the calculated bedrock groundwater contribution. The bedrock groundwater contribution had significant negative linear correlation with stream DOC concentration, no significant correlation with stream DIN concentration, and significant positive linear correlation with stream DIP concentration. These results highlighted the importance of bedrock groundwater discharge in establishing stream DOC and DIP concentrations. In addition, stream DOC and DIP concentrations were higher and lower, respectively, than those expected from end member mixing of groundwater in soil layer and bedrock springs. Spatial heterogeneity of DOC and DIP concentrations in groundwater and/or in-stream DOC production and DIP uptake were the probable reasons for these discrepancies. Our results indicate that the relationships between spatial variability of stream DOC, DIN and DIP concentrations and bedrock groundwater contribution are useful for comparing the processes that affect stream DOC, DIN and DIP concentrations among catchments beyond the spatial heterogeneity of hydrological and biogeochemical processes within a catchment.     

Imaging Hydrological Processes in Headwater Riparian Seeps with Time‐Lapse Electrical Resistivity

Delineating hydrologic and pedogenic factors influencing groundwater flow in riparian zones is central in understanding pathways of water and nutrient transport. In this study, we combined two‐dimensional time‐lapse electrical resistivity imaging (ERI) (depth of investigation approximately 2 m) with hydrometric monitoring to examine hydrological processes in the riparian area of FD‐36, a small (0.4 km²) agricultural headwater basin in the Valley and Ridge region of east‐central Pennsylvania. We selected two contrasting study sites, including a seep with groundwater discharge and an adjacent area lacking such seepage. Both sites were underlain by a fragipan at 0.6 m. We then monitored changes in electrical resistivity, shallow groundwater, and nitrate‐N concentrations as a series of storms transitioned the landscape from dry to wet conditions. Time‐lapse ERI revealed different resistivity patterns between seep and non‐seep areas during the study period. Notably, the seep displayed strong resistivity reductions (～60%) along a vertically aligned region of the soil profile, which coincided with strong upward hydraulic gradients recorded in a grid of nested piezometers (0.2‐ and 0.6‐m depth). These patterns suggested a hydraulic connection between the seep and the nitrate‐rich shallow groundwater system below the fragipan, which enabled groundwater and associated nitrate‐N to discharge through the fragipan to the surface. In contrast, time‐lapse ERI indicated no such connections in the non‐seep area, with infiltrated rainwater presumably perched above the fragipan. Results highlight the value of pairing time‐lapse ERI with hydrometric and water quality monitoring to illuminate possible groundwater and nutrient flow pathways to seeps in headwater riparian areas.     

Local diurnal upwelling driven by sea breezes in northern Monterey Bay

Sea breezes often have significant impacts on nearshore physical and biological processes. We document the effects of a diurnal sea breeze on the nearshore thermal structure and circulation of northern Monterey Bay, California, using an array of moorings during the summer upwelling season in 2006. Moorings were equipped with thermistors and Acoustic Doppler Current Profilers (ADCPs) to measure temperature and currents along the inner shelf in the bay. Temperature and current data were characteristic of traditional regional scale upwelling conditions along the central California coast during the study period. However, large diurnal fluctuations in temperature (up to 5 °C) were observed at all moorings inshore of the 60-m isobath. Examination of tidal, current, temperature, and wind records revealed that the observed temperature fluctuations were the result of local diurnal upwelling, and not a result of nearshore mixing events. Westerly diurnal sea breezes led to offshore Ekman transport of surface waters. Resulting currents in the upper mixed layer were up to 0.10 m s⁻¹ directed offshore during the afternoon upwelling period. Surface water temperatures rapidly decreased in response to offshore advection of surface waters and upwelling of cold, subsurface water, despite occurring in the mid-afternoon during the period of highest solar heat flux. Surface waters then warmed again during the night and early morning as winds relaxed and the upwelling shadow moved back to shore due to an unbalanced onshore pressure gradient. Examination of season-long, moored time series showed that local diurnal upwelling is a common, persistent feature in this location. Local diurnal upwelling may supply nutrients to nearshore kelp beds, and transport larvae to nearshore habitats.     

Performance of the White method for estimating groundwater evapotranspiration under conditions of deep and fluctuating groundwater

The White method is a simple but the most frequently applied approach to estimate groundwater evapotranspiration (ET_g) from groundwater level diurnal signals. Because of a lack of direct measurements of ET_g, it is difficult to evaluate the performance of the White method, particularly in field environments with variable groundwater fluctuations. A 2‐year field observation in a hyper‐arid riparian tamarisk (Tamarix spp.) stand with deep groundwater depth in the lower Tarim River basin of China was conducted to measure the surface evapotranspiration (ET_s) and groundwater table. The performance of the White method and the influences of the variable groundwater fluctuations on the determinations of the specific yield (S_y) and recharge rate of groundwater (r) in the White method were investigated. The results showed that the readily available S_y determined by Loheide's method was feasible but must be finely determined based on the soil textures in the layers in which the groundwater level fluctuated. A constant S_y value for a defined porous medium could be assumed regardless of the discharge or recharge processes of groundwater. The time span of 0000 h to 0600 h for r estimation for the White method worked best than other time spans. A 2‐day moving average of r values further enhance ET_g estimation. Slight effects of environmental or anthropogenic disturbances on the diurnal fluctuations of groundwater level did not influence the ET_g estimations by the White method. Our results provide valuable references to the application of the White method for estimating daily ET_g in desert riparian forests with deep groundwater depth. Copyright © 2015 John Wiley & Sons, Ltd.     

The impact of pipe flow in riparian peat deposits on nitrate transport and removal

The effect of preferential flow in soil pipes on nitrate retention in riparian zones is poorly understood. The characteristics of soil pipes and their influence on patterns of groundwater transport and nitrate dynamics were studied along four transects in a 1‐ to >3‐m deep layer of peat and marl overlying an oxic sand aquifer in a riparian zone in southern Ontario, Canada. The peat‐marl deposit, which consisted of several horizontal layers with large differences in bulk density, contained soil pipes that were generally 0.1 to 0.2 m in diameter and often extended vertically for 1 to >2 m. Springs that produced overland flow across the riparian area occurred at some sites where pipes extended to the peat surface. Concentrations of NO₃^?–N (20–30 mg L^?1) and dissolved oxygen (DO) (4–6 mg L^?1) observed in peat pipe systems and surface springs were similar to values in the underlying sand aquifer, indicating that preferential flow transported groundwater with limited nitrate depletion. Low NO₃^?–N concentrations of <5 mg L^?1 and enriched δ¹⁵N values indicated that denitrification was restricted to small areas of the peat where pipes were absent. Groundwater DO concentrations declined rapidly to <2 mg L^?1 in the peat matrix adjacent to pipes, whereas high NO₃^?–N concentrations of >15 mg L^?1 extended over a larger zone. Low dissolved organic carbon values at these locations suggest that supplies of organic carbon were not sufficient to support high rates of denitrification, despite low DO conditions. These data indicate that it is important to develop a greater understanding of pipes in peat deposits, which function as sites where the transport of large fluxes of water with low biogeochemical reaction rates can limit the nitrate removal capacity of riparian zones. Copyright © 2011 John Wiley & Sons, Ltd.     

Total Dissolved Gas Pressure Measurements for Assessing Contaminant Degradation Processes in Groundwater

The total dissolved gas pressure (P_TDG ) probe has been used in groundwater studies for over a decade, but rarely in assessing contaminant degradation, despite the many degradation reactions that produce or consume dissolved gases. Here we present three studies to demonstrate the application of P_TDG measurements to groundwater experiencing contaminant degradation, with discussion of its benefits and limitations. The first study is a pilot‐scale laboratory experiment simulating dissolved ethanol contamination of an anaerobic sand aquifer. Continuous monitoring of P_TDG showed the rapid onset of microbial hydrocarbon degradation via denitrification and fermentation. The subsequent formation of a gas phase was revealed when P_TDG began mimicking the bubbling pressure (P_G *; sum of hydrostatic and atmospheric pressure), fluctuating with atmospheric pressure. Some deviations of P_TDG above P_G * occurred also, which may hold promise for signalling substantial changes in the rate or type of degradation process (here, the onset of methanogenesis). In the second study, synoptic field measurements at a petroleum plume site demonstrated how elevated P_TDG could identify wells with evidence of hydrocarbon degradation (denitrification and/or methanogenesis). And finally, combined field measurements of dissolved oxygen (DO) and P_TDG in monitoring wells of a nitrate‐contaminated aquifer (Abbottsford‐Sumas) revealed areas where denitrification was likely occurring. Limitations to P_TDG use identified in these studies included the masking of degradation processes by the presence of a gas phase, as when trapped following water table fluctuations or formed from rigorous degradation reactions, and confounded assessment of P_TDG patterns from other natural or anthropogenic processes that can also influence groundwater P_TDG .     

Spectral responses of water level in tidal river and groundwater

The water level of five river stages and seven groundwater wells in the Taipei Basin were analysed by spectral analysis in the frequency domain. The diurnal, semi‐diurnal and quarter‐diurnal tidal components of the Tanshui River appear to relate closely to astronomical tides as K₁, M₂ and M₄, respectively. It is also found that the diurnal component reveals a reversed phase angle in the middle section of the Tanshui River; the phase of the quarter‐diurnal component is also found to be reversed at stations upstream in the Tanshui River and Hsintien Stream. It is believed that these phenomena could be caused by local variation in the river channel topography. The autospectrum and cross‐spectrum between groundwater elevation and nearby river stage were observed to correlate highly with the frequency of the astronomical tides K₁, M₂ and M₄. From the study of the phase shift and time lag of water level fluctuations at river stages and groundwater wells, it was found that the tidal effects of diurnal, semi‐diurnal, and quarter‐diurnal components were significantly different. The relationships between phase and the fluctuated range of atmospheric pressure and water level imply that change in atmospheric pressure does not affect water level fluctuation in the river stage and groundwater well. Copyright © 1999 John Wiley & Sons, Ltd.