Composition of Comets: Observations and Models

We analyze the chemical composition and abundances of comets based on in situ measurements of Comet 1P/Halley and remote sensing observations of several recent bright comets including Hale-Bopp (C/1995 O1) and Hyakutake (C/1996 B2), in light of the elemental abundances of the solar system. Nitrogen is underabundant in comets relative to the solar system because nitrogen tends to be in N₂, which is chemically relatively inert. While many details remain uncertain, some gross features are emerging. The abundance of water : silicates: carbonaceous molecules (CO, CO₂, and hydrocarbons) by mass is approximately 1 : 1 : 1. Furthermore, the mass abundance of ice : dust (silicates and hydrocarbon polycondensates) is about1 : 1. We compare a list of identified comet molecules with molecules detected in the interstellar medium, although a comparison with their relative abundances, particularly in the ice phase, would be more meaningful. However, ice-phase abundances are not yet available. One can expect a variation of the abundances of carbon-bearing molecules in comets to be associated with their place of origin in the solar nebula. However, we also note that comets are heterogeneous. Thus, observed differences may be related to the place of origin, heterogeneity of the nucleus, or acquired through evolution. The molecular and elemental compositions of the coma are most likely not the same as those in the nucleus. This is particularly true for volatile ices and their gases and for the dust-to-ice and dust-to-gas ratios. Analyses must carefully consider the three sources of gas: Water from the surface of the nucleus, gases more volatile than water from the interior of the nucleus, and gases from the sublimation of the dust distributed in the coma. Topography on the surface of the nucleus may cause important evolutionary differences in the dust-to-gas mass ratio. Relatively inactive areas on the surface of the nucleus are probably associated with convex topography. Gas sublimated from convex areas (hills and mountains) diverges more strongly relative to gas sublimated from concave areas, which can entrain dust more efficiently. Thus, the entrainment of dust from convex areas is poor and dust may fall back to the surface of the nucleus creating a dust mantle, which further inhibits outgassing.     

Modelling Gas And Dust Release From Comet Hale–Bopp

Numerical simulations of the evolving activity of comet Hale-Bopp are presented, assuming a porous, spherical nucleus, 20 km in radius, made of dust and gas-laden amorphous ice. The main effects included are: crystallization of amorphous ice and release of occluded gas, condensation, sublimation and flow of gases through the pores, changing pore sizes, and flow of dust grains. The model parameters, such as initial pore size and porosity, emissivity, dust grain size, are varied in order to match the observed activity. In all cases, a sharp rise in the activity of the nucleus occurs at a large heliocentric distance pre-perihelion, marked by a few orders of magnitude increase in the CO and the CO₂ fluxes and in the rate of dust emission. This is due to the onset of crystallization, advancing down to a few meters below the surface, accompanied by release of the trapped gases. A period of sustained, but variable, activity ensues. The emission of water molecules is found to surpass that of CO at a heliocentric distance of 3 AU. Thereafter the activity is largely determined by the behaviour of the dust. If a dust mantle is allowed to build up, the water production rate does not increase dramatically towards perihelion; if most of the dust is ejected, the surface activity increases rapidly, producing a very bright comet. This revised version was published online in July 2006 with corrections to the Cover Date.     

Dust tail of the active distant Comet C/2003 WT42 (LINEAR) studied with photometric and spectroscopic observations

We present the study of dust environment of dynamically new Comet C/2003 WT42 (LINEAR) based on spectroscopic and photometric observations. The comet was observed before and after the perihelion passage at heliocentric distances from 5.2 to 9.5 AU. Although the comet moved beyond the zone where water ice sublimation could be significant, its bright coma and extended dust tail evidenced the high level of physical activity. Afρ values exceeded 3000 cm likely reaching its maximum before the perihelion passage. At the same time, the spectrum of the comet did not reveal molecular emission features above the reflected continuum. Reddening of the continuum derived from the cometary spectrum is nonlinear along the dispersion with the steeper slop in the blue region. The pair of the blue and red continuum images was analyzed to estimate a color of the comet. The mean normalized reflectivity gradient derived from the innermost part of the cometary coma equals to 8% per 1000 Å that is typical for Oort cloud objects. However, the color map shows that the reddening of the cometary dust varies over the coma increasing to 15% per 1000 Å along the tail axis. The photometric images were fitted with a Monte Carlo model to construct the theoretical brightness distribution of the cometary coma and tail and to investigate the development of the cometary activity along the orbit. As the dust particles of distant comets are expected to be icy, we propose here the model, which describes the tail formation taking into account sublimation of grains along their orbits. The chemical composition and structure of these particles are assumed to correspond with Greenberg’s interstellar dust model of comet dust. All images were fitted with the close values of the model parameters. According to the results of the modeling, the physical activity of the comet is mainly determined by two active areas with outflows into the wide cones. The obliquity of the rotation axis of the nucleus equals to 20° relative to the comet’s orbital plane. The grains occupying the coma and tail are rather large amounting to 1 mm in size, with the exponential size distribution of a^−4.5. The outflow velocities of the dust particles vary from a few centimeters to tens of meters per second depending on their sizes. Our observations and the model findings evidence that the activity of the nucleus decreased sharply to a low-level phase at the end of April–beginning of May 2007. About 190 days later, in the first half of November 2007 the nucleus stopped any activity, however, the remnant tail did not disappear for more than 1.5 years at least.     

An analysis of spectrophotometric observations of comets Austin (1982g) and Bradfield (1980t)

Post-perihelion observed emission fluxes at 388 nm (CN) and 516 nm (C₂) of the coma of comets Austin (1982g) and Bradfield (1980t) are analysed in the framework of the Haser model. Ratios of Haser model CN and C₂ parent production rates with expansion velocity show that each comet behaves normally. For comet Austin (1982g), the Q _CN/v and Q _c2/v values decrease with increase of heliocentric distance of comet. For an assumed %; activity of the total spherical surface area of the nucleus, the water vaporization theory coupled with derived water production rates from the International Ultraviolet Explorer H and OH flux data yields a nuclear diameter of about 6 km for comet Austin (1982g). For comet Bradfield (1980t), the derived nuclear diameter is expected to be of about 1 km. In each comet, the dust mass production rates as well as ratio of dust-to-gas mass production rates decrease with increase of heliocentric distance of comet.     

On the visibility of nuclei of dusty comets

The problem of visibility of a cometary nucleus discussed in general terms for single scattering by dust grains. The ratio of radiatio scattered in the dust column above the surface and that reflected from the nucleus determines the visibility of features on the nuclear surface. A contrast parameter characterizing the ration of radiation foming from the nuclear surface and that of the nuclear vicinity describes the visibility of the full nucleus against the dust fore- and background. These quantities and the intensity distribution of scattered solar radiation across the nucleus and its vicinity are calculated for the case of comet Halley at a heliocentric distance of 0.9 AU after perihelion (Giotto encounter). The scattering calculations are based on an isotropic dust distribution derived from hydrodynamics gas-dust interactions resulting in a steep densiity increase right above the surface. For Newburn's nominal model of comet Halley, an optical depth of about 0.5 impairs the visibility of the nucleus somewhat.     

Evidence for methane and ammonia in the coma of comet P/Halley

Methane and ammonia abundances in the coma of Halley are derived from Giotto IMS data using an Eulerian model of chemical and physical processes inside the contact surface to simulate Giotto HIS ion mass spectral data for mass-to-charge ratios (m/q) from 15 to 19. The ratio m/q = 19/18 as a function of distance from the nucleus is not reproduced by a model for a pure water coma. It is necessary to include the presence of NH3, and uniquely NH3, in coma gases in order to explain the data. A ratio of production rates Q(NH3)/Q(H2O) = 0.01-0.02 results in model values approximating the Giotto data. Methane is identified as the most probable source of the distinct peak at m/q = 15. The observations are fit best with Q(CH4)/Q(H2O) = 0.02. The chemical composition of the comet nucleus implied by these production rate ratios is unlike that of the outer planets. On the other hand, there are also significant differences from observations of gas phase interstellar material.     

Physical and compositional studies of Comet 81P/Wild 2 at multiple apparitions

We present analyses and results from both narrowband photometry and CCD imaging of Comet 81P/Wild 2 from multiple apparitions, obtained in support of the Stardust mission. These data include photometric measurements from 12 days before the encounter and imaging from 3 days after. Using narrowband photometry from the different apparitions, we analyzed the dust and gas production rates as a function of heliocentric distance, finding a substantial seasonal effect where the production of OH, NH, and dust peaks 11-12 weeks before perihelion. The CN, C₂, and C₃ production show no such asymmetry, suggesting that there may be heterogeneities among different sources on the nucleus. The water production peaked at a level of approximately in 1997. A comparison of the relative abundances of minor gas species places Wild 2 in the “depleted” category in the A'Hearn et al. (1995, Icarus 118, 223) taxonomic classifications. Continuum measurements at multiple wavelengths indicate that the comet has a low dust-to-gas ratio, with moderately reddened dust. In our images we see a dust tail, an anti-tail and two well-defined jets. The primary jet, which persists for several months and is roughly aligned with the spin axis, has a source latitude >+75°, while the secondary jet is located on the opposite hemisphere between −37° and −62°. We used the apparent position angle of the primary jet to determine the pole orientation, α=281±5°, δ=+13±7°, and surmise that the nucleus is likely in a state of simple rotation. The primary source is continuously illuminated when Wild 2 is inbound and turns away from the Sun at about the time that the comet reaches perihelion, explaining the seasonal effects in the production rates. We measured lightcurves on several observing runs but saw no significant modulation, so no constraints can be set on the rotation rate. Images at different wavelengths show that the jets have the same colors as the dust in other regions in the coma and tail, indicating that the grain properties are similar throughout the coma. Radial profiles of the coma were measured in various directions on a number of different observing runs, and we discuss the findings from these measurements. Finally, we compare our results with other published data and attempt to predict future times at which observations should be obtained to help constrain additional properties.     

Lessons of Comet Hale-Bopp for Coma Chemistry: Observations and Theory

Many new cometary molecules — both parents and daughters — were detected in the exceptionally productive comet C/1995 O1 (Hale-Bopp).The space distribution of several of these species could be investigated from radio interferometry or from long-slit spectroscopy in the infrared. The distinction between parent species — directly sublimated from nucleus ices — and secondary species — resulting from chemical processing in the coma or produced by a secondary source — is not always clear. It is important to assess whether or not observed minor species (HCOOCH₃, HCOOH...) could be synthesized by chemical reactions favoured by the high density of the coma of comet Hale-Bopp. Chemical modelling by Rodgers and Charnley suggests that this is notthe case. CO and H₂CO are abundant cometary species which partly come from distributed sources. The nature of these sources is still a mystery. A special case, now well documented, is that of HNC, for which the abundance evolution with heliocentric distance could be observed in comet Hale-Bopp and which was observed in several much less productive comets.     

C/1995 O1 (Hale-Bopp): Gas Production Curves And Their Interpretation

The discovery of C/1995 O1 (Hale-Bopp) at 7 AU from the Sun provided the first opportunity to follow the activity of a bright comet over a large range of heliocentric distances r_h. Production rates of a number of parent molecules and daughter species have been monitored both pre- and postperihelion. CO was found to be the major driver of the activity far from the Sun, surpassed by water within 3 AU whose production rate reached 10³¹ s⁻¹ at perihelion. Gas production curves obtained for various species show several behaviours with r_h. Gas production curves contain important information concerning the physical state of cometary ices, the structure of the nucleus and all the processes taking place inside the nucleus leading to outgassing. They are relevant to the study of several other phenomena such as the sublimation from icy grains, dust mantling or seasonal effects. For some species, such as H₂CO or HNC, they permit to constrain their origin in the coma. We discuss models of subsurface gas production in distant comets and predictions of how such a source may vary as the comet moves along its orbit, approaching perihelion and receding again. Features in the observed gas production curves of comet Hale-Bopp are generally interpretable in terms of either subsurface production (typical example: CO at large r_h) or free sublimation (typical example: H₂O). Possible implications for the vertical stratification of the cometary ices are reviewed, and preference is found for a model with crystallization of amorphous ice close to the nuclear surface. This revised version was published online in July 2006 with corrections to the Cover Date.     

Temporal deconvolution of the hydrogen coma: II. Pre- and post-perihelion activity of Comet Hyakutake (1996 B2)

Comet 1996 B2 (Hyakutake) displayed strong evidence for break-up, with a prominent antisunward dust spike and fragments traveling antisunward for many days after an eruptive event in late March 1996. Because of its high orbital inclination and rapid southward motion after perihelion, its post-perihelion activity was not well monitored from the ground. The SWAN all-sky Lyman-alpha camera on the SOHO spacecraft was ideally placed for long-term monitoring of the hydrogen coma of Comet Hyakutake both before and after perihelion. The SWAN images were analyzed with a new time-resolved model (TRM) that provides daily averages of the water production rate and an estimate of the hydrogen atom lifetime (dominated by charge exchange with solar wind protons) during extended periods throughout the apparition. A long-term variation of water production rate of , where r is the heliocentric distance in AU was found. The daily average values of the production rate covered the March 19 outburst and two more outbursts seen in the April before perihelion, which had progressively shorter durations at respectively smaller heliocentric distances. The long-term variation of the production rate was found to be consistent with the seasonal effect predicted by the jet rotation model of Schleicher and Woodney [2003. Analyses of dust coma morphology of Comet Hyakutake (1996 B2) near perigee: Outburst behavior, jet motion, source region locations, and the nucleus pole orientation. Icarus 162, 190-213] when added to a more steady source that is about two-thirds of the maximum of the jet source. The seasonal effect in their model found the dust jet source largely not illuminated after perihelion, coinciding with somewhat reduced overall activity and the absence of outbursts and fragmentation. The locations of the dust jets appear to be responsible for the outbursts and fragmentation before perihelion. The erratic behavior of the pre-perihelion jet sources as contrasted with the smoother variation from the rest of the surface after perihelion indicates there is a strong heterogeneity in the physical make-up of active areas on the nucleus.     

Coma Morphology And Constraints On The Rotation Of Comet Hale–Bopp (C/1995 O1)

We present constraints on the spin state of comet Hale-Bopp based on coma morphology. Three cases of rotational states are compatible with near perihelion observations: (1) principal-axis rotation, (2) complex rotational state with a small precessional angle, or (3) complex rotational state with a large ratio between the component periods. For principal axis rotators, images from 1996 (pre-perihelion) are consistent with a rotational angular momentum vector, M, directed at ecliptic longitude and latitude (250°, -5°) while images from late 1997 (post-perihelion) indicate (310°, -40°). This may suggest a change in M. A complex rotational state with small precessional angle requires only a small or no change in M over the active orbital arc. In this case, M is directed near ecliptic longitude and latitude (270°, -20°). A rotationally excited nucleus with a large ratio between component periods requires the nucleus to be nearly spherical. The transformation of dust coma morphology from near-radial jets to bright arcs and then again to near-radial jets is interpreted as a heliocentric and geocentric distance dependent evolutionary sequence. The spiral structures seen in CN filters near perihelion (in contrast to sunward side arcs seen in continuum) can be explained if the precursor of CN molecules (likely sub-micron grains) are emitted from the nucleus at low levels (≈ 10% of the peak daytime emission) during the nighttime. This may be indicative of a nucleus with a CO-rich active area(s). This revised version was published online in July 2006 with corrections to the Cover Date.     

Coma expansion and photometry of comet Bowell (1980b)

Optical and infrared observations of comet Bowell are presented. The optical observations indicate that the solid grain coma is expanding at only 0.9 ± 0.2 m sec^?1. This is two orders of magnitude slower than the local gas sound speed and may suggest that gas drag is not responsible for stripping the grains from the nucleus. The hypothesis of “electrostatic snap-off” is tentatively advanced to account for the ejection of the grains. Alternatively, the grains may have an unusual size distribution. The extrapolated motion of the grains suggests that the bulk of the coma was formed when the comet was at a heliocentric distance $\text{R ? 10}\text{AU}$. Any water ice in the nucleus would be too cold to give rise to the observed grain coma by equilibrium sublimation at this R. Further evidence against the production of the grain coma by equilibrium sublimation of the nucleus is provided by broadband (J) photometric observations. Almost all of the observed photometric variations of comet Bowell can be ascribed to geometric effects. Simple models indicate that the total grain cross section has been nearly constant since the time of the earliest observations. The present observations, which suggest that water ice sublimation does not control either the optical morphology or the near infrared photometric behavior of comet Bowell, are contrasted with reported high OH production rates. It is concluded that the grain coma may be largely a relic of activity occurring on the nucleus at $\text{R ? 10}\text{AU}$ while the OH may indicate sublimation from the nucleus near perihelion and from coma grains near $\text{R ? 4.6}\text{AU}$.     

From Hale–Bopp's Activity to Properties of its Nucleus

Because of the outstanding brightness of comet Hale–Boppreliable production rates of several moleculescould be measured over a wide range of heliocentric distances.The H₂O-activity of a comet is closelyconnected with the energy balance and the composition of itssurface. It is often assumed that more volatilemolecules originate from subsurface regions. The CO observationsprovided an important data base for abetter understanding of this matter. A thermal model has beenapplied to calculate gas production rates ofHale–Bopp. The strong obliquity of the spin axis causespronounced seasonal effects and, therefore, anasymmetry of water activity with respect to perihelion. By comparingmeasured and calculated rates properties of the nucleus have been derived.     

Charge-coupled device photometry of Comet P/Halley

Comet P/Halley has been observed during its approach to perihelion at heliocentric distancesR = 11.0 AU and R = 8.2 AU. No extended coma is seen and limits can be placed on the fraction of the total light contributed by coma. The brightness of the comet varies on a short time scale. The variations may be due to transient activity or to rotation of the irregular nucleus.     

The Visual Light Curve Of C/1995 O1 (Hale-Bopp) From Discovery To Late 1997

We present a light curve of C/1995 O1 (Hale-Bopp) compiledfrom more than 3000 visual observations of the comet made by members of the The Astronomer Group world-wide. These observations cover the period from discovery through to the end of 1997. The light curve shows that the rate of brightening of the comet varied widely at different times, with rapid rates of brightening at high heliocentric distance pre-perhelion and a comparably rapid post-perihelion fade. There is no evidence that the comet was suffering a large photometric outburst when first discovered, although a small outburst can be identified at perihelion. At least five difficult brightening regimes can be identified in the light curve between discovery and perihelion. From 2.5 AU to perihelion the rate of brightening with decreasing heliocentric distance was typical for “fairly” new comets(n ∼ 3.5, where “n” is the power law exponent of the heliocentric distance), although this was preceded by a period of very slow brightening with n ∼ 1 from r ∼ 4.0 AU to r ∼ 2.8 AU and followed by an initially more rapid brightening which appears to be related to the on-set of rapid water sublimation activity. We derive the light curve parameters at different stages of the comet's apparition. This revised version was published online in July 2006 with corrections to the Cover Date.     

Cometary science with ALMA

This paper presents a prospect for the observations of comets with ALMA. Thanks to unprecedented sensitivity, angular resolution and instantaneous uv-coverage, key measurements on a number of topics related to the chemical and physical properties of the coma and the nucleus will be obtained. These include (1) the identification of new molecular species and measurements of key isotopic ratios, (2) measurements of the composition of short-period comets coming from the trans-Neptunian scattered disc, to investigate chemical diversity within the whole comet population, (3) imaging of gas jets and their relationship with dust features, (4) the study of extended sources of gas in the coma, and (5) the study of the physical and outgassing properties of the nucleus.     

Spectrophotometry of comet West (1975n) after the perihelion passage

In the wavelength range 350 to 650 nm, the flux distribution of comet West (1975n) is presented for various dates following perihelion passage. The variations with heliocentric distance, in the flux of the emission features of the CN band at 388 nm, the C₂ bands at 474 nm, 516 nm and 563 nm and Na at 589 nm, have been discussed. It is concluded that the comet was dust rich.     

Understanding measured water rotational temperatures and column densities in the very innermost coma of Comet 73P/Schwassmann–Wachmann 3 B

Direct sublimation of a comet nucleus surface is usually considered to be the main source of gas in the coma of a comet. However, evidence from a number of comets including the recent spectacular images of Comet 103P/Hartley 2 by the EPOXI mission indicates that the nucleus alone may not be responsible for all, or possibly at times even most, of the total amount of gas seen in the coma. Indeed, the sublimation of icy grains, which have been injected into the coma, appears to constitute an important source. We use the fully-kinetic Direct Simulation Monte Carlo model of Tenishev et al. (Tenishev, V.M., Combi, M.R., Davidsson, B. [2008]. Astrophys. J., 685, 659?677; Tenishev, V.M., Combi, M.R., Rubin, M. [2011]. Astrophys. J., 732) to reproduce the measurements of column density and rotational temperature of water in Comet 73P-B/Schwassmann–Wachmann 3 obtained with a very high spatial resolution of ～30 km using IRCS/Subaru in May 2006 (Bonev, B.P., Mumma, M.J., Kawakita, H., Kobayashi, H., Villanueva, G.L. [2008]. Icarus, 196, 241?248). For gas released solely from the cometary nucleus at a heliocentric distance of 1 AU, modeled rotational temperatures start at 110 K close to the surface and decrease to only several tens of degrees by 10–20 nucleus radii. However, the measured decay of both rotational temperature and column density with distance from the nucleus is much slower than predicted by this simple model. The addition of a substantial (distributed) source of gas from icy grains in the model slows the decay in rotational temperature and provides a more gradual drop in column density profiles. Together with a contribution of rotational heating of water molecules by electrons, the combined effects allow a much better match to the IRCS/Subaru observations. From the spatial distributions of water abundance and temperature measured in 73P/SW3-B, we have identified and quantified multiple mechanisms of release. The application of this tool to other comets may permit such studies over a range of heliocentric and geocentric distances.     

Dust production of comet 21P/Giacobini‐Zinner using broadband photometry

Presented here are results from photometric analysis on broadband images taken of comet 21P/Giacobini‐Zinner from May 24, 2011 to October 24, 2011. As the parent body of the Draconids, a meteor shower known for outbursting, 21P was studied for its dust production activity, Afρ, focusing on how it changes with heliocentric distance. An expected increase in dust production with a decrease in heliocentric distance was observed. The comet went from heliocentric distance of 3.05 –1.77 AU during the observed time that corresponded to an apparent magnitude of 19.61 to 15.72 and Afρ of 16.48 cm to 284.17 cm. These values can be extrapolated to estimate a peak Afρ value at perihelion of 3824 cm. The images were obtained using a 0.5‐meter f/8.1 Ritchey‐Chrétien telescope located in Mayhill, New Mexico.     

Long-term Evolution of the Outgassing of Comet Hale-Bopp From Radio Observations

C/1995 O1 (Hale-Bopp) has been observed on a regular basis since August 1995 at millimetre and submillimetre wavelengths using IRAM, JCMT, CSO and SEST radio telescopes. The production rates of eight molecular species (CO, HCN, CH₃OH, H₂CO,H₂S, CS, CH₃CN,HNC) have been monitored as a function of heliocentric distance(r_h from 7 AU pre-perihelion to 4 AU post-perihelion. As comet Hale-Bopp approached and receded from the Sun, these species displayed different behaviours. Far from the Sun, the most volatile species were found in general relatively more abundant in the coma. In comparison to other species, HNC, H₂CO and CS showed a much steeper increase of the production rate with decreasing r_h. Less than 1.5 AU from the Sun, the relative abundances were fairly stable and approached those found in other comets near 1 AU. The kinetic temperature of the coma, estimated from the relative intensities of the CH₃OH and CO lines, increased with decreasing r_h, from about10 K at 7 AU to 110 K around perihelion. The expansion velocity of the gaseous species, derived from the line shapes, also increased with a law close tor_h ³. This revised version was published online in July 2006 with corrections to the Cover Date.