不同SAR条件下滨海含水层胶体释放与渗透性变异

在野外调查的基础上, 研究不同钠吸附比(SAR)条件下滨海含水层胶体释放规律, 采集天津平原区代表性含水层土样, 采用室内批实验和土柱实验, 研究胶体释放浓度和释放量的动态特征, 识别不同含水介质胶体释放的差异性, 同时分析胶体颗粒释放过程中含水介质渗透性变异特征.结果表明, 在NaCl和CaCl₂混合溶液系统中, 含水层含水介质胶体颗粒的释放与地下水溶液所含阳离子价态有关, Ca2+含量越高, SAR越小, 胶体越不容易释放出来, Ca2+对胶体释放的抑制作用越强烈.土柱实验表明不同吸附比情况下粉砂和中砂胶体释放浓度均很小; 当地下水中SAR为0和8时粉土胶体释放很少, 当溶液的SAR为∞时胶体有明显的释放, 释放浓度随孔隙体积数的增加而增加, 在52个孔隙体积数瞬时达到峰值73.76 mg/L, 然后缓慢减少, 最后累积释放量达0.13 mg/g.胶体释放过程中, 粉土、粉砂和中砂渗透性损失分别为98.2%、86.7%和95.9%;含水介质渗透性的降低主要是由于释放的胶体颗粒在空间上重新分布造成的.      

人工回灌条件下滨海砂质含水层渗透性的时空演变特征

人工回灌补给滨海含水层是海水入侵修复经常采用的工程措施,然而人工回灌条件下滨海砂质含水层经常出现渗透性显著降低的现象,其含水介质渗透性的时空演变规律仍不清楚。本文以青岛市大沽河下游咸水入侵区含水层砂样为研究对象,通过利用不同尺度的室内砂柱淡咸水驱替试验,对定水头和定流速条件下人工回灌咸淡水驱替过程中砂质含水层渗透性的时空演变特征进行了研究。结果表明：当淡水驱替咸水时含水介质的渗透性会发生显著变化,整个砂柱的渗透性先降低后回升,原因是回灌过程中砂柱中的黏土矿物发生释放、迁移、沉积;定水头条件下,在砂柱的前半段存在一个淘空区,渗透系数是初始渗透系数的1.6~2.0倍,砂柱其它部分渗透性是先降低再轻微回弹;定流速条件下,砂柱的渗透系数随时间的变化均呈现先降低后升高趋势,且砂柱各段离入水口的距离越远其渗透系数的值越小;砂柱黏粒含量的变化规律与渗透性的演化特征相吻合。研究成果可为人工回灌治理滨海含水层海水入侵提供一定的科学依据。     

地下咸水与水库水体交换过程中沉积物胶体释放规律

以天津滨海地区北大港水库为研究对象,采用室内柱试验,研究地下咸水与水库水体交换过程中不同位置沉积物胶体释放以及盐分释放/截留的动态特征,同时对沉积物胶体释放、盐分释放/截留机理进行了探讨。研究结果表明:水库不同位置地下咸水与水库水体交换过程中,盐分的归宿不同:接近水库入口处的沉积物能将盐分截留下来,而出水口沉积物却将盐分释放转移到水体。随孔隙体积数的增加,沉积物胶体累计释放量逐渐增加,入库口、库中心、出库口最大累计释放量分别为3.275 mg/g、0.386 mg/g和1.382 mg/g;胶体累计释放量随孔隙体积数的变化曲线符合直线型,胶体释放速率变化很小。盐分的释放或截留是沉积物颗粒的粒径、胶体含量、含盐量等多种因素作用的结果,水库水体与沉积物中的盐分处于动态平衡状态,当沉积物中含盐量高于平衡浓度时,其盐分会向水体中释放,同时吸附在胶体上的盐分也会随着胶体的释放而释放;反之,水体中的盐分会向沉积物中迁移被截留下来,沉积物粒径越小,越易吸附水中的盐分。胶体的释放规律可以用双电层理论得到很好的解释。     

同期采灌储能模式浅层咸水介质渗透性演化过程研究

针对地下浅层储能咸水介质复杂的水文地质条件与矿物构成的特殊性,开展可控三维物理模拟试验,基于表面化学与胶体稳定性理论,从介观尺度分析回灌溶液宏观参数变化与含水介质中微纳米颗粒重新分布过程的内在关联;探索复杂时空条件下咸水层孔隙结构变化规律;确定不同储能模式下低渗透帷幕带的形成区域。研究结果表明,回灌溶液温度、盐度变化是打破颗粒间受力平衡,造成含水介质渗透性能下降的诱导机制。在抽-注井固定与调换模式下,经历完整储能周期,含水层整体相对渗透率k/k0分别下降至63%、57%,表明由微纳米颗粒物质重组,导致含水介质空间结构变化具有不可逆性。两组储能试验中,由于形成机制不同,低渗透帷幕带分别形成于700～900 mm与500～700 mm的渗流单元。     

井周堵塞对承压含水层定流量回灌渗流场影响的半解析研究

为分析定流量条件下回灌堵塞对井周含水层渗流响应的影响,采用指数形式的渗透系数衰减方程反映堵塞作用下井周含水层渗透特性的时变效应,建立了考虑堵塞效应的定流量非完整回灌井流力学模型,采用变量代换、Laplace变换和有限余弦Fourier变换得到了井周含水层中水位抬升在Laplace空间的解,应用Stehfest数值逆变换方法获得了实时空间内的水头抬升和回灌压力。参数分析结果表明,较小的渐近渗透系数Kr,∞会增加回灌过程中水头抬升和回灌压力,并加剧含水层达到拟稳态时的渗流响应;较大的渗透系数衰减指数λ仅增加回灌过程中水头抬升和回灌压力,但不影响含水层达到拟稳态时的渗流响应;因Kr,∞和λ不同而引起的水头差在井筒处达到最大值并沿径向距离逐渐减小。研究结果可以为定流量回灌中井周含水层堵塞的识别与预测提供理论依据。     

济南富水孔隙黏性土地层渗透性试验研究

以济南市轨道交通R1线大杨庄站主体基坑降水工程为例,研究表明发育于济南区域孔隙黏性土地层黏性土内具有独特的空间网状孔隙、孔洞结构。通过4种渗透性试验成果对比分析,室内试验、声纳渗流试验测定的渗透系数均较小,与实际地层渗透能力相差很大;抽水试验与回灌试验测定的渗透系数相近,远远大于一般黏性土的渗透性,渗透系数随着回灌压力的增加而呈线性提高,回灌引起周边地下水位上升较小,影响范围有限,符合济南孔隙黏性土地层的富水性强和渗透性好特性,具有独特性和鲜明的区域特点。相关试验成果可以为相关区域基坑降水与回灌设计、施工和泉水环境保护提供参考。     

基于Origin的渗透系数衰减方程在地热水回灌中的应用

孔隙型热储层的回灌过程中,由于物理堵塞、生物化学堵塞、悬浮物堵塞和气体堵塞,热储层的渗透性下降,回灌能力变弱.为了定量查明渗透系数的衰减,以辽南地区某回灌试验为例,使用Origin软件计算出研究区渗透系数衰减方程,在此基础上计算了回灌井灌压-时间关系曲线和回扬周期.研究表明,利用Origin软件求取渗透系数衰减方程具有...     

回灌与回扬物理过程的解析推导及灌压变化规律

以回灌过程中渗透系数衰减模型为基础,推导了不同回扬次数的渗透系数解析表达式;将其应用于Theis公式,获得了考虑渗透系数衰减以及暂时性堵塞率条件下回灌与回扬物理过程中含水层压强的解析表达式,更准确地刻画了回灌与回扬的物理机制。计算结果表明：在连续回灌不回扬过程中,井内灌压增长符合指数曲线特征,而采取回扬措施后,由指数连续上升转变为间断式阶梯上升;回扬次数越多,灌压下降越明显,但灌压变化幅度随回扬次数的递增而减小。根据解析解定义的两种堵塞率的结果,可以实现利用实验判断不同成分回灌水源对含水层堵塞机理的分析,从而达到科学制定回灌水源标准的目的。     

热屏障井对地下水源热泵换热影响模拟

对于场地受限的地下水源热泵项目,随着系统运行时间的增加易引发热贯通现象进而降低机组运行效率。地下水源热泵设计中,在抽灌水井连线间布设热屏障井可改变地下水流场,降低热量在抽灌井间的运移速度,有利于延长热贯通发生时间并缓解热贯通程度。通过构建地下水换热模型,模拟计算夏季制冷工况条件下36组热泵运行场景,分析了热屏障井的位置,过滤管长度及回灌量对热贯通和含水层温度场的影响规律。结果表明:热屏障井回灌量的增加有利于提升热屏障效果,但提升幅度随回灌量的增加逐渐减弱;最大水位降深值随着热屏障井回灌量的增加呈线性增长;增加热屏障井滤管长度可提升热屏障效果,提升效果随屏障井回灌量的增加逐渐增强。通过模型多周期、长时间模拟计算发现,热屏障井的运行可促使回灌的冷热量集中在回灌井一侧,对于采用冬夏季抽灌井交换运行模式的热泵系统,可充分利用含水层储能,提升机组运行效率。     

矿井水深层回灌过程量质耦合模拟分析

矿井水深井回灌是矿井水“转移存储”处理的主要形式,根据鄂尔多斯盆地煤矿区地质和矿井水特征,从回灌目的层地下水与矿井水的匹配性、上下岩层的隔水性、回灌层的渗透性以及封闭性角度提出了矿井水回灌目的层选取依据。并以地下水达西定律和Dupuit理论为基础,建立极坐标系完整注水井稳定流数学模型,得出在稳定注水条件下,回灌量与注水层渗透系数、厚度、回灌压力、水位埋深以及回灌井直径正相关,与影响半径负相关,与回灌层埋深无关。提出了矿井水深层回灌水动力和溶质运移耦合仿真模型构建方法,并以矿井水回灌试验案例为分析对象,模拟得出矿井水回灌过程中含水层水压形成以注水井为中心的“高位水丘”,且注水压力越大,回灌量增加较为明显,模型分析结果与现场试验结果基本一致。溶质运移范围形成以注水井为中心的“圆柱状”弥散形态,特征离子浓度沿回灌井两侧变化剧烈,回灌层特征离子浓度被迅速稀释,随着时间的延伸,弥散稀释范围增加相对较小,说明矿井水回灌对深部高浓度含水层地下水水化学影响程度不大,研究成果可为西部煤矿区矿井水高效回灌处理提供科学依据。      

Hydrogeochemical patterns,processes and mass transfers during aquifer storage and recovery (ASR) in an anoxic sandy aquifer

The hydrogeochemical processes that took place during an aquifer storage and recovery (ASR) trial in a confined anoxic sandy aquifer (Herten, the Netherlands) were identified and quantified, using observation wells at 0.1, 8 and 25 m distance from the ASR well. Oxic drinking water was injected in 14 ASR cycles in the period 2000–2009. The main reactions consisted of the oxidation of pyrite, sedimentary organic matter, and (adsorbed) Fe(II) and Mn(II) in all aquifer layers (A–D), whereas the dissolution of carbonates (Mg-calcite and Mn-siderite) occurred mainly in aquifer layer D. Extinction of the mobilization of SO₄, Fe(II), Mn(II), As, Co, Ni, Ca and total inorganic C pointed at pyrite and calcite leaching in layer A, whereas reactions with Mn-siderite in layer D did not show a significant extinction over time. Iron(II) and Mn(II) removal during recovery was demonstrated by particle tracking and pointed at sorption to neoformed ferrihydrite. Part of the oxidants was removed by neoformed organic material in the ASR proximal zone (0 – ca. 5 m) where micro-organisms grow during injection and die away when storage exceeds about 1 month. Anoxic conditions during storage led to increased concentrations for a.o. Fe(II), Mn(II) and NH₄ as noted for the first 50–200 m³ of abstracted water during the recovery phase. With a mass balance approach the water–sediment reactions and leaching rate of the reactive solid phases were quantified. Leaching of pyrite and calcite reached completion at up to 8 m distance in layer A, but not in layer D. The mass balance approach moreover showed that Mn-siderite in layer D was probably responsible for the Mn(II) exceedances of the drinking water standard (0.9 μmol/L) in the recovered water. Leaching of the Mn-siderite up to 8 m from the ASR well would take 1600 more pore volumes of drinking water injection (on top of the realized 460).     

水化学揭示的弱透水层孔隙水演化特征及其古气候指示意义

地下水开采、弱透水层释水, 以及污染物迁移转化、高危废物深埋选址等水文地质和工程地质活动中, 弱透水层的作用越来越受到重视.了解弱透水层孔隙水的演化特征是认识弱透水层作用的首要问题.采用机械压榨法提取了曹妃甸地区某钻孔0~100 m粘性土孔隙水, 对孔隙水化学特征进行了分析.结果显示钻孔粘性土孔隙水呈碱性, 总溶解固体为7.26~26.89 g/L, 从浅到深逐渐减小; 陆相沉积层Cl/Br比趋向无穷大, 而海相沉积层仅为279~289.分析得出弱透水层孔隙水基本为岩层沉积水, 陆相和海相沉积层孔隙水分别显示出淡水和海水起源特征, 没有后期海水入侵影响迹象; Cl-、Na+变化趋势主要受蒸发浓缩作用影响, SO₄2-受硫酸盐的还原作用和石膏的溶解作用共同控制, Ca2+、Na+、K+还受到沉积过程中阳离子交换与吸附作用影响; 由δ18O重建晚更新世古气温为5.21~5.81 ℃, 浅部40 m以内计算的气温偏高是由于全新世气候变暖、孔隙水向下扩散迁移混合的影响.      

Baseline geochemical conditions in the Chalk aquifer,Berkshire, U.K.: a basis for groundwater quality management

The Chalk aquifer is the most important British aquifer and is also important over much of northern Europe. Aquifer protection requires a sound knowledge of the baseline conditions and how these might vary, or have varied, with time. This detailed geochemical study of a representative area of Chalk in Berkshire, U.K., includes a consideration of several components: (1) the inputs from the atmosphere; (2) the interstitial water of the soil and the unsaturated zone; (3) the interstitial water in the confined and unconfined sections of the aquifer; and (4) the saturated, mainly fissure flow, along the hydraulic gradient which forms an important water supply of the Thames Valley region.Atmospheric inputs form an important source of some elements, but the dominant chemical characteristics of the Chalk groundwater are acquired during percolation through the soil and the upper unsaturated zone. During saturated flow downgradient the chemistry is modified mainly by incongruent reactions of the carbonate matrix and by redox reactions, and only to a minor extent by exchange reactions and mixing with residual saline connate water. The incongruent reaction of carbonate results in a marked increase in the Mg/Ca ratio and the Sr and ¹³C contents of the groundwater with increased residence time. Oxygen concentrations are reduced mainly by oxidation of Fe²⁺, and the onset of reducing conditions allows dissolved Fe²⁺ to increase and rapid denitrification to occur. The salinity profile through the confined Chalk confirms that residual connate water, up to one-fifth sea water concentration, still remains at depth, and this accounts for some salinity increase in the confined groundwater resulting from fissure water.pore water diffusional exchange.Timescales for groundwater movement have been established using tritium, radiocarbon, and indirectly using inert gas ratios and stable isotope ratios. On balance, it is concluded that all abstracted water is of Holocene age, although inert gas temperatures indicate cooler climatic conditions for recharge for some of the confined groundwater.The implications for development and aquifer protection are discussed, especially the prospect of natural in situ denitrification, problems of Fe solubility, and the recognition of groundwater of different maturities.     

Influence of geologic layering on heat transport and storage in an aquifer thermal energy storage system

A modeling study was carried out to evaluate the influence of aquifer heterogeneity, as represented by geologic layering, on heat transport and storage in an aquifer thermal energy storage (ATES) system in Agassiz, British Columbia, Canada. Two 3D heat transport models were developed and calibrated using the flow and heat transport code FEFLOW including: a “non-layered” model domain with homogeneous hydraulic and thermal properties; and, a “layered” model domain with variable hydraulic and thermal properties assigned to discrete geological units to represent aquifer heterogeneity. The base model (non-layered) shows limited sensitivity for the ranges of all thermal and hydraulic properties expected at the site; the model is most sensitive to vertical anisotropy and hydraulic gradient. Simulated and observed temperatures within the wells reflect a combination of screen placement and layering, with inconsistencies largely explained by the lateral continuity of high permeability layers represented in the model. Simulation of heat injection, storage and recovery show preferential transport along high permeability layers, resulting in longitudinal plume distortion, and overall higher short-term storage efficiencies.     

Recharging of contaminated aquifer with reclaimed sewage water

About 40% of the water supply of Cairo, Egypt, is drawn from a groundwater reservoir located southeast of the Nile Delta. Several thousand shallow wells supply drinking water to the farmers from the same groundwater reservoir, which is recharged by seepage from Ismailia canal, the irrigation canal network, and other wastewater lagoons in the same areas. Sewage water lagoons were located at the high ground of the area, recharging contaminated water into the aquifer. Since the groundwater in this area is used for drinking purposes, it was decided to treat the sewage water recharging the aquifer for health reasons. In this paper a solution to the problem is presented using an injection well recharging good quality water into the aquifer. A pumping well located at a distance downstream is used to pump the contaminated water out of the aquifer. A three-dimensional solute transport model was developed to study the concentration distribution with remediation time in the contaminated zone.     

Potential assessment of CO2 geological storage based on injection scenario simulation: A case study in eastern Junggar Basin

Carbon Capture and Storage (CCS) is one of the effective means to deal with global warming, and saline aquifer storage is considered to be the most promising storage method. Junggar Basin, located in the northern part of Xinjiang and with a large distribution area of saline aquifer, is an effective carbon storage site. Based on well logging data and 2D seismic data, a 3D heterogeneous geological model of the Cretaceous Donggou Formation reservoir near D7 well was constructed, and dynamic simulations under two scenarios of single-well injection and multi-well injection were carried out to explore the storage potential and CO₂ storage mechanism of deep saline aquifer with real geological conditions in this study. The results show that within 100 km² of the saline aquifer of Donggou Formation in the vicinity of D7 well, the theoretical static CO₂ storage is 71.967 × 10⁶ tons (P50)^①, and the maximum dynamic CO₂ storage is 145.295 × 10⁶ tons (Case2). The heterogeneity of saline aquifer has a great influence on the spatial distribution of CO₂ in the reservoir. The multi-well injection scenario is conducive to the efficient utilization of reservoir space and safer for storage. Based on the results from theoretical static calculation and the dynamic simulation, the effective coefficient of CO₂ storage in deep saline aquifer in the eastern part of Xinjiang is recommended to be 4.9%. This study can be applied to the engineering practice of CO₂ sequestration in the deep saline aquifer in Xinjiang.