石油类污染水体吸收特性分析

石油类污染物主要以漂浮油、分散油、乳化油和分解油等形式存在于水体中,影响着水体的表观和固有光学特性。利用2008年5月在辽宁省盘锦市辽河油田境内双台子河和绕阳河所测定的水色三要素吸收系数以及对应的水体组分数据,分析了研究区域内Ⅱ类水体水色三要素的吸收光谱特性;探讨了水体中由于石油类污染物的存在,黄色物质和色素吸收光谱的变化特征;采用差值法确定了水体中石油类污染物的吸收系数。研究结果表明:(1)研究区域内,无论是石油类污染水体还是非石油类污染水体,非色素颗粒物和黄色物质的吸收光谱都遵循e指数衰减规律,色素吸收光谱在440nm和675nm处有以叶绿素为主的典型的色素吸收峰,在490nm处有类胡萝卜素的吸收峰;(2)对于石油类污染水体,在测定黄色物质和色素吸收系数时,由于包含了石油类污染物的作用,会增大黄色物质和色素的吸收系数;(3)石油类物质的吸收光谱曲线和非色素颗粒物、黄色物质一样遵循e指数衰减规律,但三者的指数函数斜率有明显的差别,这为将三者区分开来提供了可行性。     

基于光谱特征的三峡坝区水色要素反演

基于野外测定的水质参数,通过研究三峡坝区水体中水色要素浓度与反射率之间的关系,选择反演叶绿素、悬浮物、溶解性有机物的最佳波段,建立了反演水色要素浓度的遥感定量模型。研究表明,在波段比值的基础上进行幂次修正的波段组合反射率与SS浓度相关性较好(R2=0.76),可以用来估算悬浮物浓度;悬浮物浓度影响叶绿素浓度的反演精度,通过在模型中增加一个红绿波段比值指数项的方法能够抑制或削弱悬浮物的影响,提高了叶绿素浓度的反演精度(R2=0.75);DOC反演模型中,绿光波段与红光波段反射率的对数值能较好的估算DOC浓度,且与log(DOC)相关程度最高,决定系数为0.85,反演精度较高。     

水体铜离子吸收系数光谱(400-900 nm)测量

金属溶解物的吸收光谱测量是水体重金属遥感反演的关键。本文使用水体透射光测量装置,利用ASD光谱仪测量相同厚度不同浓度铜离子溶液的透射光辐亮度,运用比值法计算水体铜离子消光系数和吸收系数,最终得到400—900 nm波长范围内的水体铜离子单位浓度吸收系数光谱。该方法可以较好地消除实验装置和水中悬浮物的影响。结果表明,水体铜离子在蓝、绿光波段吸收作用极小,红光至红外波段的吸收系数快速增大,与铜离子溶液颜色相吻合;吸收峰位于810 nm。多次独立实验测量所得结果的标准差很小,说明测量结果稳定。与Jancsò测量结果的对比分析表明,本文结果与国际上著名测量结果接近,且部分波段的测量值更为合理。     

基于无人机高光谱影像的NDVI估算植被盖度精度分析

研究波段参数对NDVI估算植被生物物理参数的影响,对于提高NDVI在植被覆盖变化监测中的应用精度具有重要意义。采用无人机载Resonon Pika XC2高光谱仪获取的人工草地高光谱影像,分析红光和近红外波段位置移动与宽度变化对NDVI的影响,评估NDVI对植被盖度的敏感性和植被盖度估算精度。结果表明:波段位置固定时红光和近红外波段宽度扩展对NDVI及其敏感性影响不大,窄波段NDVI估算植被盖度的精度优于宽波段。红光和近红外波段位置向长波方向移动时对NDVI及其敏感性有不同程度的影响,随着敏感性增强NDVI抗扰动性降低,估算植被盖度的精度有所下降。窄波段NDVI的灵敏度系数及其与植被盖度线性拟合的R2波动剧烈,植被盖度估算的位置稳定性较差。10 nm NDVI在不同位置处取得了较高的盖度估算精度,R2最大值为0.83。4种主流卫星影像计算的宽波段NDVI对于高植被覆盖区盖度反演具有良好的适用性,但与窄波段10 nm NDVI相比其盖度反演精度仍然有一定程度的衰减。研究结果可为NDVI精确反演植被参数提供科学参考和依据。     

积水沉陷区水体的表观光学特性参数测量与分析

通过实际测量试验区的积水沉陷区水深值,了解水体光学特性随水深不同而引起的衰减特征变化,建立水深与光谱特性响应间的关系表达式,确定获取水深信息的最佳波谱范围;揭示了叶绿素、悬浮物质、CDOM等水体组分与水体光谱特征变化的关系,探讨因水体各主要组分变化而引起的水体光谱吸收光谱、散射光谱的变化规律.     

高光谱目标探测中的空间和光谱尺度效应

高光谱遥感目标探测主要利用目标和背景的光谱特征差异进行目标识别。一般情况下,影像的空间和光谱分辨率越高,探测效果越好。但多数情况下空间和光谱分辨率难以同时满足需求。针对该问题,本文利用Field Imaging Spectrometer System(FISS)地面高光谱成像仪器,通过在稀疏草地上布设人工绿色目标,研究了目标和背景光谱相似情况下,单一均匀背景下小目标探测问题,提出空间和光谱尺度定量分析方法,得到目标探测适用的空间和光谱尺度。结果表明:(1)利用FISS高光谱仪器进行人工目标探测,所需的空间分辨率约为目标尺寸的2倍以内;(2)当光谱分辨率优于40 nm时,目标和背景的两个主要特征:反射峰的位置和波段趋势差异均可被描述,在原始空间分辨率5倍(0.85 cm)以内,探测精度可以达到0.94以上。由于反射峰间距20 nm,当光谱分辨率低于40 nm时,该特征消失,造成探测精度的下降;(3)当光谱分辨率低于40 nm时,选取目标、背景光谱特征差异较大的波段可提高探测的有效性,在舍弃目标背景相似波段后,探测精度上升,得到本实验的最佳波段组合为红、绿、蓝、黄及红边波段。     

不同钾素处理春玉米叶片营养元素含量变化及其光谱响应

目的是研究不同钾营养水平春玉米典型生育期叶片的光谱响应,探索叶片内营养成分与叶片光谱反射率的相关性。方法是设置了不同梯度钾处理的盆栽试验,按玉米生育期进行光谱测定和取样分析。结果,通过对不同钾处理间玉米叶片养分含量的差异性分析表明,随着施钾的提高,叶片钾含量差异性达到显著水平。分析不同钾营养水平不同生育时期春玉米叶片光谱反射率与叶片钾含量的相关关系,并建立了喇叭口期利用叶片光谱反射率估测叶片钾含量的数学模型;以及分析了该处理下喇叭口期叶片内水分、叶绿素、氮、磷、钙、镁、锌、锰、铜、铁含量与叶片光谱反射率的相关性。结果表明：不同生育时期叶片钾含量与其光谱反射率的相关关系在光谱维方向存在明显差别,730—930nm和960—1100nm两波段为春玉米喇叭口期评价钾营养状况的敏感波段,光谱变量R767＋R1057,（R767＋R1057） /（logR767＋logR1057）和（R767-R1057） /（logR767-logR1057）均能很好的预测喇叭口期叶片钾含量;该时期叶片内不同成分与光谱反射率相关分析表明：550nm,710nm,950nm三波段处是各个相关曲线的突变点;叶片内各成分间高度相关的,它们的光谱相关曲线趋势也极为一致或对称。     

不同藻类水体太阳激发的叶绿素荧光峰（SICF）特性研究

采用现场实测和室内培养两种方式测定了甲藻、赤潮异弯藻、海洋蓝绿藻、叉角藻赤潮和新月菱形藻、叉鞭金藻、塔胞藻、扁藻和小球藻等非赤潮藻类光谱曲线,采用度量太阳激发的叶绿素荧光峰高度的Rmaxred/R560比值法,建立了不同藻类Rmaxred/R560与叶绿素a浓度的关系,R>0.82。随藻类的不同,Rmaxred/R560与叶绿素a的关系发生较大的变化,其关系方程的系数a的变化范围为0.037—1.135之间,b的变化范围为0.094—0.727之间。同时建立了不同藻类荧光峰位置与叶绿素a浓度的关系,除海洋蓝绿藻为0.57外,R均大于0.75。随叶绿素浓度的增加,浮游植物反射光谱荧光峰的位置向红光方向移动。随藻类不同,移动的幅度有所差异,赤潮异弯藻的移动幅度最大,其它藻类每10mgm-3浓度的移动幅度介于0.1—0.3nm之间。叉鞭金藻和塔胞藻在实验的浓度范围内未见移动。     

水合铁离子及铁络合物吸收系数光谱(400-900 nm)测量

测量铁化合物溶解物的吸收光谱曲线是水中铁离子含量遥感反演的关键。采用自主设计的水体透射光测量装置,利用ASD光谱仪测量相同厚度不同浓度铁离子溶液的透射光辐亮度,然后运用比值法计算出水中3种铁化合物(硫酸铁、氯化铁和铁氰化钾)的消光系数和吸收系数,最终得到400—900 nm波长范围内3种铁离子吸收系数光谱。该方法可以较好地消除实验装置和水中悬浮物的影响。结果表明,水中3种铁离子均在紫蓝光波段吸收作用较大,绿光次之,逐渐减少至红光波段后,吸收系数变化很小呈平缓直线。测量结果可作为水体铁离子浓度遥感反演模型所需的基础参数。     

不同传感器的模拟植被指数对水稻叶面积指数的估测精度和敏感性分析

本研究利用水稻冠层高光谱数据,模拟NOAA-AVHRR,Terra-MODIS和Landsat-TM的可见光波段反射率数据,计算各传感器的多种植被指数(NDVI,RVI,EVI,GNDVI,GRVI和Red-edge RVI),比较植被指数模型对水稻LAI的估测精度,分析不同植被指数对LAI变化的敏感性.相对于红波段植被指数,红边比值植被指数(Red-edge RVI)和绿波段指数GRVI与LAI有更好的线性相关关系,而GNDVI和LAI呈现更好的对数相关关系.MODIS的Red-edge RVI指数不仅模型拟合的精度最高,还有独立数据验证的估测精度也最高,而且它的验证精度较拟合精度下降幅度最小;其次是绿波段构建的GNDVI和GRVI植被指数的估测精度,再次是NDVI和EVI的估测精度,而RVI的估测精度最差.敏感性分析发现,13个植被指数对水稻LAI的估测能力都随着LAI的增加而下降,但归一化类植被指数和比值类植被指数对LAI变化反应的差异明显,归一化类植被指数在LAI较低时(LAI<1.5)对LAI变化的反应开始非常敏感,但迅速下降,而比值类植被指数在LAI较低时,明显小于归一化类植被指数,之后随着LAI的增大(LAI>1.5)比值类植被指数对LAI的变化敏感性,则明显高于归一化类植被指数.Red-edge RVI和绿波段指数GRVI和LAI不仅表现了很好的线性相关关系,而且在LAI大于2.9左右保持较高的敏感性.     

Re-parameterization of a quasi-analytical algorithm for colored dissolved organic matter dominant inland waters

Quasi-Analytical Algorithms (QAAs) are based on radiative transfer equations and have been used to derive inherent optical properties (IOPs) from the above surface remote sensing reflectance (R_rs) in aquatic systems in which phytoplankton is the dominant optically active constituents (OACs). However, Colored Dissolved Organic Matter (CDOM) and Non Algal Particles (NAP) can also be dominant OACs in water bodies and till now a QAA has not been parametrized for these aquatic systems. In this study, we compared the performance of three widely used QAAs in two CDOM dominated aquatic systems which were unsuccessful in retrieving the spectral shape of IOPS and produced minimum errors of 350% for the total absorption coefficient (a), 39% for colored dissolved matter absorption coefficient (a_CDM) and 7566.33% for phytoplankton absorption coefficient (a_phy). We re-parameterized a QAA for CDOM dominated (hereafter QAA_CDOM) waters which was able to not only achieve the spectral shape of the OACs absorption coefficients but also brought the error magnitude to a reasonable level. The average errors found for the 400–750 nm range were 30.71 and 14.51 for a, 14.89 and 8.95 for a_CDM and 25.90 and 29.76 for a_phy in Funil and Itumbiara Reservoirs, Brazil respectively. Although QAA_CDOM showed significant promise for retrieving IOPs in CDOM dominated waters, results indicated further tuning is needed in the estimation of a(λ) and a_phy(λ). Successful retrieval of the absorption coefficients by QAA_CDOM would be very useful in monitoring the spatio-temporal variability of IOPS in CDOM dominated waters.     

Ocean color reveals phase shift between marine plants and yellow substance

Daily high-resolution Sea-viewing Wide Field-of-view Sensor (SeaWiFS) images of the central North Atlantic Ocean (1998-2003) show that temporal changes in the absorption coefficient of colored dissolved organic matter (CDOM) or "yellow substance" follow changes in phytoplankton pigment absorption coefficient in time. CDOM peaks (between January and March) and troughs (late summer and fall) followed pigment peaks and troughs by approximately two and four weeks, respectively. This phase shift is additional strong evidence that CDOM in the marine environment is derived from phytoplankton degradation. The common assumption of linear covariation between chlorophyll and CDOM is a simplification even in this ocean gyre. Due to the temporal changes in CDOM, chlorophyll concentration estimated based on traditional remote sensing band-ratio algorithms may be overestimated by about 10% during the spring bloom and underestimated by a similar 10% during the fall. These observations are only possible through use of synoptic, precise, accurate, and frequent measurements afforded by space-based sensors because in situ technologies cannot provide the required sensitivity or synoptic coverage to observe these natural phenomena.     

Remote determination of chromophoric dissolved organic matter in lakes,China

Chromophoric dissolved organic matter (CDOM) strongly influences the water-leaving radiance from aquatic ecosystems. In most inland waters, the remote determination of CDOM absorption presents a central challenge due to their complex optical conditions. However, identifying the temporal and spatial variability of CDOM is fundamental to the understanding of aquatic biogeochemical dynamics. In the present study, semi-analytical and empirical modeling approaches were used to examine CDOM absorption in four, shallow, inland water bodies using the spectral bands and sensitivities of major satellite observational systems. Of the models examined, an empirical multiband model was found to provide the highest correlation with measured CDOM absorption. The spectral characteristics of the MERIS sensors yielded the best results with respect to the other available satellite sensors. High detrital load was observed to be a major impediment to estimating CDOM absorption, while lakes with elevated phytoplankton biomass did not present similar problems.     

Retrieval of CDOM and DOC Using In Situ Hyperspectral Data: A Case Study for Potable Waters in Northeast China

Chromophoric dissolved organic matter (CDOM), the light absorbing fraction of dissolved organic carbon (DOC), together with phytoplankton and total suspended matter are the main optically active components could be retrieved by remote sensing data. Generally, different composition of DOC and CDOM corresponds to different water surface reflectance. Absorption properties of CDOM and retrieval models for CDOM and DOC were investigated with data from potable reservoirs located in the central of Jilin Province. Water sampling field surveys were conducted on 15, 16 and 19 of September 2012 across the Shitoukoumen, Erlonghu and Xilicheng reservoirs, respectively. Both empirical regression (single band model and band ratio model) and partial least squares coupled with back-propagation artificial neural models (PLSBPNN) were established to estimate CDOM absorption coefficient at 355 nm [a_CDOM(355)] and DOC concentration with in situ measured remote sensing reflectance. It was found that the band ratio models and PLSBPNN model performed well for estimating DOC concentration while the band ratio models yielded the best result in retrieval CDOM. Moreover, all the three models performed better on the DOC concentration estimation than the performance on a_CDOM(355). Band ratio models outperformed (R ² ?=?0.55) other models for estimating CDOM absorption coefficient, while PLSBPNN model outperformed other models with respect to DOC estimation (R ² ?=?0.93). High spectral slope values indicated that CDOM in the potable waters primarily comprised low molecular weight organic substances; while sources of DOC were mainly coming from exogenous input, which was the main reason lead to the difference of model performances on DOC and a_CDOM(355) estimation. The algorithms developed in this study is needed to be tested and refined with more in situ spectral data, also future work is still needed to be undertaken for characterizing the dynamic of the potable water quality with remotely sensed imagery.     

低盐湖泊水体盐度光学遥感反演研究——以博斯腾湖为例

利用光学遥感反演盐度,可以充分利用遥感数据的空间代表性,以及目前高分率遥感数据的高时空精度。本文利用MERIS(Medium Resolution Imaging Spectrometer)300 m数据,以干旱区的博斯腾湖(博湖)为例,探讨了光学遥感数据反演低盐湖泊水体盐度的可行性。结果显示:在开都河入流影响的博湖西南角,存在光学遥感反演盐度利用的黄色物质(CDOM)与盐度的反比关系,但相关性不高,而且在博湖区域不同时间、不同区域CDOM与盐度的关系都不同。博湖盐度低于3 g·L-1,而遥感数据计算盐度的精度约为1.1 psu,因而用光学遥感数据计算博湖盐度的误差太大。博湖本身CDOM与盐度关系的时空异质性以及相关性不高,目前光学遥感反演精度有限,因此,在博湖用光学遥感数据反演整个湖区的盐度有困难。用光学数据反演水体盐度要求盐度足够高,盐度和CDOM存在梯度,并满足CDOM扩散守恒,因此用光学遥感反演低盐湖泊水体盐度较为困难。     

Dynamics of chromophoric dissolved organic matter in Mandovi and Zuari estuaries — A study through in situ and satellite data

The spatial and temporal distribution of absorption of chromophoric dissolved organic matter at 440 nm (a_CDOM (440)) in the Mandovi and Zuari estuaries situated along the west coast of India, has been analysed. The study was carried out using remotely sensed data, obtained from the Ocean Colour Monitor (OCM) on board the Indian Remote Sensing satellite — P4, together with in situ data during the period January to December 2005. Satellite retrieval of CDOM absorption was carried out by applying an algorithm developed for the site. A good correlation (R=0.98) was obtained between satellite derived CDOM and in situ data. Time series analysis revealed that spatial distribution of CDOM has a direct link with the seasonal hydrodynamics of the estuaries. The effect of remnant fresh water on CDOM distribution could be analysed by delineating a plume in the offshore region of the Zuari estuary. Though fresh water flux from terrestrial input plays a major role in the distribution of CDOM throughout the Mandovi estuary, its role in the Zuari estuary is significant up to the middle zone. Other processes responsible for feeding CDOM in both the estuaries are coastal advection, in situ production and resuspension of bottom settled sediments. The highest value of a_CDOM(440) was observed in the middle zone of the Mandovi estuary during the post-monsoon season. The relation between a_CDOM(440) and S (spectral slope coefficient of CDOM) could differentiate CDOM introduced in to estuaries through multiple sources. The algorithm developed for the Mandovi estuary is S=0.003 [a_CDOM(440)^−0.7091] while for the Zuari estuary, S=0.0031 [a_CDOM(440)^−0.777], respectively.     

Interaction of Hurricane Katrina With Optically Complex Water in the Gulf of Mexico: Interpretation Using Satellite-Derived Inherent Optical Properties and Chlorophyll Concentration

When Hurricane Katrina passed over southern Florida, Florida Bay and the West Florida Shelf, and into the Gulf of Mexico, empirically derived chl a increases were observed in the Tortugas Gyre circulation feature, and in adjacent waters. Analysis of the empirically derived chl a increase within the gyre has been primarily attributed to initiation of a phytoplankton bloom promoted by nutrients upwelled by Katrina's winds. Detailed analysis of inherent optical properties derived from remotely sensed radiances, however, indicated the interaction of Katrina with shallow coastal and shelf waters likely entrained waters with higher concentrations of chromophoric dissolved organic matter (CDOM) into the gyre circulation, augmenting the chl a signal. Storm-induced upwelling would also transport optically active CDOM to the surface. Increases in empirically derived chl a in the Florida coastal waters influenced by Katrina's winds were therefore partly due to increased absorption by CDOM. This analysis indicates that elevated empirically derived chl a in hurricane-influenced waters should not be unambiguously attributed to increased phytoplankton productivity, particularly in an optically complex coastal environment.