云南会泽铅锌矿区地下水化学和同位素分析

本文通过调查和采样测试,分析云南会泽铅锌矿区地下水的水化学特征,划分其水化学类型;根据不同水文年、不同埋深δ2 H和δ18 O的变化,分析了地表水体与地下水的相互关系,认为矿区中部含水层受到地表水的入渗,地表水与深部岩溶水的混合作用加大,中部岩溶含水层水力活动范围不断扩大,相对长江流域同位素分布规律,矿区降雨中重同位素偏富,深部岩溶水有显著的埋深效应,季节效应不明显。提供了一个矿区地下水水化学和同位素研究实例,对同类研究有借鉴价值。     

利用水化学特征识别桑树坪煤矿突水水源

及时准确地找到突水水源,是解决矿井突水问题的关键。通过对桑树坪煤矿主要含水层水样进行常规水质分析,并通过Piper三线图揭示了矿区不同地下水含水层的水化学特征,并通过出水点与背景值的水文地球化学特征对比,正确地判断出了该矿区突水水源为奥灰岩溶水。研究认为,水化学特征分析是一种快速判别突水水源的有效方法。     

利用水化学特征识别桑树坪煤矿突水水源

及时准确地找到突水水源,是解决矿井突水问题的关键。通过对桑树坪煤矿主要含水层水样进行常规水质分析,并通过Piper三线图揭示了矿区不同地下水含水层的水化学特征,并通过出水点与背景值的水文地球化学特征对比,正确地判断出了该矿区突水水源为奥灰岩溶水。研究认为,水化学特征分析是一种快速判别突水水源的有效方法。      

微量元素在福建马坑铁矿崎濑泉形成条件识别中的应用

崎濑泉是福建马坑铁矿区附近流量最大的泉,与矿区的关系一直没有查清。本文通过对前人勘察资料研究和在不同部位采水样进行分析的基础上,运用聚类分析和指示岩溶水、碎屑岩地下水补给来源和径流过程的Sr /Ca与Rb /K值研究了福建马坑铁矿崎濑泉补给来源和径流途径。结果表明,取自崎濑泉泉口水样与及矿区水文钻孔的岩溶水水样相关系数达到0.98,而与取自矿区北部砂岩裂隙水的水样相关性则很差;灰岩水和砂岩水间的相关系数仅为0. 26;崎濑泉水的Sr / Ca、Rb /K值与岩溶水的都比较相近,而砂岩裂隙水的Rb /K值则明显地较崎濑泉水与岩溶水的高,说明崎濑泉水的来源应当是深部的岩溶水,与其上部的砂岩裂隙水并无密切关系;崎濑泉的形成是大气降水在矿区东北部天山凹附近的灰岩裸露区渗入岩溶含水层并向西径流,至矿区中西部沿F10断层附近的岩溶强径流带径流至崎濑村,受陈坑- 崎濑断层阻挡然后涌出地面,而并非前人所说的是先由大气降水补给砂岩裂隙含水层,然后再由砂岩裂隙含水层补给下部的岩溶含水层。      

孔集井田地下水化学特征

本文在大量水化学资料的基础上，对淮南矿区孔集井田的水化学特征、类型及水中各离子含量间的关系等进行了分析与研究，采用水化学三线图的方法来揭示不同的水源主要离子组份所占的相应位置，提出了孔集井田岩溶、裂隙、孔隙、老塘及煤系顶板砂岩水的水质特征及差异，同时对同一岩溶含水层划分出不同的水文地质区段。     

潞安矿区奥陶系岩溶水化学成分的成因

潞安矿区奥陶系岩溶水由于埋藏深,水交替缓慢,水文地球化学条件复杂。本文在因子分析的基础上,深入分析了深部岩溶含水层中水-岩作用机理和水化学成分的成因。      

荥巩矿区岩溶地下水系统的水文地球化学特征及其指示意义

本文在分析荥巩矿区水文地质条件的基础上,重点对岩溶地下水系统的水化学特征进行分析。结果表明:岩溶水水化学类型自补给区到排泄区,从单一的HCO3型向复杂的HCO3.SO4型和SO4.HCO3型转变,TDS和Sr2+/Ca2+值均增加。地下水氢氧稳定同位素分析结果表明,本区岩溶地下水主要接受大气降水的入渗补给。根据同位素计算的补给高程推断岩溶水补给范围和划分的流动系统与地面调查结果及水化学研究成果一致:矿区处于区域流动系统排泄带,中寒武统张夏组—中奥陶统灰岩在矿区南部出露的范围接受降水补给,以侧向径流的方式进入矿区充水含水层。     

太原盆地地下水系统水化学特征及形成演化机制

在对太原盆地水文地质进行详细调查基础上,集成应用水化学统计、水化学模拟技术,系统研究了盆地地下水水化学类型、空间分布特征,并对其形成演化机制进行了系统分析,取得了一系列新的认识。按水质类型和分布特征,盆地浅层地下水-含水层埋深小于50 m大致分为盆地边缘地带浅层淡水、盆地中心浅层咸水和浅层高矿化硫酸盐水3种类型。高矿化硫酸盐水主要是由于接受了富含硫酸根离子的周边基岩水补给所致。盆地中深层孔隙水可分为盆地边缘中深层水、盆地中心中深层水和中深层混合水3种类型。浅层地下水存在2种形成机制,一种是高矿化Ca·Mg-SO_4^2-型岩溶水的混合补给形成,另一种高矿化水是在径流演化过程中受蒸发浓缩作用影响,使地下水矿化度不断增高而形成。自盆地边缘至中心地带,中深层地下水水化学特征具有明显的水平变化规律,在盆地中心形成2个高值区,水化学类型依次为Ca·MgHCO₃→Na·CaHCO₃·SO₄→Na·MgHCO₃·Cl→NaHCO₃。      

南方岩溶金属矿区地下水非均质性及防治水意义:以福建马坑铁矿为例

岩溶水系统非均质性是制约南方岩溶金属矿区防治水工作的关键难题之一.通过充分挖掘勘察及采掘过程中积累的水文地质资料,查明断层、岩溶、火成岩带等地质结构非均质因素的分布特征;通过绘制马坑矿区岩溶水系统7个不同时期的流场图,分析了天然条件及疏干降水条件下矿区岩溶水系统的特点,得出断层及岩溶发育控制着岩溶水的强径流带,可作为超前探水及疏干降水的主要目标;而火成岩局部隔水带的隔水作用使矿区岩溶水表现出强烈的不统一性,利用局部隔水带对矿区岩溶水进行分期防治,可尽快解放该区矿体,增加矿区产量,对马坑矿区长期发展具有重要意义.      

山西庞庞塔矿地下水化学特征及含水层间水力联系分析

依据矿区补勘钻孔抽水取得的水质化验资料,重点对影响煤层开采的奥陶系中统石灰岩岩溶裂隙含水层和太原组灰岩岩溶裂隙含水层进行了水化学特征分析,结果发现,奥陶系峰峰组含水层中SO42-离子含量普遍较高,大部分地段高于HCO3-离子含量,阳离子以Ca2+和Mg2+离子为主,水化学类型以SO4-Ca· Mg型为主;上马家沟组含水层SO42-离子含量较峰峰组岩溶裂隙水明显下降.根据各钻孔水质化验的主要离子成分、矿化度、总硬度及水化学类型进行各含水层间的水力联系分析,认为峰峰组含水层与上马家沟组含水层、太灰含水层与奥灰含水层水力联系均较弱.该研究可为矿井开采中开展水害防治提供参考.     

Geochemical characterization of karst groundwater in the cradle of humankind world heritage site,South Africa

The karst of the Cradle of Humankind World Heritage Site plays a major role in the assimilation or carrying of acid mine drainage, sewage effluent return flow and agricultural run-off. Infiltration of contaminated water has altered the chemical composition of the natural waters of the karst system. A multivariate statistical method in combination with conventional geochemical and spatial analysis was applied on groundwater and surface water quality samples to determine the spatial extent of hydrochemical impacts from different anthropogenic sources. The application of hierarchical cluster analysis of the major ions (148 samples) recognised three distinct hydrochemical regimes. Cluster 1 is moderately mineralized, especially with regard to chloride, nitrate and sulphate, cluster 2 has a low mineralization with all elements well within the recommended drinking water limits of South Africa and cluster 3 represents highly mineralized samples taken in the vicinity of decanting mineshafts. The cluster solution is confirmed by a simple mixing model, indicating varying contributions of three identified end members (acid mine drainage, treated sewage effluents and pristine dolomitic groundwater) to the groundwater quality in the catchment. The combination of statistical, geochemical and spatial methods in conjunction with end-member mixing analysis provides a reliable method to understand the processes responsible for the groundwater quality variations and to assist in the identification of anthropogenic impacts.     

Multivariate statistical analysis of geochemical data of groundwater in Veeranam catchment area,Tamil Nadu

The study of hydrogeochemistry of the Mio-Pliocene sedimentary rock aquifer system in Veeranam catchment area produced a large geochemical dataset. Groundwater samples were collected at 52 sites over 963.86 km² area and analyzed for major ions. The large number of data can lead to difficulties in the integration, interpretation and representation of the results. Two multivariate statistical methods, Hierarchical cluster analysis (HCA) and Factor analysis (FA), were applied to a subgroup of the dataset to evaluate their usefulness to classify the groundwater samples, and to identify geochemical processes controlling groundwater geochemistry. Hydrochemical data for 52 groundwater samples were subjected to Q- and R- mode factor and cluster analysis. R-mode analysis reveals the inter-relations among the variables studied and the Q-mode analysis reveals the inter-relations among the samples studied. The R-mode factor analysis shows that Ca, Mg and Cl with HCO₃ account for most of the electrical conductivity, total dissolved solids and total hardness of groundwater. The ‘single dominance’ nature of the majority of the factors in the R-mode analysis indicates non-mixing or partial mixing of different types of groundwater. Both Q-mode factor and Q-mode cluster analyses indicate an exchange between the river water and the groundwater in the vicinity. The rock water interaction like flood basin back swamp deposits of silty clayey formation is the major cause for the cluster II classification. Cluster classification map reveals that 58% of the study area comes under cluster II classification.     

Groundwater geochemistry of Ain Azel area,Algeria

Hydrogeochemical data for 18 groundwater samples and 11 hydrochemical parameters were subjected to Q- and R-mode cluster analysis and inverse geochemical modeling. Q-mode cluster analysis resulted in three distinct water types (brackish water type, saline water type and highly saline water type). R-mode cluster analysis led to the conclusion that the water–rock interaction is the major source of contamination for the groundwater in the area. Geochemical modeling results show that carbonates, gypsum, halite, carbon dioxide (gas), and chlorite are dissolving, whereas Ca-montmorillonite, gibbsite, illite, K-mica, kaolinite, and quartz are mostly precipitating along different flow paths in the groundwater system of the area.     

用氢氧稳定同位素评价闽江河口区地下水输入

通过分析闽江河口区降水、地表水和地下水的氢氧稳定同位素特征,揭示降水的环境同位素效应和地下水的形成演化规律,定量评价河口区多种水体的混合过程及地下水输入量。夏季的降水氢氧同位素组成相对贫化,呈现出降雨量效应。在δ18O与δD关系图上,闽江北岸基岩裂隙水、平原及丘陵区浅层地下水均落在福州降水线上,而南岸平原及丘陵区浅层地下水大部分落在福州降水线右下方,其拟合线与降水线交点与5~9月农灌期降水氢氧同位素加权值接近,表明北岸地下水主要来自降水补给,而南岸地下水同时接受灌溉水和降水补给,并在入渗过程中经历了不同程度的蒸发作用。闽江河口段除接受两岸地下水补给外,局部河段还接受断裂带裂隙水补给。将线性端元混合模型、数字高程模型和地下水文分析法结合起来定量评价地下水的输入和各水体的混合过程,结果显示,在河口段淡水区,地下水混合比率上限为8.8%,其中包括0.4%的断裂带裂隙水;在河口段淡咸水混合区,淡水(河水、地下水)和海水的混合比为53:47,其中地下水的保守混合比率为1.7%;枯水期闽江河口段地下水保守输入量为87.0 m3/s,是闽江径流量的12.8%。     

CFC在中国高放废物处置库预选区地下水研究中的应用

本文介绍了地下水测年的CFC方法及其原理,并将这种方法实际应用于我国高放废物处置库预选区——甘肃北山地区的水文地质研究,结果表明,研究区内沟谷洼地浅部地下水的CFC年龄在15~26a,基岩裂隙浅部地下水多为不含CFC的老水与含CFC的新水的混合水。在描述了确定混合比方法的基础上,根据样品CFC含量计算了研究区地下水的混合比。与氚相比,CFC是目前年轻地下水测年更好的工具,具有更多的优越性。     

Hydrogeochemistry of the Saloum (Senegal) superficial coastal aquifer

Seawater has entered and concentrated in the Saloum hydrologic system up to 100 km upstream, contaminating both the surface water and the superficial 'Continental terminal' (CT) groundwater resources, and large proportions of cultivated lands. In the areas affected by saltwater contamination, chloride concentrations as high as 3,195 mg/l have been measured in the groundwater samples collected from wells located in the vicinity of the Saloum River, making the water inadequate for drinking water purposes. This paper presents the results of a study designed to characterise the current extent of the saline groundwater and the mechanism of saline surface water body/fresh groundwater mixing in relation to the groundwater flow trends. It also describes the groundwater chemical and isotopic composition and geochemical processes controlling the chemical patterns. Four major water types occur in the study area, namely Na-rich saline groundwater, Ca-Na-rich saline groundwater, Na-dominant fresh groundwater and Ca-dominant fresh groundwater. A hydrogeochemical zonation of the aquifer, based on the presence of different water families and on the groundwater flow, led to the identification of the main processes controlling the groundwater chemistry. Cation exchange reactions on the kaolinite clay mineral, calcite dissolution in the eastern zone where calcite minerals have been identified, reverse cation exchange reactions in the saline-contaminated band along the Saloum River and, to a lesser extent, a gypsum dissolution are the predominant processes. Results of i¹⁸O and iD analysis in 15 groundwater samples compared with the local meteoric line indicate that the groundwater has been affected by evaporation, and the groundwater is isotopically lighter as the depth of water table increases. In this study, i¹⁸O data were used in conjunction with chloride data to identify the source of high chloride. Results show a departure of the contaminated water samples from the seawater mixing line, which indicates that other processes rather than mixing between modern seawater and native groundwater alone increase the chloride concentrations.     

Geochemical evolution of groundwater in southern Bengal Basin: The example of Rajarhat and adjoining areas,West Bengal,India

Detailed geochemical analysis of groundwater beneath 1223 km² area in southern Bengal Basin along with statistical analysis on the chemical data was attempted, to develop a better understanding of the geochemical processes that control the groundwater evolution in the deltaic aquifer of the region. Groundwater is categorized into three types: ‘excellent’, ‘good’ and ‘poor’ and seven hydrochemical facies are assigned to three broad types: ‘fresh’, ‘mixed’ and ‘brackish’ waters. The ‘fresh’ water type dominated with sodium indicates active flushing of the aquifer, whereas chloride-rich ‘brackish’ groundwater represents freshening of modified connate water. The ‘mixed’ type groundwater has possibly evolved due to hydraulic mixing of ‘fresh’ and ‘brackish’ waters. Enrichment of major ions in groundwater is due to weathering of feldspathic and ferro-magnesian minerals by percolating water. The groundwater of Rajarhat New Town (RNT) and adjacent areas in the north and southeast is contaminated with arsenic. Current-pumping may induce more arsenic to flow into the aquifers of RNT and Kolkata cities. Future large-scale pumping of groundwater beneath RNT can modify the hydrological system, which may transport arsenic and low quality water from adjacent aquifers to presently unpolluted aquifer.     

联合稳定同位素与水化学方法确定地下水污染源

地下水污染是废水参与地球水循环的结果,稳定同位素在全球水循环中的应用原理同样适用于研究地下水的地表污染源.通过与水化学方法结合,确定地下水的地表污染来源,计算了污水的混入比例,为今后地下水污染的治理提供了可靠的依据.     

关中地区地下热水的分类

环境同位素研究结果表明,研究区地热水为大气降水成因。根据降水补给的年代及混合程度可将地下热水分为主要由现代大气降水补给的混合型地下热水;由现代大气降水和古代降水补给的混合型地下热水;主要由古代大气降水补给的深部循环型地下热水。      

Hydrogeochemical processes affecting groundwater in an irrigated land in Central Tunisia

Detailed hydrogeochemical investigation has provided new information concerning the major factors and mechanisms controlling the groundwater chemistry of Chougafiya basin. The hydrogeochemical characteristics of groundwaters comprise three main types: Cl–SO₄–Ca, Cl–SO₄–Na and Cl–Na. Hydrochemical characteristics based on the bivariate diagrams of major (Cl^?, SO₄ ^2?, NO₃ ^?, HCO₃ ^?, Na⁺, Mg²⁺, K⁺ and Ca²⁺) and some trace (Br^? and Sr²⁺) ions, mineral saturation indices and hierarchical cluster analysis indicate different origins of groundwater mineralization. The water–rock interaction (dissolution of evaporitic minerals), followed by cation exchange reactions with clay minerals, constitute the main processes that control groundwater salinization. However, the chemical composition of brackish groundwater in the central and southern parts of the study area is influenced by a mixing process with Sabkhas salt groundwater. The mixing proportions inferred from chloride mass balance prove that the contribution of Sabkhas groundwater to Quaternary aquifer ranges between 2.7 and 9.1 %. These intrusion rates reflect the progress of the saltwater–freshwater interface, which is mainly controlled by the piezometric level variation and the distance to the Sabkhas.