Geochemical characteristics of the metapelites from the Xingxingxia group in the Eastern Segment of the Central Tianshan: Implications for the provenance and paleoweathering

Clastic sedimentary rocks record a number of in-formation about the compositions and paleoweathering conditions of the source areas, and the tectonic setting of the depositional basin[1―6]. The traditionallypetrological study commonly utilizes the major com-ponents (Quartz, Feldspar and Lithics) of the silici-clastic sedimentary rocks to investigate the source rock composition and tectonic setting[7]. However, thepetrological method is somewhat limited, because many of the mafic components f…     

Major and trace element provenance signatures in stream sediments from the Kando River, San'in district, southwest Japan

Abstract Basement rocks in the catchment of the Kando River in southwest Japan can be divided into two main groups. Paleogene to Cretaceous felsic granitoids and volcanic rocks dominate in the upstream section, and more mafic, mostly Miocene volcanic and volcaniclastic rocks occur in the downstream reaches. Geochemically distinctive Mount Sambe adakitic volcanic products also crop out in the west. X‐ray fluorescence analyses of major elements and 14 trace elements were made of two size fractions (<180 and 180–2000 µm) from 86 stream sediments collected within the catchment, to examine contrasts in composition between the fractions as a result of sorting and varying source lithotype. The <180 µm fractions are depleted in SiO₂ and enriched in most other major and trace elements relative to the 180–2000 µm fractions. Na₂O, K₂O, Ba, Rb and Sr are either depleted relative to the 180–2000 µm fractions, or show little contrast in abundance. Sediments from granitoid‐dominated catchments are distinguished by greater K₂O, Th, Rb, Ba and Nb than those derived from the Miocene volcanic rocks. Granitoid‐derived <180 µm fractions are also enriched in Zr, Ce and Y. Sediments derived from the Miocene volcanic rocks generally contain greater TiO₂, Fe₂O₃*, Sc, V, MgO and P₂O₅, reflecting their more mafic source. Sediments containing Sambe volcanic rocks in their source are marked by higher Sr, CaO, Na₂O and lower Y, reflecting an adakitic signature that persists into the lower main channel, where compositions become less variable as the bedload is homogenized. Normalization against source averages shows that compositions of the 180–2000 µm fractions are less fractionated from their parents than are the <180 µm fractions, which are enriched for some elements. Contrast between the size fractions is greatest for the granitoid‐derived sediments. Weathering indices of the sediments are relatively low, indicating source weathering is moderate, and typical of temperate climates. Some zircon concentration has occurred in granitoid‐derived <180 µm fractions relative to 180–2000 µm counterparts, but Th/Sc and Zr/Sc ratios overall closely reflect both provenance and homogenization in the lower reaches.     

Origin of the anomalies in light and middle REE in sediments of an estuary affected by phosphogypsum wastes (south-western Spain)

Sc, Y, Th, Cu and rare earth elements (REE) concentrations have been analyzed in 14 samples of surface sediments and in two gravity cores by means of ICP-MS. Mean concentrations of Sc, Y and Th in surface sediments are 6.23, 4.76 and 16.30 ppm, respectively, lower than those present in the Upper Continental Crust (UCC). Cu concentration in these sediments is very high, 1466 ppm, and is caused by inputs from the Odiel and Tinto rivers, affected by acid mine drainage. SigmaREE mean concentration is 106.8 ppm, lower than that observed in other rivers and estuaries. In the cores, Sc, Y and Th concentrations show a significant increase in the intermediate levels, between 10 and 40 cm depth. The same pattern exists with Cu, where concentrations of 4440 ppm can be reached. Vertical evolution patterns for Sc, Y, Cu and heavy REE (HREE) are similar, and contrary to those shown by Th, light REE (LREE) and middle REE (MREE). Plots of North American Shale Composite (NASC)-normalized REE data of surface sediments show a slight depletion in REE concentrations. Most samples present with middle REE enrichment relative to light REE and heavy REE. Conversely, samples of the intermediate levels of the cores show significant enrichment of REE relative to NASC and high values in the (La/Gd)NASC and (La/Yb)NASC ratios. These anomalies in the fractionation patterns caused by enrichments in LREE and MREE concentrations is related to the presence of high concentrations of Th. They were generated by effluents from fertilizer factories between 1968 and 1998 which used phosphorite as source material.     

Petrography and geochemistry of upper Triassic sandstones from the Tumengela Formation in the Woruo Mountain area,North Qiangtang Basin,Tibet: Implications for provenance,source area weathering,and tectonic setting

The petrography and major and trace element concentrations of the sandstones from the Tumengela Formation in the Woruo Mountain area, North Qiangtang Basin, are studied to determine their provenance, intensity of weathering and tectonic setting. The detrital compositions of the Tumengela sandstone samples are dominated by quartz (58.0–70.1 %, average 64.7 %) and lithic fragments (21.8–35.9 %, average 27.3 %), but low in feldspar content (4.9–12.9 %, average 8.0 %). The sandstones can be classified as litharenite and feldspathic litharenite according to their detrital compositions, which is consistent with the geochemical data. The detrital modal compositions reflect that these sandstones are probably derived from a recycled orogenic source. The index of chemical variability (ICV) and SiO₂/Al₂O₃ ratio values suggest that the compositional maturity and recycling were moderate. The weathering indices such as the chemical index of alteration (CIA), plagioclase index of alteration (PIA), chemical index of weathering (CIW), and Al₂O₃–(CaO* + Na₂O)–K₂O (A–CN–K) diagram indicate that the intensities of weathering in the source area were moderate. The Al₂O₃/TiO₂, Th/Co, La/Sc, La/Co, Th/Sc, Cr/Th ratio values and the discriminant function of the Tumengela sandstones indicate that the sediments were mainly derived from felsic source rocks, while also mixed with intermediate source rocks. The comparison of rare earth element patterns and its Eu anomalies to the probable source rocks infer that the sandstones were derived from the combination of granite, rhyolite, dacite, and gneisses. The proximal central uplift belt was probably the primary provenance area as evidenced by the petrographical and geochemical features of the Tumengela sandstones. The multidimensional tectonic discrimination diagram based on major elements show a collision setting (80 %) combined with a rift setting (20 %) for the Tumengela sandstones, which is consistent with the general geology of the study areas.     

Petrochemistry of sandstones from Neoproterozoic basins of the Bastar craton, Central Indian Shield: Implications for paleoweathering, provenance and tectonic history

Petrographic analysis and chemical analysis of major and trace elements including rare earth elements of the Neoproterozoic sandstones from the Chandarpur Group and the Tiratgarh Formation have been carried out to determine their provenance, tectonic setting and weathering conditions. All sandstone samples are highly enriched in quartz but very poor in feldspar and lithic fragments. Petrographically and geochemically these sandstones are classified as subarkose, sublitharenite and arenite. The Chemical Index of Alteration (CIA mean 68) and Th/U ratios (mean 4.2) for these sandstones suggest their moderate weathering nature. Generally, all sandstone samples are strongly depleted in major elements (except SiO₂), trace elements (except Zr) and REE in comparison with Post Archean Australian Shale (PAAS) and Upper Continental Crust (UCC). Their mineralogy and mean of elemental ratios suitable for determination of provenance and tectonic setting, e.g. Al₂O₃/SiO₂ (0.02), K₂O/Na₂O (10), Eu/Eu* (0.67), (La/Lu)n (10.4), La/Sc (3), Th/Sc (1.2), La/Co (0.22), Th/Co (0.08), and Cr/Th (7.2), support a felsic source and a passive margin tectonic setting for these sandstones. Also these key elemental ratios do not show much variation over a range of SiO₂. Thus we attest their significance in determining source rock characteristics of quartz rich sandstones. Chondrite‐normalized REE patterns with LREE enrichment and a strong negative Eu anomaly are also attributed to felsic source rock characteristics for these sandstones. The source rocks identified are granite and gneiss of the Bastar craton. Minor amounts may have been derived from older supracrustals of the Bastar craton. However, the major element data of the Paleoproterozoic Sakoli schists when compared with those of the Neoproterozoic sandstones indicate that the schists were derived from a mafic source and deposited in an active continental margin tectonic setting. There is, however, little difference in CIA values between the Paleoproterozoic Sakoli schists and Neoproterozoic sandstones, indicating prevailing of similar (moderate‐intense) weathering conditions throughout the Proterozoic in the Bastar craton. Our study also suggests a change in the provenance and tectonic setting of deposition of sediments from dominantly a mafic source and an active continental margin in the Paleoproterozoic to dominantly granite and gneiss (felsic source) and a passive continental margin in the Neoproterozoic in the Bastar craton.     

Geochemistry of the High Dam Lake sediments,south Egypt： implications for environmental significance

The goal of the present work is to perform a geochemical assessment of High Dam Lake bottom sediments for determining the fate, dispersion and levels of trace elements causing environmental pollution, and provided an access to their probable sources. The sediment samples were analyzed using ICP-MS for 20 elements; Ag, Ba, Cr, Cu, Ga, Hf, Mn, Pb, Rb, Sc, Se, Sn, Sr, Ta Th Ti, T1, U, V and Zr, and their obtained data were treated using statistical, graphical and mapping techniques. The results showed the data set of all analyzed elements affected by outliers and extreme values that caused deviation away from normality. Kruskal-Wallis test revealed that median of some trace element levels in Lake sediments, was not significantly different and other elements rejected the Null hypothesis. Most analyzed elements had high values of median and mean in sediments of Lake Nubia rather than Lake Nasser and their normalization gave the same results of calculated environment factors. Subsequently, Lake Nubia sediments possessed high combined EF levels ofTh, Sc, Sn, Ag, Zr, Hf, Ta, Sr, U, Ti, V, Cr, and Mn, causing significant contamination, which was great potentially related to industrial, agricultural, urbanization and mining activities. Whereas, combined EF of Se, Cu, Ga, Pb, Ba, Rb, and Tl, which are highly elevated in southern Lake Nasser sediments owing to their source are great possibly derived from Lake Nubia and geogenic activities. With decreasing distance towards the High Dam body, the contaminant elements were diminished due to reduction in the environmental factors and Sudanese pollution sources leading to the northern Lake Nasser considered to be less contaminated. Overall, the present study is an environmental alert for contaminated sediments that carried contaminants and considered the secondary source of pollution impact on ecosystem, and subsequently, their environmental risk on Human health.     

Geochemical baselines of major, minor and trace elements in the tropical sediments of the Terengganu River basin, Malaysia

The geochemical baselines and distribution of 31 elements (Al, Fe, K, Na, Mg, Ca, Mn, Ba, Cr, Zr, Ni, Sr, Zn, Y, Li, Cu, Mo, Nb, Th, Co, Ga, W, Ta, Be, Ti, Ge, Se, Bi, Te, Sc and Re) and physico-chemical parameters of the tropical surface sediments of the Terengganu River basin, Malaysia, are reported. Sediments are sandy loam to sand in texture consisting of mostly quartz, low organic matter content (average-2.68%), low CEC (average-2.02 cmol(+)/kg) and mildly acidic pH1:5 (average-5.91). Concentrations of Mn, Fe, Ba, Cr, Ni, Cu, Mo and Se were measured to be above the environmental sediment quality criteria at various locations. Lake sediments registered significantly higher Al, Fe, Ti, Mg, Ca, Mn, Te and Sc concentrations as compared to the river sediments. Most of the elements investigated showed an association with silt size fraction (2-63 μm). Among the investigated metals, Mo and Fe concentrations showed an increasing (5-fold) and decreasing (3-fold) trend, respectively, along the river path from the upstream to the downstream depending on the stream pH-redox conditions. The enrichment factor values (EF 5) of Cr, Ni, Mo and Se indicated enrichment from anthropogenic activities. Alkali and alkali earth metals registered a significant depletion (EF values 0.7) as compared to the Earth's crust. Principal component analysis of the two main components (PC1, 87.4% and PC2, 8.7%) revealed a well-defined group of estuary sediments. Lake and river sediment sampling locations did not form defined groups revealing heterogeneity in the origin of geologic material and the in-stream geochemical processes. However, Cr, Ni, Mo and Se formed a separate group with elevated concentrations (e.g. Cr1,000 mg/kg) indicating contamination of sediments. This work presents the geochemical baselines of the tropical sediments as industrial development and urbanization along the north east coast of Peninsular Malaysia are advancing rapidly.     

Chronology and petrogenesis of the Hejiazhuang granitoid pluton and its constraints on the Early Triassic tectonic evolution of the South Qinling Belt

The Hejiazhuang pluton is located in the South Qinling Tectonic Belt(SQTB)in the north side of the Mianxian-Lueyang Suture Zone,and consists dominantly of granodiorites.LA-ICP-MS zircon U-Pb dating and Lu-Hf isotopic analyses reveal that these granodiorites of the Hejiazhaung pluton emplaced at~248 Ma,and show a large variation in zirconεHf(t)values from4.8 to 8.8.These granodiorite samples are attributed to high-K to mid-K calc-alkaline series,and characterized by high SiO2(66.6%–70.0%),Al2O3(15.04%–16.10%)and Na2O(3.74%–4.33%)concentrations,with high Mg#(54.2–61.7).All samples have high Sr(627–751 ppm),Cr(55–373 ppm)and Ni(17.2–182 ppm),but low Y(5.42–8.41 ppm)and Yb(0.59–0.74 ppm)concentrations with high Sr/Y ratios(84.90–120.66).They also display highly fractionated REE patterns with(La/Yb)N ratios of 18.9–34.0 and positive Eu anomalies(δEu=1.10–2.22)in the chondrite-normalized REE patterns.In the primitive mantle normalized spidergrams,these samples exhibit enrichment in LILEs but depletion in Nb,Ta,P and Ti.These geochemical features indicate that the granodioritic magma of the Hejiazhuang pluton was derived from the partial melting of hybrid sources comprising the subducted oceanic slab and sediments,and the melts were polluted by the mantle wedge materials during their ascent.The emplacement ages and petrogenesis of the Hejiazhuang pluton prove that the initial subduction of the Mianlue oceanic crust occurred at~248 Ma ago,and the SQTB was still under subduction tectonic setting in the Early Triassic.     

柴达木盆地苏干湖表层沉积与尘暴事件——元素示踪的初步结果

通过分析苏干湖地区10个地表表层沉积物、9个大气降尘(含2个尘暴降尘)、16个湖泊表层沉积物等样品的8种常量-微量元素和11种稀土元素的含量,以及同类沉积不同元素含量和不同沉积同一元素含量的相关性,结果表明,在湖泊沉积体系中Al、Fe、Sc含量的变化与强风-尘暴过程有关,指示了湖泊沉积碎屑颗粒风成输入的可能性．元素Fe、Sc含量在3种不同的沉积物中差异不大,与尘暴事件的强度和频次有关．稀土元素结果显示3类沉积具有同源性．苏干湖沉积可以用来重建研究区尘暴演化历史．     

Lower crustal melting via magma underplating: Elemental and Sr–Nd–Pb isotopic constraints from late Mesozoic intermediate–felsic volcanic rocks in the northeastern North China Block

Ar–Ar dating, major and trace element analyses, and Sr–Nd–Pb isotope results of two groups of Lower Cretaceous (erupted at 126 and 119 Ma, respectively) intermediate–felsic lava from the northeastern North China Block (NCB) suggest their derivation from melting of mixtures between the heterogeneous lower crust and underplated basalts. Both groups exhibit high‐K calc‐alkaline to shoshonitic affinities, characterized by light rare earth element (LREE) and large ion lithophile element (LILE) enrichment and variable high field strength element (HFSE, e.g. Nb, Ta and Ti) depletion, and moderately radiogenic Sr and unradiogenic Nd and Pb isotopic compositions. Compared with Group 2, Group 1 rocks have relatively higher K₂O and Al₂O₃/(CaO + K₂O + Na₂O) in molar ratio, higher HFSE concentrations and lower Nb/Ta ratios, and higher Sr–Nd–Pb isotope ratios. Group 1 rocks were derived from a mixture of an enriched mantle‐derived magma and a lower crust that has developed radiogenic Sr and unradiogenic Nd and Pb isotopic compositions, whereas the Group 2 magmas were melts of another mixture between the same mantle‐derived component and another type of lower crust having even lower Sr, Nd, and Pb isotopic ratios. Shift in source region from Group 1 to Group 2 coincided with a change in melting conditions: hydrous melting of both the underplated basalt and the lower crust produced the earlier high‐Nb and low‐Nb/Ta melts with little or no residual Ti‐rich phases; while the younger low‐Nb and high‐Nb/Ta magmas were melted under a water‐deficient system, in which Ti‐rich phases were retained in the source. Generation of the two groups of intermediate–felsic volcanic rocks was genetically linked with the contemporaneous magma underplating event as a result of lithospheric thinning in the eastern NCB.     

Geochemistry, K–Ar geochronology and Sr–Nd–Pb isotope compositions of pitchstone in Gohado, southwestern Okcheon Belt, South Korea

Abstract Geochemical and Sr–Nd–Pb isotope characteristics, as well as K–Ar geochronology of a massive pitchstone (volcanic glass) stock erupted into Late Cretaceous lapilli tuff and rhyolite in the Gohado area, southwestern Okcheon Belt, South Korea, are reported. The pitchstones are highly evolved with SiO₂ contents ranging from ～72 to 73 wt%, K₂O/Na₂O ratios of 1.04–1.23 and low MgO/FeO^t values (0.17–0.20). The pitchstones are weakly peraluminous and the ASI (molar Al₂O₃/Na₂O + K₂O + CaO) values are significantly lower than 1.1. The pitchstones also display a general calc‐alkaline nature with significant alkali contents. The rare earth elements (REE) compositions show moderately fractionated nature with (La/Yb)_N ranging from 11 to 16. Chondrite normalized REE patterns show relative enrichment of light REE over heavy REE and moderate Eu anomaly (Eu/Eu* ratio varies from 0.53 to 0.57). A distinct negative Nb anomaly is observed for all pitchstones on a primitive mantle normalized trace element diagram, typical of subduction‐related magmatism and crustal‐derived granites. All these features are characteristic of I‐type granites derived from a continental arc. The pitchstones have Zr contents of 98.5–103.5 ppm with zircon thermometry yielding temperatures of 749–755°C (mean 752°C). The K–Ar analyses of representative pitchstone samples yielded ages of 58.7 ± 2.3 and 62.4 ± 2.1 Ma with a mean age of 61 Ma. The rocks show nearly uniform initial ⁸⁷Sr/⁸⁶Sr isotopic ratios of 0.7104–0.7106 and identical ¹⁴³Nd/¹⁴⁴Nd initial ratio of 0.5120. The rocks display negative εNd (61 Ma) values of ?12. The depleted mantle model ages (T_DM) range from 1.54 Ga to 1.57 Ga. The Pb isotope ratios are ²⁰⁶Pb/²⁰⁴Pb = 18.522–18.552, ²⁰⁷Pb/²⁰⁴Pb = 15.642–15.680 and ²⁰⁸Pb/²⁰⁴Pb = 38.794–38.923. These ratios suggest that the Gohado pitchstones were formed in a continental arc environment by partial melting of a 1.54 Ga to 1.57 Ga parental sources of lower crustal rocks probably of mafic or intermediate compositions.     

Zircon U–Pb ages of Miocene granitic rocks in the Koshikijima Islands: Implications for Neogene tectonics in the Kyushu region,southwest Japan

The opening of the Japan Sea separated southwest Japan from the Eurasian continent during the Early to Middle Miocene. Since then, diverse igneous activities have occurred in relation to the subduction of the Philippine Sea Plate beneath southwest Japan. The Okinawa Trough formed in the back-arc region of the Ryukyu Arc since the Late Miocene. In the Koshikijima Islands, off the west coast of Kyushu and near the northern end of the Okinawa Trough, felsic to intermediate igneous rocks with Middle to Late Miocene radiometric ages occur as granitic intrusions and dikes. We obtained zircon U–Pb ages and whole-rock major- and trace-element compositions of Koshikijima granitic rocks to elucidate their magmagenesis. The U–Pb ages of granitic rocks in Kamikoshikijima and Shimokoshikijima and a dacite dike are about 10 Ma, suggesting that most magmatism on the Koshikijima Islands was coeval with early rifting in the Okinawa Trough. We infer that magmagenesis occurred via melting of lower crustal mafic rocks related to rifting in the Okinawa Trough based on the arc-like trace-element compositions of these I-type granites. Andesitic dikes preceded felsic igneous activity on the Koshikijima Islands, and their ages and petrochemistry will help elucidate the magmatism and tectonics in this area throughout the Miocene.     

Geochemical characteristics of organic matter-rich strata of lower Cambrian in Tarim Basin and its origin

The organic matter-rich strata of the Yurtusi Formation of Lower Cambrian are wildly spread and steady in the Tarim Basin, in which cherts are developed, companied with phosphorite. Al/(Al+Fe+Mn) ratio and Si/(Si+Al+Fe) ratio of cherts range from 0.0023 to 0.0046 and 0.965 to 0.98, respectively, suggesting that cherts are formed in submarine hydrothermal activity and far away from terrestrial. Trace elements, such as As, Hg, Pb, Zn, Cu, Co, P, V, Ba, etc., are markedly rich in organic matter-rich sedimentary rocks of which Ba/Sr ratios are between 21.2 and 158.1. Compared with modern hydrothermal sediments, their Ba/Sr ratios are similar, it indicates that the organic matter-rich strata have the geochemical feature of submarine hydrothermal sediments. The total content of rare earth elements (ЕREE) in cherts is from 8.81 to 56.682 μg/g, on average 31.41 μg/g and the ΕREE of cherts is between continental margin chert's and abyssal chert's. The LREE/HREE ratio of cherts varies from 1.01 to 3.56, which reveals the characteristics of hydrothermal sediments. There is positive correlation between the total organic content (TOC) and Ba/Sr ratio which is geochemical index of submarine hydrothermal activity, which indicates that the submarine hydrothermal activity obviously influences the richness of organic matter in the Yurtusi Formation.     

Hf–Nd isotope constraints on the origin of Dehshir Ophiolite,Central Iran

The peri‐Arabian ophiolite belt, from Cyprus in the west, eastward through Northwest Syria, Southeast Turkey, Northeast Iraq, Southwest Iran, and into Oman, marks a 3000 km‐long convergent margin that formed during a Late Cretaceous (ca 100 Ma) episode of subduction initiation on the north side of Neotethys. The Zagros ophiolites of Iran are part of this belt and are divided into Outer (OB) and Inner (IB) Ophiolitic Belts. We here report the first Nd–Hf isotopic study of this ophiolite belt, focusing on the Dehshir ophiolite (a part of IB). Our results confirm the Indian mid‐oceanic ridge basalt (MORB) mantle domain origin for the Dehshir mafic and felsic igneous rocks. All lavas have similar Hf isotopic compositions, but felsic dikes have significantly less‐radiogenic Nd isotopic compositions compared to mafic lavas. Elevated Th/Nb and Th/Yb in felsic samples accompany nonradiogenic Nd, suggesting the involvement of sediments or continental crust.     

Combined high-resolution aeromagnetic and radiometric mapping of uranium mineralization and tectonic settings in Northeastern Nigeria

Geological lineaments, depths to the basement, uranium concentrations, and remobilization in parts of the Upper Benue Trough, covering about 55 × 55 km² (longitudes 11°30′–12°00′E and 10°30′–10°30′N), Northeastern Nigeria were investigated using integrated High-Resolution Aeromagnetic Data (HRAD) and radiometric data. This was with a view to identifying the potential zones of uranium occurrence in the area. The HRAD was processed to accentuate anomalies of interest and depths estimate of 150–1941 m were obtained from source parameter imaging technique. The results from the superposition of the horizontal gradient magnitude, analytical signal amplitude, first vertical derivative, and 3D Euler solutions of the HRAD revealed that the study area was dissected by linear structures that trend ENE–WSW, NE–SW, E–W, NNE–SSW, WNW–ESE, and NW–SE; among which the ENE–WSW and NE–SW trends dominated. Analyses of radiometric data showed that uranium ores in the study area were possibly remobilized epigenetically from the granitic rocks, and were later deposited into sedimentary rocks (Bima formation). Burashika group (Bongna hills) and Wawa area of the study area showed vein-type deposits, while the anatectic migmatite in the northeastern region and the uranium rich Bima formation showed both fault/fracture and contact types of deposition. It was also observed the northwesterly and southeasterly, dominant dip direction, dipping faults dip in the same direction as the paleocurrent direction (direction of depositions of sediments), and trend in a direction perpendicular to the hypothetical direction of uranium deposition. The study concluded that the studied area is dissected by several linear structures and the studied area possibly contains deposits of uranium ore, which are likely to be found in: the Bima Sandstones of Wade, Shinga, Bima hill, Wuyo, Teli, Bryel, Dali, Barkan, Gasi, Kunkun, Boragara, Deba, and Gberundi localities; the anatectic migmatite at Kubuku, Whada, and Hyama; and the Bongna hills and agglomerates around Burashika, Kawaba, and Galu.     

Zircon saturation revisited: temperature and composition effects in a variety of crustal magma types

Hydrothermal experiments in the temperature range 750–1020°C have defined the saturation behavior of zircon in crustal anatectic melts as a function of both temperature and composition. The results provide a model of zircon solubility given by: In D_Zr^zircon/melt= ?3.80?[0.85(M?1)]+12900/T where D_Zr^zircon/melt is the concentration ratio of Zr in the stoichiometric zircon to that in the melt, T is the absolute temperature, and M is the cation ratio (Na + K + 2Ca)/(Al · Si). This solubility model is based principally upon experiments at 860°, 930°, and 1020°C, but has also been confirmed at temperatures up to 1500°C for M = 1.3. The lowest temperature experiments (750° and 800°C) yielded relatively imprecise, low solubilities, but the measured values (with assigned errors) are nevertheless in agreement with the predictions of the model.For M = 1.3 (a normal peraluminous granite), these results predict zircon solubilities ranging from ～ 100 ppm dissolved Zr at 750°C to 1330 ppm at 1020°C. Thus, in view of the substantial range of bulk Zr concentrations observed in crustal granitoids (～ 50–350 ppm), it is clear that anatectic magmas can show contrasting behavior toward zircon in the source rock. Those melts containing insufficient Zr for saturation in zircon during melting can have achieved that condition only by consuming all zircon in the source. On the other hand, melts with higher Zr contents (appropriate to saturation in zircon) must be regarded as incapable of dissolving additional zircon, whether it be located in the residual rocks or as crystals entrained in the departing melt fraction. This latter possibility is particularly interesting, inasmuch as the inability of a melt to consume zircon means that critical geochemical “indicators” contained in the undissolved zircon (e.g. heavy rare earths, Hf, U, Th, and radiogenic Pb) can equilibrate with the contacting melt only by solid-state diffusion, which may be slow relative to the time scale of the melting event.     

Lithium isotope variations in Tonga–Kermadec arc–Lau back‐arc lavas and Deep Sea Drilling Project (DSDP) Site 204 sediments

Lithium isotopes have been identified as a promising tracer of subducted materials in arc lavas due to the observable variations in related reservoirs such as subducting sediments and altered oceanic crust. The Tonga–Kermadec arc–Lau back‐arc provides an end‐member of subduction zones with the coldest thermal structure on Earth. Reported here are Li isotope data for 14 lavas from the arc front and 7 back‐arc lavas as well as 12 pelagic and volcaniclastic sediments along a profile through the sedimentary sequence at DSDP Site 204. The arc and back‐arc lavas range from basalts to dacites in composition with SiO₂ = 48.3–65.3 wt% over which Li concentrations increase from 2 ppm to 16 ppm. Li/Y ratios range from 0.08 to 0.77 and from 0.24 to 0.65 in the arc and back‐arc lavas, respectively. The majority of the lavas have δ⁷Li that ranges from 2.5 ‰ to 5.0 ‰ with an average of (3.6 ±0.7) ‰, similar to that reported from other arcs and there is no distinction between the arc front and back‐arc lavas. The pelagic sediments have variable Li concentrations (33–133 ppm) and δ⁷Li that ranges from 1.2 ‰ to 10.2 ‰ while the volcaniclastic sediments have an even greater range of Li concentrations (3.6–165 ppm) and generally higher δ⁷Li values (8–14 ‰). However, δ⁷Li in the lavas does not correlate with commonly used trace element ratio or isotope signatures indicative of slab‐derived fluids or the sediments. This is probably because the range of δ⁷Li in the lavas and sediments overlap. Calculated sediment mass‐balance models require significantly more sediment than previous estimates based on Th–Nd–Be isotopes. This may indicate that a sizeable proportion of the total Li budget in the lavas is provided by Li‐enriched fluids from the subducting sediments and/or altered oceanic crust.     

Volcanic resurfacing and the early terrestrial crust: Zircon U-Pb and REE constraints from the Isua Greenstone Belt, southern West Greenland

The oldest known bona fide succession of clastic metasediments occurs in the Isua Greenstone Belt, SW Greenland and consists of a variety of mica schists and rare metaconglomerates. The metasediments are in direct contact with a felsic metavolcanic lithology that has previously been dated to 3.71 Ga. Based on trace element geochemical data for > 30 metasediments, we selected the six samples with highest Zr concentrations for zircon extraction. These samples all yielded very few or no zircon. Those extracted from mica schists yielded ion probe U/Pb ages between 3.70 and 3.71 Ga. One metaconglomerate sample yielded just a single zircon of 3.74 Ga age.The mica schist hosted zircons have U/Pb ages, Th / U ratios, REE patterns and Eu anomalies indistinguishable from zircon in the adjacent 3.71 Ga felsic metavolcanic unit. Trace element modelling requires the bulk of material in the metasediments to be derived from variably weathered mafic lithologies but some metasediments contain substantial contribution from more evolved source lithologies. The paucity of zircon in the mica schists is thus explained by incorporation of material from largely zircon-free volcanic lithologies. The absence of older zircon in the mica schists and the preponderance of mafic source material imply intense, mainly basaltic resurfacing of the early Earth. The implications of this process are discussed.Thermal considerations suggest that horizontal growth of Hadean crust by addition of mafic-ultramafic lavas must have triggered self-reorganisation of the protocrust by remelting. Reworking of Hadean crust may have been aided by burial of hydrated (weathered) metabasalt due to semi-continuous addition of new voluminous basalt outpourings. This process causes a bias towards eruption of Zr-saturated partial melts at the surface with O-isotope compositions potentially different from the mantle. The oldest zircons hosted in sediments would have been buried to substantial depth or formed in plutons that crystallised at some depth, from which it took hundreds of millions of years for them to be exhumed and incorporated into much younger sediments.     

Isotopic composition (δ18O and δD) of precipitation and groundwater in a semi‐arid,mountainous area (Guadiana Menor basin,Southeast Spain)

We characterize the precipitation and groundwater in a mountainous (peaks slightly above 3000 m a.s.l.), semi‐arid river basin in SE Spain in terms of the isotopes ¹⁸O and ²H. This basin, with an extension of about 7000 km², is an ideal site for such a study because fronts from the Atlantic and the Mediterranean converge here. Much of the land is farmed and irrigated both by groundwater and runoff water collected in reservoirs. A total of approximately 100 water samples from precipitation and 300 from groundwater have been analysed. To sample precipitation we set up a network of 39 stations at different altitudes (800–1700 m a.s.l.), with which we were able to collect the rain and snowfall from 29 separate events between July 2005 and April 2007 and take monthly samples during the periods of maximum recharge of the aquifers. To characterize the groundwater we set up a control network of 43 points (23 springs and 20 wells) to sample every 3 months the main aquifers and both the thermal and non‐thermal groundwater. We also sampled two shallow‐water sites (a reservoir and a river). The isotope composition of the precipitation forms a local meteoric water line (LMWL) characterized by the equation δD = 7·72δ¹⁸O + 9·90, with mean values for δ¹⁸O and δD of − 10·28‰ and − 69·33‰, respectively, and 12·9‰ for the d‐excess value. To correlate the isotope composition of the rainfall water with groundwater we calculated the weighted local meteoric water line (WLMWL), characterized by the equation δD = 7·40δ¹⁸O + 7·24, which takes into account the quantity of water precipitated during each event. These values of (dδD/dδ¹⁸O)< 8 and d‐excess (δD–8δ¹⁸O)< 10 in each curve bear witness to the ‘amount effect’, an effect which is more manifest between May and September, when the ground temperature is higher. Other effects noted in the basin were those of altitude and the continental influence. The isotopic compositions of the groundwater are represented by the equation δD = 4·79δ¹⁸O − 18·64. The groundwater is richer in heavy isotopes than the rainfall, with mean values of − 8·48‰ for δ¹⁸O and − 59·27‰ for δD. The isotope enrichment processes detected include a higher rate of evaporation from detrital aquifers than from carbonate ones, the effects of recharging aquifers from irrigation return flow and/or from reservoirs' leakage and enrichment in δ¹⁸O from thermal water. Copyright © 2010 John Wiley & Sons, Ltd.