夏季浙江沿岸陆架区泥沙输运机制

基于2014年夏季浙江沿岸陆架区的水文、泥沙、底质沉积物等实测资料,运用物质通量分析方法和Gao-Collins粒径趋势分析法,探讨了泥沙的输运通量、输运方向、动力机制及净输运趋势。夏季,近岸含沙量规律性较强,由西至东逐渐降低,由南至北逐渐升高,且与潮流有非常好的对应关系,呈现出明显的潮周期变化特征。研究区净悬沙通量自岸向外海迅速变小,悬沙输运中平流输运占主导地位,其次是垂向净环流对悬沙输运的影响,近岸海域表现为向海输沙,30 m以深海域表现为东北向输沙,同时台湾暖流的屏障作用也影响了悬沙向海扩散。粒径趋势分析显示浙江沿岸陆架表层沉积物的长期输运机制为由东北向西南输运,在流系以及海底地形的影响下,中部海域出现粒径趋势较弱的沉积中心。而在夏季,悬浮泥沙主要为平行岸线向东北输运,估算每天进入研究海域的净悬浮泥沙约为1.9×106 t。     

A study of stability of the seafloor foundation on a gently sloping continental shelf

Abstract

The possibility of seafloor failure under external loadings on a gently sloping continental shelf is controlled, to a large extent, by the geotechnical characters of subbottom sediments (e.g., shear strength, compressibility, and liquefaction potential) and structural factors (e.g., sedimentary stratification). By means of undis‐turbing coring, in‐situ acoustic measurement, and subbottom profiling, the authors conducted an investigation into the seafloor instabilities and possibilities of sediment slope failure within the continental shelf off the Pearl River mouth, which is one of the most important areas for offshore development in the northern South China Sea. Based on in‐situ and laboratory measurements and tests for sediment physical properties, static and dynamic behavior, and acoustic characteristics, the analyses indicate: (1) subbottom sediments that originated from terrigenous clay during the Pleistocene are compact and overconsolidated, and the mean sound velocity in such sediments is relatively high; (2) the maximum vertical bearing capacity of subbottom sediments is efficiently conservative on the safe side for dead loads of light structures, and the trench walls are stable enough while trenching to a depth of about 2 m below the seafloor under still water; and (3) it is quite improbable that the subbottom sediments liquefy under earthquake (M ≤ 6) or storm wave loading.     

Geological aspects of marine slope stability,northwestern Gulf of Mexico

Abstract

The improvement of sensors such as various high‐resolution seismic and navigational systems and side‐scan sonar, of offshore shallow‐water drilling techniques, and of laboratory analyses has allowed the marine geologist to make more accurate identifications and maps of the distribution of numerous types of marine sediment instabilities, as well as to determine the mechanisms responsible for their occurrence. A large number of data on the continental shelf and upper continental slope off the modern delta of the Mississippi river have been compiled; these data will be used to document the major types of slope instabilities. The continental shelf and slope off the modern Mississippi river delta display various types of sediment instability. High rates of sedimentation (up to 80 m per century), weak, high‐water‐content clays, and differential weighting of clay sediments characterize this region. The major types of sediment instabilities that have been documented include (a) Peripheral slumping, with dimensions of slumps ranging from 200 to 1000 m; slumping often occurring in multiple stairstep arrangement; and downslope movement as high as 700 m per year. (b) Shallow diapiric intrusions, ranging in size from a few hundred meters to 2 km in diameter; vertical displacement ranging from 200 to 500 m; rate of sediment movement several meters per year; and intrusions caused by differential sediment loading, (c) Radial graben (tensional faulting), with widths from 50 to 500 m and lengths of several kilometers; both vertical and downslope lateral movements occurring; and downslope movements of surface material as much as 5 m per year common. (d) Circular collapse depressions, with diameters of depressions ranging from 50 to 500 m; topography of depression interiors, hummocky; and depressions possibly caused by dewatering or degassing of sediments under the influence of cyclic wave loading. (e) Surface mudflows, thick (often more than 35 m) masses of surface sediment flowage; often bounded by abrupt seaward slope; mudflows often extending laterally for distances in excess of 100 km; movement sporadic and lobate and rates of movement as much as several hundred meters per year; often being associated with extremely hummocky topography and mud volcanoes; and with extrusion of sediments the possible mechanism. (f) Shelf‐edge arcuate slumps, with large arcuate slumps displacing several hundred meters of sediment; slippage planes are commonly concave. Finally, (g) Various deep‐seated faults, with faults extending from deep horizons up to modern sediment surface; commonly being associated with abrupt scarps on the seafloor; numerous contemporaneous faults; and local slumping associated with fault scarps.     

Sediments on the continental shelf and slope between Napier and castlepoint,New Zealand

Sediments from the seabed off the eastern side of the North Island, New Zealand, are divided into 12 facies on the basis of grain size and mineralogy of the sand fraction. The facies are grouped into three types; modern detrital sediments, relict detrital sediments, and non‐detrital sediments. The sediments are described in terms of a modified Wentworth grain‐size scale and a modified Folk sediment classification.

The modern detrital sediments range from fine sand near the shore to clayey fine silt on the lower slope. At most places they are bimodal, probably because floes and single grains are deposited together. The relict detrital sediments, which include sands and gravels, occur where deposition is slow on the inner continental shelf and near the shelf edge. Those near the shelf edge include Last Glacial sandy muds that have been winnowed and mixed with Holocene volcanic ash and glauconite. The non‐detrital sediments, which contain forarninifera, volcanic ash, and glauconite, but no detrital sand, occur on anticlinal ridges on the continental slope. In places they overlie muddier sediment deposited during the last glaciation when the sources of river‐borne detritus were nearer than at present and when mud was deposited more rapidly on the ridges than at present.     

Suspended sediment transport of the Hangzhou Bay and its related hydrodynamic analyses

The 25-h measurements of current speed, flow direction, water depth, suspended sediment concentration and salinity were carried out at six anchored stations in the study area during spring and neap tides in winter of 1987 and summer of 1989. Caculations and analyses of the data obtained show that large amounts of suspended sediments are moved back and forth under the action of tidal current, and the net transport of sediment is small, with its predominance upstream in winter and downstream in summer. These calculations and analyses also suggest that the advective transport of sediment is dominant, while the vertical gravitational circulation of the suspended sediment comes next. Meantime, it is indicated that tidal currents play a major role in the suspended sediment transport, and residual flows have effect on the net transport of the suspended sediment, which is more remarkable during neap tide than during spring tide.     

Suspended sediment transport from the Gironde estuary (France) onto the adjacent continental shelf

Current velocity and suspended sediment concentration measurements at anchor stations in the downstream extremity of the Gironde estuary indicate that during periods of high river discharge, a significant amount of suspended sediment is transported out of the estuary onto the adjacent continental shelf. The vertical profile of the residual (non-tidal) suspended sediment flux is similar to that of the residual current velocity, with a net upstream flux near the bottom and an overlying seaward-directed transport. The overall, depth-integrated result is a net seaward transport of suspended sediment out of the estuary. It appears that this net seaward transport varies directly with tidal amplitude.Aerial photography and water sampling indicate that during high river inflow, the downstream extremity of the turbidity maximum extends onto the continental shelf at ebb tide. The tidal and coastal current patterns of the inlet and inner shelf induce a northward transport of the turbid estuarine water, and at each tidal cycle, a certain amount of suspended sediment leaves the estuary; part of this sediment is deposited in a silt and clay zone on the continental shelf.     

Preliminary observations of the internal tide over the shelf west of New Zealand

Abstract

Semidiurnal variations in the depth of the thermocline observed near the shelf edge north‐west of Cape Egmont are probably caused bv an internal tide generated at around 200 m depth over the continental slope. The observations suggest that in this region an internal tide, with amplitude of about 20 m, propagates onto the shelf with a speed of approximately 0.5 m·s^?1 and a wavelength of about 22 km.     

Distribution and morphology of large submarine sediment slides and slumps on Atlantic continental margins

Abstract

Numerous large sediment slides and slumps have been discovered and surveyed on the continental margins of Northwest Africa, Southwest Africa, Brazil (Amazon Cone), the Mediterranean, the Gulf of Mexico, and North America over the past 10 years. The mass movements are of two primary types: (1) translational slides, and (2) rotational slumps. Translational slides are characterized by a slide scar and a downslope zone of debris flows, after traveling in some areas for several hundreds of kilometers on slopes of less than 0.5°. Rotational slumps are bounded by steep scarps, but they do not involve large‐scale translation of sediments, although seismic records indicate disturbance in the down‐dropped block. Many of the slides and slumps have occurred in water depths greater than 2000 m on initial slopes of less than 1.5°. The largest slide so far discovered is off Spanish Sahara; in this case, the slide scar is 18,000 km² in area, at least 600 km³ in volume of translated sediments. No apparent consistent relationship has yet been observed between the presence of the slides and the sedimentary environment in which they occurred. The slides off Southwest Africa and Spanish Sahara occurred in pelagic sediments rich in planktonic organic matter. In contrast, the slides off North America, Senegal‐Mauritania, and Brazil (Amazon Cone) occurred in sediments containing a high percentage of terrigenous material from nearby landmasses. Large sediment slides have also occurred in pelagic sediments on isolated oceanic rises such as the Madeira Rise (East‐Central Atlantic) and the Ontong‐Java Plateau (Pacific), where sedimentation rates are less than 2 cm/1000 years. The failure mechanism of the slides initiated near the shelf edge can probably be explained by sediment overloading during low glacio‐eustatic sea level, which allowed rivers to debouch sediments directly onto the outer shelf or upper slope. Possible mechanisms of failure of the deepwater slides and slumps include earthquakes, undercutting of the slope by bottom currents, and changes in porewater pressures induced as a direct or indirect result of glacio‐eustatic changes in sea level.     

Input of Glaciomarine Sediments along the East Antarctic Continental Margin; Depositional Processes on the Cosmonaut Sea Continental Slope and Rise and a Regional Acoustic Stratigraphic Correlation from 40° W to 80° E

Multichannel seismic reflection data from the Cosmonaut Sea margin of East Antarctica have been interpreted in terms of depositional processes in the continental slope and rise area. A major sediment lens is present below the upper continental rise along the entire Cosmonaut Sea margin. The lens probably consists of sediments supplied from the shelf and slope, being constantly reworked by westward flowing bottom currents, which redeposited the sediments into a large scale drift deposit prior to the main glaciogenic input along the margin. High-relief semicircular or elongated depositional structures are also found on the upper continental rise stratigraphically above the regional sediment lens, and were deposited by the combined influence of downslope and alongslope sediment transport. On the lower continental rise, large-scale sediment bodies extend perpendicular to the continental margin and were deposited as a result of downslope turbidity transport and westward flowing bottom currents after initiation of glacigenic input to the slope and rise. We compare the seismostratigraphic signatures along the continental margin segments of the adjacent Riiser Larsen Sea, the Weddell Sea and the Prydz Bay/Cooperation Sea, focussing on indications that may be interpreted as a preglacial-glaciomarine transition in the depositional environment. We suggest that earliest glaciogenic input to the continental slope and rise occurred in the Prydz Bay and possibly in the Weddell Sea. At a later stage, an intensification of the oceanic circulation pattern occurred, resulting in the deposition of the regional plastered drift deposit along the Cosmonaut Sea margin, as well as the initiation of large drift deposits in the Cooperation Sea. At an even later stage, possibly in the middle Miocene, glacial advances across the continental shelf were initiated along the Cosmonaut Sea and the Riiser Larsen Sea continental margins.     

Seismic analyses of Cenozoic contourite drift development in the Northern Norwegian Sea

Four drift accumulations have been identified on the continental margin of northern Norway; the Lofoten Drift, the Vesterålen Drift, the Nyk Drift and the Sklinnadjupet Drift. Based on seismic character these drifts were found to belong to two main groups; (1) mounded, elongated, upslope accretion drifts (Lofoten Drift, Vesterålen Drift and Nyk Drift), and (2) infilling drifts (Sklinnadjupet Drift). The drifts are located on the continental slope. Mainly surface and intermediate water circulation, contrary to many North Atlantic and Antarctic drifts that are related to bottom water circulation, and sediment availability have controlled their growth. Sediments were derived both from winnowing of the shelf and upper slope and from ice sheets when present on the shelf. The main source area was the Vøring margin. This explains the high maximum average sedimentation rate of the nearby Nyk (1.2 m/ka) and Sklinnadjupet (0.5 m/ka) Drifts compared with the distal Lofoten (0.036 m/ka) and Vesterålen (0.060 m/ka) Drifts. The high sedimentation rate of the Nyk Drift, deposited during the period between the late Saalian and the late Weichselian is of the same order of magnitude as previously reported for glacigenic slope sediments deposited during glacial maximum periods only. The Sklinnadjupet Drift is infilling a paleo-slide scar. The development of the infilling drift was possible due to the available accommodation space, a slide scar acting as a sediment trap. Based on the formation of diapirs originating from the Sklinnadjupet Drift sediments we infer these sediments to have a muddy composition with relatively high water content and low density, more easily liquefied and mobilised compared with the glacigenic diamictons.     

Benthic microalgal biomass in sediments of Onslow Bay, North Carolina

Sediment samples were collected at stations along cross-shelf transects in Onslow Bay, North Carolina, during two cruises in 1984 and 1985. Station depths ranged from 11 to 285 m. Sediment chlorophyll a concentrations ranged from 0·06 to 1·87 μg g⁻¹ sediment (mean, 0·55), or 2·6–62·0 mg m². Areal sediment chlorophyll a exceeded water column chlorophyll a a at 16 of 17 stations, especially at inshore and mid-shelf stations. Sediment ATP concentrations ranged from 0 to 0·67 μg g⁻¹ sediment (mean, 0·28). Values for both biomass indicators were lowest in the depth range including the shelf break (50–99 m). Organic carbon contents of the sediments were uniformly low across the shelf, averaging 0·159% by weight. Photography of the sediments revealed extensive patches of microalgae on the sediment surface.Our data suggest that viable benthic microalgae occur across the North Carolina continental shelf. The distribution of benthic macroflora on the North Carolina shelf indicates that sufficient light and nutrients are available to support primary production out to the shelf break. Frequent storm-induced perturbations do not favour settling of phytoplankton, an alternative explanation for the presence of microalgal pigments in the sediments. Therefore, we propose that a distinct, productive benthic microflora exists across the North Carolina continental shelf.     

Sediment distribution and transport across the continental shelf and slope under idealized wind forcing

Resuspension, transport, and deposition of sediments over the continental shelf and slope are complex processes and there is still a need to understand the underlying spatial and temporal dynamical scales. As a step towards this goal, a two-dimensional slice model (zero gradients in the alongshore direction) based on the primitive flow equations and a range of sediment classes has been developed. The circulation is forced from rest by upwelling or downwelling winds, which are spatially uniform. Results are presented for a range of wind speeds and sediment settling speeds. Upwelling flows carry fine sediments (low settling speeds) far offshore within the surface Ekman layer, and significant deposition eventually occurs beyond the shelf break. However, coarser sediments quickly settle out of the deeper onshore component of the circulation, which can lead to accumulation of bottom sediments within the coastal zone. Downwelling flows are more effective at transporting coarse sediments off the shelf. However, strong vertical mixing at the shelf break ensures that some material is also carried into the surface Ekman layer and returned onshore. The concentrations and settling fluxes of coarse sediments decrease offshore and increase with depth under both upwelling and downwelling conditions, consistent with trends observed in sediment trap data. However, finer sediments decrease with depth (upwelling) or reach a maximum around the depth of the shelf break (downwelling). It is shown that under uniform wind conditions, suspended sediment concentrations and settling fluxes decay offshore over a length scale of order τ_s/ρf|w_s|, where τ_s is the wind stress, ρ the water density, f the Coriolis parameter, and w_s is the sediment settling velocity. This scaling applies to both upwelling and downwelling conditions, provided offshore transport is dominated by wind-driven advection, rather than horizontal diffusion.     

An instrumentation system to measure near-bottom conditions on the continental shelf

In recent years significant interest has emerged regarding bottom currents and sediment dispersal over continental shelves and shallow marine waters. Although many papers have been written on sediment dispersal mechanisms, they include relatively few long-term observations of bottom currents and/or sediment transport. Lack of observational data is related to the hostile nature of the environment, and the difficulty associated with placing and retrieving instruments on the floor of the continental shelf during some seasons and environmental conditions.This paper describes an instrumentation system designed for use on the floor of the continental shelf. It can remain submerged for periods of one month continuously recording water speed and direction 1 m from the sea bed, differential pressure, and bed nature by means of half-hourly photographs. Four of these systems are presently in use in arrays across the continental shelf of Washington.     

Zambezi continental margin: compartmentalized sediment transfer routes to the abyssal Mozambique Channel

Sediment delivery to the abyssal regions of the oceans is an integral process in the source to sink cycle of material derived from adjacent continents and islands. The Zambezi River, the largest in southern Africa, delivers vast amounts of material to the inner continental shelf of central Mozambique. The aim of this contribution is to better constrain sediment transport pathways to the abyssal plains using the latest, regional, high-resolution multibeam bathymetry data available, taking into account the effects of bottom water circulation, antecedent basin morphology and sea-level change. Results show that sediment transport and delivery to the abyssal plains is partitioned into three distinct domains; southern, central and northern. Sediment partitioning is primarily controlled by changes in continental shelf and shelf-break morphology under the influence of a clockwise rotating shelf circulation system. However, changes in sea-level have an overarching control on sediment delivery to particular domains. During highstand conditions, such as today, limited sediment delivery to the submarine Zambezi Valley and Channel is proposed, with increased sediment delivery to the deepwater basin being envisaged during regression and lowstand conditions. However, there is a pronounced along-strike variation in sediment transport during the sea-level cycle due to changes in the width, depth and orientation of the shelf. This combination of features outlines a sequence stratigraphic concept not generally considered in the strike-aligned shelf-slope-abyssal continuum.     

Marine geology of the Sodwana Bay shelf, southeast Africa

The geostrophic current-controlled northern Zululand shelf displays a unique assemblage of interesting physical, sedimentological and biological phenomena. The shelf in this area is extremely narrow (3 km) and is characterised by submarine canyons, coral reefs, and steep gradients on the continental slope. Three submarine canyons occur in the study area and are classified as mature- or youthful-phase canyons depending on the degree to which they breach the shelf. These canyons originated as mass-wasting features which were exploited by palaeo-drainage during sea-level regressions. Shelf lithology is dominated by a series of coast-parallel patch coral reefs which have colonised beachrock and aeolianite sequences that extend semi-continuously from −5 to −95 m, and delineate late Pleistocene palaeocoastline events. The unconsolidated sediment on the shelf is either shelf sand (mainly terrigenous quartz grains) or bioclastic sediment. Large-scale subaqueous dunes commonly form in the unconsolidated sediment on the outer-shelf due to the Agulhas Current flow. These dunes occur as two distinct fields at depths of −35 to −70 m; the major sediment transport direction is towards the south, but occasional bedload parting zones exist where the bedform migration direction changes from south to north.     

北黄海西部海底沉积物的粒度特征和净输运趋势

根据对北黄西部海底沉积物的粒度测试,运用“粒度趋势分析”方法,分析探讨了北黄海西部（渤海海峡区）海底表层底质的粒度分布特征和净输运趋势,结果表明,本区的细颗粒沉积物主要位于北黄海中部和山东半岛沿岸,大连湾附近,粗颗粒沉积物则主要分布于庙岛群岛以东和大连湾东南侧海区,沉积物的平均粒径、分选系数、偏态系数闰度参数的分布特征有一定的对应性,除庙岛群东侧的砂质沉积,分选较好之外,其它海区的沉积物总体特征是,粒径越粗,分选越差,偏态更正偏;而粒径越细,分选越好,偏态系数也较低。山 岛北侧的沉积物具有向东和向东北的输运趋势,西中沉积物的输运趋势向东南并转向东,北部喾物的输运趋势向南,形成了向北黄海中部汇聚的趋势,本碛研究还表明“粒度趋势分析”方法在大范围的陆架区域具有较好的适用性,在操作中,使用规则的正方形网格可以较全面判     

Relationship between hydrology and seasonal distribution of suspended sediments on the continental shelf of the Bay of Biscay

Numerous oceanographic cruises (with hydrology, water sampling, drift current measurements) carried out since 1980 on the continental shelf of the Bay of Biscay, together with available NOAA/AVHRR infra-red images, form the basis of a proposed explanation for the processes responsible for the distribution of suspended sediments on the shelf. The seasonal hydrographic structure of continental shelf waters is of paramount importance in sediment distribution. In summer, there is an horizontal stratification of water masses, and suspended sediment distribution is closely related to the thermo-haline structure. A fresher water mass with less suspended material lies on a thicker and more turbid homogeneous layer. During winter, when sediment discharge from the rivers often reaches its annual maximum, an oceanic thermo-haline wedge occurs on the shelf at around −100 m. As a result, winter turbidity values on the outer continental shelf are low (comparable to summer values), and a permanent nepheloı̈d layer is never observed. The wedge, which lasts for several months, may act as a filter, preventing transport to the slope. High turbidities on the external shelf and the continental slope are only measured in spring, when the thermo-haline wedge disappears. It seems possible that during winter time, suspended materials brought by rivers are deposited in the “Grande Vasière” (the “large mud patch”). It is postulated that the position of this mud patch is linked to the long-term stable location of the thermo-haline front that separates oceanic waters from the colder and less salty coastal waters.     

Active diapirism and slope steepening,northern gulf of Mexico continental slope

Abstract

Large diapiric and nondiapiric masses of Jurassic salt and Tertiary shale underlie the northern Gulf of Mexico continental slope and adjacent outer continental shelf. These masses show evidence of being structurally active at present and in the very recent geologic past. Local steepening of the sea floor in response to the vertical growth of these structures is a serious concern to those involved in the site selection and the construction of future oil and gas production and transportation facilities in this frontier petroleum province.

The seabed of the northern Gulf slope is hummocky and consists of many hillocks, knolls, and ridges interspersed by topographic depressions and canyon systems. Topographic highs and lows relate respectively to vertical diapiric growth and to withdrawal of large volumes of salt and shale. Topographic highs vary considerably in shape and size, but all have very limited areas of nearly flat sea floor. Intraslope topographic lows consist of three principal types: (1) remnants of submarine canyons blocked by diapiric uplift that terminated active downslope sediment transport common during stages of low sea level; (2) closed depressions formed by subsidence in response to salt and shale withdrawal and flow into surrounding diapiric uplifts; and (3) small collapse basins formed by faulting in strata arched over structural crests of diapirs.

Distribution patterns of both diapiric features and sediment accumulations on the slope are the result of the complex relationship that exists between sediment loading and diapirism. Diapiric activity is proportional to the thickness of salt or underconsolidated shale available for mobilization, and to the sedimentary load distribution on these highly plastic deposits. Variations in overburden load, in turn, are dependent on rates, volumes, and bulk densities of depo‐sitional influx; proximity to sources of supply, erosion, and distribution of sediments; and topographic control of sediment accumulation. Sediment capture in diapirically controlled interdomal basins and canyon systems localizes overburden load, thus inducing further diapiric growth, and complex structural and stratigraphic patterns are induced throughout the continental slope region.

Drill cores in the slope province indicate that most of the slope sediments are fine‐grained muds; appreciable quantities of sand‐size sediment are present principally in canyon axes. Turbidite sand layers drilled on a topographic high adjacent to the Gyre Basin reflect uplift far above their original deposition level, and calculations yield rates of uplift that average 2 to 4 m per 100 years. Seismic reflection profiles provide considerable evidence of “fresh”; slumps and ero‐sional surfaces on the flanks of many topographic highs not yet blanketed by a veneer of young sediments. This evidence thus supports our conclusion that the present continental slope region of the northern Gulf of Mexico is undergoing active diapirism and consequent slope steepening. Because most of the sediment on the flanks of diapiric structures consists of underconsolidated muds, slumping will take place regularly in response to further diapiric movement.     

Copper in the resurrection fjord, Alaska

Copper concentrations have been measured in more than 200 samples collected from an Alaskan fjord and continental shelf and slope regions in the northwestern Gulf of Alaska. Concentrations were lowest (2·1 nmol kg⁻¹) at depths of 400–1000 m in the continental slope waters of the Gulf of Alaska. Copper increased systematically with decreasing salinities shoreward to concentrations >30 nmol kg⁻¹ in fjord surface waters during summer months of high freshwater runoff. Copper concentrations increased with depth at an inner fjord station where deep basin waters have restricted circulation, and these data together with surface (<5 cm) pore water copper concentrations (mean=122 nmol kg⁻¹) about an order of magnitude higher than bottom water copper concentrations are indicative of a flux of copper across the sediment-seawater interface. This latter was estimated at 32±12 nmol cm⁻² annually, and represented less than 20% of the annual input to fjord surface water (228–411 nmol cm⁻²) added during summer months. Mass balances in bottom waters indicate a vigorous recycling of copper with a residence time estimated at 21±11 days. Most copper that is remobilized in surface sediments is returned to bottom waters and little (3%) is removed by subsequent diagenetic reaction in the buried sediments. However, an estimate of copper accumulating in anoxic fjord sediments was comparable with copper added to fjord surface waters suggesting that input-removal reactions rather than internal cycling controls copper geochemistry in this estuary.     

Pathways of clay mineral transport in the coastal zone of the Brazilian continental shelf from Ceará to the mouth of the Amazon River

The transport pathways of fine sediments (fraction <2 μm) along the Brazilian continental shelf from Ceará to the Amazon River mouth were studied by means of clay mineral analyses. On the continental shelf southeast of the Amazon mouth, fluctuations in clay mineral compositions reflect simple mixing between the suspended load of the North Brazil Current and sediment from several smaller rivers. Previously, clay mineral variations west of the Amazon mouth have been explained by variable settling velocities of different grain-size classes within the <2 μm fraction or by selective coagulation of individual clay mineral groups. By contrast, our experiments with river bank samples show that selective coagulation does not occur in Amazon River sediments. A more appropriate explanation for observed variations in clay mineral composition off the Amazon mouth seems to be, similarly to that for the shelf between Ceará and the Amazon mouth, a mixing of Amazon sediments with suspended material of the North Brazil Current. This interpretation is supported by data on clay mineral composition east and south of the Amazon mouth, showing more affinity to sediments of the North Brazil Current than to the suspended load of the Amazon River. Additionally, relatively low sedimentation rates and low concentrations of fine-grained sediments on the shelf suggest that high riverine input by the Amazon River does not overprint the sediments of the North Brazil Current in this region. The strong North Brazil Current shunts the Amazon suspended load in a north-westerly direction along the north-eastern coast of South America. Hence, stronger sedimentation of Amazon sediments would occur only west of the river mouth.