Computer-processed potentiometric titration for the determination of calcium and magnesium in sea water

An improved potentiometric titration method for the determination of calcium and magnesium in sea water has been newly devised. In this method, a mini-computer is used for the automation of titrations, and ion-selective electrodes are used as an end-point detector. Calcium is determined by titration with EGTA, and total alkaline earth metals (magnesium + calcium + strontium) by titration with EDTA. Magnesium can be determined by the difference, strontium having been determined by a suitable method. In the present method, calcium and magnesium in sea water can be determined with a precision of 0.1 %.     

The chemical characteristics of aerosols in the Kuroshio area——Ⅰ. Sources and fluxes

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黑鯛对Ca,P，K,Mg和Mn的营养需求

矿物质是鱼类必需的营养素之一。海水中含有大量的无机盐,海水鱼类虽可通过饮用海水直接摄取,但是这些矿物质并不能满足鱼类的全部需求,在饲料中还必需予以添加,因此研究海水鱼类对矿物质的需求具有重要的意义。 黑鲷(Sparus macrocephalus)是我国北方最有价值的海水养殖鱼类之一,目前黑鲷养殖业已经逐步发展起来,开展黑鲷营养需求和人工配合饲料的研究已成为当务之急。本文报道了黑鯛对Ca,P,K,Mg和Mn的需求研究结果。     

Electrodeposition of minerals in sea water: Experiments and applications

By establishing a direct electrical current between electrodes in an electrolyte like sea water, calcium carbonates, magnesium hydroxides, and hydrogen are precipitated at the cathode, while the anode produces oxygen and chlorine. Recent experiments have demonstrated in part the feasibility of using the electrodeposited minerals as building materials for a wide variety of purposes, including the construction of artificial reefs. Several of these experiments are described and some implications for marine building technology are discussed.     

Modelling the equilibrium speciation of nickel in the Tweed Estuary, UK: Voltammetric determinations and simulations using WHAM

The complexation of dissolved Ni has been evaluated in a rapidly-flushed, rural estuary (Tweed, UK) by ligand exchange-adsorptive cathodic stripping voltammetry. Results suggest the presence of strongly binding ligands, L, throughout, with average stability constants of about 10¹⁹ and which are saturated by ambient Ni concentrations. Equilibrium speciation calculations incorporating these constants in WHAM, version 6, predict an increase in Ni complexation (as NiL) from about 50% of total dissolved Ni in fresh water to over 90% in sea water. Equivalent calculations using the default-mode fulvic and humic substances (FS and HS, respectively) encoded in the WHAM database predict a reduction in complexation (as NiFS + NiHS) from about 20% in fresh water to less than 1% in sea water. Discrepancies arising from the two approaches are largely attributed to the different analytical detection windows employed. Thus, a better representation of Ni complexation is derived from including both types of complexant in the speciation calculations, resulting in estimates of net complexation in excess of 60% of total dissolved Ni throughout the estuary. The uncertainties and assumptions inherent in all computations illustrate the difficulty in measuring or predicting metal complexation in estuaries.     

上新世以来南海海水表层温度（SST）的变化

The reconstruction of sea surface temperature(SST) is a key issue in research on paleoceanography. The recently related studies are mainly concentrated on the Quaternary. The skeletons of a typical species of benthonic foraminifer(Amphistegina radiata) in the top 0–375.30 m interval of Well "Xike-1" reef core, Shidao Island, the Xisha Islands, are uniformly selected. The ratios of magnesium to calcium concentrations and other indicators are analyzed by an electron microprobe analysis(EMPA) with the purpose of estimating the paleo-SSTs since the Pliocene and further investigating the periodic change law of paleoclimate in the South China Sea(SCS).Meanwhile, the geologic significance of paleoclimatic events in the SCS is discussed with global perspectives. The results indicate that the paleo-SSTs reconstructed by the ratios of magnesium to calcium concentrations in the SCS show a general periodic trend of "high–low–high–low" in values changes since the Pliocene. By comparison,the fluctuations of reconstructed paleo-SSTs are much stronger in the Quaternary. Moreover, the variations of the ratios of magnesium to calcium concentrations in the A. radiata skeletons have recorded a series of major paleoclimatic events since the Pliocene, of which the Quaternary glaciation events and the Arctic ice cap forming events during the late Pliocene are more significant. Thus, using the changes of the ratios of magnesium to calcium concentrations in the A. radiata skeletons from Well "Xike-1" reef core to reflect the relative changes of paleo-SSTs is a relatively feasible and reliable way in the SCS, which is also proved by the correlation of drilling cores characteristics in this area.     

自动分析仪次溴酸钠氧化法测定海水中氨氮的研究

海水中氨的含量变化幅度在5—50mg-N/m~3之间,一般采用此色法测定。自1856年Nessler提出利用碱性[HgI_4]~=与氨生成黄色化合物进行其测定开始,一个多世纪来分析方法虽多并屡加改进提高,但结果仍远不能令人满意。     

古镇口港海域水质状况调查及其评价

根据1998—2002年对古镇口港海域5期的监测结果，初步探讨了该海域环境因子的变化特征和营养水平。结果表明：该海域水质较好，除油类和CODMn外，1998年达到GB 3097—1997第一类海水水质标准，1999年水质超过第四类标准，2000，2001年水质达到第三类标准，2002年达到第二类标准。其中无机氮和活性磷酸盐含量近年略有上升，氮磷比平均为26．8。富营养化指数平均为37．2，并呈迅速下降态势，已从1999年的137降为2002年的0．733。但该水域受油类和CODMn污染较严重，CODMn的含量从1999年开始连续3年超过第四类海水水质标准，2002年明显好转，达到第一类海水水质标准；油类的含量连续5a达到第三类海水水质标准。综合来看，古镇口港海域水质目前状况较好。     

Sediments of lakes Rotoroa and Rotoiti,South Island,New Zealand

The chemistry and mineralogy of the sediments of Lakes Rotoroa and Rotoiti, South Island, New Zealand (41° 51 S, 172° 38 E and 41° 50 S, 172° 50 E respectively) , were studied. In general, the cation exchange properties, element concentrations, and mineral compositions of the sediments show little variation between samples from each lake. However, some nutrient concentrations, notably exchangeable calcium, magnesium, and potassium, and total nitrogen and sulphur, are higher in sediments from weed beds than in sediments underlying deeper water; iron and manganese concentrations tend to show the opposite trend. Concentrations of exchangeable calcium and total nitrogen, sulphur, manganese, and iron generally decrease down the sediment profiles from the sediment/water interface. Differences between lakes, notably higher concentrations of illite and of the elements potassium, aluminium, titanium, and zirconium, and lower concentrations of calcium in the sediments of Lake Rotoiti than in those from Lake Rotoroa, are probably due mainly to the different geological settings rather than to differences in the diagenetic processes operating within the lakes. Mineralogical analyses indicate that the lake sediments are derived mainly from the valleys of the major inflow rivers rather than from the slopes at the sides of each lake.     

Calcium in the Antarctic Ocean

Calcium in sea water was determined of the samples taken from the Antarctic and Indian Oceans. Surface water commonly contains less calcium relative to chlorinity than does deep water. The tendency, however, is very faint in the Antarctic Ocean. In the surface waters, the Ca/Cl ratio is lower in the tropical and subtropical waters and the ratio well correlates with phosphate. The Ca/P ratio is calculated as 37 in atomic ratio. These may indicate that calcium is uptaken by organisms to make skeletal parts from surface water which is supersaturated with respect to calcite or aragonite. On the other hand, no definite correlationship between calcium and phosphate is found in subsurface water. This fact suggests that the regeneration process of calcium from organic debris is different from that of phosphate. The increase-rate of calcium in the abyssal water is estimated to be 0.18g at./(1 yr), which is due to the dissolution of calcium carbonate. The rate is about a half of total carbonate increase in the water.     

Calcium-alkalinity-nitrate relationship in the north pacific and the Japan Sea

When biogenic particles of calcium carbonate and organic matter are formed or decomposed in sea water, calcium concentration, alkalinity and nitrate concentration are changed according to the following equation: ΔCa=0.5 ΔTA+0.63 ΔNO ₃, where ΔCa, ΔTA and ΔNO ₃ are the differences in calcium, alkalinity and nitrate concentration, respectively, between two waters. This relationship was pointed out in a previous paper of ours, and it holds well for data obtained from the North Pacific and the Japan Sea. Furthermore, in sea water containing little or no nutrients, the variations in calcium concentration and alkalinity are consistent with the variations expected from the formation and dissolution of calcium carbonate alone.     

Distribution of dissolved organic carbon in and near the Prydz Bay, Antarctica

INTRODUCTIONDissolvedorganiccarbon (DOC)makesupthesecondlargestofthebioactivepoolsofcar bonintheocean ,secondtothelargestpoolofdissolvedinorganiccarbon .Theglobaldissolvedorganiccarbonpoolisestimatedtobe 6 85Gt,avaluecomparabletothemassofCO2 intheat mosphere (Hedges,1 992 ) .Thesizeofthereservoir,aswellasitsdynamics ,indicatesthatDOCplaysacentralroleintheoceancarboncycle .AsitrelatestogreenhousegasessuchasCO2 andassociatesclimatecycle ,oceanicDOCbiogeochemicalcycleshavebeenoneoftheh…     

Laboratory Test on Volumetric Characteristics of Saturated Sea Sand Under Cyclic Loading

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The retrieval of the nonlinear random waves from the non-Gaussian characteristics of the sea surface elevation distribution

In this paper, without recourse to the nonlinear dynamical equations of the waves, the nonlinear random waves are retrieved from the non-Gaussian characteristic of the sea surface elevation distribution. The question of coincidence of the nonlinear wave profile, spectrum and its distributions of maximum (or minimum) values of the sea surface elevation with results derived from some existing nonlinear theories is expounded under the narrow-band spectrum condition. Taking the shoaling sea wave as an example, the nonlinear random wave process and its spectrum in shallow water are retrieved from both the non-Gaussian characteristics of the sea surface elevation distribution in shallow water and the normal sea waves in deep water and compared with the values actually measured. Results show that they can coincide with the actually measured values quite well, thus, this can confirm that the method proposed in this paper is feasible.     

Distribution of alkalinity and dissolved calcium in the Sea of Okhotsk

During the summer seasons of 2002 and 2004, the total alkalinity (TA) and dissolved calcium (Ca) were studied at 41 stations in different areas of the Sea of Okhotsk: the Kuril depression, Deryugin Basin, the slopes of the Kamchatka Peninsula and Sakhalin Island, and in Sakhalin Bay. It was shown that the distributions of the TA and Ca in the water mass of deep sea areas are determined by the processes of CaCO₃ formation and dissolution according to the relation Δ Ca = 0.5 Δ TA (1). The variations of the TA and Ca values observed in the upper 10-m layer and in the near-bottom layers of local depressions in the Deryugin Basin do not satisfy relationship (1). Probable reasons for this discrepancy are considered: organic matter mineralization, mixing of water masses with different preform TA and Ca values, sea ice melting, runoff from land, and sea bottom effects. It is shown that the enrichment in the alkalinity and calcium is caused by the Amur River runoff in the desalinated sea surface layer and by the high geochemical activity in the Deryugin Basin in the near-bottom 200-m layer of local depressions.     

A new look at the alkalinity of the Sea of Japan

The most important feature of the distribution of the alkalinity and calcium in the Sea of Japan—the increase in the potential alkalinity with depth under the conditions when the waters are supersaturated in relation to calcium carbonate—is considered. It is demonstrated that this fact cannot be accounted for by the reaction of the formation-dissolution of calcium carbonate. A new concept explaining the alkalinity distribution in the sea is proposed. According to it, the biological pump is the basic process responsible for the alkalinity transport from the euphotic layer into the interior of the sea. Photosynthesis is the driving force for this process. The role of the active element transporting the alkalinity is not calcium carbonate, as has been claimed elsewhere, but extracellular polysaccharides (EPSs) produced by phytoplankton. EPSs bind to calcium and other cations to form transparent exopolymer particles (TEPs). The proposed conception makes it possible to explain the following: (a) the vertical flux of calcium carbonate that is independent of the super-saturation—undersaturation state of the ambient water regarding calcium carbonate; (b) the existence of the calcium carbonate flux regardless of the nature of the plankton skeletons; (c) the nonstoichiometric ratio between the alkalinity and calcium fluxes.     

Growth and photosynthetic responses to copper stress of an invasive cordgrass, Spartina densiflora

Spartina densiflora Brongn. is found in coastal marshes of south-west Spain, growing in sediments with between 300 and 3000mg Cu kg(-1) total soil DW (450-4500mg Cu kg(-1) supposing that the soil porosity is 0.5). An experiment was designed to investigate the effect of copper from 0 to 5000mgkg(-1) (64mmoll(-1)) on the photosynthetic apparatus and the growth of S. densiflora. We also determined total ash, copper, calcium, magnesium and phosphorous concentrations, as well as C/N ratio. S. densiflora survived to concentrations as high as 320mg Cukg(-1) DW in leaves, although excess of Cu diminished water use efficiency and Ca-, Mg- and P-uptake. Also, quantum efficiency of PSII, net photosynthetic rate, stomatal conductance and pigment concentrations declined with increasing external Cu. Finally, the decline in the photosynthetic function resulted in a biomass reduction of between 50 and 80% (for 600 and 5000mg Cu kg(-1), respectively).     

中国近海小尺度海水水平湍流扩散规律与海洋污染预报的研究

从五十年代起,放射性废液排放入海后的湍流扩散问题,开始具有工程上的实际意义,引起了人们的注意.湍流扩散基本规律以及与之有关的污染预报是两个重要的方面.但由于海洋湍流扩散是一个随机过程,并要受到季节、海区以及水文气象等多种因素的影响,而且这些因素间又互相制约比较复杂;所以虽然至今的理论与实验研究工作很多,但大多与特定条件有关,迄今还没有一个比较满意的普适理论.因此有必要对我国近海海水湍流扩散基本规律以及适用于我国近海的污染预报问题作进一步的研究.     

Factors controlling excess radium in the Nakdong River estuary,Korea: submarine groundwater discharge versus desorption from riverine particles

The activities of naturally occurring radium isotopes (²²⁶Ra and ²²⁸Ra) in estuarine water were measured downstream of the dam constructed in the Nakdong River, Korea. The sampling of surface waters for radium, silicate, and suspended solid (SS) analyses was conducted at 18 stations during three periods (July 1997, April 1998, and June 1999). In general, radium activities exceeded the value expected from the mixing of two freshwater and seawater endmembers. We characterized the responses of Ra and Si according to three different conditions: (1) when the freshwater discharge and the water level of the dam relative to the sea level at low tide were lower (April 1998), the excess Ra and Si contents were lower in the estuary; (2) when the fresh water discharge was larger following heavy precipitation (July 1997), both excess Ra and Si contents were higher in the estuary with conservative mixing of Si; and (3) when the water level of the dam relative to the sea level at low tide was highest under low freshwater discharge (June 1999), high excess Ra but low Si levels were observed. The occurrence of high Ra activity in June 1999 was likely due to the large submarine brackish groundwater discharge downstream of the estuary. Since brackish groundwater in general contains high concentrations of nutrients, Ba, Ra, etc, our result suggests an important role for the submarine groundwater discharge on the biogeochemistry of estuarine/coastal waters, especially when the water level of the dam (hydraulic head) is high.     

Estimation of 3-D current fields near the Rhine outflow from HF radar surface current data

HF radar systems are designed to measure spatially variable sea surface currents. A methodology was developed to complement these data with information about the current variability over the water column in a stratified shallow sea. Current profiles were estimated using a diagnostic model driven by surface current measurements from an HF radar system and by sea surface slopes derived from tide gauge data. The structure of the model has a physical basis but its parameters were derived from an analysis of in-situ current profile measurements. Application of the model to HF radar data from the SCAWVEX Rhine outflow experiment showed fair agreement with in-situ current data. As applications, estimation and tidal analysis of current fields are demonstrated.