云南兰坪白秧坪铜钴多金属矿集区矿石中石英的40Ar-39Ar年龄

云南兰坪白秧坪铜钴多金属矿集区矿石中石英的⁴⁰Ar-³⁹Ar快中子活化年龄谱呈马鞍形,坪年龄为56.53±0.43Ma,最小视年龄为55.52±1.78Ma,等时线年龄为55.90±0.29Ma,三者在误差范围内一致(1σ)。⁴⁰Ar/³⁶Ar初始值为294.7±1.14,与尼尔值(295.5±5)十分接近,坪年龄和等时线年龄均可作为石英的形成时代。因此,55.90~56.53Ma(喜马拉雅早期)代表了矿床的成矿年龄。     

^40Ar-^39 Ar Dating of Quartz from Ore in the Baiyangping Cu-Co Polymetallic Ore-Concentrated Area, Lanping Basin, Yunnan

⁴⁰Ar−³⁹Ar fast neutron activation age spectrum of quartz in ore collected from the Baiyangping Cu−Co polymetallic ore-concentrated area, Lanping Basin, is saddle-shaped. The plateau age, minimum appearance age and isochron age shown on the spectra are 56.53±0.43 Ma, 55.52±1.78 Ma and 55.90±0.29 Ma respectively. The age data are consistent with each other within 1σ uncertainties. Because the given initial⁴⁰Ar/³⁶Ar value of 294.7±1.14 is very close to Nier's value (295.5±5), both plateau and isochron ages may be considered as the forming time of quartz. So the age of 55.90–56.53 Ma represents the forming age of ore deposits. It is obvious that the ore deposits were formed during the Early Himalayan period. This research project was granted by the State Basic Research, Development and Planning Program (G1999043208) and the Foundation Projects of Yunnan Provincial Education Department (No. 0142104).     

云南东川播卡-拖布卡地区含金石英脉的^40Ar／^39Ar年龄及其地质意义

东川播卡-拖布卡地区金矿是云南中部"康滇地轴"中、新元古界昆阳群岩石中发现的第一个金矿,位于接近三江褶皱带的扬子地块西缘.原生金矿化为含金黄铁矿石英脉、细脉、网脉和浸染状石英黄铁矿.四个不同产状的典型含金石英脉的石英的阶段加热40Ar/39Ar年龄谱为马鞍形,坪年龄值范围为59.93±0.21～42.38±0.32 Ma,最小视年龄范围59.30±4.30～41.90±1.8 Ma,与计算坪年龄加热阶段相应数据的40Ar-39Ar等时线年龄范围59.34±0.17～41.25±0.10 Ma,三者基本一致.等时线年龄计算的相关系数大于0.998,40Ar/3 6Ar初始值范围为293.17±1.40～295.2±0.43,与尼尔值一致.石英形成后没有受到后期地质作用.石英样品的坪年龄没有受到过剩氩和氩丢失的影响,可以作为石英和金矿的年龄.金矿形成于新生代第三纪古新世和始新世初的陆内拉张地质构造环境中.     

石英~(40)Ar-~(39)Ar阶段加热法定年的实验技术改进及意义

40 Ar 3 9Ar阶段加热法测定石英年龄始于 1986年。近年来通过样品清洗、提高真空度、提高质谱计灵敏度、减小样品用量、增加熔样阶段等实验技术改进 ,数据质量比过去有所提高。但关键问题是选择有代表性的石英样品 ,并预先对样品做镜下鉴定和电子探针分析 ,挑选钾含量较高的石英用于定年 ,以便减少失败 ,提高年龄数据测试的成功率。当钾含量高于 0 0 5 %时 ,一般都可在中温 (70 0～ 10 0 0℃左右 )阶段获得 3个以上视年龄构成的坪年龄和等时年龄 ,比过去马鞍型年龄谱中由一个最小视年龄作为成矿年龄要准确。     

40Ar-39Ar dating of lamprophyre dykes in the Baimazhai nickel deposit, Yunnan Province, China, and its geological significance

The Baimazhai nickel deposit,Yunnan Province,China,is located in the southern part of the Sanjiang (Tri-river) alkali-rich intrusive rock belt (Sanjiang ARIR). In this paper was conducted 40Ar-39Ar dating of two phlogopites in lamprophyres which are,as dikes,widely distributed in the orefield,and two plateau ages were ac-quired,i.e.,32.46±0.62 Ma and 32.01±0.60 Ma,respectively (averaging 32.23±0.60 Ma). The ages are obviously younger than those of the ore-hosted complex and mineralization of the Baimazhai nickel deposit. In combination with the characteristics,it is indicated that lamprophyres in the orefield and those in the Sanjiang ARIR are similar in tectonic setting,mineral assemblage and geochemistry. It is considered that lamprophyres in the orefield are the im-portant component of the Sanjiang ARIR,and the lamprophyres and ore-hosted complex in the orefield represent the products of two times of different magmatic activity from different mantle sources. On the other hand,the age of lamprophyres in the orefield is older than that of the strike-slip shearing of the Ailaoshan-Honghe fault belt,sug-gesting that the strike-slip shearing of the Ailaoshan-Honghe fault belt is not the factor leading to magmatic activity of lamprophyres in the orefield,while it is more possible that magmatic activity of the Sanjiang ARIR promoted strike-slip shearing of the fault belt.     

嵩县祁雨沟金矿成矿时代的40Ar-39Ar年代学证据

采用单矿物40Ar-39Ar年代学方法,对河南祁雨沟爆破角砾岩型金矿的矿化蚀变矿物进行了高精度的定年研究.矿脉中钾长石的40Ar-39Ar年龄表明,祁雨沟金矿的主要成矿阶段发生在115～125Ma期间,成矿作用持续达10Ma.结合前人研究成果分析,区域燕山期花岗岩侵位30Ma之后祁雨沟金矿开始进入主成矿期,此时正是区域伸展构造的发育时期,深部流体活动频繁而强烈.祁雨沟金矿是中国东部金的大规模成矿作用的组成部分.     

西藏弄如日金矿床蚀变绢云母~(40)Ar-~(39)Ar年龄及其地质意义

西藏弄如日金矿是冈底斯成矿带发现的第一个浅成低温热液型金矿床。为确定金矿床的成矿时代,对该矿床与金矿化有关的蚀变花岗斑岩中绢云母进行了40Ar-39Ar年龄测试,获得绢云母的加权平均年龄和等时线年龄分别为19.87±0.96Ma和19.70±0.30Ma。结果表明,弄如日金矿床金矿化的主要成矿时代为中新世。该成果的获得对于进一步认识弄如日金矿成因机制、地球动力学背景以及区域找金突破具有重要意义。     

超高压变质岩多硅白云母的外来40Ar探讨

采用激光阶段加热 40Ar-39Ar定年技术, 测定了碧溪岭榴辉岩 6个多硅白云母的 Ar同位素组成.02BX030MS形成基本平坦的 40Ar-39Ar年龄谱, 数据点构成很好的正等时线, 加权平均年龄和等时线年龄均为 697 Ma, 这一年龄可能接近原岩年龄.DB-1MS、02BX018MS和 02BX019MS之 40Ar-39Ar年龄谱起伏较大, 表观年龄范围为～ 400 Ma至～ 680 Ma.在 40Ar/36Ar-39Ar/36Ar正等时线图解上, 这 3个样品数据点落在下拟合线 Reg-Ⅰ和上拟合线 Reg-Ⅲ之间.Reg-Ⅰ对应的年龄为 436～ 463 Ma, 与榴辉岩石榴子石原生流体包裹体年龄基本一致, 可能代表了榴辉岩超高压变质作用峰期的年龄;Reg-Ⅲ对应的年龄为 541～ 659 Ma, 最高年龄值小于 02BX030MS的年龄, 表明超高压变质作用使多硅白云母产生了不同程度的放射成因 40Ar部分丢失.继承 40Ar模型可以合理解释高压-超高压变质岩石之多硅白云母 40Ar-39Ar年龄明显偏老等地质现象.     

云南兰坪盆地喜马拉雅期碱性岩^40Ar／^39Ar年龄及地质意义

对侵位于云南兰坪中新生代红层盆地中的碱性岩进行了Ar_Ar同位素定年 ,获得永平卓潘碱性杂岩体的侵入年龄为 36 .70Ma,巍山莲花山碱性石英二长斑岩的侵入年龄为 38.81Ma。兰坪盆地的构造演化受控于古特提斯的闭合及印度与亚洲大陆碰撞的造山作用 ,盆地经历了陆内裂谷、拗陷盆地和走滑盆地 3个阶段的发育过程。喜马拉雅期盆地处于走滑拉分阶段 ,可分为 4个构造幕 ,碱性岩主要在第 1构造幕期间侵入。盆地中的碱性岩体是青藏高原东缘总体呈NW走向的金沙江红河巨型富碱侵入岩带的组成部分。金沙江红河断裂带经历由转换压扭变形(42～ 2 4Ma)到转换张扭变形 (2 4～ 16Ma)、再到东西向伸展 (<16Ma)的过程 ,兰坪盆地的碱性岩发育于转换压扭变形期间。认为兰坪盆地碱性斑岩的侵入和盆地的喜马拉雅期构造演化主要受控于古特提斯扬子地块向西的俯冲板片遗迹引发的地幔上隆和部分熔融     

40Ar/39Ar Fast Neutron Activation Ages of Quartz from the J inman Vein Copper Deposit in Western Yunnan and Their Significance

Quartz samples collected from the Jinman vein copper deposit in the Lanping Basin of western Yunnan were determined by 40Ar/39Ar fast neutron activation techniques, and the spectra are characterized as being saddle-shaped. The samples yielded a plateau age of 58.05 ±0.54 Ma, a minimum appearance age of 56.76 ± 0.81 Ma and an isochron age of 54.30 ±0.15 Ma, the three ages being close to each other, indicating that the ages of the quartz samples so far determined are true and reliable. The plateau age represents the time of formation of Cu-bearing quartz veins, which is corresponding to Early Himalayan. This age is also consistent with the time at which a tectonically thermal event (60 Ma) took place within the Lanping Basin, Yunnan Province. In consideration of the fact that copper ore and other ore types in the vast area of western Yunnan are concentrated mainly in the Early Himalayan strata, the authors believe that there must have existed some indispensable key factors leading to metallogenesis on a large scale during the Early Himalayan period in western Yunnan and also constraining in union the formation of ore deposits there.     

自生伊利石40Ar-39Ar法年代学实验过程中一些重要环节的探讨

自生伊利石^40Ar-^39Ar年代学在油气勘探及其他领域具有重要意义,但由于自生伊利石晶体结构的特殊性,使这一方法从样品处理到数据解释都有一些需要探讨的问题。自生伊利石提纯方法主要由冷冻-加热碎样结合高速离心完成。样品粒度愈细,样品纯度愈大,结晶度愈差。通过X射线衍射可以获得样品纯度、结晶度方面的信息,用TEM可以获得XRD检测限（5％）以下的样品纯度信息。样品^39Ar核反冲丢失与样品中晶体的结晶度（2θ）、晶体沿c轴方向的层厚相关;真空包裹技术可以较合理地降低核反冲丢失,得到细粒样品有意义的年龄。真空包裹的细粒样品的“保留年龄”有重要的地质意义。     

诸广中段鹿井地区辉绿岩40Ar-39Ar年代学特征

诸广—贵东地区作为华南热液型铀矿最为重要的花岗岩型铀矿大型矿集区,区内发育了大量与铀矿化作用密切相关的基性岩脉。为了厘定区内基性岩年代学数据,更好地约束铀成矿时限,以诸广中段鹿井地区辉绿岩脉为研究对象,开展了⁴⁰Ar-³⁹Ar年代学研究。结果表明：辉绿岩全岩⁴⁰Ar-³⁹Ar同位素年龄为（171.7±1.6）、（169.1±3.8）Ma,反映鹿井地区在中侏罗世（约170 Ma）发生了一次岩石圈伸展裂解作用。诸广—贵东地区至少存在200、170、140、105和90 Ma 5期基性岩浆活动,195、165、125、90、75和55 Ma 6期铀成矿事件,成矿热液往往紧随每次区域性玄武岩事件之后（5~20 Ma）,铀成矿与以辉绿岩墙为代表的区域玄武岩事件有紧密的时间、空间和成因联系。辉绿岩脉与成矿构造上的关联性以及来源于地幔的深部岩浆浅部表现形式的成因特点,决定了其可以为铀成矿提供一定的挥发分（矿化剂）和后期铀沉淀富集场所,提高成矿热液对铀的携带能力,进而促进铀的成矿作用。     

云南哀牢山金矿带大坪韧性剪切带型金矿40Ar-39Ar定年

云南大坪金矿是哀牢山金矿带中最重要的金矿之一,主要赋存在受到强烈韧性剪切和水-岩反应的加里东期闪长岩中,是典型的韧性剪切带控矿型金矿。本文对大坪金矿绢英岩化近矿围岩中的热液绢云母进行了40Ar-39Ar定年,得到其坪年龄为33.76±0.65Ma,相应的反等时线和正等时线年龄分别为33.55±0.74Ma和33.57±0.74Ma,显示大坪属于喜马拉雅早期金矿。这些年龄数据与哀牢山金矿带中广泛出现的喜马拉雅期煌斑岩脉年龄(33～34Ma)非常接近,显示金矿与上地幔部分熔融形成的煌斑岩之间可能存在成因上的联系。喜马拉雅早期,本区在地壳拉张和强烈韧性剪切条件下,Moho面上升,地幔物质部分熔融并上涌,形成大量煌斑岩等基性岩脉,地幔排气形成的深源地幔流体和下地壳脱水形成的富CO2流体混合,沿韧性剪切带上升,并与糜棱岩化的加里东期闪长岩围岩发生水-岩反应,局部发生流体沸腾作用,导致成矿流体物理化学条件的改变和矿石矿物的沉淀,在剪切带脆性构造中形成含金石英脉。     

石英击碎与粉末加热40Ar-39Ar定年及其含义讨论

采用真空击碎技术提取东川汤丹铜矿床石英流体包裹体，进行40Ar-39Ar法年龄测定，获得了逐渐下降的阶梯形年龄谱，表明流体包裹体含有过剩氩；数据点在40Ar/36Ar-39Ar/36Ar图解上构成等时线，年龄为712±33Ma，这一年龄值代表了矿床的形成年龄[1]。随后对其粉末进行40Ar/39Ar阶段加热（100-800℃）分析，形成相对比较平坦的年龄谱，坪年龄为317±6Ma(39Ar占45%，含真空击碎分析在内)，全部加热分析数据点构成的等时线年龄为321±13Ma，这一年龄初步解释为流体包裹体内子     

广西中部大明山钨矿白云母40Ar/39Ar定年 及其地质意义

大明山钨矿床是一个与岩浆活动有关的多金属矿床。为确定钨矿床的成矿时代,对钨矿床中的白云母进行40Ar/39Ar快中子活化测年,获得白云母坪年龄为(97.10±0.86)Ma,相应的等时线年龄和反等时线年龄分别为(96.6±1.7)Ma和(96.5 ±1.1)Ma。结果表明,钨矿矿化年龄为97Ma,为燕山晚期本区成岩成矿活动的产物。该成果为进一步认识大明山钨矿的成因机制和成矿动力学背景提供了新的年代学证据。     

广西中部大明山钨矿白云母40Ar/39Ar定年及其地质意义

大明山钨矿床是一个与岩浆活动有关的多金属矿床。为确定钨矿床的成矿时代,对钨矿床中的白云母进行40Ar/39Ar快中子活化测年,获得白云母坪年龄为(97.10±0.86)Ma,相应的等时线年龄和反等时线年龄分别为(96.6±1.7)Ma和(96.5 ±1.1)Ma。结果表明,钨矿矿化年龄为97Ma,为燕山晚期本区成岩成矿活动的产物。该成果为进一步认识大明山钨矿的成因机制和成矿动力学背景提供了新的年代学证据。     

Metallogeny of the Baiyangping Lead‐Zinc Polymetallic Ore Concentration Area,Northern Lanping Basin of Yunnan Province,China

The Lanping Basin in the Nujiang‐Lancangjiang‐Jinshajiang (the Sanjiang) area of northeastern margin of the Tibetan Plateau is an important part of eastern Tethyan metallogenic domain. This basin hosts a number of large unique sediment‐hosted Pb‐Zn polymetallic deposits or ore districts, such as the Baiyangping ore concentration area which is one of the representative ore district. The Baiyangping ore concentration area can be divided into the east and west ore belts, which were formed in a folded tectogene of the India‐Asia continental collisional setting and was controlled by a large reverse fault. Field observations reveal that the Mesozoic and Cenozoic sedimentary strata were outcropped in the mining area, and that the orebodies are obviously controlled by faults and hosted in sandstone and carbonate rocks. However, the ore‐forming elements in the east ore belt are mainly Pb‐Zn‐Sr‐Ag, while Pb‐Zn‐Ag‐Cu‐Co elements are dominant in the west ore belt. Comparative analysis of the C‐O‐Sr‐S‐Pb isotopic compositions suggest that both ore belts had a homogeneous carbon source, and the carbon in hydrothermal calcite is derived from the dissolution of carbonate rock strata; the ore‐forming fluids were originated from formation water and precipitate water, which belonged to basin brine fluid system; sulfur was from organic thermal chemical sulfate reduction and biological sulfate reduction; the metal mineralization material was from sedimentary strata and basement, but the difference of the material source of the basement and the strata and the superimposed mineralization of the west ore belt resulted in the difference of metallogenic elements between the eastern and western metallogenic belts. The Pb‐Zn mineralization age of both ore belts was contemporary and formed in the same metallogenetic event. Both thrust formed at the same time and occurred at the Early Oligocene, which is consistent with the age constrained by field geological relationship.     

鲁东胶莱盆地青山组火山岩的^40Ar—^39Ar定年——以五莲分岭山火山机构为例

以五莲分岭山火山机构为例，运用高精度的^40Ar－^39Ar定年技术，对胶莱盆地青山组火山岩的形成年龄进行了精确测定。结果表明。青山组第一旋回中偏碱性富钾火山岩的形成年龄为109．9±0．6Ma，第二旋回酸性流纹质火山岩形成年龄为108．2±0．6Ma，据此确定胶莱盆地青山组火山岩应为早白垩世岩浆活动的产物。根据该组火山岩在空间上具有自西向东年龄渐新的演变趋势，表明中生代伊泽奈崎板块向欧亚板块碰撞俯冲应是制约区内火山活动的主要动力因素。     

砂岩储层自生伊利石40Ar-39Ar定年技术及油气成藏年龄探讨

油气成藏年龄是石油地质学和同位素年代学共同面临的科学难题之一。本文探讨砂岩储层自生伊利石40Ar-39Ar阶段加热技术获得油气成藏年龄的可能性。样品采自南海珠江口盆地第三纪珠海组砂岩储层,采用冷冻加热循环技术缓慢碎裂样品,以减少碎屑长石混入量。释出气体首先经过专门研制的纯化装置,有效地除弃有机杂质气体,然后经过2个NP10Zr/Al泵进一步纯化。06ZJ26I伊利石40Ar-39Ar激光阶段加热分析获得了阶梯状上升的年龄谱。开始3个最低激光能量阶段加权平均年龄(12.1±2.2)Ma(2σ)解释为自生伊利石的最小年龄,可能代表了油气成藏的最大年龄;而较高激光能量阶段坪年龄(98.0±0.9)Ma则代表了砂岩中陆源碎屑长石的年龄。与传统K-Ar法相比,40Ar-39Ar法可以揭示伊利石样品更多的年代学信息。     

Timing and Processes of Ore Formation in the Qingchengzi Polymetallic Orefield, Northeast China: Evidence from 40Ar/39Ar Geochronology

The Qingchengzi orefield is a large polymetallic ore concentration area in the Liaodong peninsula,northeastern China,that includes twelve Pb-Zn deposits and five Au-Ag deposits along its periphery.The ore-forming age remains much disputed,which prevents the identification of the relationship between the mineralization and the associated magmatism.In this paper,we quantitatively present the feasibility of making ore mineral ~(40)Ar/~(39)Ar dating and report reliable ~(40)Ar/~(39)Ar ages of lamprophyre groundmass,K-feldspar and sphalerite from the Zhenzigou deposit.Direct and indirect methods are applied to constrain the timing of mineralization,which plays a vital role in discussing the contribution of multistage magmatism to ore formation.The low-potassium sphalerite yielded an inverse isochron age of 232.8±41.5 Ma,which features a relatively large uncertainty.Two lamprophyre groundmasses got reliable inverse isochron ages of 193.2±1.3 Ma and 152.3±1.5 Ma,respectively.K-feldspar yielded a precise inverse isochron age of 134.9±0.9 Ma.These four ages indicate that the mineralization is closely associated with Mesozoic magmatism.Consequently,regarding the cooling age of the earliest Mesozoic Shuangdinggou intrusion(224.2±1.2 Ma)as the initial time of mineralization,we can further constrain the age of the sphalerite to 224–191 Ma.These new and existing geochronological data,combined with the interaction cutting or symbiotic relationship between the lamprophyre veins and ore veins,suggest that the Pb-Zn-Au-Ag mineralization in the Qingchengzi orefield mainly occurred during three periods:the late Triassic(ca.224–193 Ma),the late Jurassic(ca.167–152 Ma)and the early Cretaceous(ca.138–134 Ma).This polymetallic deposits are shown to have been formed during multiple events coinciding with periods of the Mesozoic magmatic activity.In contrast,the Proterozoic magmatism and submarine exhalative and hydrothermal sedimentation in the Liaolaomo paleorift served mainly to transport and concentrate the ore-forming substances at the Liaohe Group with no associated Pb-Zn-Au-Ag mineralization.