The Tornquist Sea and Baltica–Avalonia docking

Early Ordovician (Late Arenig) limestones from the SW margin of Baltica (Scania–Bornholm) have multicomponent magnetic signatures, but high unblocking components predating folding, and the corresponding palaeomagnetic pole (latitude=19°N, LONGITUDE=051°E) compares well with Arenig reference poles from Baltica. Collectively, the Arenig poles demonstrate a midsoutherly latitudinal position for Baltica, then separated from Avalonia by the Tornquist Sea.Tornquist Sea closure and the Baltica–Avalonia convergence history are evidenced from faunal mixing and increased resemblance in palaeomagnetically determined palaeolatitudes for Avalonia and Baltica during the Mid-Late Ordovician. By the Caradoc, Avalonia had drifted to palaeolatitudes compatible with those of SW Baltica, and subduction beneath Eastern Avalonia was taking place. We propose that explosive vents associated with this subduction and related to Andean-type magmatism in Avalonia were the source for the gigantic Mid-Caradoc (c. 455 Ma) ash fall in Baltica (i.e. the Kinnekulle bentonite). Avalonia was located south of the subtropical high during most of the Ordovician, and this would have provided an optimum palaeoposition to supply Baltica with large ash falls governed by westerly winds.In Scania, we observe a persistent palaeomagnetic overprint of Late Ordovician (Ashgill) age (pole: LATITUDE=4°S, LONGITUDE=012°E). The remagnetisation was probably spurred by tectonic-derived fluids since burial alone is inadequate to explain this remagnetisation event. This is the first record of a Late Ordovician event in Scania, but it is comparable with the Shelveian event in Avalonia, low-grade metamorphism in the North Sea basement of NE Germany (440–450 Ma), and sheds new light on the Baltica–Avalonia docking.     

Paleozoic northward drift of the North Tien Shan (Central Asia) as revealed by Ordovician and Carboniferous paleomagnetism

Three new Middle–Late Ordovician and two new Early Carboniferous paleomagnetic poles have been obtained from the North Tien Shan Zone (NTZ) of the Ural–Mongol belt in Kyrgyzstan and Kazakhstan. Paleolatitudes for the Carboniferous are unambiguously northerly and average 15.5°N, whereas the Ordovician paleolatitudes (6°, 9°, and 9°) are inferred to be southerly, given that a very large (180°) rotation of the NTZ would be necessary during the middle Paleozoic if the other polarity option was chosen. Thus, the NTZ drifted northward during much of the Paleozoic; east–west drift cannot be determined, as is well known, from paleomagnetic data. In addition, detailed thermal demagnetization analysis reveals two overprints, one of recent age and the other of Permian age, which is a time of strong deformation in the NTZ. The paleolatitude of the combined Permian overprint is 30.5+2°N. The paleolatitudes collectively track those predicted for the area by extrapolation from Baltica very well, but are different from those of Siberia for Ordovician times. This finding is compatible with Sengör and Natal'in's [Sengör, A.M.C., Natal'in, B.A., 1996. Paleotectonics of Asia: fragments of a synthesis. In: Yin A., Harrison, M. (Eds.), The Tectonic Evolution of Asia. Cambridge Univ. Press, Cambridge, pp. 486–640] model of tectonic evolution of the Ural–Mongol belt and disagrees with the models of other researchers. Declinations of the Ordovician and Early Carboniferous results range from northwesterly to northeasterly, and are clearly affected by local relative rotations, which seem characteristic for the entire NTZ, because the Permian overprint declinations also show such a spread. Apparently, the important latest Paleozoic–Triassic deformation involved shear zone-related rotations as well as folding and significant granitic intrusions.     

Palaeomagnetism of the Loch Doon Granite Complex, Southern Uplands of Scotland: The Late Caledonian palaeomagnetic record and an Early Devonian episode of True Polar Wander

The Southern Uplands terrane is an Ordovician–Silurian back-arc/foreland basin emplaced at the northern margin of the Iapetus Ocean and intruded by granite complexes including Loch Doon (408.3 ± 1.5 Ma) during Early Devonian times. Protracted cooling of this 130 km³ intrusion recorded magnetic remanence comprising a predominant (‘A’) magnetisation linked to initial cooling with dual polarity and mean direction D / I = 237 / 64° (α₉₅ = 4°, palaeopole at 316°E, 21°N). Subsidiary magnetisations include Mesozoic remanence correlating with extensional tectonism in the adjoining Irish Sea Basin (‘B’, D / I = 234/− 59°) and minority populations (‘C’, D / I = 106/− 2° and ‘D’, D / I = 199/1°) recording emplacement of younger ( 395 Ma) granites in adjoining terranes and the Variscan orogenic event. The ‘A’ directions have an arcuate distribution identifying anticlockwise rotation during cooling. A comparable rotation is identified in the Orthotectonic Caledonides to the north and the Paratectonic Caledonides to the south following closure of Iapetus. Continental motion from midsoutherly latitudes ( 40°S) at 408 Ma to equatorial palaeolatitudes by  395 Ma is identified and implies minimum rates of continental movement between 430 and 390 Ma of 30–70 cm/year, more than double maximum rates induced by plate forces and interpreted as a signature of true polar wander. Silurian–Devonian palaeomagnetic data from the British–Scandinavian Caledonides define a 430–385 Ma closed loop comparable to the distributed contemporaneous palaeomagnetic poles from Gondwana. They reconcile pre-430 Ma and post-380 Ma APW from this supercontinent and show that Laurentia–Baltica–Avalonia lay to the west of South America with a relict Rheic Ocean opening to the north which closed to produce Variscan orogeny by a combination of pivotal closure and right lateral transpression.     

The aqueous geochemistry of Zr and the solubility of some Zr-bearing minerals

Literature data on the thermodynamics of complexation of Zr with inorganic species, at 25°C, have been critically reviewed. The preponderance of published complexation constants deal with F⁻ and OH⁻ ions. Stability constants for the complexation reactions are relatively independent of ionic strength and thus recomended values for each ligand type are averages of the most reliable data. Complexation constants under elevated conditions (T 250°C andP_v = P_H2O) have been predicted for various Zr complexes (F⁻, Cl⁻, SO₄²⁻ and OH⁻) using Helgeson's electrostatic approach. Predominance diagrams (calculated for simple systems with these constants) suggest that, over a wide range of pH conditions, Zr(OH)_4(aq) will dominate the aqueous geochemistry of Zr except under very high activities of competing ligands (e.g., F⁻, SO₄²⁻).The solubilities of vlasovite [Na₂ZrSi₄O₁₁] and weloganite [Sr₃Na₂Zr(CO₃)₆·3H₂O have been measured in KCI solutions (0.5–1.0 M) at 50°C. Weloganite dissolution is complicated by the predictable precipitation of strontianite (SrCO₃) whereas vlasovite dissolves incongruently. Solubility products for the dissolution of welonganite and vlasovite are determined to be −28.96±0.14 and −20.40±1.18, respectively. Concentrations of Zr up to 10⁻³ m were present in the experimental solutions; the presence of large amounts of Zr in aqueous solutions support the possibility of extensive remobilization of Zr during hydrothermal mineralization.     

Reappraisal of paleomagnetic data from Gargano (South Italy)

The platform limestones of Apulia (Italy) outcropping in the Gargano peninsula have been restudied. Paleomagnetic research has been carried out on Upper Cretaceous, Lower Cretaceous and Jurassic rocks. Despite the low intensities of the NRM (10–100 μA/m), all samples (268) could be cleaned by stepwise A.F. and/or thermal demagnetization treatments. NRM directions could be determined accurately and reproducibly for 85% of the samples, using a ScT cryogenic magnetometer and double precision measuring procedures. NRM of the Jurassic limestone is carried by secondary haematite and the results are therefore rejected from further consideration. The Upper and Lower Cretaceous limestones have an NRM carried by magnetite. Minor bedding tilt corrections improve the grouping of the site-mean results. The Upper Cretaceous “Scaglia” limestone (Turonian-Senonian) reveals a characteristic mean direction of decl. = 327.7°, incl. = 38.2°, α₉₅ = 4.3° (21 sites), while the Lower Cretaceous “Maiolica” limestone (Neocomian-Aptian/Albian) reveals a characteristic mean direction of decl. = 303.1°, incl. = 35.1°, α₉₅ = 8.7° (8 sites). The Cretaceous results show a post-Aptian/Albian counterclockwise rotation of about 25°, which is expressed by the smeared distribution of the Late Cretaceous site-mean results and a post-Senonian (i.e. Tertiary) counterclockwise rotation of the same amount with respect to the pole. These results are in excellent agreement with contemporaneous paleomagnetic results from other peri-Adriatic regions. A Tertiary counterclockwise rotation of all the stable Adriatic block is strongly supported by the new results.     

Palaeomagnetism of the Guaniguanico Cordillera, western Cuba: a pilot study

A palaeo- and rock-magnetic study was carried out on the Jurassic–Cretaceous Guaniguanico Cordillera (15 sites, 112 oriented cores) in order to define a preliminary magnetostratigraphy and to obtain some constraints on the tectonic evolution of western Cuba. Rock-magnetic experiments indicate Ti-poor titanomagnetites as principal remanence carriers. Two magnetic phases seem to be present in a few samples: some spinels, which saturate at moderate magnetic fields and goethite, with higher coercivity. The presence of hematite (or mixture of spinels and hematite) is apparent in two units. In most cases the characteristic palaeodirections could be determined above 300°C. Eleven sites yield normal magnetic polarity and four reverse. The polarity zones can be tentatively correlated to chrons CM29–C24 in the reference geomagnetic polarity time scale. The mean palaeodirection calculated from all sites is Dm=335.7°, Im=43.1°, K=11, α₉₅=12.3 and N=15. The corresponding palaeopole is Plat=66.4°, Plong=205.8°, K=13, and A₉₅=11.1. This pole is not significantly different from North American Jurassic–Cretaceous poles. This suggests that no major latitudinal displacements and deformation have occurred since the Jurassic, in contrast to some previously proposed tectonic models.     

Recent plate tectonics of the Arctic Basin and of northeastern Asia

The recent tectonics of the Arctic Basin and northeastern Asia are considered as a result of interaction between three lithospheric plates: North-America, Eurasia and Spitsbergen. Seismic zones (coinciding in the Norway-Greenland basin with the Kolbeinsey, Mohns and Knipovich ridges, and in the Arctic Ocean with the Gakkel Ridge) clearly mark the boundaries between them. In southernmost Svalbard (Spitsbergen), the secondary seismic belt deviates from the major seismic zone. This belt continues into the seismic zone of the Franz Josef Land and then merges into the seismic zone of the Gakkel Ridge at 70°–90°E. The smaller Spitsbergen plate is located between the major seismic zone and its secondary branch.Within northeastern Asia, earthquake epicenters with magnitude over 4.5 are concentrated within a 300-km wide belt crossing the Eurasian continent over a distance of 3000 km from the Lena estuary to the Komandorskye Islands. A single seismic belt crosses the northern sections of the Verkhoyansky Ridge and runs along the Chersky Ridge to the Kolymo-Okhotsk Divide.To compute the poles of relative rotation of the Eurasian, North-American and Spitsbergen plates we use 23 new determinations of focal-mechanism solutions for earthquakes, and 38 azimuths of slip vectors obtained by matching of symmetric mountain pairs on both sides of the Knipovich and Gakkel ridges; we also use 14 azimuths of strike-slip faults within the Chersky Ridge determined by satellite images. The following parameters of plate displacement were obtained: Eurasia/North America: 62.2°N, 140.2°E (from the Knipovich Ridge section south of the triple junction); 61.9°N, 143.1°E (from fault strikes in the Chersky Ridge); 60.42°N, 141.56°C (from the Knipovich section and from fault strikes in the Chersky Ridge); 59.48°N, 140.83°E, α = 1.89 · 10⁻⁷ deg/year (from the Knipovich section, from fault strikes in the Chersky Ridge and from the Gakkel Ridge section east of the triple junction). The rate was calculated by fitting the 2′ magnetic lineations within the Gakkel Ridge).North-America/Spitsbergen: 70.96°N, 121.18°E, α = −2.7 · 10⁻⁷ deg/year from the Knipovich Ridge section north of the triple junction, from earthquakes in the Spitsbergen fracture zone and from the Gakkel Ridge section west of the triple junction). Eurasia/Spitsbergen: 70.7°N, 25.49°E, α = −0.99 · 10⁻⁷ deg/year (from closure of vector triangles).     

Thermal regime at the Upper Stillwater dam site, Uinta mountains, Utah: Implications for terrain, microclimate and structural corrections in heat flow studies

A detailed study of the subsurface thermal regime at the Upper Stillwater dam site, Uinta Mountains, northeast Utah, has been made. Temperature measurements were made in 36 drillholes located within a 1 km² area and ranging in depth from 20 to 97 m. Holes less than about 40 m deep were used only to obtain information about spatial variations in mean annual surface temperature. Several holes in or near talus slopes at the sides of the canyons have temperature minima approaching 0°C between 10 and 20 m indicating the presence of year-round ice at the base of the talus. Another set of holes show transient thermal effects of surface warming resulting from clearing of a construction site 3.5 years prior to our measurements. Most of the remaining holes show conductive behavior and have gradients ranging from 13° to 17°C km⁻¹. Measurements made on 44 core samples yield a thermal conductivity of 5.6 (std. dev. 0.35) W m⁻¹ K⁻¹ for the Precambrian quartzite present. Surface heat flow estimates for these holes range from 70 to 100 mW m⁻². However, the local disturbance of the thermal field by topography and microclimate is considerable. A finite difference method used to model these effects yielded a locally corrected Upper Stillwater heat flow of about 75 mW m⁻². A final correction to account for the effects of refraction of heat from the low conductivity sedimentary rocks in the Uinta Basin into the high conductivity quartzite at the dam site, produced a regionally corrected Upper Stillwater heat flow between 60 and 65 mW m⁻². This value is consistent with the observed heat flow of 60 mW m⁻² in the Green River Basin to the north and the Uinta Basin to the south.     

Fluid flow in the Duperow and Winnepegosis Formations, Williston Basin, Canada: Evidence from preliminary magnetic measurements

The Devonian Winnepegosis and Duperow Formations were examined in well 4-27-11-22W1, located in at the eastern edge of the Williston Basin in Manitoba. The variation in characteristic remanent magnetization (ChRM) direction and magnetic mineral carrier is obvious: the older Winnepegosis Formation has a primary or early post-depositional magnetization held in magnetite or pyrrhotite (n = 15; D = 324.1°, I = − 27.3°, α₉₅ = 10.4°, k = 15.7), whereas the younger Duperow Formation magnetizations are carried by hematite and could be as late as Early Jurassic. The variability may be attributable to the intervening Prairie Evaporite acting as an aquitard to fluid migration.     

Reversal asymmetry in Mesoproterozoic overprinting of the 1.88-Ga Gunflint Formation, Ontario, Canada: non-dipole effects or apparent polar wander?

Eighty-two palaeomagnetic samples of calcareous and jaspilitic grainstones (iron-formation or ‘taconite’) and chert carbonate were collected from the 1.88-Ga Gunflint Formation at 22 sites in the Thunder Bay area, Ontario. Twenty clasts of Gunflint taconite also were sampled from the basal conglomerate of the overlying Mesoproterozoic Sibley Group. Anisotropy of magnetic susceptibility measurements indicate the Gunflint Formation in the sampling area has not experienced regional dynamic metamorphism. Analyses by variable-field translation balance and X-ray diffraction show that the predominant magnetic mineral is hematite but a small amount of magnetite also is present in some samples. Altogether, 213 Gunflint specimens and 59 Sibley conglomerate specimens were subjected to stepwise thermal demagnetisation and 74 Gunflint specimens to stepwise alternating-frequency demagnetisation. The following components were isolated for the taconites:

• Gunflint magnetite: normal declination D=293.4°, inclination I=30.8°, α₉₅=7.2°, n=21; reverse D=86.7°, I=–54.6°, α₉₅=5.8°, n=29.

• Gunflint hematite: normal D=243.6°, I=23.6°, α₉₅=6.0°, n=11; reverse D=70.3°, I=–51.4°, α₉₅=3.2°, n=79.

• Sibley clasts magnetite: normal D=282.7°, I=33.4°, α₉₅=7.6°, n=20.

• Sibley clasts hematite: normal D=254.5°, I=56.2°, α₉₅=8.4°, n=13; reverse D=110.6°, I=–55.7°, α₉₅=8.3°, n=11.

None of these sets passed the reversal test, with the normal component generally being the shallower. Fold tests were negative or inconclusive and the conglomerate test also was negative. Chert carbonate at one other site appears to have acquired a remanence carried by magnetite (D=97.3°, I=−78.2°, α₉₅=6.3°, n=18) prior to folding related to Keweenawan (1.1 Ga) Logan diabase sill emplacement. Most of the components we identified match components for Keweenawan sills, volcanic rocks, intrusions and baked contact rocks in the Thunder Bay area, indicating that Keweenawan magmatism caused widespread chemical remagnetisation of the Proterozoic country rock in our sampling area. Although others have argued that asymmetry was a feature of the Keweenawan geomagnetic field, the declinations of our Gunflint and Sibley hematite and magnetite components are different, suggesting that the components were acquired at significantly different times. We conclude that the reversal asymmetry shown by our Gunflint and Sibley data may best be ascribed to apparent polar wander during Keweenawan times.     

Fluid geochemistry in the Ivigtut cryolite deposit, South Greenland

The 1.27 Ga old Ivigtut (Ivittuut) intrusion in South Greenland is world-famous for its hydrothermal cryolite deposit [Na₃AlF₆] situated within a strongly metasomatised A-type granite stock. This detailed fluid inclusion study characterises the fluid present during the formation of the cryolite deposit and thermodynamic modelling allows to constrain its formation conditions.Microthermometry revealed three different types of inclusions: (1) pure CO₂, (2) aqueous-carbonic and (3) saline-aqueous inclusions. Melting temperatures range between − 23 and − 15 °C for type 2 and from − 15 to − 10 °C for type 3 inclusions. Most inclusions homogenise between 110 and 150 °C into the liquid.Stable isotope compositions of CO₂ and H₂O were measured from crushed inclusions in quartz, cryolite, fluorite and siderite. The δ¹³C values of about − 5‰ PDB are typical of mantle-derived magmas. The differences between δ¹⁸O of CO₂ (+ 21 to + 42‰ VSMOW) and δ¹⁸O of H₂O (− 1 to − 21.7‰ VSMOW) suggest low-temperature isotope exchange. δD (H₂O) ranges from − 19 to − 144‰ VSMOW. The isotopic composition of inclusion water closely follows the meteoric water line and is comparable to Canadian Shield brines. Ion chromatography revealed the fluid's predominance in Na, Cl and F. Cl/Br ratios range between 56 and 110 and may imply intensive fluid–rock interaction with the host granite.Isochores deduced from microthermometry in conjunction with estimates for the solidification of the Ivigtut granite suggest a formation pressure of approximately 1–1.5 kbar for the fluid inclusions. Formation temperatures of different types of fluid inclusions vary between 100 and 400 °C. Thermodynamic modelling of phase assemblages and the extraordinary high concentration in F (and Na) may indicate that the cryolite body and its associated fluid inclusions could have formed during the continuous transition from a volatile-rich melt to a solute-rich fluid.     

Paleomagnetism and Detrital Zircon Geochronology of the Upper Vindhyan Sequence, Son Valley and Rajasthan, India: A ca. 1000 Ma Closure age for the Purana Basins?

The utility of paleomagnetic data gleaned from the Bhander and Rewa Groups of the “Purana-aged” Vindhyanchal Basin has been hampered by the poor age control associated with these units. Ages assigned to the Upper Vindhyan sequence range from Cambrian to the Mesoproterozoic and are derived from a variety of sources, including ⁸⁷Sr/⁸⁶Sr and δ ¹³C correlations with the global curves and Ediacara-like fossil finds in the Lakheri–Bhander limestone. New analyses of the available paleomagnetic data collected from this study and previous work on the 1073 Ma Majhgawan kimberlite, as well as detrital zircon geochronology of the Upper Bhander sandstone and sandstones from the Marwar SuperGroup suggest that the Upper Vindhyan sequence may be up to 500 Ma older than is commonly thought. Paleomagnetic analysis generated from the Bhander and Rewa Groups yields a paleomagnetic pole at 44°N, 214.0°E (A95 = 4.3°). This paleomagnetic pole closely resembles the VGP from the well-dated Majhgawan intrusion (36.8°N, 212.5°E, α₉₅ = 15.3°).Detrital zircon analysis of the Upper Bhander sandstone identifies a youngest age population at 1020 Ma. A comparison between the previously correlated Upper Bhander sandstone and the Marwar sandstone detrital suites shows virtually no similarities in the youngest detrital suite sampled. The main 840–920 Ma peak is absent in the Upper Bhander. This supports our assertion that the Upper Bhander is older than the 750–771 Ma Malani sequence, and is likely close to the age of the 1073 Ma Majhgawan kimberlite on the basis of the paleomagnetic similarities. By setting the age of the Upper Vindhyan at 1000–1070 Ma, several intriguing possibilities arise. The Bhander–Rewa paleomagnetic pole allows for a reconstruction of India at 1000–1070 Ma that overlaps with the 1073 ± 13.7 Majhgawan kimberlite VGP. Comparisons between the composite Upper Vindhyan pole (43.9°N, 210.2°E, α₉₅ = 12.2°) and the Australian 1071 ± 8 Ma Bangamall Basin sills and the 1070 Ma Alcurra dykes suggest that Australia and India were not adjacent at this time period.     

On the P-wave velocity and plate-tectonics implications for the Tyrrhenian deep-earthquake zone

P-wave velocities in the Tyrrhenian mantle have been determined for the 230–480 km depth range. Analysis of P-wave travel times for a set of Tyrrhenian deep earthquakes gives a velocity-distribution law which shows different behaviours in the 230–300 km and 300–480 km depth intervals. For the first interval the velocity gradient is 0.64 · 10⁻² sec⁻¹ and for the second one it is 0.59 · 10⁻² sec⁻¹. At a depth of 300 km the velocity decreases rapidly from 8.75 to 8.43 km/sec.The results have been analyzed in the framework of a Tyrrhenian structural model characterized by a lithospheric slab dipping 55–60° in the WNW direction.It is also pointed out that the analysis of some geodynamic features of the slabs of Pacific island arcs carried out by Oliver et al. (1973) and Sleep (1973) can be applied to the Tyrrhenian mantle geodynamic features.     

Crustal architecture above the high-pressure belt of the Grenville Province in the Manicouagan area: new structural, petrologic and U–Pb age constraints

Recent U–Pb age determinations and P–T estimates allow us to characterize the different levels of a formerly thickened crust, and provide further constraints on the make up and tectono-thermal evolution of the Grenville Province in the Manicouagan area. An important tectonic element, the Manicouagan Imbricate zone (MIZ), consists of mainly 1.65, 1.48 and 1.17 Ga igneous rocks metamorphosed under 1400–1800 MPa and 800–900 °C at 1.05–1.03 Ga, during the Ottawan episode of the Grenvillian orogenic cycle, coevally with intrusion of gabbro dykes in shear zones. The MIZ has been interpreted as representing thermally weakened deep levels of thickened crust extruded towards the NW over a parautochthonous crustal-scale ramp. Mantle-derived melts are considered as in part responsible for the high metamorphic temperatures that were registered.New data show that mid-crustal levels structurally above the MIZ are represented by the Gabriel Complex of the Berthé terrane, that consists of migmatite with boudins of 1136±15 Ma gabbro and rafts of anatectic metapelite with an inherited monazite age at 1478±30 Ma. These rocks were metamorphosed at about the same time as the MIZ (metamorphic zircon in gabbro: 1046±2 Ma; single grains of monazite in anatectic metapelite: 1053±2 Ma) and under the same T range (800–900 °C) but at lower P conditions (1000–1100 MPa). They are mainly exposed in an antiformal culmination above a high-strain zone, which has tectonic lenses of high P–T rocks from the MIZ and is intruded by synmetamorphic gabbroic rocks. This zone is interpreted as part of the hangingwall of the MIZ during extrusion. A gap of 400 MPa in metamorphic pressures between the tectonic lenses and the country rocks, together with the broad similarity in metamorphic ages, are consistent with rapid tectonic transport of the high P–T rocks over a ramp prior to the incorporation of the mafic lenses in the hangingwall.Between the antiformal culmination of the Gabriel Complex and the MIZ 1.48 Ga old granulites of the Hart Jaune terrane are exposed. They are intruded by unmetamorphosed 1228±3 Ma gabbro sills and 1166±1 Ma anorthosite. Hart Jaune Terrane represents relatively high crustal levels that truncate the MIZ-Gabriel Complex contact and are preserved in a synformal structure.Farther south, the Gabriel Complex is overlain by the Banded Complex, a composite unit including 1403+32/−25 Ma granodiorite and 1238+16/−13−1202+40/−25 Ma granite. This unit has been metamorphosed under relatively low-P (800 MPa) granulite-facies conditions. Metamorphic U–Pb data, limited to zircon lower intercept ages (971±38 Ma and 996±27 Ma) and a titanite (990±5 Ma) age, are interpreted to postdate the metamorphic peak.The general configuration of units along the section is consistent with extrusion of the MIZ during shortening and, finally, normal displacement along discrete shear zones.     

Late Paleozoic remagnetization of the Trenton Formation in Ordovician petroleum reservoirs of southwestern Ontario

A paleomagnetic study of subsurface core samples from dolomitized carbonates of two producing reservoirs in the Upper Ordovician Trenton Formation, collected from four wells in southwestern Ontario yielded a paleomagnetic direction of D = 152.3°, I = − 12.3° (N = 49, α₉₅ = 8.7). This characteristic remanent magnetization (ChRM) direction was azimuth-corrected by aligning the viscous remanence magnetization (VRM) with the present Earth's magnetic field direction. A drilling-induced magnetization (VRMdi) was present in less than half the specimens sampled in this study. In addition, where the VRM correction could not be made, a paleolatitudinal arc calculated from the inclination-only mean of I = − 9.0° (N = 34, α₉₅ = 3.0°) intersected the apparent polar wander path in the Late Permian–Early Triassic. These paleodirections are similar to the paleomagnetic directions observed in Ordovician Trenton carbonates from the Michigan Basin and New York State, U.S.A., suggesting a related regional late Paleozoic remagnetization.     

Hydrology of a spring complex, studied by geochemical time-series data, Acquarossa, Switzerland

A case study of three springs in Switzerland is used to demonstrate the value of geochemical time-series data as a powerful tool to study the dynamics of groundwater systems. Values of repeatedly measured parameters revealed intermixings of two water types: (a) a 29°C water, circulating to a depth of 1100 m and containing approximately 700 mg/l Ca, 2000 mg/l SO₄, 700 mg/l HCO₃, 20 mg/l of Na and Cl, 6 mg/l Fe, at least 47 mg/l SiO₂, and with an isotopic composition of δD = − 73.0‰ and δ¹⁸ O = −10.9‰, and (b) a 12°C or colder water, shallow, and of a post-1953 age, containing 420 mg/l TDI or less, very low in Na and Cl (4 mg/l or less), isotopic values of δD = −71.0‰ and δ¹⁸ O = −10.5‰ and tritium as in recent (post-bomb) precipitation.     

Palaeomagnetism of Upper Bhander Sandstones from Central India and implications for a tentative Cambrian Gondwanaland reconstruction

A virtual geomagnetic pole position for the uppermost Vindhyan sediments in Central India, probably correlative with the Cambrian of the Salt Range (W. Pakistan), was obtained from 43 oriented cores (7 sites) drilled from the Upper Bhander sandstones in the Great Vindhyan basin.Alternating field and thermal demagnetization resulted in a mean direction: D = 207.5°, I = +9.5° (k = 137.5, α₉₅ = 5.5°) and a virtual geomagnetic northpole position: 146.5° W48.5°N (dp = 3°, dm = 5.5°).This pole position disagrees with the Cambrian palaeomagnetic results from the Salt Range. Implications of this disagreement for the pre-drift configuration of Gondwanaland, based on palaeomagnetc results, are discussed.     

Tectonic significance of the young mineral dates and the rates of cooling and uplift in the Himalaya

More than two-thirds of the published K-Ar, Rb-Sr and fission-track mineral dates from the Himalaya lie in the 5–75 m.y. range as a result of metamorphic overprint, uplift and cooling during the Late Cretaceous—Tertiary Himalayan orogeny. In contrast, the few but almost invariably old, Rb-Sr whole-rock ages reveal pre-Tertiary magmaticmetamorphic events.The pattern of distribution of these young dates vis-á-vis geological evidence reveals three phases, of the Himalayan orogeny, viz.: (1) folding and metamorphism (50–75 m.y.); (2) uplift (25–40 m.y.); and (3) major uplift, thrusting, formation of nappe structures, mylonitization and regional retrogression. The maximum concentration of dates in the 10–25 m.y. period marks this paroxysmal phase of the Himalayan orogeny.The Rb-Sr dates of co-existing muscovites and biotites have been used to compute the rates of cooling and uplift. Thus, slow cooling at the rate of about 4°C m.y.⁻¹ from 50 to 25 m.y. and rapid cooling at the rate of 19°-21°C m.y.⁻ from 25 m.y. to present have been inferred. The high rate of cooling over the past 25 m.y. is the result of major uplift at the rate of 0.7–0.8 mm yr⁻¹, which is in conformity with the current rate of uplift obtained from geodetic survey.     

Creep of olivine during hot-pressing

The densification curves for the hot-pressing of pure olivine powders were obtained as a function of grain size (5 μ–2000 μ), temperature (1000–1600°C), and compacting stress (166–298 bars). This range of variables was found to straddle two fields of hot-pressing behavior, one dominated by power-law creep, one by Coble creep. The time required to density a powder to 99% of the single crystal density could be represented by the shorter of the two times: t₁ = 2.2 · 10³σ^−3.4exp(85,000/RT)t₂ = 1.3 · 10⁴σ^−1.5(G)⁺³exp(85,000/RT) where the compacting stress or pressure, σ, is given in bars and the grain size, G, in centimeters. It was also possible to estimate the parameters appropriate to Coble creep in a solid polycrystalline aggregate from the hot-pressing data; and these were:

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The strain rates computed from this formula are close to those predicted by Stocker and Ashby (1973) and those found by Twiss (1976).     

Late orogenic, large-scale rotations in the Tien Shan and adjacent mobile belts in Kyrgyzstan and Kazakhstan

Most of Kazakhstan belongs to the central part of the Eurasian Paleozoic mobile belts for which previously proposed tectonic scenarios have been rather disparate. Of particular interest is the origin of strongly curved Middle and Late Paleozoic volcanic belts of island-arc and Andean-arc affinities that dominate the structure of Kazakhstan. We undertook a paleomagnetic study of Carboniferous to Upper Permian volcanics and sediments from several localities in the Ili River basin between the Tien Shan and the Junggar–Alatau ranges in southeast Kazakhstan. Our main goal was to investigate the Permian kinematic evolution of these belts, particularly in terms of rotations about vertical axes, in the hope of deciphering the dynamics that played a role during the latest Paleozoic deformation in this area. This deformation, in turn, can then be related to the amalgamation of this area with Baltica, Siberia, and Tarim in the expanding Eurasian supercontinent. Thermal demagnetization revealed that most Permian rocks retained a pretilting and likely primary component, which is of reversed polarity at three localities and normal at the fourth. In contrast, most Carboniferous rocks are dominated by postfolding reversed overprints of probably “mid-Permian” age, whereas presumably primary components are isolated from a few sites at two localities. Mean inclinations of primary components generally agree with coeval reference values extrapolated from Baltica, whereas declinations from primary as well as secondary components are deflected counterclockwise (ccw) by up to  90°. Such ccw rotated directions have previously also been observed in other Tien Shan sampling areas and in the adjacent Tarim Block to the south. However, two other areas in Kazakhstan show clockwise (cw) rotations of Permian magnetization directions. One area is located in the Kendyktas block about 300 km to the west of the Ili River valley, and the other is found in the Chingiz Range, to the north of Lake Balkhash and about 400 km to the north of the Ili River valley. The timing of the ccw as well as cw rotations is clearly later than the disappearance of any marine basins from northern Tarim, the Tien Shan and eastern Kazakhstan, so that the rotations cannot be attributed to island-arc or Andean-margin plate settings — instead we attribute the rotations to large-scale, east–west (present-day coordinates), sinistral wrenching in an intracontinental setting, related to convergence between Siberia and Baltica, as recently proposed by Natal'in and Şengör [Natal'in, B.A., and Şengör, A.M.C., 2005. Late Palaeozoic to Triassic evolution of the Turan and Scythian platforms: the pre-history of the palaeo-Tethyan closure, Tectonophysics, 404, 175–202.]. Our previous work in the Chingiz and North Tien Shan areas on Ordovician and Silurian rocks suggested relative rotations of  180°, whereas the Permian declination differences are of the order of 90° between the two areas. Thus, we assume that about 50% of the total post-Ordovician rotations are of pre-Late Permian age, with the other half of Late Permian–earliest Mesozoic age. The pre-Late Permian rotations are likely related to oroclinal bending during plate boundary evolution in a supra-subduction setting, given the calc-alkaline character of nearly all of the pre-Late Permian volcanics in the strongly curved belts.