西秦岭天水地区流水沟岩浆杂岩LA-ICP-MS锆石U-Pb测年和岩石地球化学特征

流水沟岩浆杂岩分布于西秦岭北缘天水关子镇地区,主要由变辉长岩、变辉长闪长岩和变闪长岩组成。为确定其构造属性,探讨西秦岭北缘构造演化过程,对其进行了LA-ICP-MS锆石U-Pb测年和主量、微量、稀土元素分析。结果表明,岩浆杂岩体的锆石为岩浆成因,其形成时代为548.7Ma±1.8Ma（MSWD=0.56）。流水沟岩浆杂岩具有SiO2变化范围大（52.47%～66.95%）,低TiO2,低碱,Mg#值变化范围较大的特征,主量元素在SiO2-氧化物变异图解上具有较好的线性相关性。稀土元素配分曲线总体呈近平坦型,LREE/HREE比值多数在1.14～2.60之间,轻重稀土元素分馏较弱,δEu介于0.65～1.90之间,大多数具有弱的负Eu异常;在微量元素蛛网图上,大离子亲石元素Cs、Sr、Th、U富集,Rb、K和高场强元素Nb、P、Ti、Y亏损,Ti/Y=113～253,Th/Yb=0.23～2.85,Th/Nb=0.09～1.00,Hf/Th=0.41～2.97,显示了流水沟岩浆杂岩形成于岛弧环境。流水沟岩浆杂岩可能反映在中央造山系中存在一期与＂泛非造山运动＂有关的构造热事件,为中央造山系在新元古代晚期—早古生代的构造演化提供了证据。     

西秦岭早子沟金矿中酸性侵入岩地球化学、年代学特征及成矿地质体的确定

西秦岭早子沟金矿是与岩浆活动有关的特大型金矿床,矿区中酸性侵入岩集中发育,主要有闪长玢岩、黑云石英闪长玢岩、花岗斑岩、石英闪长岩4种岩石类型。岩石微量元素均表现出富集大离子亲石元素Rb、K,亏损高场强元素Nb、Ta、P、Ti的特征。稀土元素总量整体上黑云石英闪长玢岩>闪长玢岩>石英闪长岩,闪长玢岩、黑云母石英闪长玢岩、花岗斑岩具有弱-中等的负铕异常(δEu=0.60～0.89),深部石英闪长岩以不具Eu异常(δEu=0.96～1.07)、“Nb-Ta谷”较深明显区别于浅部脉岩。石英闪长岩锆石U-Pb年龄为230 Ma,晚于浅部脉岩10～20 Ma,与蚀变矿物绢云母年龄基本一致,推测金成矿可能始于230 Ma,主成矿期为230～211 Ma,深部石英闪长岩为早子沟金矿的成矿地质体。     

赞比亚北部省卡萨马西部石英闪长岩锆石U- Pb和Lu- Hf同位素及地球化学特征

石英闪长岩锆石U-Pb和Lu-Hf同位素及地球化学特征研究对赞比亚东北部班韦乌卢地块的形成时代及构造演化具有重要的研究意义。采用LA-MC-ICP MS方法测得班韦乌卢地块中卡萨马西部地区出露的两个石英闪长岩体中锆石的~(207)Pb/~(206)Pb年龄加权平均值分别为1964±8 Ma(MSWD=0.87,N=32)和1913±10 Ma(MSWD=0.77,N=19),表明两期石英闪长岩均形成于古元古代且可能与古元古代乌本迪构造带的活动有关。全岩地球化学分析显示,石英闪长岩属准铝质、高钾钙碱性系列岩石。稀土配分曲线均呈右倾型,具有富含轻稀土元素(LREE)、贫重稀土元素(HREE)以及δEu (0.77～0.80)弱负异常特点。微量元素均显示大离子亲石元素(如Rb、Ba及K)和活泼的不相容元素(如Th及U)相对富集,高场强元素Nb、Ta、P、Sr和Ti相对亏损。Nd/Th=3.60～4.65,Nb/Ta=12.05～13.87,Th/Ta=11.14～11.81,Ti/Zr=36.84～41.71,Ti/Y=220.28～300.00和具有不均一的ε_(Hf)(t)值(分别为-3.8～1.3和-4.3～8.6)均显示石英闪长岩的原始岩浆具有壳幔混合的特点。Zr/Y=5.98～7.19,La/Nb=2.91～3.88,La/Yb=12.19～13.92及构造判别图解均显示石英闪长岩形成于安第斯型活动大陆边缘。     

吉林省兰家金矿南泉眼闪长岩U-Pb年代学和地球化学特征

南泉眼闪长岩是兰家矽卡岩型金矿的成矿岩体,研究程度极低.通过岩石地球化学和LA-ICP-MSU-Pb年代学研究,讨论了岩石成因、来源和构造背景.研究表明,南泉眼闪长岩为准铝质的钙碱性岩石;岩石明显富集大离子亲石元素(如Rb、K、Sr)、活泼的不相容元素(如Th、U)和轻稀土元素,相对亏损高场强元素(如Nb、Ta、Ti、P)和重稀土元素,具有明显的负Eu异常,Nb/Ta、La/Nb、Th/La比值显示岩石具壳源特征,Al2O3+MgO+FeOt图解显示岩浆具弧型活动大陆边缘特征.闪长岩岩浆锆石LA-ICP-MSU-Pb加权平均年龄为170.21±0.73Ma(MSWD=0.14);谐和年龄值为170.21±0.39Ma(MSWD=0.018),为中侏罗世.成岩构造背景为燕山早期太平洋板块俯冲引起大陆弧伸展和岩石圈减薄,软流圈物质上涌、底侵提供热动力,不成熟下地壳物质部分熔融形成南泉眼闪长岩.     

西秦岭天水地区岛弧型基性岩浆杂岩的地球化学特征及形成时代

天水地区关子镇流水沟变质中基性岩浆杂岩主要由变质辉长岩—辉长闪长岩—闪长岩组成,百花变质岩浆杂岩主要由辉石岩—辉长(闪长)岩—闪长岩—石英闪长岩组成,构成较完整的同源岩浆演化序列。基性—中基性岩浆岩的地球化学特征表明其属于拉斑玄武岩系列,稀土元素分布型式呈REE近平坦型—LREE轻微富集型,微量元素原始地幔标准化的蛛网图和MORB标准化蛛网图上的分布型式总体很相似,富集大离子亲石元素(LILE)Cs、Ba、Sr、Th、U而相对亏损Rb、K和高场强元素(HFSE)Nb、P、Zr、Sm、Ti和Y,显示同源岩浆演化成因特征。微量元素构造环境判别显示其形成于岛弧构造环境。关子镇流水沟变质中基性岩浆杂岩的TIMS法锆石U-Pb同位素年龄为(507.5±3.0)Ma,代表了杂岩体的形成时代,表明西秦岭北带岛弧型岩浆岩的形成时代为晚寒武世,同时也揭示出以关子镇蛇绿岩为代表的古洋盆的俯冲作用及产生岛弧型岩浆活动的时限可能为晚寒武世—早奥陶世。     

青海南山构造带西段黑马河花岗杂岩体锆石U-Pb年代学、地球化学特征及其地质意义

本文对青海南山构造带西段黑马河花岗杂岩体中的石英闪长岩和花岗闪长岩以及花岗闪长岩中的暗色微粒包体进行了详细的岩石学、岩石地球化学和LA-ICP-MS锆石U-Pb年代学研究。结果表明,花岗闪长岩及暗色微粒包体的结晶年龄分别为244.4±1.1 Ma和243.0±1.2 Ma,表明岩体形成于中三叠世早期。石英闪长岩和花岗闪长岩为准铝质高钾钙碱性系列,暗色微粒包体为高钾钙碱性—钾玄岩系列,稀土元素配分曲线均具有轻重稀土明显分异的右倾特征,具弱负Eu异常(δEu=0.65~0.83),富集大离子亲石元素(Cs、Rb、Th、K)和Pb,亏损高场强元素(Nb、Ta、Ti)和P、Ba负异常。岩相学和岩石地球化学特征指示黑马河花岗杂岩体具壳幔岩浆混合特征,形成于活动大陆边缘的俯冲环境,石英闪长岩为受俯冲流体交代的地幔楔部分熔融产生的基性岩浆演化的产物,花岗闪长岩则源自壳源岩浆与少量幔源岩浆的混合。黑马河花岗杂岩体是中三叠世早期宗务隆洋向南俯冲消减的岩浆记录。     

藏南亚东地区片麻状含石榴子石黑云花岗闪长岩LA-ICP-MS锆石U-Pb测年及其地质意义

亚东岩组是高喜马拉雅地区重要的前寒武纪变质地层之一。利用LA-ICP-MS锆石U-Pb测年技术对侵入亚东岩组的片麻状含石榴子石黑云花岗闪长岩进行了测年,获得岩浆结晶年龄为(499.2±3.9)Ma(中寒武世),提供了泛非构造-岩浆事件的记录。岩石地球化学分析表明,黑云花岗闪长岩SiO2含量为68.04%～68.92%,在(K2O+Na2O)-SiO2图解上样品点落入亚碱性系列的花岗闪长岩区,A/CNK指数均大于1.1,在Shand指数图解上落入过铝质系列区。稀土元素配分模式属轻稀土元素富集的右倾曲线,出现弱Eu负异常(δEu=0.62～0.79);微量元素表现出Ba、Nb、Ta、Sr亏损和Rb、Th、U相对富集的特征。通过Rb-(Y+Nb)和Rb-Hf-Ta图解判别,认为亚东地区片麻状含石榴子石黑云花岗闪长岩形成于后碰撞构造阶段。     

内蒙古毕力赫斑岩型金矿成矿岩体地球化学、锆石U-Pb年代学及Hf同位素研究

毕力赫金矿位于中亚造山带东南段华北克拉通北缘白乃庙早古生代弧增生杂岩带内,该矿床为一个斑岩型矿床,成矿岩体为早中二叠世花岗闪长岩。文中对成矿岩体进行了主微量元素地球化学以及锆石U-Pb年代学和Lu-Hf同位素研究。毕力赫花岗闪长岩具有安第斯型陆缘弧岩浆岩的地球化学亲缘性：岩体SiO2含量(质量分数)介于61.3%~64.4%,K2O/Na2O值介于0.52~0.87,A/CNK值介于0.82~0.95,属准铝高钾钙碱性系列岩石;岩体相对富集Rb、Th、U等大离子亲石元素和轻稀土元素,亏损Nb、Ta、Ti等高场强元素和重稀土元素,显示负Eu异常(δEu=0.50~1.03)。岩体浅部(zk086-53)与深部(zkI005-105)两个样品的锆石206Pb/238U加权平均年龄分别为(268.1±1.8) Ma(MSWD=1.17,1σ)和(267.7±4.1) Ma(MSWD=1.06,1σ);继承锆石除外,样品中锆石εHf(t)值分别为3.2~8.7和-0.6~8.3,二阶段模式年龄TDM2分别为1 085~737 Ma和1 330~762 Ma。成矿岩体可能源于洋壳俯冲脱水导致的新生地壳部分熔融而产生的底侵中基性岩浆与由底侵导致的古老基底物质部分熔融形成的长英质岩浆的混合。     

内蒙古东乌旗葛根敖包石英闪长岩岩体年代学、地球化学及其地质意义

内蒙古东乌旗地区新近发现的葛根敖包铅锌矿,成矿与赋矿岩体石英闪长岩关系密切,对石英闪长岩进行系统的LAICP-MS锆石U-Pb定年及锆石Hf同位素分析,并对石英闪长岩进行主量、微量和稀土元素分析。锆石U-Pb定年结果显示,石英闪长岩2个样品的锆石U-Pb年龄分别为299±1Ma和301±1Ma,均为晚石炭世。岩石主量、微量及稀土元素分析显示,石英闪长岩具有典型的富硅、富碱特征,Na_2O/K_2O值为1.14～1.93,平均1.39,明显富钠高钾,属高钾钙碱性系列;铝饱和指数A/CNK值为0.79～0.95,为准铝质或铝不饱和花岗岩类;轻、重稀土元素分馏显著,球粒陨石标准化稀土元素配分模式表现为明显的右倾,显示岩浆源区可能有石榴子石残留;并有微弱负Eu异常,δEu=0.80～0.91,δCe=0.89～0.96,均靠近1,指示源区无斜长石残留;同时具低Sr、高Yb特征;并指示高场强元素U、La、Nd、Zr相对富集,而Th、Nb、Sr、P、Ti相对亏损,且大离子亲石元素Rb、Ba、K相对富集,Nb/Ta值低,指示岩浆源区可能为幔源为主。锆石Hf同位素分析显示,εHf(t)值全部为正值,+10.8～+13.6(全部大于10,较高),TDM2介于440～629Ma之间,相对集中,明显大于其锆石U-Pb年龄,其年轻的TDM2年龄和较高的εHf(t)值表明,岩浆中有相当大的幔源物质的贡献。结合区域构造演化,认为葛根敖包石英闪长岩岩浆源区可能为亏损地幔物质部分熔融并在上升过程中受到少量壳源物质的混染,为活动陆缘弧环境的产物。     

阿尔泰南缘可可托海地区二厂房岩体 LA-ICP-MS 锆石 U-Pb 年代学、岩石成因及其地质意义

对出露于阿尔泰造山带南缘可可托海地区二厂房岩体中的黑云母花岗闪长岩进行了LA-ICP-MS锆石UPb定年和岩石地球化学分析。结果显示,锆石的206Pb/238U年龄加权平均值为398.0±3.5 Ma(MSWD=1.3),表明该岩体形成于早中泥盆世。岩体的SiO2含量介于65.40%～69.31%之间,里特曼指数值为1.27～1.65,A/CNK值为0.92～1.02,属中钾、钙碱性、准铝质岩石。具有富集Cs、Rb、Th、U等大离子亲石元素和轻稀土元素,相对亏损重稀土元素和Nb、Ta、Zr、Hf等高场强元素,负Eu异常明显(δEu=0.48～0.65)的岛弧岩浆岩特征。结合区域地质资料,认为二厂房岩体形成于陆缘弧构造环境,是在古亚洲洋俯冲过程中,幔源的基性岩浆底侵下地壳后使之熔融并发生了岩浆混合作用的产物。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

Mountains,nations, parks,and conservation

Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km² and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).     

NEW SET OF LOW CONCENTRATION STANDARDS FOR LA, CE, SM, YB, LU, Y, SC, V, NB AND TA IN SILICATES

We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al₂O₃-SiO₂ ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses.