The topographic imprint of a transient climate episode: the western Andean flank between 15·5° and 41·5°S

Mountain‐range topography is determined by the complex interplay between tectonics and climate. However, often it is not clear to what extent climate forces topographic evolution and how past climatic episodes are reflected in present‐day relief. The Andes are a tectonically active mountain belt encompassing various climatic zones with pronounced differences in rainfall, erosion, and glacier extent under similar plate‐boundary conditions. In the central to south‐western Andes, climatic zones range from hyperarid desert with mean annual rainfall of 5 mm/a (22·5°S) to year‐round humidity with 2500 mm/a (40°S). The Andes thus provide a unique setting for investigating the relationship between tectonics, climate, and topography. We present an analysis of 120 catchments along the western Andean watersheds between 15·5° and 41·5°S, which is based on SRTMV3‐90m data and new medium‐resolution rainfall, tropical rainfall measurement mission (TRMM) dataset. For each basin, we extracted geometry, relief, and climate parameters to test whether Andean topography shows a climatic imprint and to analyze how climate influences relief. Our data document that elevation and relief decrease with increasing rainfall and descending snowline elevation. Furthermore, we show that local relief reaches high values of 750 m in a zone between 28°S to 35°S. During Pleistocene glacial stages this region was affected by the northward shifting southern hemisphere Westerlies, which provided moisture for valley‐glacier formation and extended glacial coverage as well as glacial erosion. In contrast, the southern regions between 35°S to 40°S receive higher rainfall and have a lower local relief of 200 m, probably related to an increased drainage density. We distinguish two different, climatically‐controlled mechanisms shaping topography: (1) fluvial erosion by prolonged channel‐hillslope coupling, which smoothes relief, and (2) erosion by valley glaciers that generates relief. Finally, Our results suggests that the catchment‐scale relief of the Andes between 28°S to 35°S is characterized by a pronounced transient component reflecting past climatic conditions. Copyright © 2010 John Wiley & Sons, Ltd.     

The Carbonate Radical (HCO3·/CO3–·) as a Reactive Intermediate in Water Chemistry: Kinetics and Modelling

Results from kinetic laboratory studies of reactions of the carbonate radical anion (CO₃^–·) with aromatic compounds in aqueous solution at T = 298 K are presented. Data were obtained in using a laser photolysis laser long-path absorption (LP-LPLA) apparatus which was designed for direct time-resolved studies of radical reactions. For the reactions of CO₃^–· with hydroquinone dimethyl ether (2), methyl anisole (3), benzene (4), p-xylene (5), toluene (6), chlorobenzene (7), nitrobenzene (8), and benzonitrile (9), rate coefficients of k₂ = (3.0 ± 0.6)·10⁷ M^–1 s^–1, k₃ = (9.7 ± 1.7)·10⁵ M^–1 s^–1, k₄ = (3.2 ± 0.7)·10⁵ M^–1 s^–1, k₅ = (3.8 ± 0.9)·10⁴ M^–1 s^–1, k₆ = (6.8 ± 2.3)·10⁴ M^–1 s^–1, k₇ = (2.7 ± 0.6)·10⁵ M^–1 s^–1, k₈ = (1.4 ± 0.5)·10⁴ M^–1 s^–1, and k₉ < 1.3·10² M^–1 s^–1 were obtained. In further studies the effect of temperature on the reactions (2), (4), and (5) has been studied. The kinetic data obtained for the reaction of the carbonate radical anion with aromatic compounds were compared to the corresponding reactions of the hydroxyl radical. Finally, these kinetic data were used within a simple model system to investigate the implications of carbonate radical anion kinetics within water treatment processes. It is shown that the degradation of organic pollutants in ^·OH-radical based water treatment may proceed via the CO₃^–·/HCO_3· radical under certain conditions.     

Geochemical morphology of the North Mid-Atlantic Ridge, 10°–24°N: Trace element-isotope complementarity

The new data presented here from a 10–24°N segment of the North Mid-Atlantic Ridge show that this segment is the most depleted of the 10–70°N ridge section. They also show the existence of: (1) a geochemical gradient from the 14°N anomaly to 17°10′N; (2) a very depleted mantle source (the lowest Sr isotopic ratios found so far in the North Atlantic); and (3) a geochemical limit located at about 17°10′N without any obvious relation with any structural feature. The 15°20′N fracture zone does not show any relationship with respect to this gradient. The basalts located north of 17°10′N have very homogeneous features, which allow their characteristics to be averaged (i.e., ⁸⁷Sr/⁸⁶Sr= 0.70238 ± 0.00004, (Nb/Zr)_N = 0.28 ± 0.1) and they are defined as normal mid-ocean ridge basalts. The basaltic glasses located south of 17°10′N present a wide spectrum of isotopic compositions and extended rare earth element patterns (from depleted to enriched). Despite this, they have a constant K/Nb of 233 ± 9 (1s_M, n = 18) whereas this ratio is 344 ± 29 north of 17°10′N. These observations illustrate the strong coherence of behaviour between K and Nb (Ta) during the petrogenic processes involved in the generation of these mid-ocean ridge basalts and also their fractionation during previous mantle processes. Possible interpretations of mixing processes are discussed and sources at the ridge segment scale are favoured. However, when looking in detail, local heterogeneities are still common and can even be traced back off-axis to 115 my.

Placed in the context of the North Atlantic Ridge from 10° to 70°N, the Sr isotopic ratios reveal the Azores superstructure (23–50°N), whereas the trace element ratios (La/Sm-Nb/Zr) trace the second-order structures (33–40°N, 42–48°N) superimposed on the superstructure. This study illustrates the complementarity of information given by certain well chosen trace element ratios on the one hand and by isotopic ratios on the other. Since there is evidence of decoupling between isotopic ratios and/or trace element ratios, it introduces the notion of complementary “chemical memory” as recorded by a given type of trace element ratio or a given type of isotopic ratio     

Structural changes in trend parameters of the MLT winds based on wind measurements at Obninsk (55°N, 37°E) and Collm (52°N, 15°E)

Recent analysis of the long-term behavior of different geophysical data has demonstrated that trend parameters can change during a period of observation. Sophisticated general methods for an objective analysis of structural changes in linear trends have been developed during the last 10 years. Such methods are applied for an analysis of changes in trend parameters of the mesosphere/lower thermosphere wind observed over Obninsk (55°N, 37°E) from 1964 to 2007 and Collm (52°N, 15°E) from 1979 to 2008, respectively. We found that trend models with breakpoints are generally preferred against straight lines. At Obninsk, there are break-years in trends of the winter prevailing winds close to 1977, when a climatic regime shift was observed. The break-years in trends of the semidiurnal tides for both stations are close to years of possible changes in stratospheric ozone. Correlations of the Obninsk and Collm winds with atmospheric indices are also considered.