Rates of peat formation in relation to degree of humification and local environment, as shown by studies of a raised bog in Deninark

In the raised bog Draved Mose, rates of peat formation and degrees of humification were determined in two peat sections. Based on 59 calibrated C-14 dates, accumulation rates during the last 6500 years of 0.16 to 0.80 mm/year were found. The peat layers were analyscd for Sphagnum species, rhizopods, and pollen and spores. A clear relation between humification degrees and humidity at the time of formation was found, while the relation between measured growth rates and degrees of humification varied throughout the 2.5 m thick peat section. These variations are thought to be mostly a result of autocompaction.     

Holocene hydro-climatic change and effects on carbon accumulation inferred from a peat bog in the Attawapiskat River watershed,Hudson Bay Lowlands,Canada

Multiple proxies from a 319-cm peat core collected from the Hudson Bay Lowlands, northern Ontario, Canada were analyzed to determine how carbon accumulation has varied as a function of paleohydrology and paleoclimate. Testate amoeba assemblages, analysis of peat composition and humification, and a pollen record from a nearby lake suggest that isostatic rebound and climate may have influenced peatland growth and carbon dynamics over the past 6700 cal yr BP. Long-term apparent rates of carbon accumulation ranged between 8.1 and 36.7 g C m^? 2 yr^? 1 (average = 18.9 g C m^? 2 yr^? 1). The highest carbon accumulation estimates were recorded prior to 5400 cal yr BP when a fen existed at this site, however following the fen-to-bog transition carbon accumulation stabilized. Carbon accumulation remained relatively constant through the Neoglacial period after 2400 cal yr BP when pollen-based paleoclimate reconstructions from a nearby lake (McAndrews et al., 1982) and reconstructions of the depth to the water table derived from testate amoeba data suggest a wetter climate. More carbon accumulated per unit time between 1000 and 600 cal yr BP, coinciding in part with the Medieval Climate Anomaly.     

Distribution of As,Cr, Ni,Rb, Ti and Zr between peat and its humic fraction along an undisturbed ombrotrophic bog profile (NW Switzerland)

Ombrotrophic bogs are useful records of the impact of historical human activity on heavy metal contamination. Several studies concerning the trace element record (mainly Pb and Hg) in these particular environments have been carried out in recent years, although the role of humic substances has often not been considered. In particular, of the components of peat organic matter, fulvic acids and low molecular weight compounds are generally responsible for the mobility of trace elements through the profile, while humic acids (HAs) are involved in the formation of more stable organo-mineral complexes. In order to study the parallel distribution of As, Cr, Ni, Rb, Ti and Zr in bulk peat and the corresponding HAs, a peat core (10 × 10 × 81 cm) was collected from Etang de la Gruère (Switzerland) and cut into 27 slices of 3 cm. The samples were freeze-dried and milled very finely, and HAs extracted from each sample. Both peat and HAs were analyzed using an energy-dispersive miniprobe X-ray fluorescence multielement analyser (EMMA-XRF). Of the considered elements, Ni showed a great affinity for the humic acid component, while Cr was concentrated mainly into humic material from the deeper layers. On the other hand, Ti, Zr and Rb seemed to reflect the variation in mineral material both in peat and HA samples, while the As content of both materials reflected the environmental conditions characterizing the bog.     

Holocene evolution of mud depocentres on a high-energy, low-accumulation shelf (NW Iberia)

The high-energy, low-accumulation NW Iberian shelf features three confined Holocene mud depocentres. Here, we show that the evolution of such depocentres follows successive steps. The flooding of inner shelf zones and river catchment areas by the late deglacial sea-level rise provided the precondition for shelf mud deposition. Following this, the Holocene deceleration of the sea-level rise caused a rapid refill of the accommodation space within river valleys. Subsequently, the export of major amounts of fines was initiated. The initial onset and loci of shelf mud deposition were related to deposition-favouring conditions in mid-shelf position or to the presence of morphological highs, which act as sediment traps by providing protection against stronger hydrodynamic energy. The detailed reconstruction of the Holocene depocentre evolution shows for the first time that the expansion of such shelf mud deposits cannot only occur by linear growth off the associated sediment source. Rather, they might develop around centres that are fully disconnected from the source of original sediment supply, and expand later into specific directions. Based on these differences and on the connection of the individual mud depocentres to the material source we propose a conceptual subdivision of the group “mid-shelf mud depocentres”.     

A Holocene record of climate,vegetation change and peat bog development,east Otago,South Island,New Zealand

A Holocene record of pollen, macrofossils, testate amoebae and peat humification is presented from a small montane bog. Sediment accumulation began before 9000 yr BP, but peat growth not until ca. 7000 BP. From 12 000 to 7000 yr BP, a shrub–grassland dominated under a dry climate, with increasing conifer forest and tall scrub from ca. 9600 yr BP. At 7000 yr BP a dense montane–subalpine low conifer forest established under a moist, cool climatic regime. Between 7000 and 700 yr BP the bog surface was shrubby, tending to be dry but with highly variable surface wetness. The catchment was affected by major fire at least four times between 4000 and 1000 yr BP. Both fire and bog surface wetness may have been linked to ENSO-caused variations in rainfall. Cooler, cloudier winters and disturbance by fire promoted the expansion of the broadleaf tree Nothofagus menziesii between 4000 yr BP and 1300 yr BP at the expense of the previous conifer forest–scrub vegetation. Polynesian fires (ca. 700 yr BP) reduced the vegetation to tussock grassland and bracken. Deforestation did not markedly affect the hydrology of the site. European pastoralism since ad 1860 has increased run-off and rising water tables in the bog have led to a Sphagnum-dominated cover. Copyright © 1999 John Wiley & Sons, Ltd.     

Stratigraphy of peat bog in the Gorobets River valley and development of natural environments of Shikotan Island (Lesser Kurile Ridge) in the Holocene

The stratigraphic subdivision of peat in the Gorobets River valley, the largest river on Shikotan Island, is conducted based on the study of palynological and diatom assemblages, tephrostratigraphy, and radiocarbon dating. The study object is one of the oldest peats in the South Kurile region and reflects the development of natural environments beginning from the early Holocene. Nine phases are distinguished in the development of vegetation on Shikotan Island. The changes in vegetable communities were determined by climatic fluctuations during the Holocene. Their ages, the factors responsible for the appearance and extinction of particular coniferous, small-, and broad-leaved taxa, and changes in their landscape-forming role during different periods of the Holocene, as well as specific features in the formation of the present-day vegetation on the Lesser Kurile Ridge representing a separate floral area, are established. In addition to the climatic and sea-level fluctuations, the development of the island landscapes was determined to a significant extent by its topography, size, and isolation.     

Nepheline-bearing alkali feldspar syenite (pulaskite) in the Khibina pluton,Kola Peninsula,NW Russia: petrological investigation

The geological position and probable origin of nepheline-bearing alkaline syenite (pulaskite) found within foyaite of the Khibina pluton, Kola Peninsula, Russia, are discussed. A large body of pulaskite (4.5 km²) was identified under the Quaternary deposits in the eastern part of the pluton as a result of gravimetric surveying and drilling. Genetic relations between pulaskite and the host foyaite were examined by whole-rock chemistry, including major and trace elements, the composition of the rock-forming clinopyroxenes and the diagram of phase equilibria in the system NaAlSiO₄–KAlSiO₄–SiO₂–H₂O. The results regarding mafic silicates show that pulaskite may constitute the less evolved member of a pulaskite-foyaite series, which suggests that it was formed by feldspar fractionation from an almost eutectic phonolitic melt, the parental one for both foyaite and pulaskite. The geochemical data, however, also enable us to assume the probability of additional petrogenetic mechanisms. The trace element abundance patterns may provide preliminary evidence for a process of crustal contamination of a mantle-derived phonolite magma. This process may have contributed to the genesis of the pulaskite.     

Sedimentology, stratigraphy and landscape evolution of a Holocene coastal dune system, Lodbjerg, NW Jutland, Denmark

The stratigraphy and landscape evolution of the Lodbjerg coastal dune system record the interplay of environmental and cultural changes since the Late Neolithic. The modern dunefield forms part of a 40 km long belt of dunes and aeolian sand‐plains that stretches along the west coast of Thy, NW Jutland. The dunefield, which is now stabilized, forms the upper part of a 15–30 m thick aeolian succession. The aeolian deposits drape a glacial landscape or Middle Holocene lake sediments. The aeolian deposits were studied in coastal cliff exposures and their large‐scale stratigraphy was examined by ground‐penetrating radar mapping. The contact between the aeolian and underlying sediments is a well‐developed peaty palaeosol, the top of which yields dates between 2300 BC and 600 BC . Four main aeolian units are distinguished, but there is some lateral stratigraphic variation in relation to underlying topography. The three lower aeolian units are separated by peaty palaeosols and primarily developed as 1–4 m thick sand‐plain deposits; these are interpreted as trailing edge deposits of parabolic dunes that moved inland episodically. Local occurrence of large‐scale cross‐stratification may record the head section of a migrating parabolic dune. The upper unit is dominated by large‐scale cross‐stratification of various types and records cliff‐top dune deposition. The nature of the aeolian succession indicates that the aeolian landscape was characterized by alternating phases of activity and stabilization. Most sand transported inland was apparently preserved. Combined evidence from luminescence dating of aeolian sand and radiocarbon dating of palaeosols indicates that phases of aeolian sand movement were initiated at about 2200 BC , 700 BC and AD 1100. Episodes of inland sand movement were apparently initiated during marked climate shifts towards cooler, wetter and more stormy conditions; these episodes are thought to record increased coastal erosion and strong‐wind reworking of beach and foredune sediments. The intensity, duration and areal importance of these sand‐drift events increased with time, probably reflecting the increasing anthropogenic pressure on the landscape. The formation of the cliff‐top dunes after AD 1800 records the modern retreat of the coastal cliffs.     

The active-layer hydrology of a peat plateau with thawing permafrost (Scotty Creek, Canada)

The southern margin of permafrost is experiencing unprecedented rates of thaw, yet the effect of this thaw on northern water resources is poorly understood. The hydrology of the active layer on a thawing peat plateau in the wetland-dominated zone of discontinuous permafrost was studied at Scotty Creek, Northwest Territories (Canada), from 2001 to 2010. Two distinct and seasonally characteristic levels of unfrozen moisture were evident in the 0.7-m active layer. Over-winter moisture migration produced a zone of high ice content near the ground surface. The runoff response of a plateau depends on which of the three distinct zones of hydraulic conductivity the water table is displaced into. The moisture and temperature of the active layer steadily rose with each year, with the largest increases close to the ground surface. Permafrost thaw reduced subsurface runoff by (1) lowering the hydraulic gradient, (2) thickening the active layer and, most importantly, (3) reducing the surface area of the plateau. By 2010, the cumulative permafrost thaw had reduced plateau runoff to 47 % of what it would have been had there been no change in hydraulic gradient, active layer thickness and plateau surface area over the decade.     

Distribution, classification, petrological and related gochemical (SRA) characteristics of a tropical lowland peat dome in the Kota Samarahan-Asajaya area, West Sarawak, Malaysia

Petrographic studies indicate that lateral variations in the decomposition levels of peat are associated with the predominantly occurring peat macerals. Source Rock Analyzer (SRA) results indicate lateral variation in peat organic matter types from type II to III and back again to type II, occurring laterally within the top 0-m to 0.5-m layer at the basin margin to the midsection and further towards the near-center areas of the peat dome. This variation is most likely caused by a combination of factors: (a) Horizontal zonation and lateral variation of the dominant species of plant assemblages (b) Fibric (marginal) peats and hemic to sapric peats associated with type II organic matter (kerogen). Sample organic matter (coal-equivalent kerogen) typing indicates that the relative abundance of phytoclasts and palynomorphs generally supports the organic matter classification obtained by the SRA method. Lateral variations in the peat organic matter types may support the lateral vegetation variation concept. The classification of peat organic matter types (interpreted from visual analyses of palynological slides) occurring from the basin periphery to the mid-section and further towards the basin center yields organic matter of type II to type III and mixed types II to III (coal kerogen-equivalent), respectively.     

The structural evolution of the Asinara Island (NW Sardinia,Italy)

The metamorphic basement of the Asinara island represents a key area of the Sardinia Variscan segment, because it displays an almost complete cross-section through the inner part of the Sardinia Variscan belt, where different tectono-metamorphic complexes have been juxtaposed along narrow belts of high-strain concentration. Detailed field mapping coupled with preliminary studies on the structural and metamorphic features of this small island, allow to draw a better picture of the structural frame issued from the Variscan collision in the inner zone of the belt. Three deformation phases related to crustal thickening in a compressive and transpressive, partitioned tectonic regime, followed by a later phase of extensional deformation have been recognised. In spite of a general HT/LP metamorphic overprint, linked to the post-collisional deformation phases, a relic Barrovian zoneography is still detectable. The Barrovian assemblages are preto syn-kinematic with respect to the D2 deformation phase, and pre-date the third, contractional tectonic event.

The HT/LP assemblage indicates a static growth of weakly deformed by the last deformation events. The complex geometry of the fabric associated to the D2 and D3 deformation events suggests an heterogenous deformation history with a monoclinic geometry characterized by switching of the stretching lineation orientation and a contrasting sense of displacement, probably controlled by a northward partitioned pure shear.     

A multiproxy record of late Holocene natural and anthropogenic environmental change from the Sphagnum peat bog Dürres Maar,Germany: implications for quantitative climate reconstructions based on pollen

Pollen data are well established for quantitative climate reconstructions over long timescales, including the Holocene and older interglacials. However, anthropogenically induced environmental change in central Europe was strong during the last 4 ka, challenging quantitative reconstructions of this time period. Here we present quantitative climate reconstructions based on pollen analyses and evaluate them with the peat humification record and the stable carbon isotopes of Sphagnum plant material (δ¹³C_cellulose). All analyses were carried out on the same 7.5 m long, largely ombrotrophic peat bog section from Dürres Maar. Three different methods were used for the quantitative climate reconstructions on the basis of the pollen data: (1) a probabilistic indicator taxa approach (the ‘pdf method’); (2) a modern analogue technique based on pollen taxa from modern surface samples (cMAT); and (3) a modern analogue technique expanded by plant functional types (pMAT). At Dürres Maar the peat humification is only affected by peat cutting during the Roman period and the Middle Ages. The stable carbon isotopes are seemingly unaffected by human impact. Thus both proxies provide independent data to evaluate the reconstructions on the basis of pollen data. The quantitative climate reconstructions on the basis of the individual methods are in general relatively similar. Nevertheless, distinct differences between the individual approaches are also apparent, which could be attributed to taxa that reflect human impact on a local to regional scale. While the pdf method appears to be relatively robust to all observed anthropogenically induced vegetation changes, it potentially underestimates climate variability. This method is therefore expected to be independent of local site characteristics and to provide robust quantitative estimates of climatic trends rather than of climatic variability of small amplitude. This is of value for palaeoclimate reconstructions of older interglacials, for which neither multiple sites nor independent climate proxies are available for comparison. Copyright © 2009 John Wiley & Sons, Ltd.     

Tectonothermal evolution of a foreland fold and thrust belt: the Cantabrian Zone (Iberian Variscan belt,NW Spain)

Analysis of the conodont colour alteration index and the Kübler index of illite allowed us the characterization of four types of very low‐ or low‐grade metamorphism in the Cantabrian Zone (CZ) and determination of their regional and temporal distribution. These types are: (1) an orogenic Variscan metamorphism present only in restricted areas of the western and north‐western parts of the CZ where epizonal conditions are reached; (2) a burial metamorphism that appears in the basal part of some nappes, where anchizonal conditions are sometimes achieved; the thermal peak preceded emplacement of the nappes; (3) a late‐Variscan metamorphism in the southern and south‐eastern parts of the CZ; a cleavage, cutting most of the Variscan folds, is associated with this metamorphism, which has been related to an extensional episode; (4) a contact metamorphism and hydrothermal activity associated with minor intrusive bodies. The extension continued after the Variscan deformation giving rise to hydrothermal activity during Permian times.     

Identification of Icelandic tephras from the last two millennia in the White Sea region (Vodoprovodnoe peat bog,northwestern Russia)

The generation of reliable age models for palaeoenvironmental and archaeological records in the Eurasian Arctic is often problematic when using conventional dating techniques. Tephrochronology can potentially improve the chronologies of such records and synchronise disparate sedimentary archives. However, to date, systematic tephra studies are lacking for this region. This paper presents the first cryptotephra data from the White Sea region (northwestern Russia) based on a peat core spanning the past ~1800 years. We identify seven geochemical glass populations that derive from six Icelandic volcanoes and correlate four of them to north European tephra isochrons; these include Askja ad 1875, the basaltic component of the ad 877 Landnám tephra, and tephras BTD-15 (c. ad 1750–1650) and SL-2/SB-2 (ad 803–767) from unknown eruptions of Katla and Snæfellsjökull, respectively. The remaining three populations originate from Grímsvötn, Hekla and Katla; however, their attribution to individual eruptions remains ambiguous. These findings highlight the potential to extend the Late Holocene tephrochronological framework of northern Europe to the west Eurasian Arctic. The detection of at least three basaltic tephras in the core suggests that basaltic shards can be transported over larger distances than previously known and that peatlands are well suited to preserve such components.     

A cold Early Palaeozoic subduction zone in the North Qilian Mountains, NW China: petrological and U-Pb geochronological constraints

The north Qilian high‐pressure (HP)/low‐temperature (LT) metamorphic belt is composed mainly of blueschists, eclogites and greenschist facies rocks. It formed within an Early Palaeozoic accretionary wedge associated with the subduction of the oceanic crust and is considered to be one of the best preserved HP/LT metamorphic belts in China. Here we report new lawsonite‐bearing eclogites and eclogitic rocks enclosed within epidote blueschists in the North Qilian Mountains. Five samples contain unaltered lawsonite coexisting with omphacite and phengite as inclusions in garnet, indicating eclogite facies garnet growth and lawsonite pseudomorphs were observed in garnet from an additional 11 eclogites and eclogitic rocks. Peak pressure conditions estimated from lawsonite omphacite‐phengite‐garnet assemblages were 2.1–2.4 GPa at temperatures of 420–510 °C, in or near the stability field of lawsonite eclogite, and implying formation under an apparent geothermal gradient of 6–8 °C km^?1, consistent with metamorphism in a cold subduction zone. SHRIMP U‐Pb dating of zircon from two lawsonite‐bearing eclogitic metabasites yields ages of 489 ± 7 Ma and 477 ± 16 Ma, respectively. CL images and mineral inclusions in zircon grains indicate that these ages reflect an eclogite facies metamorphism. An age of 502 ± 16 Ma is recorded in igneous cores of zircon grains from one lawsonite pseudomorph‐bearing eclogite, which is in agreement with the formation age of Early Ordovician for some ophiolite sequences in the North Qilian Mountains, and may be associated with a period of oceanic crust formation. The petrological and chronological data demonstrate the existence of a cold Early Palaeozoic subduction zone in the North Qilian Mountains.     

Petrogenesis of the anorthosite-chromitite association: crystal-chemical and petrological insights from the Rum Layered Suite, NW Scotland

Thirteen Cr-bearing spinels from major horizons of magma replenishment in the open-system Rum Layered Suite have been analysed by X-ray single crystal diffraction and electron microprobe analyses. On the basis of the structural parameters and the chemistry of these spinels the so-called Rum trend, in which Al-content increases at the expense of Cr and Fe³⁺, has been easily recognised. In addition, natural spinels with Fe³⁺ content similar to synthetic spinels on the MgCr₂O₄?CMgFe₂O₄ join have been analysed for the first time. Layers of chromitite, anorthosite and peridotite situated within several cm of one another have yielded different intracrystalline exchange temperatures using an intercrystalline spinel-olivine thermometer. The Rum anorthosite Cr-spinels are interpreted as having crystallised within the cumulus pile following rejuvenation of the crystal mush. Their low Al-content is a function of simultaneous plagioclase crystallisation, reducing the amount of Al³⁺ present for the Cr-spinel. By contrast, Cr-spinels in well-known Archean anorthosites (e.g. Ujaragssuit nunat and Fisken?sset, western Greenland) and Sittampundi (southern India) are very aluminous in composition, attributed to crystallisation of Cr-spinel from high-alumina basalts in lower crustal magma chambers and linked to the control exerted by plagioclase crystallisation on Al content of the melt, in the absence of clinopyroxene crystallisation. The compositional differences between the Rum anorthosite Cr-spinels and the Fisken?sset and Sittampundi Cr-spinels suggest that postcumulus reaction of Cr-spinel and melt to low (800?C900°C) temperatures, as invoked for the Rum crystals, may not have been as important a process in the Archean anorthosites.     

Modelling retention of heavy metals in the Oostriku peat bog,Estonia: Comparison of predicted and observed results

In this study, the retention of Ca and other metals (Pb, Cu, Fe, Zn and Mn) in the Oostriku peat bog (central Estonia) was modelled. Equilibrium sorption of metals on amorphous ferric oxyhydroxide and solid organic matter was simulated at steady-state. Ferric oxyhydroxide formation and possible precipitation of other metals (Mn, Pb and Cu) in the peat was also assessed. Evolution of metal sorption fronts along a peat profile over time was simulated with a dynamic model to test if metal–metal competition effects could cause Pb and Cu to sorb at higher amounts in the uppermost peat than in the lower peat, as observed in the field. The predicted sorbed amounts of metals were compared with those previously observed in the peat. In general, good agreement between both batch and dynamic model results and the independent observations at the Oostriku peat site was obtained. This suggests that the relatively simple model approach employed here might be generally useful for assessing other peat sites and similar applications.     

Late Quaternary–Holocene evolution of Dun structure and the Himalayan Frontal Fault zone of the Garhwal Sub-Himalaya,NW India

Dun structures are common in the Sub-Himalayan zone of the Himalaya bounded by the Main Boundary Thrust (MBT) and the Himalayan Frontal Thrust (HFT). They are broad synclinal longitudinal valleys formed as a consequence of the exhumation of the range front of the Himalaya. In the Garhwal Sub-Himalaya, these structures have grown since 0.5 Ma, with the peak activity postdating ∼100 ka. A series of out-of-sequence deformation structures have been identified within the MBT-HFT-bounded Dun structures. They are identified on the basis of geomorphic, post-100 ka stratigraphic, and structural expressions, with activity as young as the early Holocene. To the south of the range front of the Himalaya, uplift has been observed in the Piedmont Zone, with peculiar active tectonic geomorphic expressions. Piedmont sediments of 15–5 ka, determined by Optically Simulated Luminescence (OSL), have been affected by the above uplift. The complete tectonic scenario has been analyzed and an attempt has been made to delineate the sequential evolution of these structures during the post-100 ka period (Late Quaternary–Holocene) in the Himalayan range front.     

Evolution of organic matter indicators in response to major environmental changes: The case of a formerly cut-over peat bog (Le Russey, Jura Mountains, France)

To assess whether the biochemical characteristics of peat can provide clues for past ecosystem changes or not, a study was carried out combining elemental analysis, micro-morphological counts and neutral monosaccharide determination of peat organic matter (OM) and the dominant living plants from a formerly cut-over peat bog in the Jura Mountains. Peat profiles (up to 50 cm depth) from two distinctive zones (bare peat, FRA and a regenerating stage, FRC) were compared with the reference profile (FRD) taken from an unexploited area of the bog. The results show contrasting OM composition along the profiles. In the upper sections of the FRD and FRC profiles, high C/N ratios and sugar contents (in the same range as in the source plants) and the large predominance of well preserved plant tissues indicate good preservation of primary biological inputs. In contrast, in peat from the FRA profile and deeper levels of the FRC profile, lower C/N ratios, lower amounts of sugars and a predominance of amorphous OM and mucilage suggest more extensive OM degradation. These features delineate a clear threshold between an uppermost “new” regenerating peat section and an “old” catotelm peat below. Nevertheless, even in the latter, the sugar contents remain relatively high (>80 mg/g) compared with other organic and mineral soils. Analysis of typical peat-forming plants and of bulk peat and fine grained fractions allowed identification of the following source indicators: xylose and arabinose for Cyperaceae; rhamnose, galactose and mannose for mosses; and ribose (and to a lesser extent, hemicellulosic glucose) possibly for microbial synthesis.