C.I.P.W.标准矿物计算法计算机程序

C.I.P.W.标准矿物计算法,是岩浆岩化学成份计算方法中应用较广的一种。该方法计算的内容比较庞杂,在对大量岩石样品进行计算时,工作量很大,且容易出错。采用便于地质工作者随身携带的袖珍计算机处理,不仅迅速准确,而且方便可靠。     

ГЕОЛОГИЧЕСКИЕ И ГЕОГРАФИЧЕСКИЕ ИССЛЕДОВАНИЯ АКАДЕМИКА В.А.ОБРУЧЕВА В КИТАЕ И НЕКОТОРЫЕ ВОПРОСЫ ГЕОЛОГИИ ЦЕНТРАЛЬНОЙ АЗИИ

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悼念R.J.E.布朗博士

R.J.E.布朗博士是加拿大著名的冻土学家,在国际冻土学界享有盛名,是我国冻土科学工作者的好朋友。两年前的1980年11月,癌症夺去了他的生命,结识他的中国朋友无不感到悲痛,他的逝世对冻土科学的发展是莫大的损失。     

“V.P.R.H”钻机简介

遵照毛主席“洋为中用”的教导，对“V．P．R．H”钻机予以介绍，希各单位根据自己实际情况，取其精华，加以利用。     

Determination of naphthenic acids in crude oil by chemical ionization mass spectrometry

Naphthenic acids in petroleum are considered a class of biological markers. Their potential use in source correlation and as an indicator of biodegradation was reported in the past ( Dzidic et al. ,1988 ; Behar and Albrecht, 1984). Due to their highly complicated properties, detailed characterization of the acids is difficult. A method based on positive ion CI (chemical ionization) mass spectrometry using isobutane reagent gas to produce ( M 15)^ ions was applied to the analysis of naphthenic acid esters. Since the complex mixture of naphthenic acids cannot be separated into individual components, only the determination of relative distribution of acids classified in terms of hydrogen deficiency was possible. The identities and relative distribution of fatty and mono-, di-, tri-, and higher polycyclic acids were obtained from the intensities of the ( M 15 )^ ions according to z-series formula CπH2π 2 O2 of naphthenic acids. The components are characterized on the basis of group type and carbon number distributions. A comparison of the FAB and CI results showed that the group type distributions obtained bv both methods agree surprisingly well.The results indicated this method is simple, rapid and easy to operate. The geochemical implication of naphthenic acids was investigated by using a set of well-characterized crude oil samples. It is found that the naphthenic acid distribution can be used as a fingerprint for oil-oil and oil-source correlations.