Zonal mean properties of Jupiter's upper troposphere from voyager infrared observations

The highest spatial resolution Voyager IRIS spectra are used to produce zonal averages of the temperature at the 150- and 270-mb pressure levels, of the para-hydrogen fraction at 270 mb, of the ammonia abundance near the 680-mb level, and of two infrared cloud optical depths, one near 5 μm and one near 45 μm wavelength. There are two cloud components, one uniformly distributed and only apparent at 5 μm, and another that correlates strongly with the ammonia abundance and that is apparent at both 5 and 45 μm. From the ratio of optical depths at the two wavelengths, the particles in the variable cloud are between 3 and 10 μm in radius. This cloud is located near the ammonia condensation level. The other particles are either smaller or deeper. The cloud and ammonia distribution is consistent with concentration by upward vertical motion at the equatorward edges of prograde atmospheric jets. The temperature field is also consistent with such vertical motion, with radiative heating balancing adiabatic expansional cooling. The para-hydrogen distribution also appears consistent, but noise levels are high. The thermal wind shear indicates decay of the jets with height within the upper troposphere, with a vertical scale of two or three scale heights. The entire set of upper troposphere data is consistent with a simple axisymmetric dynamical model with Coriolis acceleration of the zonal wind balanced by a linear drag. The meridional residual mean circulation in the model, if interpreted also as a Lagrangian mean circulation, would explain nicely the distribution of ammonia and para-hydrogen. The circulation is a response to a deeper tropospheric flow of unknown origin. However, the horizontal scale of jets is on the order of the deformation radius based on a scale height at the base of the upper troposphere. It is conjectured that the physics of the flow may require this to be true, and may also require that the relative vorticity gradient be of the same order as the planetary vorticity gradient, thereby fixing both the dimensions and amplitudes of the jets.     

The cloud structure of the jovian atmosphere as seen by the Cassini/CIRS experiment

We analyze the thermal infrared spectra of Jupiter obtained by the Cassini-CIRS instrument during the 2000 flyby to infer temperature and cloud density in the jovian stratosphere and upper troposphere. We use an inversion technique to derive zonal mean vertical profiles of cloud absorption coefficient and optical thickness from a narrow spectral window centered at 1392 cm⁻¹ (7.18 μm). At this wavenumber atmospheric absorption due to ammonia gas is very weak and uncertainties in the ammonia abundance do not impact the cloud retrieval results. For cloud-free conditions the atmospheric transmission is limited by the absorption of molecular hydrogen and methane. The gaseous optical depth of the atmosphere is of order unity at about 1200 mbar. This allows us to probe the structure of the atmosphere through a layer where ammonia cloud formation is expected. The results are presented as height vs latitude cross-sections of the zonal mean cloud optical depth and cloud absorption coefficient. The cloud optical depth and the cloud base pressure exhibit a significant variability with latitude. In regions with thin cloud cover (cloud optical depth less than 2), the cloud absorption coefficient peaks at 1.1±0.05 bar, whereas in regions with thick clouds the peak cloud absorption coefficient occurs in the vicinity of 900±50 mbar. If the cloud optical depth is too large the location of the cloud peak cannot be identified. Based on theoretical expectations for the ammonia condensation pressure we conclude that the detected clouds are probably a system of two different cloud layers: a top ammonia ice layer at about 900 mbar covering only limited latitudes and a second, deeper layer at 1100 mbar, possibly made of ammonium hydrosulfide.     

Vertical cloud structure of Jupiter's Equitorial Plumes

A model for the vertical cloud structure of Jupiter's Equitorial Plumes is deduced based on an analysis of Voyager images of the equitorial region in the 6190Å methane band and the 6000-Å continuum, and ground-based 8900-Å methane band images of Jupiter. A computer code that represents scattering and absorption from aerosol and gas layers was applied to a heirarchy of increasingly complex model aerosol structures to match the observations in the three wavelengths. The observations are consistent with a model for the vertical cloud structure of the equitorial region that consists of four aerosol layers. A high-altitude haze layer (HAL) with optical depth τ = 1 uniformly blankets the equitorial region at an altitude between 100 and 250 mbar. Below that, a middle-level cloud layer between 400 and 800 mbar contains the well-known Equatorial Plumes. The Plume clouds are optically thick (τ ≥ 12), bright clouds with single scattering albedo $\text{ω}\text{= 0.997}$. They are probably composed of ammonia ice. The darker ($\text{ω}\text{= 0.990}$) interplume regions contain optically thinner clouds (2 ≤ τ ≤ 5) at the same altitude as the Plumes. An opaque cloud deck between 4000 and 6000 mbar, which is probably composed of water, forms the lowest model layer. In addition to these three layers, a thin forward scattering haze layer above 100 mbar was included in the models for consistency with previous work (Tomasko et al., 1978). We conclude that the vertical structure of the Equatorial Plume clouds is consistent with the hypothesis (Hunt et al., 1981) that the Plumes are caused by upwelling at the ammonia condensation level produced by bouyancy due to latent heat release from the condensation of water clouds nearly three scale heights below the Plumes.     

Inhomogeneous models of Titan's aerosol distribution

A model of Titan's aerosol is presented which allows the particle size to vary with height. The model assumes a refractive index appropriate to an ethylene polymer and a mass flux independent of height equal to the value derived from laboratory measurements. The free parameters of the model are determined by fitting to the observed geometric albedo at 4000 and 6000 Å. A methane spectrum is derived which is in excellent agreement with observations. An aerosol optical depth of ～5 is found in the visible, with the particle radius varying from 0.01 to 8 μm. The presence of an optically thick methane cloud at the temperature minimum is indicated.     

The meridional phosphine distribution in Saturn's upper troposphere from Cassini/CIRS observations

The Cassini Composite Infrared Spectrometer (CIRS) has been used to derive the vertical and meridional variation of temperature and phosphine (PH₃) abundance in Saturn's upper troposphere. PH₃ has a significant effect on the measured radiances in the thermal infrared and between May 2004 and September 2005 CIRS recorded thousands of spectra in both the far (10-600 cm⁻¹) and mid (600-1400 cm⁻¹) infrared, at a variety of latitudes covering the southern hemisphere. Low spectral resolution (15 cm⁻¹) data has been used to constrain the temperature structure of the troposphere between 100 and 500 mbar. The vertical distributions of phosphine and ammonia were retrieved from far-infrared spectra at the highest spectral resolution (0.5 cm⁻¹), and lower resolution (2.5 cm⁻¹) mid-infrared data were used to map the meridional variation in the abundance of phosphine in the 250-500 mbar range. Temperature variations at the 250 mbar level are shown to occur on the same scale as the prograde and retrograde jets in Saturn's atmosphere [Porco, C.C., and 34 colleagues, 2005. Science 307, 1243-1247]. The PH₃ abundance at 250 mbar is found to be enhanced at the equator when compared with mid-latitudes. At mid latitudes we see anti-correlation between temperature and PH₃ abundance at 250 mbar, phosphine being enhanced at 45° S and depleted at 25 and 55° S. The vertical distribution is markedly different polewards of 60-65° S, with depleted PH₃ at 500 mbar but a slower decline in abundance with altitude when compared with the mid-latitudes. This variation is similar to the variations of cloud and aerosol parameters observed in the visible and near infrared, and may indicate the subsidence of tropospheric air at polar latitudes, coupled with a diminished sunlight penetration depth reducing the rate of PH₃ photolysis in the polar region.     

Broadband Submillimeter Spectroscopy of HCN, NH3, and PH3in the Troposphere of Jupiter

We report measurements of the Jupiter brightness spectrum in the 850-μm and 1100-μm atmospheric windows with a spectral resolution of 125 MHz, obtained with a Fourier transform spectrometer on the James Clerk Maxwell Telescope. Three results were obtained. First, the predicted absorption features due to the rotational lines of HCN at 266 and 354 GHz were not detected within our error limits of less than 1%. We establish new upper limits for the HCN abundance in the jovian troposphere for five assumed abundance distributions and for two assumed NH₃abundances. The upper limits are 1.7 to 13 times smaller than the abundance value obtained in the only reported detection of HCN in Jupiter prior to the impact of Shoemaker–Levy 9. Second, the continuum brightness temperature spectrum at 850 μm was determined and is in agreement with previous measurements, but has large error bars due to uncertainties in the photometric calibration. We estimate the ammonia abundance in the 1–2 bar region to be 1.7 times solar, but this result is tentative since scattering by NH₃cloud particles and absorption by gaseous H₂S were neglected in our atmospheric model. Finally, the first rotational line of PH₃at 267 GHz was not detected, a result which we demonstrate is consistent with the statistical noise level in these measurements, with current values of the spectroscopic parameters, and with phosphine measurements at other wavelengths.     

Retrievals of jovian tropospheric phosphine from Cassini/CIRS

On December 30th, 2000, the Cassini-Huygens spacecraft reached the perijove milestone on its continuing journey to the Saturnian System. During an extended six-month encounter, the Composite Infrared Spectrometer (CIRS) returned spectra of the jovian atmosphere, rings and satellites from 10-1400 cm⁻¹ (1000-7 μm) at a programmable spectral resolution of 0.5 to 15 cm⁻¹. The improved spectral resolution of CIRS over previous IR instrument-missions to Jupiter, the extended spectral range, and higher signal-to-noise performance provide significant advantages over previous data sets.CIRS global observations of the mid-infrared spectrum of Jupiter at medium resolution (2.5 cm⁻¹) have been analysed both with a radiance differencing scheme and an optimal estimation retrieval model to retrieve the spatial variation of phosphine and ammonia fractional scale height in the troposphere between 60° S and 60° N at a spatial resolution of 6°. The ammonia fractional scale height appears to be high over the Equatorial Zone (EZ) but low over the North Equatorial Belt (NEB) and South Equatorial Belt (SEB) indicating rapid uplift or strong vertical mixing in the EZ. The abundance of phosphine shows a similar strong latitudinal variation which generally matches that of the ammonia fractional scale height. However while the ammonia fractional scale height distribution is to a first order symmetric in latitude, the phosphine distribution shows a North/South asymmetry at mid latitudes with higher amounts detected at 40° N than 40° S. In addition the data show that while the ammonia fractional scale height at this spatial resolution appears to be low over the Great Red Spot (GRS), indicating reduced vertical mixing above the ∼500 mb level, the abundance of phosphine at deeper levels may be enhanced at the northern edge of the GRS indicating upwelling.     

Study of the deep cloud structure in the equatorial region of Jupiter from voyager infrared and visible data

High spatial resolution infrared and visible data obtained by the Voyager 1 spacecraft have been analyzed simultaneously to infer properties of the deep cloud structure of the Jovian troposphere in the 1- to 4-bar pressure range. Influence of the ammonia upper cloud layer, in the 5μm Jovian window, has been investigated through a cloud model derived from far ir Voyager IRIS measurements. The attenuation, computed with an anisotropic scattering formulation, is too weak to explain 5-μm measurements and provides evidence for existence of a cloud structure at deeper levels. The main conclusions derived from the present analysis are summarized below: (1) the deep cloud structure appears to be vertically associated with the NH₃ upper layer; (2) the ammonia cloud is mainly responsible for the visible appearance of the Jovian equatorial region; (3) the deep cloud structure exhibits a grey opacity in the 5-μm window; (4) coldest 5-μm spectra can be interpreted by the existence of a thick cloud layer located at levels in the 180–195°K temperature range. Implications of these results are discussed in conjunction with predictions of dynamical and thermochemical models. NH₄SH is shown to be a likely candidate for the main deep cloud constituent. An even deeper thick H₂O cloud may be present too, but should not be responsible for the observed spread in 5-μm brightness temperatures.     

The effect of ammonia ice on the outgoing thermal radiance from the atmosphere of Jupiter

We examine the effects of NH₃ ice particle clouds in the atmosphere of Jupiter on outgoing thermal radiances. The cloud models are characterized by a number density at the cloud base, by the ratio of the scale height of the vertical distribution of particles (H_p) to the gas scale height (H_g), and by an effective particle radius. NH₃ ice particle-scattering properties are scaled from laboratory measurements. The number density for the various particle radius and scale height models is inferred from the observed disk average radiance at 246 cm^?1, and preliminary lower limits on particle sizes are inferred from the lack of apparent NH₃ absorption features in the observed spectral radiances as well as the observed minimum flux near 2100 cm^?1. We find lower limits on the particle size of 3 μm if H_p/H_g = 0.15, or 10μmif H_p/H_g = 0.50 or 0.05. NH₃ ice particles are relatively dark near the far-infrared and 8.5-μm atmospheric windows, and the outgoing thermal radiances are not very sensitive to various assumptions about the particle-scattering function as opposed to radiances at 5 μm, where particles are relatively brighter. We examined observations in these three different spectral window regions which provide, in principle, complementary constraints on cloud parameters. Characterization of the cloud scale height is difficult, but a promising approach is the examination of radiances and their center-to-limb variation in spectral regions where there is significant opacity provided by gases of known vertical distribution. A blackbody cloud top model can reduce systematic errors due to clouds in temperature sounding to the level of 1K or less. The NH₃ clouds provide a substantial influence on the internal infrared flux field near the 600-mbar level.     

Clouds, haze, and CH4, CH3D, HCN, and C2H2 in the atmosphere of Titan probed via 3 μm spectroscopy

Using synthetic spectra derived from an updated model atmosphere together with a continuum model that includes contributions from haze, cloud and ground, we have re-analyzed the recently published (Geballe et al., 2003, Astrophys. J. 583, L39-L42) high-resolution 3 μm spectrum of Titan which contains newly-detected bands of HCN (in emission) and C₂H₂ and CH₃D (in absorption), in addition to previously detected bands of CH₄. In the 3.10-3.54 μm interval the analysis yields strong evidence for the existence of a cloud deck or optically thick haze layer at about the 10 mbar (∼ 100 km) level. The haze must extend well above this altitude in order to mask the strong CH₄ lines at 3.20-3.50 μm. These cloud and haze components must be transparent at 2.87-2.92 μm, where analysis of the CH₃D spectrum demonstrates that Titan's surface is glimpsed through a second cloud deck at about the 100 mbar (∼ 50 km) level. Through a combination of areal distribution and optical depth this cloud deck has an effective transmittance of ∼ 20%. The spectral shape of Titan's continuum indicates that the higher altitude cloud and haze particles responsible for suppressing the CH₄ absorptions have a largely organic make-up. The rotational temperature of the HCN ranges from 140 to 180 K, indicating that the HCN emission occurs over a wide range of altitudes. This emission, remodeled using an improved collisional deactivation rate, implies mesospheric mixing ratio curves that are consistent with previously predictions. The stratospheric and mesospheric C₂H₂ mixing ratios are ∼¹⁰⁻⁵, considerably less than previous model predictions (Yung et al., 1984), but approximately consistent with recent observational results. Upper limits to mixing ratios of HC₃N and C₄H₂ are derived from non-detections of those species near 3.0 μm.     

High altitude Venus haze from Pioneer Venus limb scans

High vertical resolution scans of the Venus limb made by the Pioneer Venus Orbiter Cloud Photopolarimeter at 365 nm and 690 nm wavelengths are used to investigate the level of the haze top, and haze particle properties and scale height. Haze particle vertical optical depth 0.01 occurs at altitude 80 to 85 km based on knowledge of instrument pointing. The lowest haze tops were observed close to subsolar longitudes but the data set supports a longitude dependence no more than a temporal variation. Single scattering computations for a spherical shell atmosphere show good agreement with observed intensities for particles smaller than 0.3 μm radius and refractive index less than 1.7, consistent with, but not limited to, concentrated sulfuric acid. Particle scale height in the 0.5 to 2 mbar pressure regions varies between 1 and 3 km over the season (12 of 92 days), latitude (15–45°N), and local time (0900–1800) ranges of the observations. Detached layers of haze are sometimes present. An average particle scale height of 2.2 km at 84 km altitude yields an eddy diffusion coefficient of 1.3 × 10⁵ cm² sec^?1.     

Spectral imaging of martian water ice clouds and their diurnal behavior during the 1999 aphelion season (Ls = 130°)

We report high-spectral-resolution (λ/δλ = 800-2300) near-infrared mapping observations of Mars at L_s = 130° (April 1999), which were obtained by drift-scanning the cryogenic long-slit spectrometer at the KPNO 2.2-m telescope across the disk. Data were reformatted into calibrated spectral image cubes (x,y,λ) spanning 2.19 to 4.12 μm, which distinguish atmospheric CO₂ features, solar lines, and surface and aerosol features. Maps of relative band depth between 3.0 and 3.5 μm trace water ice clouds and show the diurnal evolution of features in the persistent northern summer aphelion cloud belt, which was mapped contemporaneously but at fixed local time by the Mars Global Surveyor Thermal Emission Spectrometer (MGS/TES). Cloud optical depth, particle sizes, and ice aerosol content were estimated using a two-stream, single-layer scattering model, with Mie coefficients derived from recently published ice optical constants, followed by a linear spectral deconvolution process. A comparison of data and model spectra shows evaporating nighttime clouds in the morning followed by afternoon growth of a prominent orographic cloud feature on the west flank of Elysium Mons. Cloud optical depth at 3.2 μm evolved to 0.28 ± 0.13 and ice aerosol column abundance to 0.9 ± 0.3 pr μm in the afternoon. Column abundances as large as 0.17 pr μm were retrieved in nonorographic clouds within the aphelion cloud band around midday. These clouds exhibit a modest decline in optical depth during the afternoon. Results show that ice particle radii from <2 μm to >4 μm exist in both cloud types. However, large particles dominate the spectra, consistent with recent MGS/TES emission phase function measurements of aphelion cloud aerosol properties.     

Photometry and polarimetry of Jupiter at large phase angles: I. Analysis of imaging data of a prominent belt and a zone from pioneer 10

Limb-darkening curves are derived from Pioneer 10 imaging data for Jupiter's STrZ (?18 to ?21° latitude) and SEBn (?5 to ?8° latitude) in red and blue light at phase angles of 12, 23, 34, 109, 120, 127, and 150°. Inhomogeneous scattering models are computed and compared with the data to constrain the vertical structure and the single-scattering phase functions of the belt and the zone in each color. The very high brightness observed at a 150° phase angle seems to require the presence of at lleast a thin layer of reasonably bright and strongly forward-scattering haze particles at pressure levelsof about 100 mbar or less above both belts and zones. Marginally successful models have been constructed in which a moderate optical thickness (τ ≥ 0.5) of haze particles was uniformly distributed in the upper 25 km-amagats of H₂. Excellent fits to the data were obtained with models having a thin (optical depths of a few tenths) haze conentraated above most of the gas. Following recent spectrospcopicanalyses, we have placed the main “cloud” layer or layers beneath about 25 km-amagats of H₂, although successful fits to our continuum data probably could be achieved also if the clouds were permitted to extend all the way up to the thin haze layer. Similarly, below the haze level our data cannot distinguish between models having two clouds separated by a clear space as suggested by R. E. Danielson and M. G. Tomasko and models with a single extensive diffuse cloud having an H₂ abundance of a few kilometer-amagats per scattering mean free path as described by W. D. Cochran. In either case, the relative brightness of the planet at each phase angle primarily serves to constrain the single-scattering phase functions of the Jovian clouds at the corresponding scattering angles. The clouds in these models are characterized by single-scattering phase functions having strong forward peaks and modest backward-scattering peaks, indicating cloud particles with dimensions larger than about 0.6 μm. In our models, a lower single-scattering albedo of the cloud particles in the belt relative to the zone accounts for the contrast between these regions. If an increased abundance of absorbing dust above uniformly bright clouds is used to explain the contrast between belts and zones at visible wavelengths, the limb darkening is steeper than that observed for the SEBn in blue light at small phase angles. The phase integral for the planet calculated for either the belt or the zone model in either color lies in the range 1.2 to 1.3. If a value of 1.25 is used with D.J. Taylor's bolometric geometric albedo of 0.28, the planet emits 2.25 or 1.7 times the energy it absorbs from the Sun if it effective temperature is 134 or 125°K, respectively—roughly as expected from current theories of the cooling of Jupiter's interior.     

Study of the Ammonia ice cloud layer in the equatorial region of Jupiter from the infrared interferometric experiment on voyager

Spectra from the Voyager 1 infrared interferometer spectrometer (IRIS) obtained near the time of closest approach to Jupiter were analyzed for the purpose of inferring ammonia cloud properties associated with the Equatorial Region. Comparisons of observed spectra with synthetic spectra computed from a radiative transfer formulation, that includes multiple scattering, yielded the following conclusions: (1) very few NH₃ ice particles with radii less than 3 μm contribute to the cloud opacity; (2) the major source of cloud opacity arises from particles with radii in excess of 30 μm; (3) column particle densities are between 1 and 2 orders of magnitude smaller than those derived from thermochemical considerations alone, implying the presence of important atmospheric motion; and (4) another cloud system is confirmed to exist deeper in the Jovian troposphere.     

Multiple frequency sounding of a Jovian cloud

Prior analysis of 20- and 45-μm flux measurements made from Pioneer 10 of broad regions near the Jovian equator revealed a cold longitudinal inhomogeneity (interpreted as a cloud obscuration) on the rising limb in the South Equatorial Belt. This feature appeared quite prominently at 45 μm and also at 5 μm in ground-based maps made simultaneously with the spacecraft measurements, but it does not appear at visible wavelengths. We describe a method by which the 5-μm observations are used to determine the fraction of 45-μm flux originating from only the region of the SEB obscured by this “anomalous” cloud. This allows the 45-μm data to constrain the cloud properties. On one extreme, the top of the SEB cloud was about 160°K, some 10°K warmer than a cloud in the neighboring South Tropical Zone, if the cloud was optically thick (nontransmissive). On the other hand, if the SEB cloud was as cool as the STrZ cloud, it must have been 60 to 80% transmissive, i.e., somewhat diffuse. With less uncertainty in the fraction of cloud obscuration, the ambiguity between tansmissivity and temperature is significantly diminished. The method described offers a potentially valuable tool for monitoring properties of clouds which do not necessarily appear at visible wavelengths.     

Theoretical interpretation of the 0.7820 μm CO2 band and 0.8226 μm H2O line on Venus

We have analyzed the P6, P8, and P10 lines in the 0.7820 μm CO₂ band of Venus using a scattering model. Our new results compare favorably with previous results from the 1.05 μm CO₂ band. We considered nonabsorbing and absorbing clouds. We found that the anisotropic scattering mean free path for both models at the 0.2atm level is between 0.55 and 0.73km, a range close to the value of 1 km for terrestrial hazes. We used our scattering models to synthesize the 0.8226 μm H₂O line, assuming that the clouds are composed of sulfuric acid drops, and found our nonabsorbing cloud required a sulfuric acid concentration of 82% by weight, while our thicker absorbing cloud required a concentration of 89%. A comparison of the variation of optical depth with height for our cloud models with the variation reported by Prinn (1973, Science182, 1132–1134) showed that, within a factor of 2, the variation for Prinn's thinnest cloud agreed with ours. Whitehill and Hansen (1973, Icarus20, 146–152) have recently confirmed the work of Regas et al. (1973a, J. Quant. Spectry. Radiative Transfer13, 461–463) which showed that two cloud layers are not required to explain the CO₂ phase variation of Venus. Prinn's recent photochemical study of sulfuric acid clouds further supports a single, continuous cloud layer in the line formation region instead of two cloud layers with an extensive clear region between. The single layer model appears more likely because the maximum particle density in Prinn's cloud occurs in the clear region between the two layers in the models of Hunt (1972, J. Quant. Spectry. Radiative Transfer12, 405–419) and Carleton and Traub (1972, Bull. Amer. Astron. Soc.4, 362.).     

Voyager 1 imaging and IRIS observations of Jovian methane absorption and thermal emission: Implications for cloud structure

Images from three filters of the Voyager 1 wide-angle camera were used to measure the continuum reflectivity and spectral gradient near 6000 Å and the 6190-Å band methane/continuum ratio for a variety of cloud features in Jupiter's atmosphere. The dark “barge” features in the North Equatorial Belt have anomalously strong positive continuum spectral gradients suggesting unique composition, probably not elemental sulfur. Methane absorption was shown at unprecedented spatial scales for the Great Red Spot and its immediate environment, for a dark barge feature in the North Equatorial Belt, and for two hot spot and plume regions in the North Equatorial Belt. Some small-scale features, unresolvable at ground-based resolution, show significant enhancement in methane absorption. Any enhancement in methane absorption is conspicuously absent in both hot spot regions with 5-μm brightness temperature 255°K. Methane absorption and 5-μm emission are correlated in the vicinity of the Great Red Spot but are anticorrelated in one of the plume hot spot regions. Methane absorption and simultaneously maps of 5-μm brightness temperature were quantitatively compared to realistic cloud structure models which include multiple scattering at 5 μm as well as in the visible. A curve in parameter space defines the solution to any observed quantity, ranging from a shallow atmosphere and thin NH₃ cloud to a deep atmosphere with a thick ammonia cloud. Without additional constraints, such as center-to-limb information, it is impossible to specify the NH₃ cloud optical depth and pressure of a deeper cloud top independently. Variability in H₂ quadrupole lines was also investigated and it was found that the constancy of the 4-0 S(1)-line equivalent width is consistent with the constancy of the methane 6190-Å band equivalent width at ground-based resolution, but the much greater variability of the 3-0 S(1) line is inconsistent with either the methane band or 4-0 S(1) line. In hot spot regions the 255°K brightness temperature requires a cloud optical depth of about 2 or less at 5 μm in the NH₃ cloud layer. To be consistent with the observed 6190-Å methane absorption in hot spot regions, the NH₃ cloud optical depth in the visible is about 7.5, implying that aerosols in hot spot regions have effective radii near 1 μm or less.     

Scattering in the Atmosphere of Venus. I. Line profiles and curves of growth for isotropic scattering

We have computed line profiles and curves of growth for both reflected and transmitted radiation for typical lines in CO₂ bands (in the photographic infrared) which occur in the spectrum of Venus. In our model the pressure variation with altitude was considered and the base of the cloud deck was set at the 2 bar level. The temperature was held constant at 250K and a Voigt profile was used for the lineshape. We also assumed that the scale height of the cloud particles was equal to the scale height of the gas. The calculations were made for four values of the scattering optical thickness (τ_c = 0.1, 1.0, 10, and 100) using a continuum single scattering albedo $\text{ω}{}_{\mathrm{<mtext>c</mtext>}}\text{= 0.9975}$ (which gives a Bond albedo of 0.896 for τ_c = 100, the value observed for Venus at these wavelengths). Curves of growth are also presented for reflected radiation which has been averaged over the visible disk for three values of the Venus phase angle (0, 86, and 166°).     

On the vertical wind shear of Saturn's Equatorial Jet at cloud level

In this work we analyze and compare the vertical cloud structure of Saturn's Equatorial Zone in two different epochs: the first one close to the Voyagers flybys (1979-1981) and the second one in 2004, when the Cassini spacecraft entered its orbit around the planet. Our goal is to retrieve the altitude of cloud features used as zonal wind tracers in both epochs. We reanalyze three different sets of photometrically calibrated published data: ground-based in 1979, Voyager 2 PPS and ISS observations in 1981, and we analyze a new set of Hubble Space Telescope images for 2004. For all situations we reproduced the observed reflectivity by means of a similar vertical model with three layers. The results indicate the presence of a changing tropospheric haze in 1979-1981 (Ptop∼100 mbar, τ∼10) and in 2004 (Ptop∼50 mbar, τ∼15) where the tracers are embedded. According to this model the Voyager 2 ISS images locate cloud tracers moving with zonal velocities of 455 to 465 (±2) m/s at a pressure level of 360 ± 140 mbar. For HST observations, our previous works had showed cloud tracers moving with zonal wind speeds of 280±10 m/s at a pressure level of about 50±10 mbar. All these values are calculated in the same region (3°±2° N). This speed difference, if interpreted as a vertical wind shear, requires a change of per scale height, two times greater than that estimated from temperature observations. We also perform an initial guess on Cassini ISS vertical sounding levels, retrieving values compatible with HST ones and Cassini CIRS derived vertical wind shear, but not with Voyager wind measurements. We conclude that the wind speed velocity differences measured between 1979-1981 and 2004 cannot be explained as a wind shear effect alone and demand dynamical processes.     

Methane absorption in the atmosphere of Jupiter from 1800 to 9500 cm and implications for vertical cloud structure

New measurements of the low-temperature near-infrared absorption of methane (Sihra, 1998, Laboratory measurements of near-infrared methane bands for remote sensing of the jovian atmosphere, Ph.D. thesis, University of Oxford) have been combined with existing, longer path-length, higher-temperature data of Strong et al. (1993, Spectral parameters of self- and hydrogen-broadened methane from 2000 to 9500 cm⁻¹ for remote sounding of the atmosphere of Jupiter, J. Quant. Spectrosc. Radiat. Trans. 50, 309-325) and fitted with band models. The combined data set is found to be more consistent with previous low-temperature methane absorption measurements than that of Strong et al. (1993, J. Quant. Spectrosc. Radiat. Trans. 50, 309-325) but covers the same wider wavelength range and accounts for both self- and hydrogen-broadening conditions. These data have been fitted with k-coefficients in the manner described by Irwin et al. (1996, Calculated k-distribution coefficients for hydrogen- and self-broadened methane in the range 2000-9500 cm⁻¹ from exponential sum fitting to band modelled spectra, J. Geophys. Res. 101, 26,137-26,154) and have been used in multiple-scattering radiative transfer models to assess their impact on our previous estimates of the jovian cloud structure obtained from Galileo Near-Infrared Mapping Spectrometer (NIMS) observations (Irwin et al., 1998, Cloud structure and atmospheric composition of Jupiter retrieved from Galileo NIMS real-time spectra, J. Geophys. Res. 103, 23,001-23,021; Irwin et al., 2001, The origin of belt/zone contrasts in the atmosphere of Jupiter and their correlation with 5-μm opacity, Icarus 149, 397-415; Irwin and Dyudina, 2002, The retrieval of cloud structure maps in the equatorial region of Jupiter using a principal component analysis of Galileo/NIMS data, Icarus 156, 52-63). Although significant differences in methane opacity are found at cooler temperatures, the difference in the optical depth of the atmosphere due to methane is found to diminish rapidly with increasing pressure and temperature and thus has negligible effect on the cloud structure inferred at deeper levels. Hence the main cloud opacity variation is still found to peak at around 1-2 bar using our previous analytical approach, and is thus still in disagreement with Galileo Solid State Imager (SSI) determinations (Banfield et al., 1998, Jupiter's cloud structure from Galileo imaging data, Icarus 135, 230-250; Simon-Miller et al., 2001, Color and the vertical structure in Jupiter's belts, zones and weather systems, Icarus 154, 459-474) which place the main cloud deck near 0.9 bar. Further analysis of our retrievals reveals that this discrepancy is probably due to the different assumptions of the two analyses. Our retrievals use a smooth vertically extended cloud profile while the SSI determinations assume a thin NH₃ cloud below an extended haze. When the main opacity in our model is similarly assumed to be due to a thin cloud below an extended haze, we find the main level of cloud opacity variation to be near the 1 bar level—close to that determined by SSI and moderately close to the expected condensation level of ammonia ice of 0.85 bar, assuming that the abundance of ammonia on Jupiter is (7±1)×¹⁰⁻⁴ (Folkner et al., 1998, Ammonia abundance in Jupiter's atmosphere derived from the attenuation of the Galileo probe's radio signal, J. Geophys. Res. 103, 22,847-22,855; Atreya et al., 1999, A comparison of the atmospheres of Jupiter and Saturn: deep atmospheric composition, cloud structure, vertical mixing, and origin, Planet. Space Sci. 47, 1243-1262). However our data in the 1-2.5 μm range have good height discrimination and our lowest estimate of the cloud base pressure of 1 bar is still too great to be consistent with the most recent estimates of the ammonia abundance of 3.5 × solar. Furthermore the observed limited spatial distribution of ammonia ice absorption features on Jupiter suggests that pure ammonia ice is only present in regions of localised vigorous uplift (Baines et al., 2002, Fresh ammonia ice clouds in Jupiter: spectroscopic identification, spatial distribution, and dynamical implications, Icarus 159, 74-94) and is subsequently rapidly modified in some way which masks its pure absorption features. Hence we conclude that the main cloud deck on Jupiter is unlikely to be composed of pure ammonia ice and instead find that it must be composed of either NH₄SH or some other unknown combination of ammonia, water, and hydrogen sulphide and exists at pressures of between 1 and 2 bar.