变质矿床成因分类的讨论

在探讨了变质矿床的定义并结合前人研究的基础上,对变质矿床初步提出了一个新的成因分类方案。该方案共分为五个大类和十三个亚类,并对每个大类和亚类都提出了一些代表性矿床实例。新的变质矿床成因分类方案为：（1）受变质矿床类,分为受变质硅铁质建造沉积矿床、受变质硅铁质建造火山–沉积矿床、受变质其它建造沉积–火山沉积矿床、受变质火成岩改造矿床和受变质细碧角斑质火山喷发沉积矿床五个亚类;（2）区域变质作用变成矿床类,分为变质重结晶型、变质化学反应重组型和变质热液型三个亚类;（3）局部变质作用变成矿床类,分为接触交代夕卡岩矿床、局部接触热变质变成矿床和局部动力变质变成矿床三个亚类;（4）受变质沉积–火山沉积变质热液叠加改造矿床类;（5）混合岩化作用形成矿床类,又分为混合岩化交代型和后期混合岩化热液型两个亚类。     

New Ore Minerals from the Kingash Ultramafic Massif,Northwestern Eastern Sayan

The paper discusses earlier poorly studied mineralized rocks of the Kingash ultramafic complex in the Kan Block of the Eastern Sayan, including the large Cu–Ni–PGE deposit of the same name. Despite many researchers' increased interest in the Kingash massif, a number of questions related to the petrology, formation mechanism, and localization of Cu–Ni–PGE ore remain controversial. Along with already known ore minerals, we have identified and described a number of new mineral species: argentite, Fe-enriched sperrylite, a bismuth variety of merenskyite, gersdorffite, cobaltite, and thorianite. The ore minerals are distinguished by a higher relative amount of Fe, and this makes the Kingash deposits close to other Paleoproterozoic Cu–Ni deposits, e.g., the Jinchuan in China, Pechenga in Russia, Ungava in Canada, Mt. Scholl in Australia, etc.     

Geological Characteristics of Epithermal Ore Concentrated Areas and Epithermal Ore Deposits in China

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Formation conditions of paleovalley uranium deposits hosted in upper Eocene–lower Oligocene rocks of Bulgaria

The uranium deposits of Bulgaria related to the Late Alpine tectonomagmatic reactivation are subdivided into two groups: exogenic–epigenetic paleovalley deposits related to the basins filled with upper Eocene–lower Oligocene volcanic–sedimentary rocks and the hydrothermal deposits hosted in the coeval depressions. The geological and lithofacies conditions of their localization, the epigenetic alteration of rocks, mineralogy and geochemistry of uranium ore are exemplified in thoroughly studied paleovalley deposits of the Maritsa ore district. Argumentation of the genetic concepts providing insights into both sedimentation–diagenetic and exogenic–epigenetic mineralization with development of stratal oxidation zones is discussed. A new exfiltration model has been proposed to explain the origin of the aforementioned deposits on the basis of additional analysis with consideration of archival factual data and possible causes of specific ningyoite uranium ore composition.     

Ore Genesis for Stratiform Ore Bodies of the Dongfengnanshan Copper Polymetallic Deposit in the Yanbian Area, NE China：Constraints from LA-ICP-MS in situ Trace Elements and Sulfide S–Pb Isotopes

The Dongfengnanshan Cu polymetallic deposit is one representative deposit of the Tianbaoshan ore district in the Yanbian area, northeast(NE) China. There occur two types of ore bodies in this deposit, the stratiform ore bodies and veintype ones, controlled by the Early Permian strata and the Late Hercynian diorite intrusion, respectively. Due to the ambiguous genetic type of the stratiform ore bodies, there has been controversy on the relationship between them and veintype ore bodies. To determine the genetic type of stratiform ore bodies, laser ablation inductively coupled plasma mass spectrometry(LA-ICP-MS) in situ trace elements and S–Pb isotope analysis have been carried on the sulfides in the stratiform ore bodies. Compared with that in skarn, Mississippi Valley-type(MVT), and epithermal deposits, sphalerite samples in the stratiform ore bodies of the Dongfengnanshan deposit are significantly enriched in Fe, Mn, and In, while depleted in Ga, Ge, and Cd, which is similar to the sphalerite in volcanic-associated massive sulfide(VMS) deposits. Co/Ni ratio of pyrrhotites in the stratiform ore bodies is similar to that in VMS-type deposits. The concentrations of Zn and Cd of chalcopyrites are similar to those of recrystallized VMS-type deposits. These characteristics also reflect the intermediate ore-forming temperature of the stratiform ore bodies in this deposit. Sulfur isotope compositions of sulfides are similar to those of VMS-type deposits, reflecting that sulfur originated from the Permian Miaoling Formation. Lead isotope compositions indicate mixed-source for lead. Moreover, the comparison of the Dongfengnanshan stratiform ore bodies with some VMStype deposits in China and abroad, on the trace elements and S–Pb isotope characteristics of the sulfides reveals that the stratiform ore bodies of the Dongfengnanshan deposit belong to the VMS-type, and have closely genetic relationship with the early Permian marine volcanic sedimentary rocks.     

中国超大型矿床的若干统计特征

中国是世界上矿产资源丰富的国家之一，具有形成超大型矿床的优越地质条件。作者以全国权威性的矿产储量信息和最新的矿产勘查资料为基础，提出了适合我国国情的超大型矿床储量规模划分标准，对我国４８种主要矿产的１９８个超大型矿床进行了全面的统计分析。文中从超大型矿床储量与矿产地之间的数量关系的角度，讨论了不同矿产的储量集中程度和富集能力，就我国超大型矿床对矿床类型的选择性及其时空分布规律等问题进行了讨论，并提出了新的认识。     

北京市铁矿资源形势及找矿方向

目前,我国年钢铁产量快速增长,造成市场上铁矿石供小于求,价格快速上扬。铁矿为北京市允许开采矿种,保有储量仅2亿吨,可供现有铁矿山开采35年,因此应加大铁矿资源的勘查力度,增添新的矿产地,满足钢铁生产的需求。北京密云、怀柔北部山区的变质岩中鞍山式铁矿石,为主要找矿方向。     

云南腾冲锡矿带地质背景及锡矿类型

云南腾冲锡矿带是近几年才发现的。以往许多地质学者把东南亚锡矿向北延伸仅与云南境内的个旧锡矿相连接,因那时腾冲地区是个处女地。自七十年代末,本区开展了1/20万区调,发现了若干锡石重砂异常,与此同时,第四地质大队对旧矿点、老窿和铁帽露头取样分析,找到和评价了一批锡矿床,从而揭示了在滇西找锡的良好前景。     

中国铜矿成矿规律概要

中国铜矿资源丰富.本文在对全国814处铜矿床及其他5000余个矿(化)点资料系统梳理的基础上,完善了对中国铜矿产预测类型的划分方案,分为10个类型,认为斑岩型、矽卡岩型应该作为重点预测类型;其中又以斑岩型铜矿资源最主要,集中分布于冈底斯、昌都-三江、德兴、东天山等地区;成矿时代以新生代和中生代最为重要.系统搜集了全国范围内有关铜矿床的成矿年代学资料,划分为4个铜的主要成矿期;厘定出27个以铜为主的矿床成矿系列,提升了我国铜矿成矿规律研究的程度,为我国铜矿资源的潜力评价预测工作提供了理论依据.     

Sources and formation conditions of ferromanganese mineralization of the Bureya and Khanka massifs,Russian Far East

The geochemical features of typical representatives of ferromanganese deposits are studied in the eastern Bureya and Khanka massifs (Russian Far East). Based on the major-, trace-, and rare-earth element distribution, the hydrothermal–sedimentary (with hydrogenic component) nature of their mineralization is established and the geodynamic setting and depth of ore formation are estimated. The differences in the depth and redox conditions of ore formation resulted in the metallogenic zonation of the Khingan block (Bureya Massif), which is expressed in a westward change in ore composition from the magnetite ores of the Kosten’ga–Kimkan zone to the hematite–magnetite and iron–manganese ores of the South Khingan zone. The conclusions about the participation of hydrothermal sources in the formation of ore mineralization of the studied deposits and the specifics of their localization require revision of the strategy of exploration and evaluation of ferromanganese ores in the southern Far East.     

中国天山东部铁矿分布规律

中国天山东部地区(简称东疆)作为一个铁的矿化集中区,是早已公认的事实。然而,究竟是什么原因导致在东径89°—97°,北纬41°—42°之间这一狭长地带中,铁矿分布如此密集并明显呈带状分布呢?此早已引起地质工作者的极大兴趣。     

与镁铁－超镁铁质岩石有关的矿床类型

本文综述了近年来的研究成果,介绍了与镁铁质-超镁铁质岩有关的矿床类型和成矿作用。重点讨论的矿种有钒钛磁铁矿、铜-镍、铬铁矿、磁铁矿、铂族、钴、金、镁、磷灰石、金刚石、石棉、蛭石、宝玉石等,涉及的矿床成因类型主要有:岩浆型(包括岩浆熔离、贯入、分异和爆发型)、热液型、矽卡岩型、变质型、火山喷溢型、风化型(包括风化壳和砂矿)以及复合型等。从勘查找矿考虑,可从含矿镁铁-超镁铁质岩石类型入手,结合矿床成因类型和产出构造环境因素,将矿床分为与深成岩、浅成岩和喷出岩有关的三大类和若干亚类矿床,并详细介绍了各类的主要矿床类型、成矿地质特征、成因特点和矿床实例。在此基础上,对与镁铁-超镁铁质岩有关的成矿作用进行了4个层次讨论,包括单一矿床的复合成矿作用、杂岩体本身的不同矿床类型和矿种的组合、不同镁铁-超镁铁质岩套之间的伴生,以及与非超镁铁质岩套的共生与组合。     

Li同位素在矿床学中的应用:现状与展望

矿床的形成受制于多种复杂的地质作用,包括全球尺度的板块构造运动、岩浆活动、变质沉积改造等过程,并普遍伴随热液活动、流体迁移、水-岩相互作用、元素分异及同位素分馏等一系列局部区域地质和地球化学过程.在过去的矿床学研究中,地球化学方法主要围绕在主、微量元素和传统的稳定同位素等手段,解决了很多矿床成因问题.但仍存在不少的多解和难解问题,比如许多矿床在矿化类型、蚀变分带与金属矿物组合方面具有诸多相似之处,常规地球化学指标难以区分.随着测试精度的提高和自然储库组成的完善,Li同位素近些年来已成为新兴的稳定同位素体系.Li同位素在自然界过程中高达80‰的同位素分馏使其具有更好的辨识能力,同时兼有直接和间接指示作用,有潜力成为研究各种复杂成矿过程的良好示踪剂.本文总结了近年来有关矿床学中Li同位素的研究和应用进展,以俯冲带成矿为主,阐述了斑岩型-热液矿床、伟晶岩型矿床和沉积矿床等类型矿床的Li同位素地球化学特征,并探究新的Li同位素方法在矿床中的应用前景.基于Li同位素体系在各类矿床的应用实例,我们认为Li同位素体系将为矿床学研究提供更多的指示信息和依据.      

新疆南天山成矿带矿床成矿系列

在系统分析南天山成矿带地质构造演化和成矿特点基础上,划分了5个矿床成矿系列、5个矿床成矿亚系列和13个矿床式。南天山成矿带矿床成矿系列的分布受区域构造－岩浆演化制约,具有鲜明的古生代,尤其是晚古生代成矿作用特点。区域构造演化的规律, 决定了矿床成矿系列的分布规律,即构造－岩浆演经随时间推移有由北向南推进的趋势。     

Sulfur Isotope Variations of Metallic Ore Deposits in the Gyeongsang Basin,South Korea

Many metallic ore deposits of the Late Cretaceous to Early Tertiary periods are distributed in the Gyeongsang Basin. Previous and newly analyzed sulfur isotope data of 309 sulfide samples from 56 ore deposits were reviewed to discuss the genetic characteristics in relation to granitoid rocks. The metallogenic provinces of the Gyeongsang Basin are divided into the Au–Ag(–Cu–Pb–Zn) province in the western basin where the sedimentary rocks of the Shindong and Hayang groups are distributed, Pb–Zn(–Au–Ag–Cu), Cu–Pb–Zn(–Au–Ag), and Fe–W(–Mo) province in the central basin where the volcanic rocks of the Yucheon Group are dominant, and Cu(–Mo–W–Fe) province in the southeastern basin where both sedimentary rocks of the Hayang Group and Tertiary volcanic rocks are present. Average sulfur isotope compositions of the ore deposits show high tendencies ranging from 2.2 to 11.7‰ (average 5.4‰) in the Pb–Zn(–Au–Ag–Cu) province, ?0.7 to 11.5‰ (average 4.6‰) in the Cu–Pb–Zn(–Au–Ag) province, and 3.7 to 11.4‰ (average 7.5‰) in the Fe–W(–Mo) province in relation to magnetite‐series granitoids, whereas they are low in the Au–Ag(–Cu–Pb–Zn) province in relation to ilmenite‐series granitoids, ranging from ?2.9 to 5.7‰ (average 1.7‰). In the Cu(–Mo–W–Fe) province δ³⁴S values are intermediate ranging from 0.3 to 7.7‰ (average 3.6‰) and locally high δ³⁴S values are likely attributable to sulfur derived from the Tertiary volcanic rocks during hydrothermal alteration through faults commonly developed in this region. Magma originated by the partial melting of the ³⁴S‐enriched oceanic plate intruded into the volcanic rocks and formed magnetite‐series granitoids in the central basin, which contributed to high δ³⁴S values of the metallic deposits. Conversely, ilmenite‐series granitoids were formed by assimilation of sedimentary rocks rich in organic sulfur that influenced the low δ³⁴S values of the deposits in the western and southeastern provinces.     

中国某些特大型矿床的同位素地球化学研究

超大型矿床因其巨大的经济价值和特殊的产出地质环境与条件历来受到重视。为了查明这些矿床的形成年代，弄清成矿物质来源，了解成矿环境与条件，前人对这些矿床从同位素角度已做了许多研究。近年来，我们对国内若干特大型矿床的同位素特征进行了补充研究。本文结合前人的资料，对这些矿床的同位素研究成果作一概括性总结。     

从流体包裹体研究探讨金属矿床成矿条件

根据作者多年来对流体包裹体的研究成果，参考了国内外的研究结论，提出了一个新的成矿流体分类方案，并评述了我国若干典型金属矿床的研究状况，由此探讨了金属矿床的形成机制。     

The Tanlu Fault Zone and Gold Ore Metallogenesis in Eastern China

The Tanlu Fault Zone (TFZ) is a large NE-trending fault system in eastern China that is the locus of several significant gold deposits. At different periods of its evolution and in different zones along its length, the TFZ has distinct geological features that control gold mineralization. In the northeastern part of the TFZ, early-stage faulting activity (from the Jurassic to Cretaceous) is associated with abundant calc-alkaline volcanic rocks, reflecting the compressive structural setting in the Jurassic and Cretaceous. However, activities in the late stage (Cenozoic) produced alkali basalts, indicating a mainly extensional tectonic regime. In the middle and southern segments of the TFZ, early-stage (Jurassic) activity was characterized by calc-alkalic granite intrusions, followed later (Cretaceous) by partial alkalic and alkalic volcanic-intrusive complexes, and in the latest stage (Cenozoic) by alkalic volcanic eruptions.

The TFZ system controls the distribution of gold metallogenic provinces in eastern China, and periods of mineralization of gold ore deposits coincide with the major stages of faulting. Gold ore deposits in eastern China are products of the evolution of the TFZ. During the early evolution of the TFZ, gold ore deposits related to calc-alkalic granite intrusions were formed—e.g., of the quartz-vein and altered-rock types. Gold deposits of the interlayer–sliding fault breccia type were formed along the margin of the extensional basin during the middle period of TFZ evolution. Finally, epithermal gold deposits related to alkalic magmatism were formed during the latest stage of TFZ evolution.     

Noble Gas and Stable Isotopic Constraints on the Origin of the Ag–Cu Polymetallic Ore Deposits in the Baiyangping Area,Yunnan Province,SW China

The Lanping basin, Yunnan province, SW China, is located at the juncture of the Eurasian and Indian Plates in the eastern part of the Tibetan Plateau. The Lanping basin, in the Sanjiang Tethyan metallogenic province, is a significant Cu–Ag–Zn–Pb mineralized belt in China that includes the largest sandstone‐hosted Zn–Pb deposit in the world, the Jinding deposit, as well as several Ag–Cu deposits (the Baiyangping and Jinman deposits). These deposits, with total reserves of over 16.0 Mt Pb + Zn, 0.6 Mt Cu, and 7,000 t Ag, are mainly hosted in Meso‐Cenozoic clastic rocks and are dominantly controlled by two Cenozoic thrust systems developed in the western and eastern segments of the basin. The Baiyangping, Babaoshan, and Hetaoqing ore deposits are representative of the epithermal base metal deposits in the Lanping basin. The microthermometric data show that the ore‐forming fluids for these deposits were low temperature (110–180 °C) and had bimodal distribution of salinity at moderate and mid to high salinities (approximately 2–8 wt.% and 18–26 wt.% NaCl equivalent). The C and O isotope data indicate that the ore‐forming fluids were related to hot basin brines. We present new He and Ar isotope data on volatiles released from fluid inclusions contained in sulfides and in barite in these three deposits. ³He/⁴He ratios of the ore‐forming fluids are 0.01 to 0.14 R/Ra with a mean of 0.07 Ra (where R is the ³He/⁴He ratio and Ra is the ratio for atmospheric helium). This mean value is intermediate to typical ³He/⁴He ratios for the crust (R/Ra = 0.01 to 0.05) and the ratio for air‐saturated water (R/Ra = 1). The mean ratio is also significantly lower than the ratios found for mantle‐derived fluids (R/Ra = 6 to 9). The ⁴⁰Ar/³⁶Ar ratios of the ore‐forming fluids range from 298 to 382 with a mean of 323. This value is slightly higher than that for the air‐saturated water (295.5). The ³He/⁴He ratios of fluids from the fluid inclusions imply that the ore‐forming fluid for the Baiyangping, Babaoshan, and Hetaoqing deposits was derived from the crust and that any mantle‐derived He was negligible. The content of the radiogenic Ar ranges between 0.2 to 20.4%, and the proportion of air‐derived ⁴⁰Ar averages 94.1%. This indicates that atmospheric Ar was important in the formation of these deposits but that some radiogenic ⁴⁰Ar was derived from crustal rocks. Based on these observations coupled with other geochemical evidence, we suggest that the ore‐forming fluids responsible for the formation of the Ag–Cu–Pb–Zn polymetallic ore deposits in the Baiyangping area of the Lanping basin were mainly derived from crustal fluids. The fluids may have mixed with some amount of air‐saturated water, but there was no significant involvement of mantle‐derived fluids.     

河南省南召县梅子垛铁矿矿床成矿地质特征及矿石加工技术性能

2005～2007年,在河南省南召县白土岗-南河店-带发现数十个风化花岗闪长岩型超贫磁铁矿床。矿体的形态、产状、规模与花岗闪长岩体基本一致,矿石类型、成分简单,磁性铁品位2．79～13．28％,平均9．02％,矿石易采易选,在当前经济技术条件下,开采该类矿床具较好经济效益。笔者以梅子垛铁矿为例分析说明该类矿床成矿地质特征及矿石加工技术性能。