Peat Formation Processes Through the Millennia in Tidal Marshes of the Sacramento–San Joaquin Delta,California, USA

The purpose of this study was to determine peat formation processes throughout the millennia in four tidal marshes in the Sacramento–San Joaquin Delta. Peat cores collected at each site were analyzed for bulk density, loss on ignition, and percent organic carbon. Core data and spline fit age–depth models were used to estimate inorganic sedimentation, organic accumulation, and carbon sequestration rates in the marshes. Bulk density and percent organic matter content of peat fluctuated through time at all sites, suggesting that peat formation processes are dynamic and responsive to watershed conditions. The balance between inorganic sedimentation and organic accumulation at the sites also varied through time, indicating that marshes may rely more strongly on either inorganic or organic matter for peat formation at particular times in their existence. Mean carbon sequestration rates found in this study (0.38–0.79 Mg C ha⁻¹ year⁻¹) were similar to other long-term estimates for temperate peatlands.     

Statistical Models of Temperature in the Sacramento–San Joaquin Delta Under Climate-Change Scenarios and Ecological Implications

Changes in water temperatures caused by climate change in California’s Sacramento–San Joaquin Delta will affect the ecosystem through physiological rates of fishes and invertebrates. This study presents statistical models that can be used to forecast water temperature within the Delta as a response to atmospheric conditions. The daily average model performed well (R ² values greater than 0.93 during verification periods) for all stations within the Delta and San Francisco Bay provided there was at least 1 year of calibration data. To provide long-term projections of Delta water temperature, we forced the model with downscaled data from climate scenarios. Based on these projections, the ecological implications for the delta smelt, a key species, were assessed based on temperature thresholds. The model forecasts increases in the number of days above temperatures causing high mortality (especially along the Sacramento River) and a shift in thermal conditions for spawning to earlier in the year.     

Implications for Future Survival of Delta Smelt from Four Climate Change Scenarios for the Sacramento–San Joaquin Delta, California

Changes in the position of the low salinity zone, a habitat suitability index, turbidity, and water temperature modeled from four 100-year scenarios of climate change were evaluated for possible effects on delta smelt Hypomesus transpacificus, which is endemic to the Sacramento–San Joaquin Delta. The persistence of delta smelt in much of its current habitat into the next century appears uncertain. By mid-century, the position of the low salinity zone in the fall and the habitat suitability index converged on values only observed during the worst droughts of the baseline period (1969–2000). Projected higher water temperatures would render waters historically inhabited by delta smelt near the confluence of the Sacramento and San Joaquin rivers largely uninhabitable. However, the scenarios of climate change are based on assumptions that require caution in the interpretation of the results. Projections like these provide managers with a useful tool for anticipating long-term challenges to managing fish populations and possibly adapting water management to ameliorate those challenges.     

234U/238U and δ87Sr in peat as tracers of paleosalinity in the Sacramento-San Joaquin Delta of California,USA

The purpose of this study was to determine the history of paleosalinity over the past 6000+ years in the Sacramento-San Joaquin Delta (the Delta), which is the innermost part of the San Francisco Estuary. We used a combination of Sr and U concentrations, δ⁸⁷Sr values, and ²³⁴U/²³⁸U activity ratios (AR) in peat as proxies for tracking paleosalinity. Peat cores were collected in marshes on Browns Island, Franks Wetland, and Bacon Channel Island in the Delta. Cores were dated using ¹³⁷Cs, the onset of Pb and Hg contamination from hydraulic gold mining, and ¹⁴C. A proof of concept study showed that the dominant emergent macrophyte and major component of peat in the Delta, Schoenoplectus spp., incorporates Sr and U and that the isotopic composition of these elements tracks the ambient water salinity across the Estuary. Concentrations and isotopic compositions of Sr and U in the three main water sources contributing to the Delta (seawater, Sacramento River water, and San Joaquin River water) were used to construct a three-end-member mixing model. Delta paleosalinity was determined by examining variations in the distribution of peat samples through time within the area delineated by the mixing model.The Delta has long been considered a tidal freshwater marsh region, but only peat samples from Franks Wetland and Bacon Channel Island have shown a consistently fresh signal (<0.5 ppt) through time. Therefore, the eastern Delta, which occurs upstream from Bacon Channel Island along the San Joaquin River and its tributaries, has also been fresh for this time period. Over the past 6000+ years, the salinity regime at the western boundary of the Delta (Browns Island) has alternated between fresh and oligohaline (0.5–5 ppt).     

Upstream—Downstream Shifts in Peak Recruitment of the Native Olympia Oyster in San Francisco Bay During Wet and Dry Years

Understanding the conditions that drive variation in recruitment of key estuarine species can be important for effective conservation and management of their populations. The Olympia oyster (Ostrea lurida) is native to the Pacific coast of North America and has been a target of conservation efforts, though relatively little information on larval recruitment exists across much of its range. This study examined the recruitment of Olympia oysters at biweekly to monthly intervals at four sites in northern San Francisco Bay from 2010 to 2015 (except 2013). Mean monthly temperatures warmed at all sites during the study, while winter (January–April) mean monthly salinity decreased significantly during a wet year (2011), but otherwise remained high as a result of a drought. A recurring peak in oyster recruitment was identified in mid-estuary, in conditions corresponding to a salinity range of 25–30 and >16 °C at the time of settlement (April–November). Higher average salinities and temperatures were positively correlated with greater peak recruitment. Interannual variation in the timing of favorable conditions for recruitment at each site appears to explain geographic and temporal variation in recruitment onset. Higher winter/spring salinities and warmer temperatures at the time of recruitment corresponded with earlier recruitment onset within individual sites. Across all sites, higher winter/spring salinities were also correlated with earlier onset and earlier peak recruitment. Lower winter salinities during 2011 also resulted in a downstream shift in the location of peak recruitment.     

Chloride as tracer of solute transport in the aquifer–aquitard system in the Pearl River Delta,China

A 1D numerical model is constructed to investigate the impact of sedimentation and sea level changes on transport of Cl^? in the aquifer–aquitard system in the Pearl River Delta (PRD), China. The model simulates the evolution of the vertical Cl^? concentration profiles during the Holocene. Sedimentation is modeled as a moving boundary problem. Chloride concentration profiles are reconstructed for nine boreholes, covering a wide area of the PRD, from northwest to southeast. Satisfactory agreement is obtained between simulated and measured Cl^? concentration profiles. Diffusion solely is adequate to reproduce the vertical Cl^? concentration profiles, which indicates that diffusion is the regionally dominant vertical transport mechanism across the aquitards in the PRD. The estimated effective diffusion coefficients of the aquitards range from 2.0?×?10^–11 to 2.0?×?10^–10 m²/s. The effective diffusion coefficients of the aquifers range from 3.0?×?10^–11 to 4.0?×?10^–10 m²/s. Advective transport tends to underestimate Cl^? concentrations in the aquitard and overestimate Cl^? concentrations in the basal aquifer. The results of this study will help understand the mechanisms of solute transport in the PRD and other deltas with similar geological and hydrogeological characteristics.     

Hydrothermal alteration and Cu–Ni–PGE mobilization in the charnockitic rocks of the footwall of the South Kawishiwi intrusion,Duluth Complex,USA

In the Neoarchean (~ 2.7 Ga) contact metamorphosed charnockitic footwall of the Mesoproterosoic (1.1 Ga) South Kawishiwi intrusion of the Duluth Complex, the primary metamorphic mineral assemblage and Cu–Ni–PGE sulfide mineralization is overprinted by an actinolite + chlorite + cummingtonite + prehnite + pumpellyite + quartz + calcite hydrothermal mineral assemblage along 2–3 cm thick veins. In calcite, hosted by the hydrothermal alteration zones and in a single recrystallized quartz porphyroblast, four different fluid inclusion assemblages are documented; the composition of these fluid inclusions provide p–T conditions of the fluid flow, and helps to define the origin of the fluids and evaluate their role in the remobilization and reprecipitation of the primary metamorphic sulfide assemblage.Pure CO₂ fluid inclusions were found as early inclusions in recrystallized quartz porphyroblast. These inclusions may have been trapped during the recrystallization of the quartz during the contact metamorphism of the footwall charnockite in the footwall of the SKI. The estimated trapping pressure (1.6–2.0 kbar) and temperature (810–920 °C) conditions correspond to estimates based on felsic veins in the basal zones of the South Kawishiwi intrusion.Fluid inclusion assemblages with CO₂–H₂O–NaCl and CH₄–N₂–H₂O–NaCl compositions found in this study along healed microfractures in the recrystallized quartz porphyroblast establish the heterogeneous state of the fluids during entrapment. The estimated trapping pressure and temperature conditions (240–650 bar and 120–150 °C for CO₂–H₂O–NaCl inclusions and 315–360 bar and 145–165 °C for CH₄–N₂–H₂O–NaCl inclusions) are significantly lower than the p–T conditions (> 700 °C and 1.6–2 kbar) during the contact metamorphism, indicating that this fluid flow might not be related to the cooling of the Duluth Complex and its contact aureole. The presence of chalcopyrite inclusions in these fluid inclusions and in the trails of these fluid inclusion assemblages confirms that at least on local scale these fluids played a role in base metal remobilization. No evidences have been observed for PGE remobilization and transport in the samples. The source of the carbonic phase in the carbonic assemblages (CO₂; CH₄) could be the graphite, present in the metasedimentary hornfelsed inclusions in the basal zones of the South Kawishiwi intrusion.The hydrothermal veins in the charnockite can be characterized by an actinolite + cummingtonite + chlorite + prehnite + pumpellyite + calcite (I–II) + quartz mineral assemblage. Chlorite thermometry yields temperatures around 276–308 °C during the earliest phase of the fluid flow. In the late calcite (II) phase, high salinity (21.6–28.8 NaCl + CaCl₂ equiv. wt.%), low temperature (90–160 °C), primary aqueous inclusions were found. Chalcopyrite (± sphalerite ± millerite), replacing and intersecting the early hydrothermal phases, are associated to the late calcite (II) phase. The composition of the formational fluids in the Canadian Shield is comparable with the composition of the studied fluid inclusions. This suggests that the composition of the fluids did not change in the past 2 Ga and base metal remobilization by formational fluids could have taken place any time after the formation of the South Kawishiwi intrusion.Sulfur isotope studies carried out on the primary metamorphic (δ³⁴S = 7.4–8.9‰) and the hydrothermal sulfide mineral assemblage (δ³⁴S = 5.5–5.7‰) proves, that during the hydrothermal fluid flow the primary metamorphic ores were remobilized.     

Assessment of regional change in nitrate concentrations in groundwater in the Central Valley, California, USA, 1950s–2000s

A regional assessment of multi-decadal changes in nitrate concentrations was done using historical data and a spatially stratified non-biased approach. Data were stratified into physiographic subregions on the basis of geomorphology and soils data to represent zones of historical recharge and discharge patterns in the basin. Data were also stratified by depth to represent a shallow zone generally representing domestic drinking-water supplies and a deep zone generally representing public drinking-water supplies. These stratifications were designed to characterize the regional extent of groundwater with common redox and age characteristics, two factors expected to influence changes in nitrate concentrations over time. Overall, increasing trends in nitrate concentrations and the proportion of nitrate concentrations above 5 mg/L were observed in the east fans subregion of the Central Valley. Whereas the west fans subregion has elevated nitrate concentrations, temporal trends were not detected, likely due to the heterogeneous nature of the water quality in this area and geologic sources of nitrate, combined with sparse and uneven data coverage. Generally low nitrate concentrations in the basin subregion are consistent with reduced geochemical conditions resulting from low permeability soils and higher organic content, reflecting the distal portions of alluvial fans and historical groundwater discharge areas. Very small increases in the shallow aquifer in the basin subregion may reflect downgradient movement of high nitrate groundwater from adjacent areas or overlying intensive agricultural inputs. Because of the general lack of regionally extensive long-term monitoring networks, the results from this study highlight the importance of placing studies of trends in water quality into regional context. Earlier work concluded that nitrate concentrations were steadily increasing over time in the eastern San Joaquin Valley, but clearly those trends do not apply to other physiographic subregions within the Central Valley, even where land use and climate are similar.     

Simulating the impacts of groundwater pumping on stream–aquifer dynamics in semiarid northwestern Oklahoma,USA

Visual MODFLOW, a numerical groundwater flow model, was used to evaluate the impacts of groundwater exploitation on streamflow depletion in the Alluvium and Terrace aquifer of the Beaver-North Canadian River (BNCR) in northwestern Oklahoma, USA. Water demand in semi-arid northwestern Oklahoma is projected to increase by 53% during the next five decades, driven primarily by irrigation, public water supply, and agricultural demand. Using MODFLOW’s streamflow routing package, pumping-induced changes in baseflow and stream leakage were analyzed to estimate streamflow depletion in the BNCR system. Simulation results indicate groundwater pumping has reduced baseflow to streams by approximately 29% and has also increased stream leakage into the aquifer by 18% for a net streamflow loss of 47%. The magnitude and intensity of streamflow depletion, however, varies for different stream segments, ranging from 0 to 20,804 m³/d. The method provides a framework for isolating and quantifying impacts of aquifer pumping on stream function in semiarid alluvial environments.

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Résumé  Visual MODFLOW, un modèle numérique d’écoulement des eaux souterraines, a été utilisé pour évaluer les impacts de l’exploitation de l’eau souterraine sur la réduction du régime de la rivière dans un aquifère d’alluvions et de terrasse de la Rivière canadienne Beaver-North (BNCR) au nord-ouest de l’Oklahoma, aux USA. La demande d’eau dans le nord-ouest semi-aride de l’Oklahoma devrait augmenter de 53% durant les cinq prochaines décennies, essentiellement du fait de l’irrigation, la demande en eau potable et la demande agricole. En utilisant le module numérique traitant les rivières dans MODFLOW, les changements sur le régime de base des cours d’eau induits par le pompage et la recharge par la rivière ont été analysés pour estimer la réduction du régime de la rivière du système BNCR. Les résultats de la simulation indiquent que le pompage de l’eau souterraine réduit le débit de base de la rivière de 18% pour une perte nette du débit de la rivière de 47%. L’importance et l’intensité de la réduction du débit de base, toutefois, varie selon le bief, de 0 à 20,840 m³/d. La méthode apporte un cadre pour isoler et quantifier les impacts sur le pompage de l’aquifère sur le fonctionnement de la rivière dans un environnement alluvial semi-aride.

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Resumen  El Visual MODFLOW, que es un modelo numérico de flujo de agua subterránea, fue usado para evaluar los impactos de la explotación del agua subterránea, en la disminución de la cantidad de flujo de una corriente superficial, relacionada al acuífero del aluvión y de la terraza del Río canadiense Beaver-North (BNCR) en Oklahoma del noroeste, EUA. Se proyecta que la demanda de agua aumentará en un 53%, en el sector semiárido de Oklahoma del noroeste, durante las próximas cinco décadas, principalmente debido a la irrigación, suministro de agua público, y la demanda agrícola. Mediante el uso del paquete especial para relaciones corriente superficial- acuífero (SFR) de MODFLOW, se analizaron cambios inducidos por el bombeo, tanto en el flujo base, como en el goteo del río, para estimar la disminución del flujo de la corriente en el sistema de BNCR. Los resultados de la simulación indican, que el bombeo de agua subterránea ha reducido el flujo base a los arroyos aproximadamente en un 29% y también ha aumentado el goteo del arroyo hacia el acuífero en 18%, resultando una pérdida neta del flujo del río de un 47%. La magnitud e intensidad de la disminución del flujo del río, sin embargo, varía en sus diferentes segmentos, oscilando de 0 a 20,804 m³/d. El método suministra un marco, para aislar y cuantificar los impactos del bombeo del acuífero, sobre el funcionamiento de una corriente superficial en los ambientes aluviales semiáridos.

     

Deposition in a changing paleogulf: evidence from the Pliocene–Quaternary sedimentary succession of the Nile Delta,Egypt

Sedimentary complexes of ancient gulfs provide valuable information about paleoenvironmental dynamics. The study of several Pliocene–Pleistocene sections allowed reconstruction of the regional stratigraphical framework in the southwestern fringes of the Nile Delta. The Kafr El-Shiekh, the Gar El-Muluk, and the Kom El-Shelul formations of the Zanclean Age and the Wastani Formation of the Piacenzian Age constitute the Pliocene sedimentary succession in the study area. The establishment of 11 facies types related to 5 facies associations coupled with the results of the stratigraphical study indicate the existence of a paleogulf corresponding to the modern delta and lower valley of the Nile. This Nile Paleogulf appeared and reached its maximum spatial extent in the beginning of the Pliocene. Then, it retreated gradually and disappeared before the end of this epoch when alluvial sedimentation reestablished. There was significant flux of siliciclastic material to the study area. The Zanclean Flood in the Mediterranean Sea allowed marine incursion in the study area where the river valley incised during the precedent Messinian Salinity Crisis. Regional tectonic uplift and filling of the accommodation space with siliciclastic material from the eroded land were the main controls on the paleogulf evolution. Strengthened glaciation triggered global sea level fall, and alluvial deposition dominated the study area in the late Pliocene–Pleistocene.     

A Before–After–Control–Impact Analysis of the Effects of a Mississippi River Freshwater Diversion on Estuarine Nekton in Louisiana, USA

Since 1991, the Caernarvon Freshwater Diversion has been reintroducing Mississippi River water into a previously hydrologically isolated estuary in an effort to restore wetlands. To determine the effect of freshwater inflow on estuarine nekton community structure, a Before?CAfter?CControl?CImpact study design was applied. As a result of the opening, salinities in the impact area decreased, and the nekton community structure in the estuary changed significantly. Species of economical or ecological importance either increased in biomass or exhibited no response to the opening of the diversion. Higher abundances of small fish were observed in the area receiving freshwater flow, which is an indication that the area serves as a refuge from large marine predators. Because a salinity gradient was established, as opposed to a uniform but lower salinity regime, aquatic habitat was available to nekton species from a wide spectrum of salinity tolerances.     

Differentiation of nelsonitic magmas in the formation of the ~1.74 Ga Damiao Fe–Ti–P ore deposit, North China

The ~1.74 Ga Damiao anorthosite complex, North China, is composed of anorthosite and leuconorite with subordinate melanorite, mangerite, oxide-apatite gabbronorite, perthite noritic (i.e., jotunitic) and ferrodioritic dykes. The complex hosts abundant vein-, pod- and lens-like Fe–Ti–P ores containing variable amounts of apatite (10–60 modal%) and Fe–Ti oxides. In addition to Fe–Ti–P ores, there are also abundant Fe–Ti ores which are closely associated with Fe–Ti–P ores in the deposit. Most of Fe–Ti–P ores are dominated by Fe–Ti oxides and apatite, devoid of silicate minerals, mineralogically similar to the common nelsonites elsewhere. In contrast, Fe–Ti ores are dominated by Fe–Ti oxides with minor apatite (<5 modal %). The parental magma of these ores, estimated from olivine and apatite compositions using mineral-melt partition coefficients, has composition similar to the ferrodioritic dykes. Fe–Ti–P ores have variable Fe–Ti oxides and apatite proportions, indicating that they are cumulates. Their simple assemblage of Fe–Ti oxides and apatite and local net-texture suggest that the Fe–Ti–P ores in Damiao have formed from nelsonitic melts immiscibly separated from the ferrodioritic magma during late-stage differentiation. Fe–Ti ores are also cumulates and have mineral compositions similar to Fe–Ti–P ores. The close association between Fe–Ti and Fe–Ti–P ores indicates that the Fe–Ti ores may have also formed from the nelsonitic melts. We proposed that differentiation of nelsonitic melts accompanied by gravity settling is responsible for the formation of Fe–Ti and Fe–Ti–P ores. Such a differentiation process in nelsonitic melts is well supported by variations of Sr, Y, Th, U, REE and Eu/Eu* of apatite in Fe–Ti–P ores. Using oxides/apatite ratio of 2:1 and compositions of apatite and calculated primary oxides, we estimate the composition of the nelsonitic melt as ~52.0 wt% Fe₂O₃t, ~18.5 wt% CaO, ~14.2 wt% P₂O₅, ~8.7 wt% TiO₂, ~4.0 wt% Al₂O₃ and ~1.1 wt% MgO with minor SiO₂, K₂O, Na₂O and F. Such a nelsonitic melt is suggested to be possibly conjugated with Si-rich melts compositionally similar to the Damiao jotunitic dykes (~50 wt% SiO₂ and ~15 wt% Fe₂O₃t) which may subsequently evolve to mangeritic rocks in Damiao. Our modeling also indicates that the onset of immiscibility occurs at a time when the evolved melt has ~44 wt% SiO₂, ~21 wt% Fe₂O₃t, ~3.0 wt% TiO₂ and ~2.6 wt% P₂O₅. High oxygen fugacity and phosphorous content in magmas may play important roles in the immiscibility of nelsonitic magmas, including promoting iron enrichments and widening the two-liquid field.     

Geological controls and effects of floodplain asymmetry on river–groundwater interactions in the southeastern Coastal Plain, USA

Channel sediment and alluvial aquifer hydraulic properties exert a major control on river–groundwater interactions. Channels and floodplains are often asymmetrical, resulting in differences in sediment hydraulic properties across the river. Floodplain asymmetry is common along Coastal Plain rivers in South Carolina and North Carolina, USA. The Tar River, North Carolina, has an asymmetrical valley. The study objective was to characterize the effects of floodplain asymmetry and geological controls on river–groundwater interactions. Floodplain and river channel sediments adjacent to the river were characterized with split spoon cores and hand auger samples along a 22-km reach. Hydrogeology was characterized with 38 piezometers and water level recorders in and adjacent to the river. Ground penetrating radar was used to define the shallow stratigraphy. Channel sediments were significantly different between the north and south sides of the river. Hydraulic conductivity and groundwater inputs were greater on the side of the river (north) that contained more permeable fluvial deposits. Groundwater chemistry (δ¹⁸O, specific conductance) data also suggested greater exchange between surface water and groundwater on the north side of the river channel. A conceptual hydrogeological model illustrates that groundwater movement and contaminant transport to the river differs across the channel due to asymmetrical geology.     

Continental ca 1.7 – 1.69 Ga Fe-rich metatholeiites in the Curnamona Province,Australia: a record of melting of a heterogeneous,subduction-modified lithospheric mantle

Mg-rich and Fe-rich metatholeiites intruded the Willyama Supergroup of the southern Australian Curnamona Province in the Late Palaeoproterozoic at ca 1700 Ma and 1685 Ma, respectively. Intrusion of the Fe-rich metatholeiites occurred during a period of punctuated extension in the Willyama basin. Major-element concentrations are variable (SiO₂ 45.4 – 56.5 wt%; Fe₂O₃? 8.5 – 20.7; TiO₂ 0.46 – 2.52 wt%; Mg# 70.5 – 29.1) and, in conjunction with trace-element data, support near-closed-system fractionation of a mantle-derived melt with little or no replenishment. Fractionation produced progressively Fe-rich derivative melts. Crystallising phases were dominated by clinopyroxene and olivine, whereas Fe – (Ti) oxide crystallisation was hindered. Primitive mantle-normalised immobile trace elements are characterised by variable Th, Nb, Sr, P and Ti anomalies. Chondrite-normalised rare-earth element patterns for the most primitive, Mg-rich samples from the western Broken Hill Domain have La_N/Sm_N < 1, whereas the most evolved Fe-rich samples from the Olary Domain have ratios of La_N/Sm_N > 1. Initial εNd values range between – 2.2 and + 2.7 for the majority of the samples, with the isotopic compositions showing no correlation with differentiation or assimilation. The combined geochemical and isotopic data suggest that the southern Curnamona Province metatholeiites were extracted from a depleted mantle in the western Broken Hill Domain, and a variably enriched, heterogeneous subcontinental lithospheric mantle in the Olary Domain. Magmatism most likely occurred in a backarc basin or intracontinental setting. It is speculated that the geochemically enriched mantle component was derived from subduction-related processes, probably related to pre-Willyama basin accretionary processes along the southern and eastern margins of the North Australian Craton.     

Holocene fire occurrence and alluvial responses at the leading edge of pinyon–juniper migration in the Northern Great Basin,USA

Fire and vegetation records at the City of Rocks National Reserve (CIRO), south-central Idaho, display the interaction of changing climate, fire and vegetation along the migrating front of single-leaf pinyon (Pinus monophylla) and Utah juniper (Juniperus osteosperma). Radiocarbon dating of alluvial charcoal reconstructed local fire occurrence and geomorphic response, and fossil woodrat (Neotoma) middens revealed pinyon and juniper arrivals. Fire peaks occurred ~ 10,700–9500, 7200–6700, 2400–2000, 850–700, and 550–400 cal yr BP, whereas ~ 9500–7200, 6700–4700 and ~ 1500–1000 cal yr BP are fire-free. Wetter climates and denser vegetation fueled episodic fires and debris flows during the early and late Holocene, whereas drier climates and reduced vegetation caused frequent sheetflooding during the mid-Holocene. Increased fires during the wetter and more variable late Holocene suggest variable climate and adequate fuels augment fires at CIRO. Utah juniper and single-leaf pinyon colonized CIRO by 3800 and 2800 cal yr BP, respectively, though pinyon did not expand broadly until ~ 700 cal yr BP. Increased fire-related deposition coincided with regional droughts and pinyon infilling ~ 850–700 and 550–400 cal yr BP. Early and late Holocene vegetation change probably played a major role in accelerated fire activity, which may be sustained into the future due to pinyon–juniper densification and cheatgrass invasion.     

Fluid–rock reactions in the 1.3 Ga siderite carbonatite of the Grønnedal–Íka alkaline complex,Southwest Greenland

Petrogenetic studies of carbonatites are challenging, because carbonatite mineral assemblages and mineral chemistry typically reflect both variable pressure–temperature conditions during crystallization and fluid–rock interaction caused by magmatic–hydrothermal fluids. However, this complexity results in recognizable alteration textures and trace-element signatures in the mineral archive that can be used to reconstruct the magmatic evolution and fluid–rock interaction history of carbonatites. We present new LA–ICP–MS trace-element data for magnetite, calcite, siderite, and ankerite–dolomite–kutnohorite from the iron-rich carbonatites of the 1.3 Ga Grønnedal–Íka alkaline complex, Southwest Greenland. We use these data, in combination with detailed cathodoluminescence imaging, to identify magmatic and secondary geochemical fingerprints preserved in these minerals. The chemical and textural gradients show that a 55 m-thick basaltic dike that crosscuts the carbonatite intrusion has acted as the pathway for hydrothermal fluids enriched in F and CO₂, which have caused mobilization of the LREEs, Nb, Ta, Ba, Sr, Mn, and P. These fluids reacted with and altered the composition of the surrounding carbonatites up to a distance of 40 m from the dike contact and caused formation of magnetite through oxidation of siderite. Our results can be used for discrimination between primary magmatic minerals and later alteration-related assemblages in carbonatites in general, which can lead to a better understanding of how these rare rocks are formed. Our data provide evidence that siderite-bearing ferrocarbonatites can form during late stages of calciocarbonatitic magma evolution.     

On the origin of mixed-layered clay minerals from the San Andreas Fault at 2.5–3 km vertical depth (SAFOD drillhole at Parkfield,California)

A detailed mineralogical study is presented of the matrix of mudrocks sampled from spot coring at three key locations along the San Andreas Fault Observatory at depth (SAFOD) drill hole. The characteristics of authigenic illite–smectite (I–S) and chlorite–smectite (C–S) mixed-layer mineral clays indicate a deep diagenetic origin. A randomly ordered I–S mineral with ca. 20–25% smectite layers is one of the dominant authigenic clay species across the San Andreas Fault zone (sampled at 3,066 and 3,436 m measured depths/MD), whereas an authigenic illite with ca. 2–5% smectite layers is the dominant phase beneath the fault (sampled at 3,992 m MD). The most smectite-rich mixed-layered assemblage with the highest water content occurs in the actively deforming creep zone at ca. 3,300–3,353 m (true vertical depth of ca. 2.7 km), with I–S (70:30) and C–S (50:50). The matrix of all mudrock samples show extensive quartz and feldspar (both plagioclase and K-feldspar) dissolution associated with the crystallization of pore-filling clay minerals. However, the effect of rock deformation in the matrix appears only minor, with weak flattening fabrics defined largely by kinked and fractured mica grains. Adopting available kinetic models for the crystallization of I–S in burial sedimentary environments and the current borehole depths and thermal structure, the conditions and timing of I–S growth can be evaluated. Assuming a typical K⁺ concentration of 100–200 ppm for sedimentary brines, a present-day geothermal gradient of 35°C/km and a borehole temperature of ca. 112°C for the sampled depths, most of the I–S minerals can be predicted to have formed over the last 4–11 Ma and are probably still in equilibrium with circulating fluids. The exception to this simple burial pattern is the occurrence of the mixed layered phases with higher smectite content than predicted by the burial model. These minerals, which characterize the actively creeping section of the fault and local thin film clay coating on polished brittle slip surfaces, can be explained by the influence of either cooler fluids circulating along this segment of the fault or the flow of K⁺-depleted brines.     

Insights into North American Paleogeography and Paleotectonics from U–Pb ages of detrital zircons in Mesozoic strata of the Colorado Plateau, USA

Individual U–Pb ages for 5,655 detrital zircons (DZ) in 61 sandstone samples from Mesozoic strata of the Colorado Plateau and nearby areas provide insights into paleogeographic relations across the interior of North America and the paleotectonic evolution of North American continental margins. Pre-Mesozoic DZ grains derived either directly, or ultimately through sediment recycling, from distant sources in eastern North America are more abundant than DZ grains derived from the nearby Cordilleran magmatic arc of western North America. Sediment dispersal patterns included Triassic fluvial transport of detritus westward from the Ouachita orogen uplifted along the northern flank of rift highlands precursor to the oceanic Gulf of Mexico, Jurassic eolian transport southward into widespread ergs from deflation of floodplains of transcontinental paleorivers with headwaters in pre-Atlantic Appalachian highlands, and Jurassic-Cretaceous recycling of eolianite DZ from retroarc Sevier thrust sheets and from sedimentary cover of the Mogollon paleohighlands flanking the Border rift system.