Character and origin of variably deformed granitoids in central southern Sweden: implications from geochemistry and Nd isotopes

We present major and trace element data for eighteen 1.71–1.66 Ga granitoid samples, and Sm–Nd whole‐rock isotope data for eleven of these samples, in a transect across the border between the Transscandinavian Igneous Belt (TIB) and the Eastern Segment in central southern Sweden. The geochemistry of the granitoids varies from alkalic to alkali‐calcic and peraluminous in the east to predominantly calc‐alkaline and metaluminous in the west. Rocks in the west also have lower SiO₂ contents. Trace element signatures favour formation in an active continental margin setting. Nd isotope data are completely overlapping along the transect and initial ε_Nd values are mildly depleted in the range +0.3 to +2.6. The combined data suggest that the magmas were derived mainly from juvenile, pre‐existing crust, increasingly mafic and less alkaline towards the west. Copyright © 2011 John Wiley & Sons, Ltd.     

Late Cretaceous redbeds from the Gan-Hang Belt in Southeast China: petrography and geochemistry implications for provenance,source weathering,and tectonic setting

ABSTRACT

The distinct basin and range tectonics in Southeast China were generated by crustal extension associated with subduction of the Palaeo-Pacific plate during the late Mesozoic. Compared with adjacent granitoids of the ranges, the redbeds of the basins have not been well characterized. In this article, provenance, source weathering, and tectonic setting of the redbeds are investigated by petrographic and geochemical studies of sandstones from the Late Cretaceous Guifeng Group in the Yongchong Basin, Southeast China. Detrital grains are subangular to subrounded, poorly sorted, and rich in lithic fragments. Variable Chemical Index of Alternation values (59.55–79.82, avg. 66.79) and high Index of Compositional Variability (ICV) values (0.67–3.08, avg. 1.40) indicate an overall low degree of chemical weathering and rapid physical erosion of source rocks. Such features are consistent with an active extension tectonic setting. Other chemical indices (e.g. Al₂O₃/TiO₂, Th/U, Cr/Th, Th/Sc, Zr/Sc) also suggest significant first-cycle sediment input to the basin and a dominant felsic source nature. Thus, the Guifeng Group possibly underwent moderate to low degrees of weathering upwards. Sandstone framework models and geochemical characteristics suggest the provenance was likely a combination of passive margin (PM) and active continental margin (ACM) with minor continental island arc (CIA) tectonic settings. Sediment derivation from Neoproterozoic metamorphic rocks and Cambrian to Triassic granitoids indicates PM provenance, whereas sediments derived from Jurassic to Cretaceous granitoids suggest ACM and CIA nature. Therefore, the Late Cretaceous redbeds were deposited in a dustpan-like half-graben basin under the back-arc extension regime when Southeast China was possibly influenced by northwestward subduction of the Palaeo-Pacific plate beneath East Asia.     

Petrographic and geochemical characteristics of Mesoproterozoic Kumbalgarh clastic rocks,NW Indian shield: implications for provenance,tectonic setting,and crustal evolution

The Kumbalgarh Group of the south Delhi fold belt are the main bedrock series exposed in the axial region of the Aravalli craton. Quartzites and greywackes, the chief clastic constituents of this group, are well exposed. Petrographic and bulk-rock analyses of these rocks permit determination of their provenance, tectonic setting of the basin, and the Archaean to Proterozoic crustal evolution. Greywackes comprise quartz, plagioclase, amphiboles, K-feldspar, and rock fragments. Based on mineralogy, we divided the quartzites into three categories: QTZ1 is chiefly composed of quartz with a silty matrix and a minor quantity of feldspars and QTZ2 contains significant mafic minerals as well as quartz and feldspars, whereas QTZ3 is more feldspathic than the other groups. All the lithounits have SiO₂/Al₂O₃ ratios <～10 suggesting textural immaturity consistent with their sedimentary petrography. Greywackes display the least fractionated rare earth elements (REEs) (La/Yb _N : avg. 2.55) with positive Eu anomalies (avg. Eu/Eu* = 1.34). QTZ1 contains strongly fractionated REE patterns (avg. La/Yb _N : 13.56, avg. Eu/Eu* = 0.60), QTZ2 shows moderate REE fractionation (avg. La/Yb _N : 4.97, avg. Eu/Eu* = 0.61), and QTZ3 possesses the least fractionated V-shaped REE patterns (avg. La/Yb _N : 1.97, avg. Eu/Eu* = 0.51). Weathering attributes including chemical index of alteration (CIA), plagioclase index of alteration (PIA), chemical index of weathering (CIW), and A–CN–K plots assign a low to moderate degree of weathering to the Kumbalgarh sediments under a subtropical climate. Based on our synthesis of the petrographic and geochemical data, we suggest a provenance comprising basalts, tonalite–trondhjemite–granodiorite (TTG), and granite. Geochemical attributes indicate deposition of the detritus in an extensional backarc basin receiving sedimentary input from opposite directions. The opening and then closure of the South Delhi Basin was the last phase of the break-up of the supercontinent, columbia, which began by abortive rifting of the Udaipur belt and culminated in separation of the Aravalli–Bundelkhand–Dharwar block in the east and the East African orogen in the west.     

Geochemical and Nd isotope composition of detrital sediments on the north margin of the South China Sea: provenance and tectonic implications

A major re‐organization of regional drainages in eastern Tibet and south‐western China took place in the Cenozoic as deformation from the growing Himalayas and Tibetan Plateau affected an increasingly wider area. The effects of these changes on the regional sediment routing systems is not well constrained. This study examines the geochemical and Nd signatures of sedimentary rocks from the Ying‐Qiong and Nanxiong basins on the northern margin of the South China Sea to constrain and identify any significant changes in sediment source. Upper Cretaceous to Lower Eocene sedimentary rocks in the Nanxiong Basin show higher Th/Sc, La/Sc, Th/Cr and Th/Co ratios and lower Eu/Eu* ratios than PAAS (post‐Archaean Australian Shale), which indicates that Palaeozoic sedimentary rocks of the South China Block were the main basin sediment source. In contrast, Oligocene to Pleistocene sedimentary rocks of the Ying‐Qiong Basin show an abrupt change in these trace‐element ratios between 16·3 and 10·4 Ma, indicating a mid‐Miocene shift in provenance. ɛ_Nd values from the Ying‐Qiong Basin (range = −11·1 to −2·1) reinforce this, with pre‐13·8 Ma sedimentary rocks having average ɛ_Nd of −5·6 (range = −2·1 to −7·4), and post‐13·8 Ma sedimentary rocks having average ɛ_Nd of −9·3 (range = −8·7 to −11·1). During the Oligocene, the centre of rifting transferred south and basins on the north margin of the South China Sea experienced rapid subsidence. Further uplift and erosion then exposed Mesozoic and Cenozoic granites that supplied large amounts of granitic detritus, especially to the Ying‐Qiong Basin. Then a change occurred at ca 13 Ma resulting in less input from local sources (i.e. the fault blocks formed by Mesozoic‐Cenozoic tectonics and magmatism) to an increasing contribution of older continental material, mostly from Indochina to the west of the South China Sea.     

Basement–cover relationships of the Kalak Nappe Complex, Arctic Norwegian Caledonides and constraints on Neoproterozoic terrane assembly in the North Atlantic region

The Kalak Nappe Complex (KNC) has been regarded as Baltica passive margin metasediments telescoped eastwards onto the Baltic (Fennoscandian) Shield during the Caledonian Orogeny. Recent studies have questioned this interpretation, instead pointing to a Neoproterozoic exotic origin. In an effort to resolve this controversy we present a Sm–Nd and U–Th–Pb study of gnessic units, traditionally considered as the depositional basement, along with cover rock sediments and intrusives. Late Palaeoproterozoic gneisses now beneath the KNC were deposited after 1948 ± 33 Ma, before intrusion of the Tjukkfjellet Granite at 1796 ± 3 Ma, and were affected by later melting events at 1765 ± 9 and 1727 ± 9 Ma. These gneisses are interpreted as part of the Baltic Shield and underlie the KNC across a tectonic contact. An unconformity between psammites of the KNC and other paragneisses previously considered as its Precambrian basement is reinterpreted as a modified sedimentary contact between Neoproterozoic metasediments. These metasediments have statistically very similar detrital zircon populations with grains as young as 1034 ± 22, 1025 ± 32 and 1014 ± 14 Ma. The results indicate that the KNC sediments were deposited during the Neoproterozoic in basins along the Laurentian margin of eastern Rodinia and were not connected to Baltica via a depositional basement. Dating of the 851 ± 5 Ma Eidvågvatnet and 853 ± 4 Ma Nordneset granites shows that intrusive material associated with the Porsanger Orogeny (c. 850 Ma) affected a considerable region of the upper KNC terrane. Later Neoproterozoic events at 711 ± 6, 687 ± 12 and 617 ± 6 Ma are also recognised the latest of which may be an expression of rifting. Since early Neoproterozoic magmatism (c. 840–690 Ma) is unknown in Baltica, these results support an exotic origin for the KNC terranes.     

Sr and Nd isotope data from the fluorspar district of Asturias, northern Spain

The origin and age of the hydrothermal fluids related to the precipitation of fluorite, barite and calcite in the Villabona, La Collada and Berbes localities (Asturias fluorspar district, N Spain) have been evaluated from Sr and Nd radiogenic isotopes. Sr isotope data (⁸⁷Sr / ⁸⁶Sr = 0.7081 to 0.7096) are compatible with mixing between seawater and a more evolved groundwater that interacted with the basement. From Nd isotopes in fluorite, an isochron age of 185 ± 29 Ma (Lower Jurassic) was obtained, consistent with other hydrothermal events in the Iberian Peninsula and Europe. These constraints are essential to proceed with a quantitative model for the genesis of the mineralization that includes fluid and heat flow together with reactive transport of solutes.     

Sediment geochemistry as a provenance indicator: Unravelling the cryptic signatures of polycyclic sources,climate change,tectonism and volcanism

Interpretation of bulk‐sediment geochemistry is one of several approaches for determining sediment provenance. This study investigates the value added by bulk‐sediment geochemical analysis in interpreting provenance in a passive margin clastic basin, the Upper Jurassic–Lower Cretaceous deltaic sediments of the Scotian Basin. Provenance studies in this basin are challenging because source tectonic terranes are parallel to the basin margin and polycyclic sediment sources are abundant. More than 400 samples of mudstone and sandstone representing the geographical and stratigraphic range of interest were analysed for 57 elements. Diagenetic processes added calcium to many samples and removed potassium in rocks buried below 3 km, thus impacting principal component analysis and published weathering indices. However, multiple geochemical approaches to assessing the degree of weathering showed climatically controlled changes in weathering in the Tithonian and Barremian, and changes in supply from major tectonic events, such as the top‐Aptian uplift in the Labrador rift. Covariance of elements in heavy minerals demonstrates the varying magnitude of polycyclic supply and stratigraphic changes in sources. Geochemical analyses revealed a previously unsuspected Tithonian alkali volcanic sediment source, characterized by high niobium and tantalum. The lack of highly contrasting sources means that geochemistry alone is inadequate to determine sediment provenance. Published discrimination diagrams are of limited value. Statistical analysis of geochemical data is strongly influenced by diagenetic processes, episodic volcanic inputs and polycyclic concentration of resistant heavy minerals in sandstones. Single indicator elements for particular sources are generally lacking. Nevertheless, careful consideration of geochemical variability on a case by case basis, integrated with detrital mineral studies, provides new insights into palaeoclimate, sediment provenance and, hence, regional tectonics. Although there is no simple template for such analysis, this study demonstrates an approach that can be used for other basins.     

Carboniferous subvolcanic activity on the Beara Peninsula,SW Ireland

Magmatic activity associated with the Munster Basin has been more widespread than previously reported. The Munster Basin is a substantial sedimentary basin, and towards the end of its extensional phase of development, at the beginning of the Variscan orogeny in Ireland, numerous intrusions were emplaced into consolidated Upper Devonian and Lower Carboniferous sediments on the Beara Peninsula. One hundred and sixty-four sills and dykes have been mapped which are subalkaline to alkaline in nature. Two separate suites have been identified. The northern suite comprises subalkaline basalts of Cod's Head and Dursey Island which are intruded into Devonian Red Beds, and the southern suite comprises alkali basalts, trachytes and phonolites which crop out along 9 km of the south coast of the Beara Peninsula and are suggested as Brigantian in age. They are intruded into Devonian Red Beds and marine Lower Carboniferous strata and are therefore later than the tholeiitic magmatism on the Iveragh peninsula to the north. The alkaline magmatism on Beara was induced by lithospheric thinning and controlled partly by pre-existing zones of weakness in the Caledonide crust and partly by fracture zones that developed parallel to the Munster Basin margin as it subsided. In contrast to the Iveragh Peninsula, the stretching factor for the Beara lithosphere was never large enough to lead to the production of tholeiitic magmas. © 1997 John Wiley & Sons, Ltd.     

Eclogite and garnet pyroxenite from Stor Jougdan,Seve Nappe Complex,Sweden: implications for UHP metamorphism of allochthons in the Scandinavian Caledonides

Ultrahigh‐pressure metamorphism (UHPM) has recently been discovered in far‐travelled allochthons of the Scandinavian Caledonides, including finding of diamond in the Seve Nappe Complex. This UHPM of Late Ordovician age is older and less recognized than that in the Western Gneiss Region of southwestern Norway, which was related to terminal collision between Baltica and Laurentia. Here we report new evidence of UHPM in the Lower Seve Nappe, recorded by eclogite and garnet pyroxenite from the area of Stor Jougdan in northern Jämtland, central Sweden. Peak‐metamorphic assemblage of eclogite, garnet + omphacite + phengite + rutile + coesite? yields P–T conditions of 2.8–4.0 GPa and 750–900 °C, constrained by conventional geothermobarometry and thermodynamic modelling in the NCKFMTASH system. The prograde metamorphic evolution of the eclogite is inferred from inclusions of zoisite and amphibole in garnet, which are stable at lower pressure, whereas the retrograde evolution is recorded by formation of diopsidic clinopyroxene + plagioclase symplectites after omphacite, growth of amphibole replacing these symplectites, and of titanite around rutile. In garnet pyroxenite the peak‐metamorphic assemblage consists of garnet + orthopyroxene + clinopyroxene + olivine. P–T conditions of 2.3–3.8 GPa and 810–960 °C have been derived based on the conventional geothermobarometry and thermodynamic modelling in the CFMASH and CFMAS systems. Retrograde evolution has been recognized from replacement of pyroxene and garnet by amphibole. The results show that eclogite was metamorphosed during deep subduction of continental crust, most probably derived from the continental margin of Baltica, whereas the origin and tectonic setting of the garnet pyroxenite is ambiguous. The studied pyroxenite/peridotite of Baltican subcontinental affinity could have been metamorphosed as a part of the subducting plate and exhumed due to the downward extraction of a forearc lithospheric block.     

Tectonic Setting and Nature of the Provenance of Sedimentary Rocks in Lanping Mesozoic- Cenozoic Basin： Evidence from Geochemistry of Sandstones

The geochemical composition of sandstones in the sedimentary basin is controlled mainly by the tectonic setting of the provenance, and it is therefore possible to reveal the tectonic setting of the provenance and the nature of source rocks in terms of the geochemical composition of sandstones. The major elements, rare-earth dements and trace elements of the Mesozoic-Cenozoic sandstones in the Lanping Basin are studied in this paper, revealing that the tectonic settings of the provenance for Mesozoic-Cenozoic sedimentary rocks in the Lanping Basin belong to a passive continental margin and a continental island arc. Combined with the data on sedimentary facies and palaeogeography, it is referred that the eastern part of the basin is located mainly at the tectonic setting of the passive continental margin before Mesozoic, whereas the western part may be represented by a continental island arc. This is compatible with the regional geology data. The protoliths of sedimentary rocks should be derived from the upper continental crust, and are composed mainly of felsic rocks, mixed with some andesitic rocks and old sediment components. Therefore, the Lanping Mesozoic-Cenozoic Basin is a typical continental-type basin. This provides strong geochemical evidence for the evolution of the paleo-Tethys and theb asin-range transition.     

Deciphering polymetamorphic episodes in high-grade metamorphic orogens: Constraints from PbSL, Sm/Nd and Lu/Hf garnet dating of low- to high-grade metasedimentary rocks from the Kaoko belt (Namibia)

Three dating techniques for metamorphic minerals using the Sm–Nd, Lu–Hf and Pb isotope systems are combined and interpreted in context with detailed petrologic data from crustal segments in NW Namibia. The combination of isochron ages using these different approaches is a valuable tool to testify for the validity of metamorphic mineral dating. Here, PbSL, Lu–Hf and Sm–Nd garnet ages obtained on low- to medium-grade metasedimentary rocks from the Central Kaoko Zone of the Neoproterozoic Kaoko belt (NW Namibia) indicate that these samples were metamorphosed at around 550–560 Ma. On the other hand, granulite facies metasedimentary rocks from the Western Kaoko Zone underwent two phases of high-grade metamorphism, one at ca. 660–625 Ma and another at ca. 550 Ma providing substantial evidence that the 660–625 Ma-event was indeed a major tectonothermal episode in the Kaoko belt. Our age data suggest that interpreting metamorphic ages by applying a single dating method only is not reliable enough when studying complex metamorphic systems. However, a combination of all three dating techniques used here provides a reliable basis for geochronological age interpretation.     

西大别山早白垩世谭冲和陈冲花岗岩体U- Pb年龄、地球化学和Sr- Nd- Hf同位素特征：对岩石成因和下地壳拆沉时限的约束

谭冲和陈冲岩体出露于西大别造山带新县岩基北缘,主要岩性分别为二长花岗岩和花岗斑岩。为理解其岩石成因和构造属性,对两个岩体开展了激光等离子质谱(LA-ICP-MS)锆石U-Pb测年、元素地球化学和Sr-Nd-Hf同位素研究。结果表明,谭冲和陈冲岩体锆石U-Pb年龄分别为133.5±1.1Ma(MSDW=0.63)和132.9±1.1Ma(MSDW=1.30),暗示其形成于早白垩世。岩石均具有较高的SiO_2(69.40%～77.82%)、Al_2O_3(11.72%～15.26%)和总碱(Na_2O+K_2O=6.40%～8.70%)含量,K_2O/Na_2O比值大于1,过铝质(A/CNK=1.14～1.66,一个样品值0.97除外)等特点,总体归为高钾钙碱性系列。岩石富集轻稀土((La/Yb)_N=22.98～28.64),负Eu异常不明显,亏损Ba、Nb、Ta、P、Ti和Y元素。岩石锶同位素初始比值I_(Sr)为0.707220～0.707557,钕同位素ε_(Nd)(t)值为-17.7～-18.1,两阶段Nd模式年龄T_(DM2)=2.36～2.40Ga。锆石ε_(Hf)(t)值集中于-21.4～-25.8,两阶段Hf模式年龄T_(DM2)=2.24～2.48Ga。详细的矿物组成、岩石地球化学和Sr-Nd-Hf同位素分析揭示,两个岩体成因类型均为分异的I型花岗岩,起源于残留相含有石榴子石的部分熔融岩浆。岩浆房形成压力和深度较大,可能是在加厚下地壳环境扬子陆块北缘古老陆壳物质重熔的产物。结合区域同期岩浆岩对比研究认为,西大别地区与东大别地区加厚下地壳拆沉时限基本一致,发生在133Ma左右。     

徐淮地区中生代侵入杂岩中角闪岩和片麻岩类捕虏体的岩石学和地球化学:对深部地壳物质组成的制约

徐淮地区中生代侵入杂岩中角闪岩和片麻岩类捕虏体的主要元素、微量元素地球化学特征及其岩相学的研究表明,它们经历了两期变质作用的改造,即早期的榴辉岩相变质和晚期的角闪岩相退化变质。其原岩为拉斑玄武质岩石,在其形成过程中有较强的陆壳物质混染;部分捕虏体可能代表了本区深部地壳的物质组成,且具有华北地块基底的性质。中生代早期该区上地幔是多种岩石构成的构造混杂岩带,深部地壳主要由片麻岩类、角闪岩类和少量石榴辉石岩类组成。早白垩世时期深部地壳主要由一套快速折返至下地壳的榴辉岩相变质岩石所构成,它们普遍发生了角闪岩相退化变质,并与原下部地壳的深变质岩(片麻岩和角闪岩)混杂在一起,构成了一个构造混杂体。     

Integrated garnet and zircon–titanite geochronology constrains the evolution of ultra‐high–pressure terranes: An example from the Sulu orogen

Dating ultra‐high–pressure (UHP) metamorphic rocks provides important timing constraints on deep subduction zone processes. Eclogites, deeply subducted rocks now exposed at the surface, undergo a wide range of metamorphic conditions (i.e. deep subduction and exhumation) and their mineralogy can preserve a detailed record of chronologic information of these dynamic processes. Here, we present an approach that integrates multiple radiogenic isotope systems in the same sample to provide a more complete timeline for the subduction–collision–exhumation processes, based on eclogites from the Dabie–Sulu orogenic belt in eastern China, one of the largest UHP terranes on Earth. In this study, we integrate garnet Lu–Hf and Sm–Nd ages with zircon and titanite U–Pb ages for three eclogite samples from the Sulu UHP terrane. We combine this age information with Zr‐in‐rutile temperature estimates, and relate these multiple chronometers to different P–T conditions. Two types of rutile, one present as inclusions in garnet and the other in the matrix, record the temperatures of UHP conditions and a hotter stage, subsequent to the peak pressure (‘hot exhumation') respectively. Garnet Lu–Hf ages (c. 238–235 Ma) record the initial prograde growth of garnet, while coupled Sm–Nd ages (c. 219–213 Ma) reflect cooling following hot exhumation. The maximum duration of UHP conditions is constrained by the age difference of these two systems in garnet (c. 235–220 Ma). Complementary zircon and titanite U–Pb ages of c. 235–230 Ma and c. 216–206 Ma provide further constraints on the timing of prograde metamorphism and the ‘cold exhumation' respectively. We demonstrate that timing of various metamorphic stages can thus be determined by employing complementary chronometers from the same samples. These age results, combined with published data from adjacent areas, show lateral diachroneity in the Dabie–Sulu orogeny. Three sub‐blocks are thus defined by progressively younger garnet ages: western Dabie (243–238 Ma), eastern Dabie–northern Sulu (238–235 Ma) and southern Sulu terranes (225–220 Ma), which possibly correlate to different crustal slices in the recently proposed subduction channel model. These observed lateral chronologic variations in a large UHP terrane can possibly be extended to other suture zones.     

Petrography and geochemistry of the late Eocene–early Oligocene submarine fans and shelf deposits on Lemnos Island,NE Greece. Implications for provenance and tectonic setting

Provenance and tectonic history of the late Eocene‐early Oligocene submarine fans and shelf deposits on Lemnos Island, NE Greece, were studied using sandstone framework composition, sedimentological data and sandstone and mudstone geochemistry. The resulting tectonic–sedimentological model is based on the late Eocene–early Oligocene Lemnos Island being in a forearc basin with the outer arc ridge as a major sediment source. Modal petrographic analysis of the studied sandstones shows that the source area comprises sedimentary, metamorphic and plutonic igneous rocks deposited in the studied area in a recycled orogenic environment. Moreover, within the above sediments, the minor occurrence of volcanic fragments suggests little or no influence of a volcanic source. Provenance results, based on major, trace and rare earth element (REE) data, suggest an active continental margin/continental island arc signature. All the samples are LREE, enriched relative to HREE, with a flat HREE pattern and positive Eu anomalies, suggesting that the processes of intracrustal differentiation (involving plagioclase fractionation) were not of great importance. Results derived from the multi‐element diagrams also suggest an active margin character, and a mafic/ultramafic source rock composition, while the positive anomaly of Zr that can be attributed to a passive continental margin source, is most likely associated with reworking and sorting during sediment transfer. Palaeocurrents, with a NE–NNE direction, indicate a northeast flow, towards the location of the late Eocene–early Oligocene magmatic belt in the north‐east Aegean region. Conglomerates are composed of chert, gneiss and igneous fragments, such as basalts and gabbros, suggesting this outer arc ridge as a likely source area. Copyright © 2009 John Wiley & Sons, Ltd.     

西藏雅鲁藏布缝合带三叠系朗杰学群沉积岩古生物、地球化学特征及其物源区和构造背景分析

随着近年来对朗杰学群的解体,发现前人对于朗杰学群、涅如组、修康群及洛林岩群的研究存在混淆,研究对象是否为朗杰学群应重新审慎,同时,几者是否为同一构造背景产物仍存在较大争议。本文对朗杰学群命名地(贡嘎县姐德秀镇-朗杰学乡一带)的朗杰学群重矿物特征、地球化学特征及古生物化石进行了研究。朗杰学群砂岩主量元素和微量元素化学成分低于地壳克拉克值,SiO₂含量平均为74.14%,K₂O/Na₂O值平均为0.70,反映砂岩成熟度较低,没有经历明显的成岩后生改造;化学蚀变指数(CIA)较集中,平均为71.55,属低级-中等风化程度,指示气候和构造环境都处于相对稳定状态;古环境分析显示,100Mg/Al₂O₃值平均为7.85,CaO/Fe+CaO值平均为0.314,表明朗杰学群形成于中等盐度的深水厌氧环境,且由北向南沉积水体逐渐加深;重矿物以锆石为主,其次为金红石,分选磨圆较差,ATi指数为93.3～98.97,ZTR指数为48.01～85.75,反映朗杰学群物源区的火山岩较为丰富,且搬运距离较...     

An Australian provenance for the eastern Otago Schist protolith,South Island,New Zealand: evidence from detrital zircon age patterns and implications for the origin of its gold

Uranium–lead age patterns of detrital zircons in Otago Schist meta-sandstones from eastern Otago, including areas of orogenic gold mineralisation, are mostly consistent with a Rakaia Terrane (Torlesse Composite Terrane) accretionary wedge protolith. Southwest of the Hyde-Macraes and Rise & Shine shear zones the depositional age is regarded as Middle–Late Triassic. At the south and west margins, there are two areas in the Late Triassic Waipapa Terrane protolith. Northeast of the Hyde-Macraes Shear Zone, the schist protolith has Middle to Late Triassic and middle to late Permian depositional ages of Rakaia Terrane affinity. At the northeastern margin of the Hyde-Macraes Shear Zone, there is a narrow strip with a mid-Carboniferous protolith, which may be a counterpart of the Carboniferous accretionary wedge in the New England Orogen, eastern Australia. Ordovician–Silurian zircons are a minor but distinctive feature in many of the protolith age patterns and form significant age components at hard-rock gold locations. These constrain the provenance of Rakaia Terrane protolith sediments to Late Triassic time and within the Permian–Triassic magmatic arcs at the northeastern Australian continental margin and partly within the Ordovician–Silurian granitoids of the Charters Towers Province hinterland and environs. The latter have extensive gold mineralisation and thus upon exhumation might be the origin of Otago gold.     

准噶尔盆地东南缘芦草沟组黑色泥页岩稀土元素地球化学特征及其地质意义

对准噶尔盆地东南缘中二叠统芦草沟组上、中、下三段黑色泥页岩进行稀土元素地球化学特征研究,并讨论其地质意义。结果表明,芦草沟组黑色泥页岩的稀土元素总量∑REE为(51.39~138.27)×10^-6,平均值为94.23×10^-6,较全球平均大陆上地壳成分(UCC)和北美页岩(NASC)的平均值均偏低。∑LREE/∑HREE、(La/Yb)_N、(Ce/Yb)_N等地化参数及稀土元素配分模式均反映轻、重稀土元素的明显分异,呈现LREE富集、HREE亏损的特征,趋势曲线较为平坦。黑色泥页岩具有明显的δEu负异常和弱的δCe负异常。Ce异常值均大于-0.1,反映研究区在中二叠世水体为较强且稳定的还原环境。REE的明显分异指示沉积速率总体较低,呈现逐渐变慢的趋势,反映了沉积时期水体加深的过程,这也与滨浅湖-半深湖-深湖的沉积相吻合。根据δEu的异常情况和(La/Yb)_N与∑REE的关系,认为芦草沟组沉积物的母岩为沉积岩和花岗岩的混合。黑色泥页岩物源主要来自南部的伊连哈尔比尕山。     

Evolution of the Palaeotethys in the Eastern Mediterranean: a multi-method approach to unravel the age,provenance and tectonic setting of the Upper Palaeozoic Konya Complex and its Mesozoic cover sequence (south-central Turkey)

ABSTRACT

Siliciclastic sediments from the Upper Palaeozoic Konya Complex and its Mesozoic cover were studied by a multi-method approach combining thin-section petrography, bulk-rock geochemistry, mineral chemistry of rutile, and U–Pb geochronology of detrital zircons. Provenance sensitive data of samples from the Upper Palaeozoic Hal?c? Formation indicate sediment supply from mainly low- to medium-grade metamorphosed sedimentary rocks of felsic character, while the contribution from volcanic rocks was rare. The detrital zircon record of sediments from the Hal?c? Formation documents sediment supply from different sources and excludes a similar provenance. Some samples show great similarities with Palaeozoic sandstones from the cover sequence of the Saharan Metacraton and the Arabian–Nubian Shield, while the other samples indicate a provenance that must be sought in units with a southern Eurasian affinity. The upper limit for sediment deposition in the Hal?c? Formation is mostly constrained by Early Palaeozoic zircon populations; however, sediment accumulation in Pennsylvanian–Cisuralian time is more likely, contemporaneously with the Upper Palaeozoic succession on the Karaburun Peninsula (western Turkey). The provenance of sediments from the Upper Triassic Ard?çl? Formation remains enigmatic, but the source should be sought nonetheless in units close to the depositional site. In any case, detrital zircon age spectra and compositional data exclude recycling of underlying rock units (i.e. Hal?c? Formation). Overall, our new provenance data reveal great similarities between the Konya Complex and comparable units (Chios, Karaburun) but also highlight distinct differences in terms of sediment composition and provenance.     

苏南地区中、古生界沉积岩地球化学特征——以圣科1井为例

通过对苏南地区圣科1井333块沉积岩样品的微量元素和稀土元素进行测试和分析,揭示了苏南地区中、古生界的沉积环境、物质来源及其大地构造背景。研究表明:苏南地区二叠系栖霞组上部沉积时呈现明显的富氧特征;研究区中、古生界海陆环境交替出现。另外,通过对所有碎屑岩样品中的∑REE、∑LREE/∑HREE、w(La)、w(Ce)、La/Yb、δEu等以及La-Th-Sc和Th-Sc-Zr/10图解判定:研究区龙潭组上部、坟头组、高家边组沉积时其物质来源应为活动大陆边缘的构造环境;龙潭组下部为大陆岛弧的构造环境;并推测五通组也可能为被动大陆边缘的构造环境。依据碎屑岩样品中δEu的大小、REE配分模式和La/Yb-∑REE投影图上所体现的规律,表明苏南地区中、古生界物质主要来源于上地壳并且存在多个物源区;志留系高家边组和坟头组其母岩以沉积岩和花岗岩为主;五通组的源岩应为沉积岩,其物源区为华夏板块及江南隆起。