不同煤级煤对H2S气体的吸附差异及吸附模型

为了研究不同煤级煤对H₂S气体的吸附差异及吸附模型,采集新疆气煤,山西潞安瘦煤、晋城无烟煤3个煤样进行了工业分析、煤岩分析和平衡水条件下的等温吸附实验。采用Langmuir,BET,D-R和D-A吸附模型,利用拟合软件对等温吸附实验数据进行了非线性回归拟合,并检验拟合程度。结果表明:煤对H₂S的吸附量随着煤化程度的加深而增加,为第Ⅰ类等温吸附线;其中Langmuir模型的拟合效果最好,n=1的D-A模型的拟合效果次之,BET模型的拟合效果较差,模型对实验数据的拟合效果与吸附模型中参数个数无明显关系;煤吸附H₂S可用单分子层吸附理论来解释。      

不同煤级煤层气吸附扩散系数分析

应用扩散理论模型模拟吸附扩散过程,根据四种煤级煤样的平衡水和注水等温吸附实验数据计算吸附扩散系数,研究吸附扩散的规律。研究表明：煤的孔隙结构是影响煤吸附扩散过程的主要因素。液态水对煤的润湿性随煤级增高而降低,对吸附扩散过程的影响逐渐减小,大孔和中孔发育的煤扩散速率较快,扩散系数高,过渡孔和微孔发育的煤相对扩散速率较慢,扩散系数低。     

不同变质变形煤储层吸附/解吸特征及机理研究进展

不同变质变形煤储层包括低煤级、中煤级和高煤级变质变形环境中的脆性变形煤、韧性变形煤和过渡型变形煤,不同变质、变形程度和机制对煤层气的吸附/解吸影响较大。干燥煤和平衡水煤的甲烷吸附量随变质程度的增强呈现出不同的变化趋势,干燥煤呈横"S"形且易于解吸,而平衡水煤呈倒"U"字形且吸附/解吸强度皆低于干燥煤样,且解吸过程较干燥煤滞后。构造变形导致煤的大分子结构和纳米级孔隙发生不同程度的改变,进而影响气体的吸附/解吸能力,脆性变形主要增加煤的大、中孔,其基本结构单元堆砌度略有增大,甲烷吸附/解吸程度有所增强;韧性变形主要增加煤的微孔-超微孔,其基本结构单元堆砌度增加较快,煤层气吸附能力增强,降压时韧性变形煤比脆性变形煤具有较高的瞬时解吸速率。由此可见,不同变质变形环境中的煤储层吸附/解吸能力差异较大,这主要是由煤储层内部结构及其影响因素对其制约所决定的。     

不同煤级煤及其萃余物吸附性能的研究

采用不同溶剂对褐煤、焦煤、低级无烟煤(Ro,max2.62%)以及中级无烟煤(Ro,max3.74%)等四个煤级煤样进行分级超声萃取,然后对原煤和萃余物进行平衡水预湿的方法,进行了等温吸附实验,并结合孔隙结构测试和水分含量变化,分析了溶剂萃取后萃余物的吸附性能变化及其影响因素。研究发现:(1)平衡水条件下,原煤对甲烷的吸附能力要大于萃余物,萃取后,尽管煤的组成和孔隙结构发生了变化,但并不能改变不同煤级煤吸附甲烷的能力的对比关系;(2)原煤和各级萃余物都发生了到某一压力后,吸附量随着压力增加而下降的现象,褐煤及其萃余物甚至出现负值,这可能是由超临界状态下吸附相的体积忽视后带来的效应和煤基质在压力、水分作用发生膨胀以及随着压力增加,水分在吸附孔隙中占据吸附点位的增多,造成甲烷有效吸附点位的减少等综合作用的结果。研究认为,在讨论影响不同煤化作用的煤吸附能力的因素时,应该首先考虑到煤级对吸附能力的影响;对煤化程度相近的煤,其他因素如孔隙结构和水分的变化对吸附的影响才显现,但对不同煤级煤吸附性的主要影响因素也不尽相同。在煤层气吸附研究中,吸附量下降现象应该是一个共性,其机理的解释和寻求正确的吸附相体积校正,以及一定压力下,煤基质在水分作用下发生膨胀对吸附性的影响的规律描述,都是亟待解决的重要问题。     

低煤阶煤中甲烷扩散性能分析

甲烷在煤基质中的扩散性能是影响煤层气产出的重要储层参数。采用云南东南部地区新近系中新统小龙潭组褐煤样品,开展了低煤阶煤中甲烷等温吸附实验。基于等温吸附实验获得的吸附量与时间的关系数据,应用一元孔隙结构气体非稳态扩散模型,计算了煤中甲烷气体扩散系数,揭示了煤中甲烷扩散规律和控制机理。研究结果表明,低煤阶煤中气体扩散规律服从Langmuir方程,煤中甲烷有效扩散系数和扩散系数随着压力的增高而增大;吸附时间常数随着压力的增高而减小,服从负指数函数规律。4个实验煤样Langmuir有效扩散系数和扩散系数分别是（1.71~5.46）×10-4 s-1和（2.17~6.91）×10-12 m2/s,Langmuir压力为0.63~1.97 MPa。在相同温度和压力条件下,干燥煤样的有效扩散系数和扩散系数大于平衡水分煤样,随着温度的增高,其有效扩散系数和扩散系数增加,煤中气体扩散性能增强。      

中煤级煤吸附甲烷的物理模拟与数值模拟研究

基于184个中煤级（镜质组最大反射率Ro,max介于0.65%~2.50%）煤在平衡水条件下的等温吸附实验成果,模拟了中煤级煤的朗格缪尔体积和压力与煤级的关系,建立了不同埋深（温度、压力）条件下不同煤级煤饱和吸附气量量板,探讨了压力和温度对中煤级煤吸附甲烷能力的综合效应,对比分析了中煤级煤吸附特征与低、高煤级煤的差异,提出了中煤级煤吸附气量预测的方法。     

不同煤阶深煤层含气量差异及其变化规律

基于Langmuir 等温吸附方程式,开展不同煤阶不同温压条件下等温吸附模拟实验,实验结果表明：在煤岩镜质组反 射率Ro<3.0%时,Langmuir 等温吸附曲线随煤阶、温度、压力升高表现出明显的分带性。随着煤阶的升高,煤吸附能力逐 渐增强。温度小于55℃时不同煤阶Langmuir 体积受温度影响较小,之后影响逐渐增大。低煤阶在12 MPa、中高煤阶在 15 MPa以前随压力增加Langmuir 体积增大明显。根据实测含气量外推法结合高温高压等温吸附实验建立了深煤层含气量数 学模型,显示煤层含气量随埋深呈现快速增加—缓慢增加—不增加—缓慢减小的变化规律,其中低煤阶临界深度介 于1400~1700 m,中高煤阶临界深度介于1500~1800 m。该含气量数学模型对预测深部煤层含气量变化规律及煤层气资源评 价提供基础依据。     

水分和粒度对煤吸附甲烷性能的实验研究

为了研究水分含量和粒度对煤吸附甲烷性能的影响,取山西西山杜儿坪矿2号煤干燥样、平衡水样和注水样进行了等温吸附实验。基于分子间作用力对水含量影响机理进行分析,并运用维里方程拟合等温吸附实验结果来验证。实验结果发现,在未达到平衡水分之前,水含量对高煤级吸附能力影响小且注水煤样中的液态水影响增加了甲烷吸附量;同一种煤的高含水煤样对液态水的亲和能力要远比平衡水煤样对气态水的亲和能力强。     

液态水影响不同煤级煤吸附甲烷的差异及其机理

以IS100等温吸附解吸仪和MTS815型电液伺服岩石实验系统为主要实验平台,应用已建立的模拟储层条件下煤样注水和注水试样等温吸附实验方法,对3种不同煤级的煤储层样品开展了高压（8～20 MPa）注水和等温吸附实验,发现储层条件下煤层中的液态水（注水煤样）对不同煤级（0.46%<Ro,max<1.72%）煤吸附甲烷影响有差异,其含水量随煤级升高呈L型降低,而吸附量则线性增加。笔者认为液态水造成吸附差异的原因是煤体润湿性的差异,对于中低煤级的煤样来说,煤表面的物理化学性质起着控制作用,直接影响着煤体润湿性,吸附势和含水量的曲线都说明了这一点。     

无烟煤孔隙结构特征及其吸附特性研究

选取焦作矿区无烟煤四种不同煤体结构煤作为研究煤样,通过低温液氮吸附实验,分析了不同煤体结构煤的孔隙结构分布特征,同时对所采集的煤样分别进行高温高压平衡水分条件下CH_4气体的等温吸附实验,分析了孔隙结构、平衡水分与CH_4吸附特性之间的作用关系。研究结果表明:与原生结构煤相比,构造煤的BJH总孔容、微孔比表面积、BJH总孔比表面积随着破坏程度增大而增大。高温高压平衡水分条件下,无烟煤不同煤体结构煤表现出了吸附能力新特性,即随无烟煤破坏程度增加,朗格缪尔体积V_L呈现先增大后减小的变化趋势。不同煤体结构煤的孔隙结构由于构造应力作用而发生变化,引起平衡水分含量的不同,从而导致对CH_4的吸附能力不同。分析表明,无烟煤不同煤体结构煤表现出的吸附新特性,是特有的孔隙结构和平衡水分含量差异综合作用的结果。在不同的埋藏条件下,某一因素会占主导作用,吸附增量变化取决于主控因素控制。     

Two different geomentalities,two different gardens: the French and the Japanese cases

The French Renaissance gardens and Japanese hill gardens have constrasting garden landscapes. Japanese gardens are naturalistic and intend to give illusions that they are the beautiful spots of unspoilt nature. In contrast, the appearances of French gardens are not an imitation of nature but boldly reorganised landscapes in geometric forms. These two contrasting types of garden landscapes represent two different sets of geomentalities (frames of mind regarding geographical environment).An earlier draft of this paper was presented at the Ninth New Zealand International Conference on Asian Studies, Hamilton, 23–26 August 1991. Its abridged version is published in D. Bing and K. Henshell (ed.)Japanese Perceptions of Nature and the Natural Order (Hamilton, NZ 1992), pp. 1–11. The present paper was developed from the first half of the conference paper, and was completed during my three month's tenure in 1993 as a Japan Foundation fellow. I am grateful to the Japan Foundation for their generous support of my research on the Japanese geomentality.     

Comparison between different kriging estimators

Six different geostatistical estimators (linear kriging, lognormal kriging, and disjunctive kriging, each with and without a nonbias, i.e., universality condition) were compared using data from a polymetallic deposit in Algeria. The differences between estimators with and without the nonbias condition were far more pronounced than between the different kriging methods. This highlights the importance of choosing an appropriate stationarity model for the data. The criterion concerning kriging weight of the mean in simple kriging, proposed by Remacre (1984, 1987) and Rivoirard (1984) was found to be helpful for determining blocks where the choice of the stationarity hypothesis was critical.     

不同围压及应变速率下页岩变形及破损特性试验研究

为揭示围压及应变速率对页岩力学特性的影响规律,对志留统龙马溪组页岩试样开展了不同围压及不同应变率下的三轴压缩力学试验研究。结果表明,围压和应变率对页岩的弹性模量、峰值强度及破裂形态等均具有显著影响,弹性模量和峰值强度均随围压的升高而增加,峰值强度增加的幅度明显大于弹性模量,峰值强度呈线性增加趋势,低围压时应变率从低到高,弹性模量和峰值强度都呈逐渐升高的趋势,两者与应变率对数的关系可用二次多项式描述;随着围压增大,页岩的应变率效应逐渐减弱,在较高高围压(50 MPa)下峰值强度和弹性模量随应变速率增加而增加现象均变得极不显著。对试验后岩样的破坏模式进行分析可知,页岩在低围压高应变率状态下主要是劈裂–剪切破坏,随着围压的增加和应变率的减小,试样的破坏由脆性劈裂–剪切破坏向单一剪切破坏转变,再逐渐向延性破坏过渡。研究结果对于合理确立页岩力学参数及设计压裂方案具有较好的参考。     

地形对不同反演的影响

[摘 要]根据观测数据和模型参数之间的关系,将求误差函数的最优问题的方法通常分为线性反演和非线性反演; 线性反演要求有相当准确的背景介质模型的条件,这和地球物理问题中的实际情况相矛盾。特殊情况下,线性反演甚至出现发散的情况。而非线性反演不用求目标函数的偏导数,全局随机搜索模型空间的最优解的办法,避免了问题的线性化,在山区复杂地形条件下,通过对比论证,非线性反演能够获取更合理的真实地电模型,从而说明由于非线性反演适应性较强、精度较高已被广泛的应用于地球物理的各个领域。     

Fiddling on a different planet?

The recent commentaries in this journal by both [Hamnett, C., 2003. Contemporary human geography: fiddling while Rome burns, Geoforum 34, 1–3] and [Johnston, R., Hepple, L., Hoare, A., Jones, K., Plummer, P., 2003. Contemporary fiddling in human geography while Rome burns: has quantitative analysis been largely abandoned—and should it be? Geoforum 34, 157–161] do not recognise the phenomenal success of GIS in exporting a version of academic geography to the world at large. The note documents this success and explores possible implications for the discipline should it chose to engage with both the geographic information industry and the science that supports it.     

不同初始饱水状态红砂岩冻融损伤差异性研究

借助于红砂岩冻融循环CT扫描试验，从扫描层面内不同的感兴趣区域内CT均值数大小及其变化以及CT图像，对4种典型的不同初始饱水状态红砂岩进行冻融循环条件下损伤扩展差异性研究。研究结果表明，对于初始损伤相同的岩石，初始饱水状态将决定冻融循环对其损伤扩展的影响程度。     

Carbon isotope fractionation of Thermoanaerobacter kivui in different growth media and at different total inorganic carbon concentration

Chemolithotrophic homoacetogenic bacteria apparently express a characteristic stable carbon isotope fractionation and may contribute significantly to acetate production in anoxic environments. However, fractionation factors (ε) in bacterial cultures have rarely been determined and the effect of substrate availability has not been assessed. We therefore studied the kinetic carbon isotope effect in cultures of Thermoanaerobacter kivui grown at 55 °C. The fractionation factor in HCO₃⁻ buffered medium was ca. 15‰ more negative than that in PO₄³⁻ buffered medium. To test whether the difference was caused by the initial substrate ratio of H₂ and total inorganic carbon (TIC; 0.5 in HCO₃⁻ vs. 4.0 in PO₄³⁻ buffered medium), T. kivui was grown in either [3-(N-morpholino) propanesulfonic acid, MOPS] buffered or PO₄³⁻ buffered media with different HCO₃⁻ concentration. Indeed, the fractionation factor became more negative with increasing HCO₃⁻ concentration and decreasing H₂/TIC ratio. While pH had only a small effect, the fractionation was generally more negative in MOPS buffered than in phosphate buffered media, indicating that the buffer system also affected fractionation. Collectively, the results show that substrate availability and other environmental factors affect the magnitude of isotope fractionation during acetate production by chemolithotrophic homoacetogenesis.     

High-resolution simulations of particulate matter emitted by different agriculture tillage under different weather conditions in California,USA

Agriculture tillage can result in the high concentration of particulate matter with an aerodynamic diameter of 10 μm or less (PM₁₀) that can cause serious health problems. To understand how different agriculture tillage methods and wind conditions affect the transmission and distribution of PM₁₀, four model runs were performed using the high resolution Weather Research and Forecasting model coupled with a chemistry component (WRF-Chem). In these runs, the observed emission rates under the conventional and combined tillage methods and different wind speeds were inputted into WRF-Chem. The simulated results show that the WRF-Chem model can reasonably capture the meteorological conditions at 500 m horizontal resolution over an agricultural field in California. The atmospheric concentration of particulate matter increases significantly with an increase in the emission area. Substantial reduction, 50%, of aerosolized PM₁₀ dust emissions can be achieved by using combined tillage, when considered under the same meteorological conditions when compared to that caused by the conventional tillage method. Using the same conventional tillage emission rates, the lower velocity wind produces larger airborne concentrations of pollutants than does a stronger wind. Conversely, a stronger wind distributes the particulate matter over a larger area though with a diminished concentration when compared to a weaker wind. The atmospheric concentration of particulate matter was found to have a direct relationship to its emission intensity and area and wind conditions.     

Identifying flood-prone landfills at different spatial scales

Landfills are mainly located in lowland areas close to settlements inducing flood risk of potential environmental contamination and adverse health effects. During recent flood events, numerous landfill sites were reportedly exposed to inundations, leading to erosion of landfilled material and release of pollutants threatening humans and the environment. Although emissions from landfills under regular operating conditions are well investigated, the behaviour and associated emissions in case of flooding are widely unknown. To enable environmental risk management, flood-prone landfills must be identified to establish priorities for subsequent protection and mitigation measures. This paper presents two flood risk assessment approaches at different spatial scales: a macro-scale assessment approach (MaSA) and a micro-scale assessment approach (MiSA). Both methodologies aim to determine the proportion of landfills endangered by flooding, and evaluate the impacts. The latter are expressed by means of risk categories (minor to serious) of impacts that flooded sites might have on humans and the environment. The evaluation of 1,064 landfills in Austria based on MaSA yields roughly 30 % of landfills located within or close to flood risk zones. Material inventories of 147 sites exposed to flooding are established, and potential emissions during a flood event are estimated. Three representative case study areas are selected and investigated in detail by applying the MiSA approach based on 2D hydrodynamic models to calculate flow depths and shear stress and by developing emission scenarios to validate the macro-scale screening approach (MaSA). The applications of MiSA and MaSA outlines that hazardous emissions due to flooding can lead to significant impacts on the environment. Uncertainty associated with related processes and data sources is considerably high. Nevertheless, both MiSA and MaSA provide a decision support tool to identify landfills with imminent risk for humans and the environment. Therefore, the described methodologies provide toolsets to enable environmental risk reduction by applying a priority-ranked flood risk management.     

Closing temperatures of different fission track clocks

The fission track closing temperatures of the minerals which are found to be suitable for fission track geochronology have been calculated for various cooling rates using the stepwise cooling. Biotite is found to have the lowest closing temperature whereas the sphene is having the highest. The closing temperature falls with decrease in cooling rate.