A contrast of two typical LUCC processes and their driving forces in oases of arid areas: A case study of Sangong River Watershed at the northern foot of Tianshan Mountains

Aerial photographs taken in 1978 and 1987, Landsat TM images in 1998 as well as soil, hydrology and socio-economic data for the oases in Sangong River Watershed were processed by Remote Sensing (RS) and Geographic Information System (GIS). There are two typical agricultural land uses in oases,Farm-based Land Use with large-scale intensified agricultural activities (FLU) and Household Responsibility-based Land Use with small-scale activities (HRLU). The Index Model of Land Use/Land Cover Change (LUCC), Weighted Index Sum (WIS) and logistic stepwise regression model were established to contrast the two typical LUCC processes and their driving forces. The land use patterns were dominated by cropland and grassland for the entire region, and cropland, residential and industrial land were increasing stably. In the HRLU areas, woodland and grassland declined dramatically, but in the FLU areas, grassland decreased only by 12.0%, whereas woodland increased by 13.7%. LUCC was stronger in the earlier stage (1978-1987) than in the later stage (1987-1998) for the entire region. LUCC was more intense in the HRLU areas than in the FLU areas during the entire period (1978-1998). Policy was a key factor in the land use change, and water resources were a precondition in land use. Under the control of policy and water resources,the main human driving factors included population and economy, and the main natural restrictions were soil fertility and groundwater depth. Human driving factors controlled the land change in the HRLU areas, but natural restriction factors dominated in the FLU areas. In the mean time,intensification of LUCC in the region had some spatiotemporal implications with a fluctuation of impact factors.     

Time-resolved Fluorescence Measurements of Aquatic Natural Organic Matter (NOM)

The fluorescence decay of aquatic natural organic matter (NOM) samples was investigated using the time-correlated single photon counting technique (TCSPC). Two different approaches for the data analysis are presented: the discrete component approach (DCA) and the exponential series method (ESM). The parameter set obtained in the DCA is discussed in terms of characterization for NOM of different origins. However, the obtained parameter set can only be interpreted as operationally defined. Using the ESM for a fluorescence decay time distribution analysis no a priori assumption about the number of fluorescing components was introduced into the data analysis. The interpretation of fluorescence decay time data for samples before and after ozonation is in good agreement with results of other analytical methods.     

1988-2018年滇池氮磷比的时空演变特征与原因解析

氮、磷浓度是制约湖泊营养状态和生产力水平的重要环境因子,而氮磷化学计量比是湖泊生态系统的主要指标,因此,判识氮磷比变化趋势及其驱动力对湖泊生态恢复具有重要意义.研究基于19882018年连续观测数据,分析了滇池氮磷浓度和氮磷摩尔比(简称氮磷比)的时空分布演变特征;采用多元线性回归模型分别对滇池草海和外海氮磷比驱动效应进行定量解析,筛选出影响湖体氮磷比变化的潜在驱动因子.结果表明:①19882018年滇池氮磷比呈现显著的线性上升趋势,其中草海和外海氮磷比分别上升1.3和0.7 a^-1.②草海和外海分别在2008年和2004年发生了氮磷比上升突变,突变前上升归因于总氮浓度快速增加,突变后则是由于总磷浓度下降较快.③滇池的氮磷浓度变化主要是受流域氮磷输入负荷、跨流域调水、流域氮磷削减、风速和水位的综合影响,但受控因子在不同区域可能存在差异.④气温是滇池氮磷比变化的主要驱动因子,流域人为氮磷输入差异是滇池氮磷比变化的次要驱动因子.     

Influences of Environmental and Operational Factors on Dark Fermentative Hydrogen Production: A Review

Hydrogen (H₂) is one of renewable energy sources known for its non‐polluting and environmentally friendly nature, as its end combustion product is water (H₂O). The biological production of H₂ is a less energy intensive alternative where processes can be operated at ambient temperature and pressure. Dark fermentation by bacterial biomass is one of multitude of approaches to produce hydrogen which is known as the cleanest renewable energy and is thus receiving increasing attention worldwide. The present study briefly reviews the biohydrogen production process with special attention on the effects of several environmental and operational factors towards the process. Factors such as organic loading rate, hydraulic retention time, temperature, and pH studied in published reports were compared and their influences are discussed in this work. This review highlights the variations in examined operating ranges for the factors as well as their reported optimum values. Divergent values observed for the environmental/operational factors merit further exploration in this field.     

Characterization of Estuarine and Fluvial Dissolved Organic Matter by Thermochemolysis using Tetramethylammonium Hydroxide

Selected samples of dissolved organic matter (DOM) isolated by ultrafiltration (UDOM) have been analyzed by thermochemolysis in the presence of tetramethylammonium hydroxide (TMAH). This technique cleaves ester and ether bonds of bio‐ and geological macromolecules and releases monomer subunits and methylates them in situ as their methyl ethers and methyl esters. Compared with conventional pyrolysis, TMAH thermochemolysis avoids decarboxylation of preexisting carboxylic moieties and produces aromatic acids as their methyl esters. Various phenolic derivatives, which might originate from incorporated lignin‐derived structures, from the highly aliphatic and resistant biopolymer cutan and also from proteinaceous materials, were identified among the products produced from UDOM upon thermochemolysis. The presence of lignin derivatives in UDOM indicates input of organic matter derived from terrestrial sources. Various aromatic acids, perhaps representing the final steps in the oxidation of the side‐chain during microbial oxidation of lignin, were released upon TMAH thermochemolysis, suggesting they are structural constituents of the UDOM. Different ratios of lignin‐derived materials, commonly determined using the CuO oxidation method, such as the Δ value, indicative of the amount of lignin present, the acid/aldehyde ratio (Ad/Al)_G, indicative of the extent of oxidative degradation of the lignin component, and the syringyl/guaiacyl (S/G) and p‐hydroxyphenyl/guaiacyl (P/G) ratios, indicative of the contribution for the different types of lignin, were determined.     

Recursive evaluation of interaction forces and property matrices from unit-impulse response functions of unbounded medium based on balancing approximation

Starting from the unit-impulse response matrix of the unbounded medium, a discrete-time formulation permitting the recursive evaluation of the interaction forces and a continuous-time formulation yielding property matrices corresponding to a model with a finite number of degrees of freedom are discussed. This is achieved using the balancing approximation method which is easily automated, guarantees stability and leads to highly accurate results. © 1998 John Wiley & Sons Ltd.     

重力位能同震变化及其构造意义——以青藏高原地区为例

地震除了以地震波的形式释放能量之外,地震还会使地球产生永久变形,该变形将使重力位能产生变化.研究表明,地壳的重力位能的同震变化能够很好地揭示构造活动的拉张或挤压状态.本文首先基于球对称、非自转、弹性和各向同性（SNREI）地球的点源位错理论,提出了一种有效的计算重力位能的同震变化的方法,该方法不仅适用于剪切型地震,而且适用于拉张型地震;然后研究了青藏高原地区在1976—2013年间发生的地震对地壳重力位能的同震变化的影响.结果表明,青藏高原中部和西部的地震使得整个地壳的位能减小,而东部的地震使位能增大;位能的减小和增大对应了该地区构造活动的拉张和挤压状态;并且1999—2013年期间较1976—1998年期间地震对地壳重力位能的影响加剧.

     

寡-中营养型水体偶发性蓝藻水华的驱动因素分析——以南京方便水库为例

寡-中营养型水体中,虽然营养盐水平偏低,但仍会偶发性出现较为严重的蓝藻水华现象,其具体机制仍有待深入探索研究.本研究以偶发水华水体方便水库为例,通过历史数据分析和调查研究,探讨了其水华蓝藻的优势类群,并分析了蓝藻水华形成的主要驱动因素.研究发现:方便水库优势的水华蓝藻为浮丝藻和长孢藻,这两种丝状蓝藻是发生偶发性蓝藻水华的潜在风险物种,其中浮丝藻的发生风险最高,风险时段为7-9月.方便水库多年来营养盐浓度呈现下降的趋势,其中总氮浓度的下降趋势快于总磷浓度,整体有利于蓝藻水华的防控,但是营养盐的波动,尤其是随着降雨导致的地表径流入库对水体总磷的脉冲式补充,降低了水体氮磷比,增加了水库偶发蓝藻水华的风险;在营养盐满足的条件下,水温、高锰酸盐指数和氧化还原电位是发生浮丝藻水华的主要驱动因素,氧化还原电位、水温和透明度是发生长孢藻水华的主要驱动因素.本研究结果有助于提升对偶发性蓝藻水华机制的认识和应急处置工作的精准性.     

A contrast of two typical LUCC processes and their driving forces in oases of arid areas: A case study of Sangong River Watershed at the northern foot of Tianshan Mountains

Aerial photographs taken in 1978 and 1987, Landsat TM images in 1998 as well as soil, hydrology and socio-economic data for the oases in Sangong River Watershed were processed by Remote Sensing (RS) and Geographic Information System (GIS). There are two typical agricultural land uses in oases, Farm-based Land Use with large-scale intensified agricultural activities (FLU) and Household Responsibility-based Land Use with small-scale activities (HRLU). The Index Model of Land Use/Land Cover Change (LUCC), Weighted Index Sum (WIS) and logistic stepwise regression model were established to contrast the two typical LUCC processes and their driving forces. The land use patterns were dominated by cropland and grassland for the entire region, and cropland, residential and industrial land were increasing stably. In the HRLU areas, woodland and grassland declined dramatically, but in the FLU areas, grassland decreased only by 12.0%, whereas woodland increased by 13.7%. LUCC was stronger in the earlier stage (1978–1987) than in the later stage (1987–1998) for the entire region. LUCC was more intense in the HRLU areas than in the FLU areas during the entire period (1978–1998). Policy was a key factor in the land use change, and water resources were a precondition in land use. Under the control of policy and water resources, the main human driving factors included population and economy, and the main natural restrictions were soil fertility and groundwater depth. Human driving factors controlled the land change in the HRLU areas, but natural restriction factors dominated in the FLU areas. In the mean time, intensification of LUCC in the region had some spatiotemporal implications with a fluctuation of impact factors.     

Dissolved Organic Carbon Fractions Formed during Composting of Municipal Solid Waste: Properties and Significance

The properties and transformation of dissolved organic matter (DOM) extracted (10 L water per kilogram compost) from municipal solid waste (MSW) compost at five stages (days 47, 77, 105, 126, and 187) of composting were investigated. The DOM was fractionated into hydrophobic or hydrophilic neutrals, acids, and bases. The unfractionated DOM, the hydrophobic acids and neutrals (HoA and HoN, respectively), and the hydrophilic neutrals (HiN) fractions were studied using solid-state ¹³C-NMR, FTIR, and DRIFT spectroscopy. The HoA fraction was found to be the dominant (percentage of total DOM) hydrophobic fraction, exhibiting a moderate increase during composting. The HoN fraction increased sharply from less than 1% to 18% of the total DOM during 187 days of composting, while the hydrophobic bases (HoB) exhibited the opposite trend. The HiN represented the major fraction of the hydrophiles up to 120 days of composting, decreasing thereafter by 38%. The relative concentration of the hydrophilic acids and bases (HiA and HiB, respectively) exhibited no consistent trend during composting. DRIFT spectra of the unfractionated DOM taken from the composting MSW revealed a decreasing level of polysaccharide structures with time. The ¹³C-NMR and FTIR spectra of the HoA fraction exhibited a polyphenol-humic structure, whereas the HoN spectra exhibited strong aliphatic features. The spectra of the HiN fraction confirmed its polysaccharide nature. During the final stage of composting, the DOM concentration was steady, while a relative decrease of HiN concomitant with an increase of HoA and HoN fractions was observed. These indicate that the DOM contained a low concentration of biodegradable organic matter and a higher content of macromolecules related to humic substances. The biological significance and heavy metal binding of these fractions are being studied based on earlier observations showing enhanced plant growth in the presence of DOM extracted from mature as opposed to immature compost.     

Radiofluorescence of quartz: A review

Radiofluorescence (RF) is the luminescence emitted during exposure to ionizing radiation. Charged particles or high-energy photons can be used as stimulation sources, and different designs for measurement equipment have been published. Only few studies have successfully used the quartz RF signal for dosimetry and dating. However, RF is a valuable tool in deciphering charge trafficking in quartz crystals, and also provides information for identifying types of defects causing specific luminescence emissions. Based on models for charge transfer in quartz, RF is seen as resulting from direct recombination of electrons with holes captured in recombination centers (or vice versa) during ionizing irradiation. Competition between reservoir and luminescent centers explains the initial decay of the modeled RF curve followed by a steady rise and also the observed ‘pre-dose’ effect. Emission spectra have been found to be similar to thermoluminescence (TL) spectra, with prevalent emissions in the UV and further emissions for some samples in the blue-green and red range. The high intensity levels and the possibility of choosing longer accumulation times compared to TL and OSL are advantages of RF for spectral measurements. Relative peak intensities in the emission spectra change with dose and absolute intensities with dose rate. Investigating the RF signal with changing measurement temperature allows calculating physical parameters of individual emissions that control thermal quenching. The degree of thermal quenching varies between the emissions, with most intense quenching in the UV. Sensitization of RF by several orders of magnitude has been observed after annealing at 500 °C.     

The assessment of sediment sources: A field experiment

The possibility of using metals from mining activity as tracers for identifying stream sediment sources is explored. Sampling of monthly bed sediment yield and of the spatial and temporal variation in Pb concentration was undertaken in a 1·02 km² catchment, and estimates of the sediment contribution from different stream reaches are calculated. The method has considerable limitations, for metal concentrations are notably dependent on sediment size, season, source availability, and the chemical mobility of the metal used. In most natural streams these must preclude the use of pollutants for simple sediment source identification.     

Physics of fracturing and seismic energy release: A review

This review was prepared as an opening lecture for the International Symposium on Physics of Fracturing and Seismic Energy Release, held at the Castle of Liblice near Prague from October 28 to November 1, 1985, and organized by the Geophysical Institute of the Czechoslovak Academy of Sciences. The review attempts to classify and synthesize results of recent studies in fracture mechanics and earthquake source physics. The following topics are discussed: recent developments in fracture mechanics, earthquake source modeling, heterogeneous fault planes, foreshocks and aftershocks, faults and fractals, and moment tensor solutions. This rather broad range of topics prevents presentation of a complete list of all relevant works, though over one hundred and seventy references are cited.     

Quantifying preferential flow in soils: A review of different techniques

Preferential flow (PF) in soil has both environmental and human health implications since it favours contaminant transport to groundwater without interaction with the chemically and biologically reactive upper layer of soil. PF is, however, difficult to measure and quantify. This paper reviews laboratory and field techniques, such as breakthrough curves, dye tracing, and scanning techniques, for evaluating PF in soil at different scales. Advanced technologies, such as scanning techniques, have increased our capability to quantify transport processes within the soil with minimal soil disturbance. Important issues with respect to quantifying PF concern large-scale studies, frozen soil conditions, tracing techniques for particles and gases, a lack of simple mathematical tools for interpreting field data, and the lack of a systematic approach for comparing PF data resulting from different measurement techniques. Also, more research is required to quantify the relative importance of the various PF processes that occur in soil rather than the integrated result of all PF processes in soils.