Stress of urban energy consumption on air environment

With rapid urbanization and heavy industrialization as well as the rapid increase of cars in China, the effect of energy consumption on urban air environment is increasingly becoming serious, and has become a hot topic for both scholars and decision-makers. This paper explores the effect mechanism and regulation of urban energy consumption on the air environment, and summarizes the framework of the stress effect relationship and the evolutionary process. In accordance with the effect relationship of the internal factors between the two, analytic approaches studying the stress effect of urban energy consumption on air environment are proposed, including the analysis of air environment effects caused by urban energy consumption structure change, and the analysis of air environment effects caused by urban energy economic efficiency change, as well as a decomposition analysis of air pollutant emission caused by urban energy consumption. Applying the above-mentioned approaches into a case study on Beijing City, this paper analyzes the effect relationship among urban energy consumption structure improvement, energy economic efficiency increase and air quality change since the period when Beijing City officially proposed to bid for the 2008 Olympic Games in 1998. In addition, it further analyzes the effect and contribution of urban industrial activity level, industrial economic structure, industrial energy intensity, and industrial energy structure as well as emission coefficients on the change in industrial SO₂ emission, which can provide valuable information to the government for making comprehensive environmental policies, with the use of the logarithmic mean Divisia index (LMDI) method. It is shown that under the precondition that the industrial economy maintain a continuous and rapid increase, improvements in energy intensity and a decline in emission coefficients are the main means for reducing Beijing’s industrial SO₂ emissions.     

Some source and medium properties of the Vrancea seismic region, Romania

Simple spectral theory of seismic sources was used to determine source parameters directly related to medium properties (stress drop, seismic efficiency and fracture energy) and quality factors of the Vrancea (Romania) seismic region. The results show an increase in maximum static stress drop, maximum seismic efficiency and fracture energy with depth. The seismic efficiency is magnitude independent, but the stress drop is magnitude independent only for events with M_L > 3.8; below this value, the logarithm of stress drop increases quasi-linearly with magnitude. In the depth interval 50–160 km the stress drop increases with a slope of about 2–3 bar/km. The fracture energy per unit area of the fault has values of the order of 10⁵–10⁸ erg/cm².The frequency independent quality factors indicate that the attenuation of P waves is generally higher than that of S waves and that Q_p values are in agreement with recent tectonic models for the Vrancea region: total decoupling of the slab now sinking gravitationally is present only in the southwestern part of the Vrancea region, as suggested by the spatial position of intermediate depth hypocenters.     

Quality of chrysotile asbestos and high-temperature conductance of the host ultramafics: possible linkage

The paper reports physical, physicochemical, and mineralogical-petrographic studies of serpentinite samples from the Bazhenovo deposit of chrysotile asbestos. The samples differ in mineralogy, physical and physicochemical parameters, and in quality (fiber tenacity) of the hosted chrysotile asbestos. The experiments allowed estimating the temperature dependence of electrical resistance of serpentinites in a range of 20 to 800 °C, the parameters of their high-temperature resistance (the activation energy E₀ and the resistance coefficient lg R₀), and the relationship between fiber tenacity of asbestos and high-temperature conductance of the host serpentinites. The serpentinite samples that host brittle and tenacious chrysotile asbestos plot different fields in the coordinates E₀–lg R₀ without any overlap. Thus, the quality of chrysotile asbestos can be inferred from the parameters of high-temperature conductance of the host serpentinites.     

The asymmetric nexus of energy-growth and CO2 emissions: An empirical evidence based on hidden cointegration analysis

Noting the significance of asymmetries in macroeconomic literature, this study aimed to estimate the asymmetric linkages between energy growth and the environment for BRICST countries between 1990 & 2017. For this purpose, this study applied hidden cointegration, panel NARDL, and asymmetric causality tests between the variables. In the first step, the results supported the existence of hidden cointegration between the variables. In the next step, empirical results obtained from panel NARDL results explained that the chosen variables have asymmetric relationships and are highly responsive to macroeconomic shocks. Initially, the positive shocks of energy consumption positively respond to environmental degradation; similarly, the negative shocks also correspond positively to CO₂ emissions. In the economic expansion phase, the positive shocks of growth have insignificant, and adverse shocks negatively respond to CO₂ emissions in BRICST countries. The results of individual countries along BRICST differ at various levels in response to asymmetric shocks. Different asymmetric causalities between the chosen dimension of variables are explored. From the asymmetric associations between the variables, the study proposes to forecast the energy demand and explore alternative ways to energy resources to shift their fossil energy bases to renewable systems. Similarly, adopting ICT products could make energy efficiency in these countries more productive towards improving environmental quality.     

Shale gas fracturing using foam-based fracturing fluid: a review

World energy resources are depleting at an alarming rate, and natural gas has been identified as an environmentally friendly energy resource, with shale gas being one option. However, the extremely low permeability of shale plays has caused them to fail to produce a commercially viable amount of gas. Therefore, appropriate production enhancement techniques, including hydro-fracturing, are required. This paper reviews the research on shale gas production enhancement using foam-based hydro-fracturing and focuses on research on shale deposit distribution around the world, the importance of shale gas recovery, major shale gas recovery enhancement techniques, the effectiveness of foam-based fracturing depending on the foam type used and the formation properties, advantages and limitations of foam-based fracturing compared to other fluids, and existing experimental and numerical studies and field studies. According to the available experimental and modelling studies on foam fracturing, N₂-based foams are stronger than CO₂-based foams. The effective viscosity that controls the foam rheology decreases with increasing temperature and decreasing pressure and foam quality, and fracture length reduces and fracture width increases with increasing foam quality. Although this technique has been tested in few shale plays worldwide, most studies have been performed in the USA and Canada. Therefore, the foam fracturing technique is still comparatively novel for other countries around the world.     

Application of the strain energy to estimate the rock load in squeezing ground condition of Eamzade Hashem tunnel in Iran

Estimation of rock load is a very important issue because the selection of a support system is highly related to this parameter. Several methods are used to estimate this parameter such as experimental, empirical, and numerical methods. This study propose a new empirical method to estimate the rock load in squeezing ground condition using actual collapses data of Emamzade Hashem tunnel of Iran based on the ration of the post-failure residual strain energy to the pre-failure stored strain energy. Prediction of squeezing ground condition in this study is performed based on Jethwa, Singh, and Hoek criterions. Results show that some sections in shale and sandstone of the Shemshak formation are prone to squeezing. Finally, the relation between the rock load and the ratio of the post-failure residual strain energy to the pre-failure stored strain energy, Ψ, in squeezing ground condition is estimated. Based on the statistical analysis, the maximum correlation between both parameters is achieved when Alejano’s equations are used to estimate the drop modulus. As the rock mass behavior changes from elastic–plastic to elastic–brittle, the drop modulus changes from 0 to infinite. The reason is that by increasing the quality of rock mass and reducing the minimum principal stresses, the ratio of post-failure residual strain energy to pre-failure stored strain energy and rock load height (H _p) reduce. So, regression analysis is used to investigate the relation between the rock load height and the ratio of post-failure residual strain energy to pre-failure stored strain energy, and finally, a formulation is presented to determine rock load height based on power function.     

Groundwater and geothermal resources of Eritrea with the emphasis on their chemical quality

Available chemical analyses have been evaluated and a water quality map prepared using electrical conductivity values. The country has been divided into three water quality regions. The quality of each region is variously a combination of climate, geology, waste disposal and irrigation practices and salt water intrusion. Region 1 has the best water quality, though in the Asmara area the groundwater is polluted by nitrate (50–150 mg l⁻¹ NO₃). The impact on the natural environment due to the salinity hazard created by high evapotranspiration and irrigation practices becomes more pronounced across Region 2 and reaches a peak in the Red Sea catchments (Region 3), where it is supplemented by saline intrusion and mineralized upflows. In this region, soil fertility has been greatly affected and the development of groundwater has been constrained. Fluoride concentrations of 7–17 mg l⁻¹ are common in Regions 2 and 3 and some dental fluorosis has been noted.Upflows of thermal water (34–100°C) exist in the Red Sea coastal zone and provide a potential energy resource. Both these and the factors affecting water resource quality in general require careful investigation and conservation measures.     

The influence of the Tula,Hidalgo complex on the air quality of the Mexico City Metropolitan Area

Using an air quality model, this study shows how emissions from the “Miguel Hidalgo” refinery of Petróleos Mexicanos (Pemex) and the thermoelectric plant “Francisco Pérez Ríos” of the Comisión Federal de Electricidad (CFE, Federal Electricity Commission) in Tula, Hidalgo influence the atmosphere of the Mexico City Metropolitan Area (MCMA). The model couples meteorology and chemistry. The weather scenario encompasses the period from October 20-28, 2005. Two scenarios are compared: the first assumes a 40% reduction in emissions of NO_x, SO₂, and volatile organic compounds (VOCs) from the Tula complex (reduction scenario), and the second considers the scenario without reduction (baseline scenario). The model is compared with measurements of the Red Automática de Monitoreo Atmosférico (Automatic Environmental Monitoring Network). We observe that under certain weather conditions, the energy sector of Tula, Hidalgo affects the air quality in the MCMA. The reduction scenario is effective in reducing SO₂ concentrations; however, despite a 40% decrease in the emissions of ozone precursors, their concentrations in the MCMA did not decrease.     

Influence of energy efficiency on VOCs decomposition in non-thermal plasma reactor

In order to promote the plasma technology for commercial application and improve the energy efficiency of non-thermal plasma, a series of experiments on energy efficiency of plasma reactor were carried out for volatile organic compounds removal. This research adopts a pipe-line reaction device with plasma generated by dielectric barrier discharge technology to examine the effects of different experimental parameters, including medium packing, electric field strength, the pollutant initial concentration, and gas velocity, on the energy efficiency. In the study, four kinds of packed materials were packed into the plasma reactor: a complex catalyst, Ba_0.8Sr_0.2Zr_0.1Ti_0.9O₃, MnO₂/γ-Al₂O₃, and γ-Al₂O₃. Through optimizing the experimental parameters, the best decomposition efficiency of toluene and the best energy efficiency were achieved. The experimental results show that the energy efficiency has a trend from increasing to decreasing with increasing pollutant gas velocity, and the energy efficiency changes from increasing to decreasing with the increasing of initial concentration of pollutants, and the decomposition efficiency and the energy efficiency have the same order from high to low with different packed materials in the plasma reactors, in turn, packed with complex catalyst, Ba_0.8Sr_0.2Zr_0.1Ti_0.9O₃, MnO₂/γ-Al₂O₃, γ-Al₂O₃ and no padding. The optimized parameters for toluene decomposition are: the gas flow rate of 2 mL/min, the initial concentration range of 1500–2000 mg/m³, the field strength intensity of 9.6 kV/cm, and the plasma reactor packed with a complex catalyst, which results in the best energy efficiency of 10 g/kWh. This research provides not only a new way to develop the plasma technology, but also a reference for the commercial application.     

Charge – transfer energy in computer modeling of structure and properties of minerals

As is known, a variable parameter for partial ionicity is often involved in the techniques of modeling structure and properties of inorganic crystals by energy-minimization methods. In such a case, to make a calculated energy comparable to experimental estimate (atomization energy) there is a need to involve an intraatomic energy term, the so-called charge-transfer energy (Urusov and Eremin 1995). For this purpose a set of charge-transfer energies for valence states of many elements is compiled. The procedure based on aspiration of equalizing the electronic levels electronegativities is proposed to estimate the total contribution of the charge-transfer energy in the cohesive energy of a crystal. The other prescribed quantities are repulsive potential parameters which are related to the energetic propertis of valence shells of bonded atoms. The final potential function consists of an effective Coulomb attraction, repulsion and covalent Morse type term, properly weighted. The energy-minimization procedure is performed for various values of the ionicity degree parameter of the crystal under study. Thereafter the charge-transfer energy correction is introduced in order for the cohesive energy calculations to be made. The calculations of structure, energy and elastic properties were performed using the METAPOCS code with ionicity variation for halides (NaCl, CaF₂), oxides (MgO, Al₂O₃, SiO₂ quartz and SnO₂), sulphide ZnS and silicate CaSnSiO₅. The resulting cohesive energies usually agree with experiment much better than those calculated in pure ionic or covalent approximations. As to elastic properties of crystals under consideration, they are generally functions of the ionicity parameter too and in most instances the predicted properties at intermediate values of the ionicity degree are in a satisfactory accordance with experimental data.     

Computation of surface energies in an electrostatic point charge model: I. Theory

The attachment energies, the slice energies and the specific surface energies can be calculated in an electrostatic point charge model using the formula derived by Madelung for the potential introduced by an infinite row of equally spaced point charges. Power series are given for the Hankel function iH ₍₀₎ ⁽¹⁾ (iy) and Ψ(x)=d ln x!/dx. The logarithmic expression in the Madelung formula converges rapidly when applying a power series, which combines equally charged cations and anions. Besides the specific surface energy (γ ^hkl), the slice energy (E _s ^hkl ) and the attachment energy (E _a ^hkl ) can be considered as special categories of surface energies as they depend on surface configurations as well. The specific surface energy γ is the energy per unit area of surface needed to split the crystal parallel to a face (hkl). The attachment energy (E _a) is the energy released per mole, when a new slice of thickness d _hkl crystallizes on an already existing crystal face (hkl). The growth rate of the crystal face (hkl) is a function of its attachment energy. The slice energy (E _s) is the energy released per mole, when a new slice d _hkl is formed from the vapour neglecting the influence of edge energies. The lattice energy (E _c) which is the energy released per mole of a crystal crystallizing from the vapour, is given by the following relation: E _c=E _a+E _s.     

Strategies for addressing climate change on the industrial level: affecting factors to CO<Subscript>2</Subscript> emissions of energy-intensive industries in China

This paper explores China’s strategies for addressing climate change on the industrial level. Focusing on six energy-intensive industries, this paper applies gray relational analysis theory to the affecting factors to CO₂ emissions of each industry after calculating each industry’s CO₂ emissions during 2001–2010. Further research based on GM(1, 1) model is conducted to forecast the trend of the factors, the energy consumption and each industry’s CO₂ emissions during the 12th Five-Year Plan period. As a breakthrough in previous conclusions, energy consumption structure was divided into the respective proportion of coal, oil, natural gas and electricity in the primary energy consumption, with which industrial output and energy intensity are combined to analyze each of their impacts on the energy-intensive industries. It turns out that all the factors’ impacts on emissions of the six major energy-intensive industries are significant, despite their differentiated extents. It is worth noting that, contrary to previous findings, industrial output is not the leading affecting factor to CO₂ emissions of the energy-intensive industries compared with the proportion of coal and electricity in the primary energy consumption. The GM(1, 1) forecast results of energy consumption and CO₂ emissions by the end of 2015 show that coal and electricity will remain a large proportion in primary energy consumption. This research may shed some light on China’s adjustment of energy structure under the pressure of addressing climate change and hence provide decision support for the acceleration of renewable energy utilization in the industrial departments.     

Computation of surface energies in an electrostatic point charge model: II. Application to zircon (ZrSiO4)

The attachment energies, the slice energies and the specific surface energies can be calculated in an electrostatic point charge model using the formula derived by Madelung for the potential introduced by an infinite row of equally spaced point charges. Power series are given for the Hankel function iH ₍₀₎ ⁽¹⁾ (iy) and (x)=d ln x!/dx. The logarithmic expression in the Madelung formula converges rapidly when applying a power series, which combines equally charged cations and anions. Besides the specific surface energy ( ^hkl), the slice energy (E _s ^hkl ) and the attachment energy (E _a ^hkl ) can be considered as special categories of surface energies as they depend on surface configurations as well. The specific surface energy is the energy per unit area of surface needed to split the crystal parallel to a face (hkl). The attachment energy (E _a) is the energy released per mole, when a new slice of thickness d _hkl crystallizes on an already existing crystal face (hkl). The growth rate of the crystal face (hkl) is a function of its attachment energy. The slice energy (E _s) is the energy released per mole, when a new slice d _hkl is formed from the vapour neglecting the influence of edge energies. The lattice energy (E _c) which is the energy released per mole of a crystal crystallizing from the vapour, is given by the following relation: E _c=E _a+E _s.     

Heavy-ion irradiation on crystallographically oriented cordierite and the conversion of molecular CO2 to CO: a Raman spectroscopic study

Crystallographically oriented sections of natural gemstone quality cordierite single-crystals have been irradiated with swift heavy ions of GeV energy and various fluences. Irradiation effects on the crystal lattice were investigated by means of Raman spectroscopy. Raman line scans along the trajectory of the ions reveal a close correlation of beam parameters (such as fluence and energy loss dE/dx along the ion path) to strain due to associated changes in lattice dimensions and defect concentration. The luminescence background also scales with the ion fluence and suggests the formation of point defects, which could also account for the macroscopically observable colouration of the irradiated samples. In addition, changes in the amount and nature of volatile species inside the structural channels are observed. They also scale with dE/dx and confirm the previously postulated irradiation-induced conversion of CO₂ to CO. Irradiations along the crystallographic a-, b- and c-axis reveal no significant anisotropy effect with respect to lattice alterations. The polarisation characteristics of the Raman-active modes confirm the preferred molecular alignment of CO and CO₂ along the a-axis direction.     

Evaluation of water quality and protection strategies of water resources in arid–semiarid climates: a case study in the Yuxi River Valley of Northern Shaanxi Province, China

Water resource structure is one of the most important factors that constrain the economic development in arid–semiarid areas. Sustainable use of water requires a thorough understanding of the local geology and hydrology and developing of effective protection strategies. Discussed in this paper is a study on the phreatic water quality of the Yuxi River Valley of Shaanxi Province, China. The Yuxi River Valley passes through the Shaanbei energy base, which demands large quantities of high-quality water. A total of 129 water samples were collected in 4,938 km² in a recent study to delineate the areas with water suitable for drinking, industrial, and agricultural usage and areas with poor quality. The study indicates that the poor quality of water contains high concentrations of NH⁴⁺ and NO₂⁻¹, indicating possible contamination by waste disposal in the nearby cities and towns. A series of strategies are proposed to protect the water in the Yuxi River Valley, including proper treatment and recycling of the waste water in the cities and towns, strict control of the waste-water discharge from any new factories and mines, and prevention of groundwater contamination by wastes containing heavy metals.     

A quantum-chemical model of calculating the bond energy of crystals

A model has been obtained from a strict expression of crystal energy by introducing S and valence approximations. The Mulliken approximation has been used for double-centered exchange and three-center integrals. The calculations have been carried out for Slater type atomic orbitals, varying the screening parameters. The bond energy has been represented as a sum of the energy for forming partial differential electronic densities, E _A, the interatomic interaction energy E _IA, and the correlation energy of atomic states in the crystal, E _S . The computed bond energies for four oxides of alkaline-earth metals and six oxides of transition (iron group) metals are in good agreement with experimental data.     

Calculation of subsolidus phase relations in carbonates and pyroxenes

This formulation of the free energy of mixing in a binary system takes as parameters a Bragg-Williams type cooperative disordering energy and the difference in free energy between different structures for the end-members. Subsolidus phase relations in carbonate systems such as CaCO₃—MgCO₃ and CdCO₃—MgCO₃ are calculated. Similar equations also reproduce the topologies of subsolidus phase relations in pyroxenes, including orthopyroxene-clinopyroxene phase boundaries in the enstatitediopside and ferrosilite-hedenbergite systems, the pigeonite-augite solvus, and the stability field of iron-free pigeonite.     

Strength characteristics of compacted pond ash

Strength properties of compacted ash layers depend to a great extent on the moulding conditions. This paper focuses on the effects of compaction energy and degree of saturation on strength characteristics of compacted pond ash. The pond ash sample, collected from the ash pond of Rourkela Steel Plant (RSP), was subjected to compactive energies varying from 357 kJ/m³ to 3488 kJ/m³. The optimum moisture content and maximum dry densities corresponding to different compactive energies were determined by conventional compaction tests. The shear strength parameters, unconfined compressive strengths (UCS) and California bearing ratio (CBR) values of specimens compacted to different dry densities and moisture content were assessed and reported. The effects of compaction energy and degree of saturation on shear strength parameters i.e. unit cohesion (c_u) and angle of internal friction (Ф) values and also the UCS values are evaluated and presented herein. The results indicate that the dry density and strength of the compacted pond ash can be suitably modified by controlling the compactive energy and moulding moisture content. The strength achieved in the present study is comparable to the good quality, similar graded conventional earth materials. Hence, it may be safely concluded that pond ash can replace the natural earth materials in geotechnical constructions.     

Changing climate and human response: The impact of recent events on climatology

Over the last decade climate has become an increasingly significant factor in world affairs because of its effect on food supplies, energy consumption and environmental quality. At the same time the scientific community has had to re-appraise the nature and scope of climatology, increasing political relevance, leading to a growth in interdisciplinary activity involving both natural and social scientists. The 1980s promise to continue this broadening of scope as the two-way interaction of human societies and the atmospheric system are further explored and evaluated. This paper examines these trends, paying particular reference to the main climate-based environmental concerns currently being debated: the effect of halocarbons on the ozone shield, climate and food production, desertification, the CO₂ ‘greenhouse’ effect, acid rain and the significance of teleconnections.     

Decomposing the changes of energy-related carbon emissions in China: evidence from the PDA approach

In order to investigate the main drivers of CO₂ emissions changes in China during the 11th Five-Year Plan period (2006–2010) and seek the main ways to reduce CO₂ emissions, we decompose the changes of energy-related CO₂ emissions using the production-theoretical decomposition analysis approach. The results indicate that, first, economic growth and energy consumption are the two main drivers of CO₂ emissions increase during the sample period; particularly in the northern coastal, northwest and central regions, where tremendous coal resources are consumed, the driving effect of their energy consumption on CO₂ emissions appears fairly evident. Second, the improvement of carbon abatement technology and the reduction in energy intensity play significant roles in curbing carbon emissions, and comparatively the effect of carbon abatement technology proves more significant. Third, energy use technical efficiency, energy use technology and carbon abatement technical efficiency have only slight influence on CO₂ emissions overall. In the end, we put forward some policy recommendations for China’s government to reduce CO₂ emissions intensity in the future.