Heat flow and heat generation in the Churchill Province of the Canadian Shield, and their palaeotectonic significance

Six new heat flow determinations are presented for Proterozoic mobile belts of the Churchill Province of the Canadian Shield, an area that was affected by several stages of the Hudsonian orogenic sequence (1.9-1.6 Ga ago). With other, previously published, values the mean of eight determinations considered reliable and representative and corrected for the effects of Pleistocene glaciation is 44 ± 7 mW m⁻². Heat generation measurements have also been made; values range from 0.1–1.04 μW m⁻³.A linear relation between heat flow and heat production is apparent. The heat flow axis intercept is 37 mW m⁻², and the scale depth is 11 km, compared with 28 mW m⁻² and 13.6 km for the Archaean Superior Province. Approximately 20% of the Churchill heat flow appears to be derived from radioactive decay in the upper crust, compared with 30% for the Superior Province and shields as a whole. The observations imply that the heat flow-heat production relation for the Churchill Province should be written as Q = Q_c + Q_e + A₀b where Q_c is equivalent to the reduced heat flow for the Archaean terrain, b is similar for the two, and Q_e is an additional component of heat flow in the Proterozoic mobile belts of the Churchill Province.A speculative tectonic model is presented. It is suggested that rifting along two axes of an original craton, which had lateral variations in near surface radiogenic element concentration, followed by erosion of the radiogenic layer and subsequent reconvergence of the cratonic segments, led to widespread redistribution of radioactive elements into the reactivated inter-rift crustal block. One result would be that crustal temperatures are higher in that part of the Churchill Province than in the Superior.     

The variability of heat flow both regional and with depth in southern Alberta, Canada: Effect of groundwater flow?

Detailed studies of terrestrial heat flow in southern and central Alberta estimated on the basis of an order of magnitude larger data base than ever used before (33653 bottom-hole temperature data from 18711 wells) and thermal conductivity values based on detailed rock studies and measured rock conductivities show significant regional and local variations and variations with depth. Heat flow values were estimated for each 3 × 3 township/range area (28.8 × 28.8 km). A difference in heat flow exists between Paleozoic and Mesozoic strata. Generally lower heat flow values are observed in the strata above the Paleozoic erosional surface (20–75 mW m⁻²). Much higher values are estimated for the Younger Paleozoic formations, with large local and regional variations between 40 and 100 mW m⁻².Average heat flow values based on heat flow determinations below and above the Paleozoic surface that agree within 20% show an increase from values less than 40 mW m⁻² in southern and southwestern Alberta to values as high as 70 mW m⁻² in central Alberta. The predominance of regional downward groundwater flows in Mesozoic strata seem to be responsible for the generally observed heat flow increase with depth.The results show that the basin heat flow pattern is influenced by water movement and even careful detailed heat flow measurements will not give correct values of background steady-state heat flow within the sedimentary strata.     

Temperature-depth profiles in Czechoslovakia and some adjacent areas derived from heat-flow measurements, deep seismic sounding and other geophysical data

The results of seismic measurements along three deep seismic sounding (DSS) profiles on the territory of Czechoslovakia and in adjacent countries have provided sufficient material about the crustal structure and the depth of the Moho discontinuity. These data, together with gravity and aeromagnetic data and the determinations of heat-flow values, were used to select several locations where the temperature—depth profiles were calculated. The Moho temperature of about 500 C beneath the Bohemian Massif increases to 800–1000 C and even more beneath the inner Neogene depressions of the Carpathian system. The regional differences in mantle heat-flow contribution between both these provinces may reach 1 μcal. cm⁻² sec⁻¹; such a variation in energy inflow may then be the driving force for the geological evolution. The geophysical implications of different thermal structure of the crust are discussed. Because of high subsurface temperatures in the Hungarian basin, partial melting at a depth of about 30 km may not be excluded.     

High-temperature flow of wet polycrystalline enstatite

Previous experiments by Raleigh et al. (1971) have shown that at strain rates of 10⁻².sec⁻¹ to 10⁻⁷.sec⁻¹ only slip occurs in dry enstatite at temperatures above 1300°C and 1000°C, respectively.The present experiments have been conducted on polycrystalline enstatite under wet conditions in this regime where enstatite only slips, polygonizes and recrystallizes. Slip occurs throughout the whole regime on the system (100)[001] and at strains greater than 40% the system (010)[001] is observed. Polygonization and intragranular recrystallization begin at about 1300°C and 10⁻⁴.sec⁻¹ and the orientation of these neoblasts is host-controlled. At lower strain rates intergranular neoblasts develop and their fabric is one of [100] maximum parallel with σ₁ and [010] and [001] girdles in the σ₂ = σ₃ plane, similar to those in natural enstatite tectonites.Dislocation substructures of experimentally deformed enstatite have been examined by transmission electron microscopy. The samples were deformed within the field in which slip polygonization and recrystallization are the dominant deformation mechanisms. Samples within this regime have microstructures that are characterized by stacking faults and partial dislocations. Under the conditions of steady-state flow in olivine, these microstructures inhibit the operation of recovery mechanisms in enstatite.Other samples deformed within the polygonization and recrystallization field have microstructures that confirm the optical observations of intragranular and intergranular growth of neoblasts. It is suggested that the former result from strain-induced tilt of subrains, whereas the latter may result from bulge nucleation into adjacent subgrains.Mechanical data from constant strain-rate experiments at steady state, stress relaxation and temperature-differential creep tests are best fit to a power-law creep equation with the stress exponent, n~3 and the apparent activation energy for creep, Q~65 kcal/mole. Extrapolation of this equation to a representative natural geologic strain rate of 10⁻⁴. sec⁻¹, over the temperature interval 1000–2000°C, gives an effective viscosity range of 10²⁰–10¹⁸ poise and stresses in the range of 7-0.1 bar, respectively. Comparison with corrected wet-olivine mechanical data (Carter, 1976) over the same environment indicates that olivine is consistently the weaker of the two minerals and will recrystallize whilst enstatite will only slip and kink, thus accounting for the different habits of olivine and enstatite in ultramafic tectonites.     

Stable carbon isotope compositions and source rock geochemistry of the giant gas accumulations in the Ordos Basin, China

Ordos Basin, the second largest sedimentary basin in China, contains enormous natural gas resources. Each of the four giant gas fields discovered so far in this basin (i.e., Sulige, Yulin, Wushenqi and Jingbian) has over 100 billion cubic meters (bcm) or 3.53 trillion cubic feet (tcf) of proven gas reserves. This study examines the stable carbon isotope data of 125 gas samples collected from the four giant gas fields in the Ordos Basin. Source rocks in the Upper Paleozoic coal measures are suggested by the generally high δ¹³C values of C₁–C₄ gaseous hydrocarbons in the gases from the Sulige, Yulin and Wushenqi gas fields. While the δ¹³C_iC4 value is higher than that of the δ¹³C_nC4, the dominant ranges for the δ¹³C₁, δ¹³C₂, and δ¹³C₃ values in these Upper Paleozoic reservoired gases are −34 to −32‰, −27 to −23‰, and −25 to −24‰, respectively. The δ¹³C values of methane, benzene and toluene in gases from the Lower Paleozoic reservoirs of the Jingbian field indicate a significant contribution from humic source rocks, as they are similar to those in the Upper Paleozoic reservoirs of the Sulige, Yulin and Wushenqi gas fields. However, the wide variation and reversal in the δ¹³C₁, δ¹³C₂ and δ¹³C₃ values in the Jinbian gases cannot be explained using a single source scenario, thus the gases were likely derived dominantly from the Carboniferous-Permian coal measures with some contribution from the carbonates in the Lower Permian Taiyuan Formation. The gas isotope data and extremely low total organic carbon contents (<0.2% TOC) suggest that the Ordovician Majiagou Formation carbonates are unlikely to be a significant gas source rock, thus almost all of the economic gas accumulations in the Ordos Basin were derived from Upper Paleozoic source rocks.     

Intrinsic and scattering attenuation in western India from aftershocks of the 26 January, 2001 Kachchh earthquake

176 vertical-component, short period observations from aftershocks of the M_w 7.7, 26 January, 2001 Kachchh earthquake are used to estimate seismic wave attenuation in western India using uniform and two layer models. The magnitudes (M_w) of the earthquakes are less than 4.5, with depths less than 46 km and hypocentral distances up to 110 km. The studied frequencies are between 1 and 30 Hz. Two seismic wave attenuation factors, intrinsic absorption (Q_i^− 1) and scattering attenuation (Q_s^− 1) are estimated using the Multiple Lapse Time Window method which compares time integrated seismic wave energies with synthetic coda wave envelopes for a multiple isotropic scattering model. We first assume spatial uniformity of Q_i^− 1, Q_s^− 1 and S wave velocity (β). A second approach extends the multiple scattering hypothesis to media consisting of several layers characterized by vertically varying scattering coefficient (g), intrinsic absorption strength (h), density of the media (ρ) and shear wave velocity structure. The predicted coda envelopes are computed using Monte Carlo simulation. Results show that, under the assumption of spatial uniformity, scattering attenuation is greater than intrinsic absorption only for the lowest frequency band (1 to 2 Hz), whereas intrinsic absorption is predominant in the attenuation process at higher frequencies (2 to 30 Hz). The values of Q obtained range from Q_t = 118, Q_i = 246 and Q_s = 227 at 1.5 Hz to Q_t ≈ 4000, Q_i ≈ 4600 and Q_s ≈ 33,300 at 28 Hz center frequencies, being Q_t^− 1 a measure of total attenuation. Results also show that Q_i^− 1, Q_s^− 1 and Q_t^− 1 decrease proportional to f^−ν. Two rates of decay are clearly observed for the low (1 to 6 Hz) and high (6 to 30 Hz) frequency ranges. Values of ν are estimated as 2.07 ± 0.05 and 0.44 ± 0.09 for total attenuation, 1.52 ± 0.21 and 0.48 ± 0.09 for intrinsic absorption and 3.63 ± 0.07 and 0.06 ± 0.08 for scattering attenuation for the low and high frequency ranges, respectively. Despite the lower resolution in deriving the attenuation parameters for a two layered crust, we find that scattering attenuation is comparable to or smaller than the intrinsic absorption in the crust whereas intrinsic absorption dominates in the mantle. Also, for a crustal layer of thickness 42 km, intrinsic absorption and scattering estimates in the crust are lower and greater than those of the mantle, respectively.     

The heat field of petroliferous regions of Ciscaucasia

Heat-flow values at 34 new sites have been calculated on the basis of heat-conductivity data for the territory of Ciscaucasia. By adding previous data, the total number of heat-flow determinations is 150, and the overall spread of its values is from 0.65 to 3. 38 μ cal/cm₂/sec.

Principal features of heat-flow distribution in Ciscaucasia result from a clear association between the geothermal parameters and the geologic-tectonic structure of the region. The overall pattern in heat-flow distribution is the universal distrotion of the heat field by anticlinal structures associated with oil and gas fields.

The values for heat generation in the crust and the subcrustal layers of the principal tectonic structures of Ciscaucasia have been assessed on the basis of content of radioactive elements. Intense subcrustal heat sources are not r e quired for the formation of hydrocarbons in the crust and their subsequent transformation. Moreover, crustal energy for achieving these processes is completely adequate, such as, for instance, occurs in the marginal foredeeps.—Author.     

Terrestrial heat flow around the aseismic front of the Japanese Island Arc

Very few data on heat flow are available in the area around the aseismic front of the Japanese Islands. In order to remedy this situation, measurements of the terrestrial heat flow were made at three locations in the eastern part of Fukushima Prefecture, northeastern Honshu, Japan. The observed values of heat flow were 37 mW/m² (0.88 μcal/cm²·s) at Soma, 52 mW/m² (1.25 μcal/cm²·s) at Kashima and 19 mW/m² (0.46 μcal/cm²·s) at Naraha, respectively. These data partially fill the gaps in the terrestrial heat flow data on land in northeastern Honshu, Japan. These values are considerably lower than the average heat flow over the world, but agree well with the previous estimation for the area.     

Micro-FTIR spectroscopy of liptinite macerals in coal

Reflectance FTIR microspectroscopy has been used to investigate the chemical structure of the liptinite macerals, alginite, bituminite, sporinite, cutinite and resinite in bituminous coals of Carboniferous to Tertiary age. In comparison with the spectra of vitrinite in the same coals, the micro-FTIR spectra of liptinite macerals are characterized by stronger aliphatic CH_x absorptions at 3000–2800 and 1460–1450 cm⁻¹, less intense aromatic C=C ring stretching vibration and aromatic CH out of plane deformation at 1610–1560 and 900–700 cm⁻¹ respectively and various intense acid C=O group absorptions at 1740–1700 cm⁻¹. The peaks at 1000–900 cm⁻¹ due to aliphatic CH₂ wagging vibrations in olefins and at 730–720 cm⁻¹ due to CH₂ rocking vibration in long chain aliphatic substances ([CH₂]_n, n≥4), are characteristic of liptinite macerals. Collectively the micro-FTIR spectral characteristics indicate that liptinite is composed of greater numbers of long chain aliphatics, fewer aromatics and a broader range of oxygen-containing groups than other macerals. Marked differences exist in micro-FTIR spectra within the liptinite maceral group. Alginite has the strongest aliphatic and least aromatic absorptions followed by bituminite, resinite, cutinite and sporinite. The aliphatic components in alginite are the longest chained and least branched whereas those in sporinite are the shortest chained and most branched. Bituminite, resinite and cutinite are intermediate. Notable differences in micro-FTIR spectra of individual liptinite macerals, such as intensities and peak locations of aromatic C=C in alginite, C=O groups in bituminite and resinite and substituted aromatic CH and C–O–C groups in cutinite and sporinite, also exist, which are attributed to differences in depositional environments or biotaxonomy.     

Contribution to the thermal regime of the Provençal Basin based on Flumed heat flow surveys and previous investigations

We present original heat flow determinations carried out during the Flumed surveys by the CEPM along three transects of the Provençal Basin (Gulf of Lions-West Sardinia; Toulon-Ajaccio; Nice-Calvi). A total of 121 thermal gradients and 37 conductivities are examined together with previous heat flow determinations along depth sections based on previous geophysical investigations. The mean observed heat flows are clearly shown to increase from NW to SE along the profiles (expect for the Toulon-Calvi transect, where results are ambiguous). The observed heat flow increases from 55–65 mW m⁻² (Gulf of Lions) to 85 ± 14 mW m⁻² (West Sardinia) and from 55–65 mW m⁻² (Var Basin) to 103–108 mW m⁻² (lower Corsican margin), suggesting an asymmetrical distribution of the observed heat flow. We examine whether this asymmetry could be caused by thermal refraction above salt structures or by any other superficial cause (sedimentation, topography, etc.) and conclude that an asymmetrical distribution of the subcrustal heat flow is probably the cause of this thermal regime. The elevated heat flows observed to the east in the abyssal plain, corrected for sedimentation, cannot be accounted for by the standard age/heat flow relations established for oceanic or attenuated continental lithosphere. The geodynamic significance of this speculative subcrustal origin remains poorly constrained, but could be related to post-rifting magmatic activity. Further investigations are necessary to elucidate the apparent high local variability of the heat flow on the upper margin of the Gulf of Lions and on the Provençal margin of the Ligurian Sea.     

Attenuation of shear-waves in the back-arc region of the Hellenic arc for frequencies from 0.6 to 16 Hz

Q_β for shear-waves is determined for the inner part of the Hellenic arc, the back-arc area, as a function of frequency in the range 0.6–16 Hz. We used 314 digital records from 32 earthquakes with magnitudes (M_w) ranging from 3.9 to 5.1. Epicentral distances ranged from 65 to 515 km. The data were obtained in 1997 during a 6-month operation of a digital portable network in Greece. The Q_β estimates were made for five frequency bands centred at 0.8, 1.5, 3.0, 6.0 and 12.0 Hz and the Q_β values obtained were 47, 79, 143, 271 and 553, respectively. The results show that Q_β for S-waves increases with frequency taking the form Q_β=55f ^0.91 (or Q_β⁻¹0.018f^−0.91). The high attenuation and the strong frequency dependence found, which is close to the frequency dependence of coda Q for Greece, are characteristic of an area with high seismicity, rapid extension, and in agreement with other similar studies in Greece.     

U–Pb SHRIMP zircon geochronology and T–t–d history of the Kampa Dome, southern Tibet

Structural, petrographic and geochronologic studies of the Kampa Dome provide insights into the tectonothermal evolution of orogenic crust exposed in the North Himalayan gneiss domes of southern Tibet. U–Pb ion microprobe dating of zircons from granite gneiss exposed at the deepest levels within the dome yields concordia ²⁰⁶Pb/²³⁸U age populations of 506 ± 3 Ma and 527 ± 6 Ma, with no evidence of new zircon growth during Himalayan orogenesis. However, the granite contains penetrative deformation fabrics that are also preserved in the overlying Paleozoic strata, implying that the Kampa granite is a Cambrian pluton that was strongly deformed and metamorphosed during Himalayan orogenesis. Zircons from deformed leucogranite sills that cross-cut Paleozoic metasedimentary rocks yield concordant Cambrian ages from oscillatory zoned cores and discordant ages ranging from ca. 491–32 Ma in metamict grains. Since these leucogranites clearly post-date the metasedimentary rocks they intrude, the zircons are interpreted as xenocrysts that are probably derived from the Kampa granite. The Kampa Dome formed via a series of progressive orogenic events including regional ~ N–S contraction and related crustal thickening (D₁), predominately top-to-N ductile shearing and crustal extension (D₂), top-to-N brittle–ductile faulting and related folding on the north limb of the dome, localized top-to-S faulting on the southern limb of the dome, and crustal doming (D₃), and continued N–S contraction, E–W extension and doming (D₄). Structural and geochronologic variability amongst adjacent North Himalayan gneiss domes may reflect changes in the magnitude of crustal exhumation along the North Himalayan antiform, possibly relating to differences in the mid-crustal geometry of the exhuming fault systems.     

Continuity of the North Qilian and North Qinling orogenic belts, Central Orogenic System of China: Evidence from newly discovered Paleozoic adakitic rocks

Adakitic intrusive rocks of  430–450 Ma were discovered in the North Qilian orogenic belt, the western section of the Central Orogenic System (COS) in China. These adakitic rocks were lower crust melts rather than slab melts as indicated by their crustal Ce/Pb, Nb/U, Ti/Eu, and Nd/Sm ratios and radiogenically enriched (⁸⁷Sr/⁸⁶Sr)_i of 0.7053–0.7066 and ε_Nd(t) of − 0.9 to − 1.7. While they are all characterized by low Yb (< 1.1 ppm) and Y (< 11.5 ppm) abundances with high Sr/Y (> 65) and (La/Yb)_N (> 13.7) ratios, these adakitic rocks are classified into the low-MgO–Ni–Cr and high-MgO–Ni–Cr groups. The low-MgO samples were derived from partial melting of thickened lower crust, whereas the high-MgO samples were melts from delaminated lower crust, which subsequently interacted with mantle peridotite upon ascent. Adakitic rocks from the adjacent North Qinling orogenic belt also originated from thickened lower crust at  430 Ma. In addition, the North Qilian and North Qinling orogenic belts both consist of lithological assemblages varying from subduction-accretionary complexes at south to central arc assemblages, which include adakitic rocks, then to backarc phases at north. Such a sequence reflects northward subduction of the Qilian and Qinling oceans. In these two orogenic belts, the occurrence of adakitic rocks of common origin and ages together with the similarities in tectonic configurations and lithological assemblages are considered to be the evidence for the continuity between eastern Qilian and western Qinling, forming a > 1000 km Early Paleozoic orogenic belt. In such a tectonic configuration, the Qilian and Qinling oceans that subducted from south possibly represent parts of the large “Proto-Tethyan Ocean”. This inference is supported by the coexistence of Early Paleozoic coral and trilobite specimens from Asia, America and Australia in the North Qilian orogenic belt. Post-400 Ma volcanic rocks occur in the North Qinling orogenic belt but are absent in the North Qilian orogenic belt, indicating that these two orogenic belts underwent distinct evolution history after the closure of the Proto-Tethyan Ocean ( 420 Ma).     

Water movement within lac du bonnet batholith as revealed by detailed thermal studies of three closely-spaced boreholes

Successive temperature logs have been obtained over a period of two years in three closely-spaced boreholes in the Lac du Bonnet batholith of the Superior Province of the Canadian Shield. Two of the boreholes, of depth 450 m and 830 m, intersect a dipping fracture zone at 435–450 m. In both holes water is flowing from near the surface to the fracture zone at approximately 1.5–1.9·10⁻⁵ m³ s⁻¹, the flow being inferred from analysis of the temperature logs. Below 25 m, temperatures in these two holes are 0.22–0.28 K lower than those in the third, 145 m, hole.The temperature data have been combined with over 200 thermal conductivity measurements on core samples to produce heat flow values. In the deepest hole heat flow above the fracture zone is 16% higher than that below the zone. This indicates that water is flowing up the fracture zone. The flow rate is approximately 0.3 g s⁻¹ m⁻¹, and the flow has existed for thousands of years.Observation of thermal effects of water flow in massive, relatively unfractured plutons in a region having little topographic relief causes one to be concerned about the reliability of heat flow values measured in similar environments.The regional heat flow is taken to be 50 mW m⁻² after correction for glaciation effects. The average value of 24 determinations of radioactive heat generation in granitic core samples is 5.23 ± 1.11 μW m⁻³, which is more than three times higher than expected for such a heat flow in the Superior Province. This implies that the layer of high radioactive heat generation is thin, being not more than 4 km and probably about 1.3 km thick.     

Relative stress variations as determined by b-values from earthquakes in circum-pacific subduction zones

Assuming a relation of “b” to stress state, the possibility of globe-wide stress variation and transmission was investigated. The NOAA earthquake data file served to determine the temporal change in “b” of log N = a − bM from 1963 to 1975.Periods of six to eight years are observed in the b-values (stress pattern) for most circum-Pacific areas (South America, Tonga, Kermadec, New Hebrides, Kamchatka and Eastern Aleutians).In the Kurils, fore- and aftershock sequences of large earthquakes seem to mask any characteristic global pattern that might exist. These sequences exhibit low b-values (high stress) through the time of foreshocks and early stages of aftershocks, followed by rapid increase in b-values (decrease in stress).Use of a worldwide earthquake data file clearly yields less resolution of the temporal “b” variation than the use of local network studies published by other authors.Incidental to the study, 1124 earthquakes of the NOAA data file yield the M_s − m_b relations: M_s = 1.16m_b − 0.835 for 4.5 m_b 6 and: log₁₀M_s = 0.1432m_b − 0.0629 form_b > 6 with correlative coefficients of 0.994 and 0.992 respectively.     

Evidence for lithospheric detachment in the central Andes from local earthquake tomography

Data from three temporary seismic networks were merged for tomographic inversion. Although the deployments did not coincide in time, spatial overlap was achieved by re-occupying existing sites. Travel times and t operators of about 1600 earthquakes were inverted for 3D models of ν_p, ν_p/ν_s and P-wave attenuation (Q_p^− 1). All three attributes provide a consistent image of the entire subduction zone on a lithospheric scale. The tomographic images reveal low velocities and high attenuation in the crust and mantle underlying the Western Cordillera and most of the Puna plateau, indicative of weak rheology and mostly asthenospheric mantle. In contrast, forearc and eastern foreland are characterized by high Q_p values, corresponding to cold temperatures in accordance with thermal models. In the backarc, between 23°S and 24°S, a high velocity, high Q_p structure beneath the Eastern Cordillera and eastern Puna is interpreted as detaching continental lithosphere that has been thickened in the orogenic process. South of this structure, the mantle is characterized by low velocities, high ν_p/ν_s ratios, and low Q_p values. Here it is believed that lithosphere originally underlying Andean crust has already been removed. This is supported by new estimates of crustal thickness and volcanic activity.     

Gravity study of the crustal structures of Somalia along International Lithosphere Program geotransects

Gravity data have been used to examine the crystalline basement morphology along five geotransects in Somalia defined by the Global Geotransect Project (Monger 1989). The gravity data were digitized from the 1:1 000 000 Gravity Anomaly Map of Somalia produced by the African Gravity Project. After the removal of the non-crustal wavelength anomalies from the observed gravity field, the remaining gravity anomalies were interpreted in terms of 2.5D crustal models. Available geophysical and well data, and other geological information, were used as constraints for the construction of the crustal sections. Mean densities varying from 3.30 to 3.15 g cm⁻³ were used for dense bodies observed on the lower continental crust of the southern Somali basins. A density of 3.00 g cm⁻³ was given to the oceanic crust offshore. The density of the crystalline basement and the overlying sediments were, respectively, assumed to be 2.85 g cm⁻³ and 2.46 g cm⁻³. Coherent and incoherent marine sediments were given densities varying from 1.70 g cm⁻³ to 2.30 g cm⁻³. The results of the 2.5D gravity modelling indicate that the basement beneath the southern Somali basins is partially or totally transformed to denser material and that, just a few hundred kilometres offshore from Somalia, the basement is of an oceanic nature.     

Heat flow and lithospheric thermal regime in the Northeast German Basin

New values of surface heat flow are reported for 13 deep borehole locations in the Northeast German Basin (NEGB) ranging from 68 to 91 mW m^− 2 with a mean of 77 ± 3 mW m^− 2. The values are derived from continuous temperature logs, measured thermal conductivity, and log-derived radiogenic heat production. The heat-flow values are supposed free of effects from surface palaeoclimatic temperature variations, from regional as well as local fluid flow and from thermal refraction in the vicinity of salt structures and thus represent unperturbed crustal heat flow. Two-D numerical lithospheric thermal models are developed for a 500 km section along the DEKORP-BASIN 9601 deep seismic line across the basin with a north-eastward extension across the Tornquist Zone. A detailed conceptual model of crustal structure and composition, thermal conductivity, and heat production distribution is developed. Different boundary conditions for the thickness of thermal lithosphere were used to fit surface heat flow. The best fit is achieved with a thickness of thermal lithosphere of about 75 km beneath the NEGB. This estimate is corroborated by seismological studies and somewhat less than typical for stabilized Phanerozoic lithosphere. Modelled Moho temperatures in the basin are about 800 °C; heat flow from the mantle is about 35 to 40 mW m^− 2. In the southernmost part of the section, beneath the Harz Mountains, higher Moho temperatures up to 900 to 1000 °C are shown. While the relatively high level of surface heat flow in the NEGB obviously is of longer wave length and related to lithosphere thickness, changes in crustal structure and composition are responsible for short-wave-length anomalies.     

Heat flow, heat production and fission track data from the Hercynian basement around the Provençal Basin (Western Mediterranean)

In the complex structural framework of the Western Mediterranean. Hercynian areas are expected to be thermally preserved from the recent tectonic evolution. The thermal regime of these areas is studied using heat flow, heat production and fission track data. The surface heat flow is significantly higher in Corsica (76 ± 10 mW m⁻²) than in the Maures and Estérel (58 ± 2 mW m⁻²). Neither heat production nor erosion subsequent to the Alpine orogeny in Corsica can explain such a difference. It is suggested that a deep thermal source related to the asymmetric evolution of the Provençal basin could explain the higher heat flow in Corsica. A model of thermal structure based on the present day thermal regime of the Maures and Estérei is proposed for the stable Hercynian crust in this area. The mantle heat flow is 20–25 mW m⁻² and the temperature at Moho level is 375–500°C, depending on the thermal parameter distribution with depth.     

Geochemistry and occurrence of inorganic gas accumulations in Chinese sedimentary basins

Inorganic gases are commonly seen in eastern China and occasionally in southern China from the shallow water columns above hot and cold springs. The gases contain 68% to nearly 100% CO₂, with δ¹³C_CO2 and δ¹³C₁ values in the range of −1.18‰ to −6.00‰ and −19.48‰ to −24.94‰, respectively. All of the 34 large inorganic CO₂ and one inorganic methane accumulations discovered in China are distributed in eastern parts of the country, from both onshore and continental shelf basins. No commercial inorganic gas accumulation has been found in central and western China. This is a review of the occurrence and geochemical characteristics of inorganic gas accumulations in Chinese sedimentary basins. A detailed study of gas samples collected from four representative inorganic CO₂ pools and one possible inorganic methane pool indicates that inorganic alkane gases typically show δ¹³C₁ values greater than −10‰ versus PDB (mostly −30‰), with a positive stable carbon isotope sequence of δ¹³C₁ < δ ¹³C₂ < δ¹³C₃ < δ ¹³C₄. In contrast, the δ¹³C₁ values of biogenic alkane gases are lighter than −30‰, with a negative isotope sequence (i.e. δ¹³C₁ > δ¹³C₂ > δ ¹³C₃ > δ¹³C₄). Inorganic gases also tend to show less negative δ¹³C_CO2 values (−10‰) than biogenic gases (<−10‰).