Seawater–freshwater mixing and resulting calcite dissolution: an example from a coastal alluvial aquifer in eastern South Korea

Abstract

In order to evaluate groundwater quality and geochemical reactions arising from mixing between seawater and dilute groundwater, we performed a hydrochemical investigation of alluvial groundwater in a limestone-rich coastal area of eastern South Korea. Two sites were chosen for comparison: an upstream site and a downstream site. Data of major ion chemistry and ratios of oxygen–hydrogen isotopes (δ¹⁸O, δD) revealed different major sources of groundwater salinity: recharge by sea-spray-affected precipitation in the upstream site, and seawater intrusion and diffusion zone fluctuation in the downstream site. The results of geochemical modelling showed that Ca²⁺ enrichment in the downstream area is caused by calcite dissolution enhanced by the ionic strength increase, as a result of seawater–groundwater mixing under open system conditions with a constant P_CO2 value (about 10^?1.5 atm). The results show that, for coastal alluvial groundwater residing on limestone, significant hydrochemical change (especially increased hardness) due to calcite dissolution enhanced by seawater mixing should be taken into account for better groundwater management. This process can be effectively evaluated using geochemical modelling.

Editor D. Koutsoyiannis; Associate editor Y. Guttman

Citation Chae, G.-T., Yun, S.-T., Yun, S.-M., Kim, K.-H., and So, C.-S., 2012. Seawater–freshwater mixing and resulting calcite dissolution: an example from a coastal alluvial aquifer in eastern South Korea. Hydrological Sciences Journal, 57 (8),1–12.     

Monsoonal precipitation variation in the East Asia since A.D. 1840 ——Tree-ring evidences from China and Korea

The main characteristic of the East Asian climate is the monsoon system. Plenty of studies have demonstrated that the Asian monsoon system plays a crucial role in the global climate sys- tem [1-4]. The Asian summer monsoon can be divided into two parts, t…     

Assessment of future water resources and water scarcity considering the factors of climate change and social–environmental change in Han River basin,Korea

Water resources are influenced by various factors such as weather, topography, geology, and environment. Therefore, there are many difficulties in evaluating and analyzing water resources for the future under climate change. In this paper, we consider climate, land cover and water demand as the most critical factors affecting change in future water resources. We subsequently introduce the procedures and methods employed to quantitatively evaluate the influence of each factor on the change in future water resources. In order to consider the change in land cover, we apply the Multi-Regression approach from the cellular automata-Markov Chain technique using two independent variables, temperature and rainfall. In order to estimate the variation of the future runoff due to climate change, the data of the SRES A2 climate change scenario were entered in the SLURP model to simulate a total of 70 years, 2021–2090, of future runoff in the Han River basin in Korea. However, since a significant amount of uncertainties are involved in predicting the future runoff due to climate change, 50 sets of daily precipitation data from the climate change scenario were generated and used for the SLURP model to forecast 50 sets of future daily runoff. This process was used to minimize the uncertainty that may occur when the prediction process is performed. For future water balance analysis, the future water demand was divided into low demand, medium demand and high demand categories. The three water demand scenarios and the 50 daily runoff scenarios were combined to form 150 sets of input data. The monthly water balance within the Han River basin was then calculated using this data and the Korean version of Water Evaluation and Planning System model. As a result, the future volume of water scarcity of the Han River basin was predicted to increase in the long term. It is mostly due to the monthly shift in the runoff characteristic, rather than the change in runoff volume resulting from climate change.     

Intensity distribution and effect of the Nov. 9, 1996 earthquake of Ms=6.1 in offshore outside the Yangtze River Mouth on the South Korea

On Nov. 9, 1996 at 21h56min (Beijing Time), an earthquake of MS=6.1 occurred in offshore outside the Yangtze River Mouth (31o43￠N, 123o04￠E). The shock affected Shanghai City and both Jiangsu and Zhejiang Provinces in China mainly. The shock was felt more strongly in the Yangtze River Mouth and Hangzhou Bay area than in the rest of them, particularly in high buildings of Shanghai City. In addition, the earthquake was felt in South Korea and also stronger in apartments or high buildings. LIU, JIN (1998) and LIU, et al (1999) described effect of the shock on the eastern China. The paper describes the effect of the earthquake on South Korea and the whole intensity distribution in South Korea and eastern China.     

Intensity distribution and effect of the Nov. 9, 1996 earthquake of M_S=6.1 in offshore outside the Yangtze River Mouth on the South Korea

On Nov. 9, 1996 at 21h56min (Beijing Time), an earthquake of MS=6.1 occurred in offshore outside the Yangtze River Mouth (31?3N, 123?4E). The shock affected Shanghai City and both Jiangsu and Zhejiang Provinces in China mainly. The shock was felt more strongly in the Yangtze River Mouth and Hangzhou Bay area than in the rest of them, particularly in high buildings of Shanghai City. In addition, the earthquake was felt in South Korea and also stronger in apartments or high buildings. …     

Comparison of the Penman‐Monteith method and regional calibration of the Hargreaves equation for actual evapotranspiration using SWAT-simulated results in the Seolma-cheon basin,South Korea

ABSTRACT

The Hargreaves method provides reference evapotranspiration (ET_o) estimates when only air temperature data are available, although it requires previous local calibration for an acceptable performance. This method was evaluated using the data from 71 meteorological stations in the Seolma-cheon basin (8.48 km²), South Korea, comparing daily estimates against those from the Penman‐Monteith (PM) method, which was used as the standard. To estimate reference ET_o more exactly, considering the climatological characteristics in South Korea, parameter regionalization of the Hargreaves equation is carried out. First, the modified Hargreaves equation is presented after an analysis of the relationship between solar radiation and temperature. Second, parameter (K_ET) optimization of the regional calibration of the Hargreaves equation (RCH) is performed using the PM method and the modified equation at 71 meteorological stations. Next, an application was carried out to evaluate the evapotranspiration methods (PM, original Hargreaves and RCH) in the SWAT (Soil and Water Assessment Tool) model by comparing these with the measured actual evapotranspiration (AET) in the basin. The SWAT model was calibrated using 3 years (2007–2009) of daily streamflow at the watershed outlet and 3 years (2007–2009) of daily AET measured at a mixed forest. The model was validated with 3 years (2010‐2012) of streamflow and AET. RCH will contribute to a better understanding of evapotranspiration of an ungauged watershed in areas where meteorological information is scarce.

EDITOR D. Koutsoyiannis ASSOCIATE EDITOR Not assigned