Arsenic, antimony and other toxic elements in the drinking water of Eastern Thessaly in Greece and its possible effects on human health

Twenty-six groundwater samples were collected from the Eastern Thessaly region and analysed by ICP-ES for these elements: Al, As, P, Pb, Zn, Mn, Fe, Cr, Sb, Cu, Na, Br, Cl, Si, Mg, Ag, Be, Bi, Dy, Er, Eu, Au, Ge, Ho, In, Ir, Os, Pt, Re, Rh, Ru, Lu, Hf, Hg, Tm, Zr and Nb. The objectives of the study were to assess the level of water contamination with respect to the EC and the USEPA health-based drinking water criteria. The geology of the studied area includes schists, amphibolites, marbles of Palaeozoic age, ophiolites, limestones of Triassic and Cretaceous age, Neogene and Quaternary deposits. The element ranges for groundwater samples are: Al 7–56 μg l⁻¹, As 1–125 μg l⁻¹, Br 6–60 μg l⁻¹, Cl 500–25,000 μg l⁻¹, Cr 1–6 μg l⁻¹, Cu 1–15 μg l⁻¹, Fe 10–352 μg l⁻¹, Mg 2,940–40,100 μg l⁻¹, Mn 0–8 μg l⁻¹, Na 3,650–13,740 μg l⁻¹, P 20–48 μg l⁻¹, Pb 0–7 μg l⁻¹, Sb 0–21 μg l⁻¹, Si 3,310–13,240 μg l⁻¹ and Zn 7–994 μg l⁻¹. The results of groundwater analyses from the region of Eastern Thessaly showed elevated concentrations of As and Sb. Factor analysis explained 77.8% of the total variance of the data through five factors. Concentration of Br, Cl, Mg, Na and Si is directly related to the presence of saltwater in the aquifer, so grouping of these variables in factor 1 probably reflects the seawater intrusion. Al, As and Sb are known to form complexes in the environment, so grouping of these elements in factor 2 indicates their similar geochemical behaviour in the environment. The high negative loading of Mn in factor 2 indicates the presence of manganese oxides–hydroxides in the study area. Pb and Zn are associated together in sulphide mineralisation; so grouping of these elements in factor 3 reflects the sulphide mineralization paragenesis in the Melivoia area. P and Cu are associated together in phosphate fertilizers; so grouping of these variables in factor 4 could be related to agricultural practices. Cr, Fe, Mn and Mg are associated together in iron and manganese oxides–hydroxides and the weathering products of the olivine of the ultrabasic rocks; so grouping of these elements in factor 5 reflects the lithology of the area. There is a natural contamination of groundwaters with elevated concentrations of As and Sb due to the presence of the arsenopyrite and stibnite mineralisation in the Melivoia, Sotiritsa and Ano Polydendri areas. Contamination over the health-based drinking water guidelines given by EC and EPA has been investigated from nine sampling sites out of 26 of Eastern Thessaly region.     

Geochemistry of sulphate-bearing water of Akra Kaur Dam,Gwadar, Balochistan,Pakistan and its assessment for drinking and irrigation purposes

This paper is an attempt to study the geochemistry of Akra Kaur Dam (AKD) water, north of Gwadar city, southern Balochistan. Representative water samples were collected from AKD reservoir to assess the suitability of water for drinking and agriculture purposes. The major ionic composition is suggestive for freshwater. The average ionic composition demonstrate SO₄ > Ca > Na > Cl > HCO₃ > Mg > K. The plots on Piper diagram reflected Ca–Mg–SO₄ type of water facies. High Ca/SO₄ and Ca/Mg ratios revealed that the water has influence of gypsum dissolution. The negative ratio of chloro-alkaline indices indicated reverse exchange between Ca and Mg in water occurred with Na and K in rocks. The pH, electrical conductivity, total dissolved salts, Ca, Mg, Na, K, HCO₃, Cl and SO₄ concentrations in the dam water were below the permissible limit, however, Na and SO₄ were above the desirable limit, set by the World Health Organization. Important parameters such as residue sodium carbonate, sodium percent, sodium adsorption ratio, permeability index, magnesium content and Kelley’s ratio were calculated to evaluate the suitability of water for irrigation purpose. The result were compared with standard permissible limits and found satisfactory. The health and agriculture hazards of sulphate-bearing water were also discussed.     

Fluoride hydrogeochemistry and its occurrence in drinking water in Morappur region of Dharmapuri District,South India

Groundwater is the major source of freshwater in region devoid of surface water resources. Once such region is the Morappur area, Dharmapuri district of Tamilnadu, wherein groundwater is major source of water for all purposes. The area is reported to be severely affected by fluorosis due to excessive Fluoride in groundwater. The area comprises of rocks of Archaean age, namely Charnockite, Epidote Hornblende Gneiss and ultramafic rocks. The area has experienced numerous tectonic disturbances in which numbers of vertical joints have developed and are filled with quartz/feldspathic veins, and highly mineralised. Two aquifer systems have been identified in the area, namely the weathered aquifer and fractured aquifer. In order to understand the factors controlling high Fluoride concentration in groundwater, 149 groundwater samples were collected during pre and post-monsoon period. Analytical results indicate that 35% groundwater samples show Fluoride concentration more than 1.5 ppm (permissible limit). Results indicate that both the aquifer units are affected by high Fluoride and deeper aquifers are more affected. Biotite and Hornblende minerals present in the area and interact with groundwater to release Calcium, Magnesium along with Fluoride. Further chloro-alkaline indices indicate that calcium ions are replaced by sodium due to reverse ion exchange, leading to high concentration of Fluoride along with high concentration of Sodium. Government has taken measures to provide Fluoride-free drinking water from distant surface water sources. However, it is important to follow certain water management methods to improve the groundwater quality.     

Seismic Hazard Assessment of District Mansehra,Khyber Pakhtoonkhawa,Pakistan

The site of Mansehra is located seismically in an active regime, known as the Crystalline Nappe Zone and Hazara-Kashmir Syntaxis in NW Himalayas, Pakistan. Seismic Hazard Assessment （SHA） for the site has been carried out by considering the earthquake source zones, selection of appropriate attenuation equations, near fault effects and maximum potential magnitude estimation. The Mansehra Thrust, Oghi Fault, Banna Thrust, Balakot Shear Zone, Main Boundary Thrust, Panjal Thrust, Jhelum Fault and Muzaffarabad Fault and, further to the south, the Sanghargali, Nathiagali, and Thandiani Thrusts are the most critical tectonic features within the 50 km radius of Mansehra. Using the available instrumental seismological data from 1904 to 2007, SHA has been carried out. Other reactivated critical tectonic features in the area have been investigated. Among them the Balakot-Bagh fault, with the fault length of 120 km from Balakot to Poonch, has been considered as the most critical tectonic feature on the basis of geological/structural/seismological data. The potential earthquake of maximum magnitude 7.8 has been assigned to the Balakot-Bagh fault using four regression relations. The peak ground acceleration value of 0.25 g （10% probability of exceedance for 50 years） and 0.5 g has been calculated with the help of the attenuation equation using probabilistic and deterministic approaches.     

Groundwater quality assessment for drinking purpose in Raipur city,Chhattisgarh using water quality index and geographic information system

An effort has been made to comprehend the groundwater quality of Raipur city for drinking purpose utilizing Water Quality Index (WQI) and Geographic Information System (GIS) techniques. In this study thirty four groundwater samples were collected during May, 2015. Standard methods has been adopted in groundwater sampling which are prescribed by the American Public Health Association (APHA, 1995). Eight water quality parameters have been considered to ascertained water quality index viz. pH, chloride, fluoride, calcium, magnesium, alkalinity, hardness and nitrate. The Bureau of Indian Standard (BIS, 2009) has been considered to assess the suitability of groundwater for drinking purposes and for the calculation of WQI. This study reveals that 76% area is falling under excellent, very good and good category and 24% area is falling under poor, very poor and unfit category as per the WQI classification. The predicted accuracy of the obtained result is around 97.05% reflecting capability of adopted techniques. Anthropogenic activities are influencing the groundwater quality of the study area. The present study is helpful in proper planning and management of available water resource for drinking purpose.     

Impacts of climate change on stream flow and water quality in a drinking water source area,Northern China

Understanding the impacts of climate change on water quality and stream flow is important for management of water resources and environment. Miyun Reservoir is the only surface drinking water source in Beijing, which is currently experiencing a serious water shortage. Therefore, it is vital to identify the impacts of climate change on water quality and quantity of the Miyun Reservoir watershed. Based on long-time-series data of meteorological observation, future climate change scenarios for this study area were predicted using global climate models (GCMs), the statistical downscaling model (SDSM), and the National Climate Centre/Gothenburg University—Weather Generator (NWG). Future trends of nonpoint source pollution load were estimated and the response of nonpoint pollution to climate change was determined using the Soil and Water Assessment Tool (SWAT) model. Results showed that the simulation results of SWAT model were reasonable in this study area. The comparative analysis of precipitation and air temperature simulated using the SDSM and NWG separately showed that both tools have similar results, but the former had a larger variability of simulation results than the latter. With respect to simulation variance, the NWG has certain advantages in the numerical simulation of precipitation, but the SDSM is superior in simulating precipitation and air temperature changes. The changes in future precipitation and air temperature under different climate scenarios occur basically in the same way, that is, an overall increase is estimated. Particularly, future precipitation will increase significantly as predicted. Due to the influence of climate change, discharge, total nitrogen (TN) and total phosphorus (TP) loads from the study area will increase over the next 30 years by model evaluation. Compared to average value of 1961?~?1990, discharge will experience the highest increase (15%), whereas TN and TP loads will experience a smaller increase with a greater range of annual fluctuations of 2021 ~ 2050.     

Arsenic in drinking and lung cancer mortality in Taiwan

The association between exposure to arsenic in drinking water and lung cancer has been observed in some epidemiology studies, but dose–response data are limited. To assess the dose–response relationship and identify hot spots, we analyzed the national death registry data of Taiwan from 1971 to 2000. We adopted data on 311 townships gathered by a nationwide survey of drinking water and divided arsenic levels into three groups: below 0.05 mg/L, 0.05–0.35 mg/L, and above 0.35 mg/L. Using the direct standardization method to adjust for the effects of age, we calculated the standardized mortality rates of lung cancer in both genders and evaluated their associations with arsenic levels. We also used the geographical information system to identify the hot spots. During the 30-year study period, we identified 64,954 male and 27,039 female lung cancer deaths in the study townships. We found significant increases in lung cancer mortality associated with arsenic levels above 0.35 mg/L in both genders, but the increases associated with levels between 0.05 and 0.35 mg/L were statistically significant in men only. Using both 0.05 and 0.35 mg/L as the cut-offs, we found most of the hot spots were in the southwestern coast and northeastern areas, but the southwestern coast area had some hot spots where the percentages of high risk population were higher than any hot spots in the northeastern area.     

Sediment–water interaction, acidity and other water quality parameters in a subtropical setting, Pimpama River, southeast Queensland

 The geological setting and landuse activities of the Pimpama River catchment are typical for many drainage systems in southeast Queensland. The river originates in coastal ranges of Late Paleozoic age, crosses a floodplain developed during the Late Pleistocene-Holocene sea-level fluctuations and flows into the southern part of the Moreton Bay. The formation of sedimentary pyrite associated with the mid-Holocene transgression is an important feature of this coastal setting. The oxidation and hydrolysis of pyrite and the consequent production of sulfuric acid are controlled by the amount and seasonality of rainfall and influenced locally by landuse activities. The acid production and the leaching of dissolved metals from river alluvium and estuarine sediments impact substantially on land and aquatic habitats. The water quality of the Pimpama River and its tributaries reflects the lithology of the bedrock and can vary largely depending on season, tidal regimes, sediment lithology, local topography and agricultural activities. Monitoring of river water for several seasons revealed four types of events, each with a different response in terms of water quality: (a) occasional showers during the dry season cause low pH and high amounts of dissolved metals in the water, (b) the first heavy rain of the wet season can produce very toxic conditions (low pH and high concentrations of metals) that can result in a fish kill, (c) towards the end of the wet season, prolonged flushing of pyrite oxidation products leads to short-term recovery of the aquatic system (neutral pH and lower amounts of dissolved metals in the water) and (d) a flood event can produce low pH, salinity and high concentrations of metals, which can represent lethal conditions for aquatic life. Assessment of saturation indexes for representative weathering and oxidation products such as clays, goethite, gibbsite and jarosite shows that these mineral phases can precipitate only when the water reaches neutral pH. Received: 21 September 1998 · Accepted: 1 December 1998     

Assessment of groundwater quality for drinking and irrigation purposes: a case study of Peddavanka watershed, Anantapur District, Andhra Pradesh, India

In India, the quantity and quality of water available for irrigation is variable from place to place. Assessment of water quality has been carried out to determine the sources of dissolved ions in groundwater. Quality of groundwater in a 398 km² Peddavanka watershed of a semi-arid region of south India is evaluated for its suitability for drinking and irrigation purposes. The middle Proterozoic Cuddapah Supergroup and Kurnool Group of rocks underlie most of the watershed. The main lithologic units consist chiefly of quartzite, limestone, and shale. Seventy-six water samples were collected from open-wells and bore-holes. Water samples were collected representative of the post-monsoon (winter) and pre-monsoon (summer). The quality assessment is made through the estimation of Ca²⁺, Mg²⁺, Na⁺, K⁺, Cl⁻, SO₄²⁻, CO₃²⁻, HCO₃⁻, total hardness as CaCO₃, TDS, EC, and pH. Based on these analyses, parameters like sodium adsorption ratio, % sodium, residual sodium carbonate, non-carbonate hardness, potential salinity, Kelley’s ratio, magnesium ratio, index of base exchange and permeability index were calculated. According to Gibbs‘ ratio samples in both seasons fall in the rock dominance field. The overall quality of waters in the study area in post-monsoon season is high for all constituents ruling out pollution from extraneous sources.     

Hydro-geochemical evaluation of groundwater with studies on water quality index and suitability for drinking in Sagardari,Jashore

Sagardari union is facing groundwater crisis because of contaminations from agriculture and urban sewage, which bring a considerable change in water quality. In view of this, hydro-chemical analyses were undertaken on 35 groundwater samples and the following hydro-geochemical parameters, pH, total dissolved solids (TDS), total hardness (TH), electrical conductivity (EC), cations and anions, were analyzed. From the analytical results, it is found that pH value was lower than WHO drinking water standard and the middle-downstream portions of the investigation region show higher EC. The piper plot indicates that the groundwater in Sagardari falls in the categories of NaClHCO₃ hydro-chemical facies. Higher TH in groundwater was detected, but still in an acceptable range. In addition, salinity and arsenic ratio are higher and moderately higher, respectively. The spatial distribution of Groundwater Quality Index (GWQI) was determined by geo-statistical modelling of Sagardari union. The study provides information and supports the administration which to make better groundwater utilization and quality control in the Sagardari union.     

Land subsidence and declining water resources in Quetta Valley, Pakistan

Extensive groundwater withdrawals in urban areas may cause water shortages, land subsidence, and water quality problems. The Quetta Valley is the largest population center in Balochistan province in western Pakistan. This area is arid and groundwater is the main water source for domestic and agricultural use. This work presents global positioning system (GPS) data and assessment of spatial and temporal variations in water levels. GPS data from two stations from mid-2006 to the beginning of 2009 show subsidence rate of 10 cm\year. Nine satellite images from 1975 to 2009 were classified and processed to quantify land cover and land use changes, which highlight an increase in agricultural areas in the central region of the Quetta Valley, as well as reduced vegetation on mountains. These data correspond to gradual temporal changes in water volumes in streams and lakes. Average temperatures have also increased and mean precipitation has decreased during this period. However, the greatest change in this area has been in population growth, which rose from 260,000 in 1975 to 1.2 million in 2010, mainly due to migration of refugees from war-torn neighboring Afghanistan. The Quetta Valley provides a good example for studying the impact of urbanization on water resources.     

Arsenic mobility and impact on recovered water quality during aquifer storage and recovery using reclaimed water in a carbonate aquifer

Arsenic release from aquifers can be a major issue for aquifer storage and recovery (ASR) schemes and understanding the processes that release and attenuate As during ASR is the first step towards managing this issue. This study utilised the first and fourth cycles of a full scale field trial to examine the fate of As within the injectant plume during all stages of the ASR cycle, and the resultant water quality. The average recovered As concentration was greater than the source concentration; by 0.19 μmol/L (14 μg As/L) in cycle 1 and by 0.34 μmol/L (25 μg As/L) in cycle 4, indicating that As was being released from the aquifer sediments during ASR and the extent of As mobilisation did not decline with subsequent cycles. In the injection phase, As mobilisation due to oxidation of reduced minerals was limited to an oxic zone in close proximity to the ASR well, while desorption from Fe oxyhydroxide or oxide surfaces by injected P occurred further in the near well zone (0–4 m from the ASR well). With further aquifer passage during injection and greater availability of sorption sites there was evidence of attenuation via adsorption to Fe oxyhydroxides which reduced concentrations on the outer fringes of the injectant plume. During the period of aquifer storage, microbial activity resulting from the injection of organic matter resulted in increased As mobility due to reductive Fe oxyhydroxide dissolution and the subsequent loss of sorption sites and partial reduction of As(V) to the more mobile As(III). A reduced zone directly around the ASR well produced the greatest As concentration and illustrated the importance of Fe oxyhydroxides for controlling As concentrations. Given the small spatial extent of this zone, this process had little effect on the overall recovered water quality.     

Irrigation and farm water management in Pakistan

Present irrigation practices and water management techniques in Pakistan are the result of a long process. Through a cultural-historical approach, generic relationships of some present patterns are traced to their origin. The origin of irrigation was probably in small alluvial valleys of Southwest Asia, which is also considered the hearth of seed agriculture. From a simple beginning the irrigation and water management systems have become extremely complicated to support Pakistan's largest irrigation network in the world.Part of the research for this paper was done at the Department of Geography, South Asia Institute, University of Heidelberg, Heidelberg, Germany during the summer of 1992.     

饮用天然矿泉水与饮用纯净水差异探讨

本文从基本特征、水处理工艺、产品对人体的作用３个方面对饮用天然矿泉水和饮用纯净水的差异进行了探讨,指出矿泉水的保健作用已得到医学研究证实,是可以依赖的饮料。但几乎不含任务矿物质的纯净水,在补充人体水分的同时,也迅速溶解了体内的微量元素,因而对人体的作用的待于进一步研究。     

Arsenic in soil, vegetation and water of a contaminated region

Arsenic concentrations of surface waters, soils and plants were surveyed in three contaminated villages of Bijar County. Total arsenic in water samples (4.5 to 280 μg/L) was correlated with electrical conductivity, total dissolved solid, total hardness, alkalinity, chloride, sulphate, bicarbonate, calcium and sodium (p<0.001). Total arsenic in the soils ranged from 105.4 to 1500 mg/kg. Some of the soil factors play an important role in soil arsenic content and its bioavailability for organisms. In general, the arsenic concentrations in plants were low, especially in the most common wild species. Among 13 plant species, the highest mean arsenic concentration was found in leaves of Mentha Longifolia (79.4 mg/kg). Arsenic levels in soils and plants were positively correlated, while the ability of the plants to accumulate the element, expressed by their biological accumulation coefficients and arsenic transfer factors, was independent of the soil arsenic concentration. Relationships between the arsenic concentrations in plants, soils and surface water and the environmental aspects of these relationships have been discussed in comparison with literature data. The accumulation of arsenic in environmental samples (soil, sediment, water, plant, etc.) poses a potential risk to human health due to the transfer of this element in aquatic media, their uptake by plants and subsequent introduction into the food chain.     

贵阳市乌当区地热田成因及水质特征分析

贵州省地热资源丰富,贵阳市乌当区地热田属于该省隐伏型地热资源之一。本文结合钻探资料和区域地质资料,分析了地热田的埋藏条件、补径排条件、地温场等特征。该地热田主要热储层为中寒武统—奥陶系灰岩及白云岩,热水径流特征和地温场特征受乌当断裂、乌当背斜等一系列构造控制。测温曲线显示,保利2号钻孔地温梯度约为2.59℃/100 m,3号钻孔约为2.25℃/100 m。本区无附加型热源,深循环为该区热水的主要形成原因。地下热水的化学类型为SO4-Ca.Mg型,氟和硅的含量较高,具有一定的医疗价值。为实现地热资源可持续开发,今后应在本地区开展地热回灌技术的相关研究。     

铬污染对土壤细菌群落结构及其构建机制的影响

重金属铬污染场迁移过程受多种不确定因素影响,其迁移特性和监测过程很难通过实验进行研究。依据地下水流动基本规律和污染物迁移机理,采用COMSOL软件仿真分析静储量铬污染源的迁移特性及其变化规律,通过开展静态土槽物理模型实验,验证数值正演模拟的可靠性和准确性;以迁移模型为监测基础模型,采用中梯剖面和对称四极测深装置,对铬污染场迁移过程进行双频激电法监测数值正演模拟,分析平整、起伏地形和测点方位布置对监测效果的影响。结果表明：在铬污染物迁移过程中,高渗透系数的透水层对重污染区域表现出强烈的吸附效应,同时会在短时间内加剧污染区域的横向扩散;在视幅频率峰值和视电阻率谷值的异常对应关系上剖面探测要优于测深探测;对称四极测深时,在污染场的投影边缘中央设置测点可更有效地提高测量精度;在进行剖面和测深探测时,山谷会造成激电曲线出现“多峰”现象;在凸起山峰两侧山陲设置供电电极,通过视幅频率和视电阻率曲线可综合确定重度污染区域的具体位置。研究成果丰富了双频激电法对重金属土壤污染场监测的理论,为铬污染场实时监测提供理论依据和技术指导,对推动生态环境保护具有积极意义。

     

Arsenic in streams,stream sediments,and ground water,fairbanks area,alaska

Arsenic concentrations of less than 5 ppb to as large as 1,260 ppb in stream waters and from 5 ppm to 4,000 ppm in stream sediments were found in the Pedro Dome-Cleary Summit area, Alaska. Waters from three of 20 wells sampled had arsenic concentrations exceeding the U.S. Public Health Service recommended limit of 50 ppb. The high arsenic levels are a consequence of arsenic enrichment in the rocks of the area. Placer and lode-gold mining may increase the arsenic content of the waters by exposing arsenic-containing rocks to surface waters and by increasing the load of arsenic-rich sediments in the streams. Finding these disturbingly large concentrations of arsenic in the waters of the Fairbanks area was the major result of this work, inasmuch as a subsequent study (to be published) revealed arsenic concentrations as large as 10 ppm in domestic wells and prompted an extensive study by Federal and State agencies of the health hazard posed by these arsenic-rich waters.